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AR030154A1 - Derivado de ftalamida, derivado de amina heterociclico util como intermediario para la produccion del mismo, insecticida agrohorticola y metodo para utilizar dicho insecticida - Google Patents

Derivado de ftalamida, derivado de amina heterociclico util como intermediario para la produccion del mismo, insecticida agrohorticola y metodo para utilizar dicho insecticida

Info

Publication number
AR030154A1
AR030154A1 ARP000103364A ARP000103364A AR030154A1 AR 030154 A1 AR030154 A1 AR 030154A1 AR P000103364 A ARP000103364 A AR P000103364A AR P000103364 A ARP000103364 A AR P000103364A AR 030154 A1 AR030154 A1 AR 030154A1
Authority
AR
Argentina
Prior art keywords
haloalkyl
same
alkyl
halogen
group
Prior art date
Application number
ARP000103364A
Other languages
English (en)
Inventor
K Sakata
Masayuki Morimoto
A Seo
K Machiya
K Endoh
T Furuya
H Nakao
M Gotoh
E Kohno
M Tohnishi
Original Assignee
Nihon Nohyaku Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nihon Nohyaku Co Ltd filed Critical Nihon Nohyaku Co Ltd
Publication of AR030154A1 publication Critical patent/AR030154A1/es

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/72—Nitrogen atoms
    • C07D213/73—Unsubstituted amino or imino radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/10—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with sulfur as the ring hetero atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
    • C—CHEMISTRY; METALLURGY
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    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
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    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/34—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/72—Nitrogen atoms
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Abstract

Un derivado ftalamida que está representado por la formula general (1) en donde: R1, R2 y R3 que pueden ser iguales o diferentes, representan hidrogeno, cicloalquilo C3-6, halocicloalquilo C3-6 o -A1-(G)r {en esta formula, A1 representa alquileno C1-8, alquenileno C3-6 o alquinileno C3-6; G, que puede ser igual o diferente, representa hidrogeno, halogeno, ciano, nitro, haloalquilo C1-6, cicloalquilo C3-6, halocicloalquilo C3-6, alcoxicarbonilo C1-6, di(C1-6)alcoxifosforilo en donde los grupos C1-6 pueden ser iguales o diferentes, di(C1-6)alcoxitiofosforilo en donde los grupos C1-6 pueden ser iguales o diferentes, difenilfosfino, difenilfosfono, fenilo, fenilo sustituido que posee por lo menos uno, iguales o diferentes, sustituyentes seleccionados del grupo que consiste de halogeno, alquilo C1-6, haloalquilo C1-6, alcoxilo C1-6, haloalcoxilo C1-6, alquiltio C1-6, haloalquiltio C1-6, alquilsulfinilo C1-6, haloalquilsulfinilo C1-6, haloalquilsulfonilo C1-6 y alquilsulfonilo C1-6, grupo hetericíclico (como se usa en la presente, el término "grupo heterocíclico" significa piridilo, piridin-N-oxido, pirimidinilo, furilo, tetrahidrofurilo, tienilo, tetrahidrotienilo, tetrahidropiranilo, oxazolilo, isoxazolilo, oxadiazolilo, tiazolilo, isotiazolilo, tiadiazolilo, imidazolilo, triazolilo o pirazolilo), grupo heterocíclico sustituido (el término "heterocíclico sustituido" es igual al definido anteriormente) teniendo por lo menos uno, iguales o diferentes, sustituyentes seleccionados del grupo que consiste de halogeno, alquilo C1-6, haloalquilo C1-6, alcoxilo C1-6, haloalcoxilo C1-6, alquiltio C1-6, haloalquiltio C1-6, alquilsulfinilo C1-6, haloalquilsulfinilo C1-6, alquilsulfonilo C1-6, y haloalquilsulfonilo C1-6, o -Z3-R4 [donde Z3 representa -O-, -S-, -SO-, -SO2-, -N(R5)- (donde R5 representa hidrogeno, alquilcarbonilo C1-6, haloalquilcarbonilo C1-6, alcoxicarbonilo C1-6, fenilcarbonilo, fenilcarbonilo sustituido por lo menos teniendo uno, iguales o diferentes sustituyentes seleccionados del grupo que consiste de halogeno, alquilo C1-6, haloalquilo C1-6, alcoxilo C1-6, haloalcoxilo C1-6, alquiltio C1-6, haloalquiltio C1-6, alquilsulfinilo C1-6, haloalquilsulfinilo C1-6, alquilsulfonilo C1-6 y haloalquilsulfonilo C1-6, fenilalcoxicarbonilo C1-4, o fenilalcoxicarbonilo C1-4 sustituido que posee, en el anillo del mismo, por lo menos uno, iguales o diferentes sustituyentes seleccionados del grupo que consiste de halogeno en el anillo, alquilo C1-6, haloalquilo C1-6, alcoxilo C1-6, haloalcoxilo C1-6, alquiltio C1-6, haloalquiltio C1-6, alquilsulfinilo C1-6, haloalquilsulfinilo C1-6, alquilsulfonilo C1-6 y haloalquilsulfonilo C1-6), -C(=O)- o -C(=NOR6)- (donde R6 representa hidrogeno, alquilo C1-6, haloalquilo C1-6, alquenilo C3-6, haloalquenilo C3-6, alquinilo C3-6, cicloalquilo C3-6, fenilalquilo C1-4, o fenilalquilo C1-4 sustituido que posee, en el anillo del mismo, por lo menos uno, iguales o diferentes sustituyentes seleccionados del grupo que consiste de halogeno, alquilo C1-6, haloalquilo C1-6, alcoxilo C1-6, haloalcoxilo C1-6, alquiltio C1-6, haloalquiltio C1-6, alquilsulfinilo C1-6, haloalquilsulfinilo C1-6, alquilsulfonilo C1-6, o haloalquilsulfonilo C1-6); y R4 representa hidrogeno, alquilo C1-6, haloalquilo C1-6, alquenilo C3-6, haloalquenilo C3-6, alquinilo C3-6, haloalquinilo C3-6, cicloalquilo C3-6, halocicloalquilo C3-6, alcoxi C1-6-alquilo C1-6, alquiltio C1-6-alquilo C1-6, formilo, alquilcarbonilo C1-6, haloalquilcarbonilo C1-6, alcoxicarbonilo C1-6, monoalquilaminocarbonilo C1-6, di(C1-6)alquilaminocarbonilo en donde los grupos (C1-6) pueden ser iguales o diferentes, monoalquilaminotiocarbonilo C1-6, di(C1-6)alquilaminotiocarbonilo en donde los grupos (C1-6) pueden ser iguales o diferentes, dialcoxifosforilo C1-6 en donde los grupos (C1-6) pueden ser iguales o diferentes, di(C1-6)alcoxitiofosforilo en donde los grupos (C1-6) pueden ser iguales o diferentes, fenilo, fenilo sustituido que posee por lo menos uno, iguales o diferentes sustituyentes seleccionados del grupo que consiste de halogeno, alquilo C1-6, haloalquilo C1-6, alcoxilo C1-6, haloalcoxilo C1-6, alquiltio C1-6, haloalquiltio C1-6, alquilsulfinilo C1-6, haloalquilsulfinilo C1-6, alquilsulfonilo C1-6 y haloalquilsulfonilo C1-6, fenilalquilo C1-4, fenil(C1-4)alquilo sustituido que posee, en el anillo del mismo, por lo menos uno, iguales o diferentes sustituyentes seleccionados del grupo que consiste de halogeno, alquilo C1-6, haloalquilo C1-6, alcoxilo C1-6, haloalcoxilo C1-6, alquiltio C1-6, haloalquiltio C1-6, alquilsulfinilo C1-6, haloalquilsulfinilo C1-6, alquilsulfonilo C1-6 y haloalquilsulfonilo C1-6, grupo heterocíclico (el término grupo heterocíclico es igual al definido precedentemente), o grupo heterocíclico sustituido (el término grupo heterocíclico es igual al definido anteriormente) que posee por le menos uno, iguales o diferentes sustituyentes seleccionados del grupo que consiste de halogeno, alquilo C1-6, haloalquilo C1-6, alcoxilo C1-6, haloalcoxilo C1-6, alquiltio C1-6, haloalquiltio C1-6, alquilsulfinilo C1-6, haloalquilsulfinilo C1-6, alquilsulfonilo C1-6 y haloalquilsulfonilo C1-6]; r representa un entero de valor 1 a 4}; además, R1 y R2 se pueden enlazar entre sí para formar anillos de 4- a 7- miembros que pueden ser interceptados por 1 a 3, iguales o diferentes átomos de oxígeno, azufre o nitrogeno; X que pueden ser iguales o diferentes representan halogeno, ciano, nitro, cicloalquilo C3-6, halocicloalquilo C3-6, fenilo, fenilo sustituido que posee por lo menos uno, iguales o diferentes sustituyentes seleccionados del grupo que consiste de halogeno, alquilo C1-6, haloalquilo C1-6, alcoxilo C1-6, haloalcoxilo C1-6, alquiltio C1-6, haloalquiltio C1-6, alquilsulfinilo C1-6, haloalquilsulfinilo C1-6, alquilsulfonilo C1-6 o haloalquilsulfonilo C1-6, grupo heterocíclico (el término grupo heterocíclico es igual al definido anteriormente), grupo heterocíclico sustituido (es igual al definido precedentemente) que posee por lo menos uno, iguales o diferentes sustituyentes seleccionados del grupo que consiste de halogeno, alquilo C1-6, haloalquilo C1-6, alcoxilo C1-6, haloalcoxilo C1-6,alquiltio C1-6, haloalquiltio C1-6, alquilsulfinilo C1-6, haloalquilsulfinilo C1-6, alquilsulfonilo C1-6, y haloalquilsulfonilo C1-6, o -A2-R7 [en esta formula, A2 representa -O-, -S-, -SO-, -SO2-, NR8- (donde R8 representa hidrogeno, alquilcarbonilo C1-6, haloalquilcarbonilo C1-6, alcoxicarbonilo C1-6, fenilcarbonilo, fenilcarbonilo sustituido que posee por lo menos uno, iguales o diferentes sustituyentes seleccionados del grupo que consiste de halogeno, alquilo C1-6, haloalquilo C1-6, alcoxilo C1-6, haloalcoxilo C1-6, alquiltio C1-6, haloalquiltio C1-6, alquilsulfinilo C1-6, haloalquilsulfinilo C1-6, alquilsulfonilo C1-6 y haloalquilsulfonilo C1-6, fenilalcoxicarbonilo C1-4 o fenilalcoxicarbonilo C1-4 sustituido que posee, en el anillo del mismo, por lo menos uno, iguales o diferentes sustituyentes seleccionados del grupo que consiste de halogeno, alquilo C1-6, haloalquilo C1-6, alcoxilo C1-6, haloalcoxilo C1-6, alquiltio C1-6, haloalquiltio C1-6, alquilsulfinilo C1-6, haloalquilsulfinilo C1-6, alquilsulfonilo C1-6 y alquilsulfonilo C1-6), -C(=O)-, -C(=NOR6)- (donde R6 es igual al definido anteriormente), alquileno C1-6, haloalquileno C1-6, alquenileno C2-6, haloalquenileno C2-6, alquinileno C2-6, o haloalquinileno C2-6; y (1) en los casos donde A2 representa -O-, -S-, -SO-, -SO2- o -NR8- (donde R8 es igual al defino anteriormente); R7 representa hidrogeno, halocicloalquilo C3-6, halocicloalquenilo C3-6, fenilo, fenilo sustituido que posee por lo menos uno, iguales o diferentes sustituyentes seleccionados del grupo que consiste de halogeno, alquilo C1-6, haloalquilo C1-6, alcoxilo C1-6, haloalcoxilo C1-6, alquiltio C1-6, haloalquiltio C1-6, alquilsulfinilo C1-6, haloalquilsulfinilo C1-6, alquilsulfonilo C1-6 y haloalquilsulfonilo C1-6, grupo heterocíclico o grupo heterocíclico sustituido (el término grupo heterocíclico es como ya se ha definido) que posee por lo menos uno, iguales o diferentes sustituyentes seleccionados del grupo consistente de halogeno, alquilo C1-6, haloalquilo C1-6, alcoxilo C1-6, haloalcoxilo C1-6, alquiltio C1-6, haloalquiltio C1-6, alquilsulfinilo C1-6, haloalquilsulfinilo C1-6, alquilsulfonilo C1-6 y haloalquilsulfonilo C1-6, o -A3-R9 (donde A3 representa alquileno C1-6, haloalquileno C1-6, alquenileno C3-6, haloalquenileno C3-6, alquinileno C3-6 o haloalquinileno C3-6; y R9 representa hidrogeno, halogeno, cicloalquilo C3-6, halocicloalquilo C3-6, alcoxicarbonilo C1-6, fenilo, fenilo sustituido que posee por lo menos uno, iguales o diferentes sustituyentes seleccionados del grupo que consiste de halogeno, alquilo C1-6, haloalquilo C1-6, alcoxilo C1-6, haloalcoxilo C1-6, alquiltio C1-6, haloalquiltio C1-6, alquilsulfinilo C1-6, haloalquilsulfinilo C1-6, alquilsulfonilo C1-6 y haloalquilsulfonilo C1-6, o -A4-R10 ( donde A4 representa -O-, -S-, -SO-, -SO2- o -C(=O)-; y R10 representa alquilo C1-6, haloalquilo C1-6, alquenilo C3-6, haloalquenilo C3-6, cicloalquilo C3-6, halocicloalquilo C3-6, fenilo, fenilo sustituido que posee por lo menos uno, iguales o diferentes sustituyentes seleccionados del grupo que consiste de halogeno, alquilo C1-6, haloalquilo C1-6, alcoxilo C1-6, haloalcoxilo C1-6, alquiltio C1-6, haloalquiltio C1-6, alquilsulfinilo C1-6, haloalquilsulfinilo C1-6, alquilsulfonilo C1-6 y haloalquilsulfonilo C1-6, grupo heterocíclico o heterocíclico sustituido (donde el término grupo heterocíclico es como se ha definido anteriormente) que posee por lo menos uno, iguales o diferentes sustituyentes seleccionados del grupo que consiste de halogeno, alquilo C1-6, haloalquilo C1-6, alcoxilo C1-6, haloalcoxilo C1-6, alquiltio C1-6, haloalquiltio C1-6, alquilsulfinilo C1-6, haloalquilsulfinilo C1-6, alquilsulfonilo C1-6 y haloalquilsulfonilo C1-6)); (2) en casos donde A2 representa -C(=O)- o -C(=NOR6)- (donde R6 es igual al de
ARP000103364A 1999-07-05 2000-06-30 Derivado de ftalamida, derivado de amina heterociclico util como intermediario para la produccion del mismo, insecticida agrohorticola y metodo para utilizar dicho insecticida AR030154A1 (es)

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IL147228A0 (en) 2002-08-14
CO5221024A1 (es) 2002-11-28
AU773377B2 (en) 2004-05-20
CZ200239A3 (cs) 2002-05-15
BR0012224B1 (pt) 2010-12-28
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CN1195734C (zh) 2005-04-06
US6875768B1 (en) 2005-04-05
EP1193254A4 (en) 2007-09-19
EG22172A (en) 2002-10-31
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