AR036631A1 - Pirazoles 3-substituidos insecticidas y acaricidas; metodo para el control de insectos o acaros; metodo para la proteccion de una planta; metodo para la proteccion de madera, productos de madera o estructuras de madera; composicion; y procedimiento para la preparacion de estos compuestos - Google Patents
Pirazoles 3-substituidos insecticidas y acaricidas; metodo para el control de insectos o acaros; metodo para la proteccion de una planta; metodo para la proteccion de madera, productos de madera o estructuras de madera; composicion; y procedimiento para la preparacion de estos compuestosInfo
- Publication number
- AR036631A1 AR036631A1 ARP020103615A ARP020103615A AR036631A1 AR 036631 A1 AR036631 A1 AR 036631A1 AR P020103615 A ARP020103615 A AR P020103615A AR P020103615 A ARP020103615 A AR P020103615A AR 036631 A1 AR036631 A1 AR 036631A1
- Authority
- AR
- Argentina
- Prior art keywords
- halogen
- haloalkyl
- alkyl
- hydrogen
- alkoxy
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 9
- 239000002023 wood Substances 0.000 title abstract 6
- 150000001875 compounds Chemical class 0.000 title abstract 5
- 241000238631 Hexapoda Species 0.000 title abstract 2
- 239000000642 acaricide Substances 0.000 title 1
- 239000002917 insecticide Substances 0.000 title 1
- 229910052736 halogen Inorganic materials 0.000 abstract 13
- 150000002367 halogens Chemical class 0.000 abstract 13
- 229910052739 hydrogen Inorganic materials 0.000 abstract 11
- 239000001257 hydrogen Substances 0.000 abstract 11
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 11
- 125000000171 (C1-C6) haloalkyl group Chemical group 0.000 abstract 10
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 abstract 7
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 7
- 125000004737 (C1-C6) haloalkoxy group Chemical group 0.000 abstract 6
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 5
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 4
- 125000004454 (C1-C6) alkoxycarbonyl group Chemical group 0.000 abstract 4
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 4
- 125000006700 (C1-C6) alkylthio group Chemical group 0.000 abstract 4
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 abstract 3
- 125000003320 C2-C6 alkenyloxy group Chemical group 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 abstract 2
- 125000004738 (C1-C6) alkyl sulfinyl group Chemical group 0.000 abstract 2
- 125000004739 (C1-C6) alkylsulfonyl group Chemical group 0.000 abstract 2
- 125000006656 (C2-C4) alkenyl group Chemical group 0.000 abstract 2
- -1 3-substituted pyrazoles Chemical class 0.000 abstract 2
- 125000004682 aminothiocarbonyl group Chemical group NC(=S)* 0.000 abstract 2
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 abstract 2
- 125000000262 haloalkenyl group Chemical group 0.000 abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 2
- 125000004890 (C1-C6) alkylamino group Chemical group 0.000 abstract 1
- 125000004916 (C1-C6) alkylcarbonyl group Chemical group 0.000 abstract 1
- 241000239223 Arachnida Species 0.000 abstract 1
- 241000238421 Arthropoda Species 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000004457 alkyl amino carbonyl group Chemical group 0.000 abstract 1
- 125000004414 alkyl thio group Chemical group 0.000 abstract 1
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 abstract 1
- 125000006254 cycloalkyl carbonyl group Chemical group 0.000 abstract 1
- 125000004663 dialkyl amino group Chemical group 0.000 abstract 1
- ORTFAQDWJHRMNX-UHFFFAOYSA-N hydroxidooxidocarbon(.) Chemical group O[C]=O ORTFAQDWJHRMNX-UHFFFAOYSA-N 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 208000015181 infectious disease Diseases 0.000 abstract 1
- CUONGYYJJVDODC-UHFFFAOYSA-N malononitrile Chemical compound N#CCC#N CUONGYYJJVDODC-UHFFFAOYSA-N 0.000 abstract 1
- 125000003884 phenylalkyl group Chemical group 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/38—Nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/16—Halogen atoms or nitro radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/18—One oxygen or sulfur atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/18—One oxygen or sulfur atom
- C07D231/20—One oxygen atom attached in position 3 or 5
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/28—Two oxygen or sulfur atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/38—Nitrogen atoms
- C07D231/40—Acylated on said nitrogen atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pyridine Compounds (AREA)
Abstract
Pirazoles 3-substituidos que tienen la fórmula (1), en la cual las variables y el índice tienen los siguientes significados: R1 es hidrógeno, halógeno, alquilo C1-6, haloalquilo C1-6, alquenilo C2-6, haloalquenilo C2-6, alquiltio C1-6, alcoxi C1-6-alquilo C1-4, alquiltio C1-6-alquilo C1-4 o fenilo que no está sustituido o está sustituido con 1 a 3 grupos Ra; Ra es halógeno, nitro, ciano, alquilo C1-6, haloalquilo C1-6, alquiltio C1-6, haloalquiltio C1-6, alcoxi C1-6 o haloalcoxi C1-6; R2 es hidrógeno, halógeno, alquilo C1-6, haloalquilo C1-6, alquenilo C2-6, haloalquenilo C2-6 o fenilo que no está sustituido o está sustituido con 1 a 3 grupos Ra; A es hidrógeno, hidroxi, ciano, nitro, halógeno, ródano, alcoxi C1-6, haloalcoxi C1-6, alqueniloxi C2-6, alquiltio C1-6, haloalquiltio C1-6, alquilsulfinilo C1-6, alquilsulfonilo C1-6, aminotiocarbonilo, hidroxicarbonilo, alcoxicarbonilo C1-6 o aminocarbonilo; B es hidrógeno, hidroxi, amino, ciano, nitro o halógeno; alquilo C1-6 no sustituido o sustituido con 1 a 3 grupos seleccionados de halógeno y ciano; alcoxi C1-6 no sustituido o sustituido con 1 a 3 grupos seleccionados de halógeno, ciano, alquenilo C2-4 y alcoxicarbonilo C1-6-alquenilo C2-4; alquenilo C2-6 no sustituido o sustituido con 1 a 3 grupos seleccionados de halógeno y ciano; alqueniloxi C2-6, alquiltio C1-6, haloalquilo C1-6, alcoxitiocarboniltio C1-6, alcoxicarbonil C1-6-alcoxi C1-4, alcoxicarbonil C1-6-alquiltio C1-4, alquilsulfinilo C1-6, alquilsulfonilo C1-6, aminotiocarbonilo, NR3R4, N=CHOR5 o N=CHNR5; R3 y R4 son cada uno independientemente hidrógeno, alquilo C1-6, alcoxicarbonil C1-6-alquilo C1-4, [(alcoxicarbonil C1-6)(alquenil C2-4)]alquilo C1-4, alcoxicarbonilo C1-6-alquenilo C2-4, alquilcarbonilo C1-6, cicloalquilcarbonilo C3-7, alquilaminocarbonilo C1-6, di-(alquil C1-6)aminocarbonilo, alcoxicarbonilo C1-6, alcoxiaminosulfonilo C1-6 o di-(alcoxi C1-6)aminosulfonilo; R5 es alquilo C1-6, haloalquilo C1-6 o fenilalquilo C1-4; Q es hidrógeno, nitro, halógeno, haloalquilo C1-4, alquilamino C1-6, dialquilamino C1-6, alcoxi C1-6, haloalcoxi C1-6 o alqueniloxi C2-6; X es hidrógeno, halógeno, haloalquilo C1-6. alcoxi C1-6 o haloalcoxi C1-6; Y es hidrógeno, halógeno, haloalquilo C1-6, alcoxi C1-6 o haloalcoxi C1-6; Z es hidrógeno, halógeno, haloalquilo C1-6, alcoxi C1-6 o haloalcoxi C1-6; M es N ó CR6; R6 es hidrógeno, nitro, halógeno o haloalquilo C1-4; y n es 0, 1, 2, 3 ó 4; con la condición de que cuando R1 es hidrógeno, n no es 0; método para el control de insectos o acáridos; método para la protección de una planta; método para la protección de madera, productos de madera o estructuras de madera; composición; y procedimiento para la preparación de estos compuestos. Estos compuestos se usan también para tratar, controlar, prevenir y proteger contra infección causada por arácnidos y artrópodos endo y ectoparasíticos.El procedimiento de preparación de los compuestos de fórmula (2), en donde A es ciano y B es amino, consiste en que compuestos de fórmula (3) se hacen reaccionar con malononitrilo en presencia de una base, donde los valores de los sustituyentes son los mencionados arriba).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US32463301P | 2001-09-25 | 2001-09-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR036631A1 true AR036631A1 (es) | 2004-09-22 |
Family
ID=23264427
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP020103615A AR036631A1 (es) | 2001-09-25 | 2002-09-25 | Pirazoles 3-substituidos insecticidas y acaricidas; metodo para el control de insectos o acaros; metodo para la proteccion de una planta; metodo para la proteccion de madera, productos de madera o estructuras de madera; composicion; y procedimiento para la preparacion de estos compuestos |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US20040260097A1 (es) |
| EP (1) | EP1432688A1 (es) |
| JP (1) | JP2005512969A (es) |
| KR (1) | KR20040035846A (es) |
| CN (1) | CN1305857C (es) |
| AR (1) | AR036631A1 (es) |
| BR (1) | BR0212385A (es) |
| CA (1) | CA2460906A1 (es) |
| EA (1) | EA007969B1 (es) |
| HU (1) | HUP0402238A3 (es) |
| IL (1) | IL160444A0 (es) |
| MX (1) | MXPA04002040A (es) |
| PL (1) | PL370353A1 (es) |
| UA (1) | UA79758C2 (es) |
| WO (1) | WO2003029222A1 (es) |
| ZA (1) | ZA200402932B (es) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004196795A (ja) * | 2002-12-16 | 2004-07-15 | Wyeth | 外部寄生虫駆除剤としてのｎ−フェニル−３−シクロプロピルピラゾール−４−カルボニトリル |
| FR2848780B1 (fr) * | 2002-12-19 | 2005-05-13 | Solvay | Utilisation d'une poudre acaricide |
| GB0905365D0 (en) | 2009-03-27 | 2009-05-13 | Norbrook Lab Ltd | A topical parasiticide composition |
| RU2514004C1 (ru) * | 2012-10-25 | 2014-04-27 | Государственное научное учреждение Курский научно-исследовательский институт агропромышленного производства Россельхозакадемии | Способ получения комплексного препарата с иммунометаболической и антгельминтной активностью |
| US20160198725A1 (en) * | 2013-08-15 | 2016-07-14 | Sylleta Inc. | Compositions and methods for control of marine ectoparasites |
| EP3872068A1 (en) * | 2015-12-16 | 2021-09-01 | Nippon Soda Co., Ltd. | Arylazole compound and pest control agent |
| US20250188094A1 (en) * | 2022-03-18 | 2025-06-12 | Insilico Medicine Ip Limited | Pyrazole membrane-associated tyrosine-and threonine-specific cdc2-inhibitory kinase (pkmyt1) inhibitors and uses thereof |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3509567A1 (de) * | 1985-03-16 | 1986-09-18 | Bayer Ag, 5090 Leverkusen | Herbizide und insektizide mittel auf basis von pyrazolderivaten |
| GB8531485D0 (en) * | 1985-12-20 | 1986-02-05 | May & Baker Ltd | Compositions of matter |
| US5232940A (en) * | 1985-12-20 | 1993-08-03 | Hatton Leslie R | Derivatives of N-phenylpyrazoles |
| WO1997003067A1 (en) * | 1995-07-13 | 1997-01-30 | Knoll Aktiengesellschaft | Piperazine derivatives as therapeutic agents |
| EP0780378B1 (en) * | 1995-12-19 | 2003-04-09 | Bayer CropScience S.A. | New 1-aryl pyrazole derivatives and their use as pesticides |
| US6531477B1 (en) * | 1998-10-13 | 2003-03-11 | Dupont Pharmaceuticals Company | 6-substituted pyrazolo [3,4-d] pyrimidin-4-ones useful as cyclin dependent kinase inhibitors |
-
2002
- 2002-09-25 UA UA20040403076A patent/UA79758C2/uk unknown
- 2002-09-25 EP EP02777196A patent/EP1432688A1/en not_active Withdrawn
- 2002-09-25 EA EA200400413A patent/EA007969B1/ru not_active IP Right Cessation
- 2002-09-25 CN CNB028187547A patent/CN1305857C/zh not_active Expired - Fee Related
- 2002-09-25 WO PCT/EP2002/010719 patent/WO2003029222A1/en not_active Ceased
- 2002-09-25 CA CA002460906A patent/CA2460906A1/en not_active Abandoned
- 2002-09-25 AR ARP020103615A patent/AR036631A1/es not_active Application Discontinuation
- 2002-09-25 HU HU0402238A patent/HUP0402238A3/hu unknown
- 2002-09-25 MX MXPA04002040A patent/MXPA04002040A/es unknown
- 2002-09-25 US US10/490,369 patent/US20040260097A1/en not_active Abandoned
- 2002-09-25 JP JP2003532472A patent/JP2005512969A/ja not_active Withdrawn
- 2002-09-25 IL IL16044402A patent/IL160444A0/xx unknown
- 2002-09-25 BR BR0212385-1A patent/BR0212385A/pt not_active IP Right Cessation
- 2002-09-25 KR KR10-2004-7004081A patent/KR20040035846A/ko not_active Withdrawn
- 2002-09-25 PL PL02370353A patent/PL370353A1/xx not_active Application Discontinuation
-
2004
- 2004-04-19 ZA ZA200402932A patent/ZA200402932B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| HUP0402238A2 (hu) | 2005-02-28 |
| UA79758C2 (en) | 2007-07-25 |
| HUP0402238A3 (en) | 2008-02-28 |
| EP1432688A1 (en) | 2004-06-30 |
| US20040260097A1 (en) | 2004-12-23 |
| JP2005512969A (ja) | 2005-05-12 |
| EA007969B1 (ru) | 2007-02-27 |
| CA2460906A1 (en) | 2003-04-10 |
| CN1558902A (zh) | 2004-12-29 |
| IL160444A0 (en) | 2004-07-25 |
| BR0212385A (pt) | 2004-08-17 |
| MXPA04002040A (es) | 2004-06-07 |
| EA200400413A1 (ru) | 2004-08-26 |
| WO2003029222A1 (en) | 2003-04-10 |
| ZA200402932B (en) | 2005-04-19 |
| KR20040035846A (ko) | 2004-04-29 |
| CN1305857C (zh) | 2007-03-21 |
| PL370353A1 (en) | 2005-05-16 |
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