AR020153A1 - Trifluormetilpirrolcarboxamidas, proceso para su preparacion, su uso para progeger plantas contra microorganismos fitopatogenos, composicion paracontrolar microorganismos y para prevenir el ataque y la infestacion de las plantas con los mismos y metodo para controlar o prevenir la infestacion deplan - Google Patents
Trifluormetilpirrolcarboxamidas, proceso para su preparacion, su uso para progeger plantas contra microorganismos fitopatogenos, composicion paracontrolar microorganismos y para prevenir el ataque y la infestacion de las plantas con los mismos y metodo para controlar o prevenir la infestacion deplanInfo
- Publication number
- AR020153A1 AR020153A1 ARP990103998A ARP990103998A AR020153A1 AR 020153 A1 AR020153 A1 AR 020153A1 AR P990103998 A ARP990103998 A AR P990103998A AR P990103998 A ARP990103998 A AR P990103998A AR 020153 A1 AR020153 A1 AR 020153A1
- Authority
- AR
- Argentina
- Prior art keywords
- alkyl
- microorganisms
- infestation
- plants
- haloalkyl
- Prior art date
Links
- 244000005700 microbiome Species 0.000 title abstract 5
- 206010061217 Infestation Diseases 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 6
- -1 C1-4-sulfonyl alkyl Chemical group 0.000 abstract 5
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 abstract 3
- 229910052736 halogen Inorganic materials 0.000 abstract 3
- 150000002367 halogens Chemical group 0.000 abstract 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 3
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 abstract 2
- 125000006272 (C3-C7) cycloalkyl group Chemical group 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 abstract 2
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 2
- 125000004465 cycloalkenyloxy group Chemical group 0.000 abstract 2
- 125000000000 cycloalkoxy group Chemical group 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- 125000003170 phenylsulfonyl group Chemical group C1(=CC=CC=C1)S(=O)(=O)* 0.000 abstract 2
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 abstract 1
- 125000004767 (C1-C4) haloalkoxy group Chemical group 0.000 abstract 1
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 1
- 125000004737 (C1-C6) haloalkoxy group Chemical group 0.000 abstract 1
- 125000000171 (C1-C6) haloalkyl group Chemical group 0.000 abstract 1
- BZVOQWMTKOJPHH-UHFFFAOYSA-N 3-(trifluoromethyl)-1h-pyrrole-2-carboxamide Chemical class NC(=O)C=1NC=CC=1C(F)(F)F BZVOQWMTKOJPHH-UHFFFAOYSA-N 0.000 abstract 1
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 abstract 1
- 125000003601 C2-C6 alkynyl group Chemical group 0.000 abstract 1
- 125000003302 alkenyloxy group Chemical group 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000004453 alkoxycarbonyl group Chemical group 0.000 abstract 1
- 125000004448 alkyl carbonyl group Chemical group 0.000 abstract 1
- 125000005133 alkynyloxy group Chemical group 0.000 abstract 1
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 abstract 1
- 125000000392 cycloalkenyl group Chemical group 0.000 abstract 1
- 125000000262 haloalkenyl group Chemical group 0.000 abstract 1
- 125000005291 haloalkenyloxy group Chemical group 0.000 abstract 1
- 125000001624 naphthyl group Chemical group 0.000 abstract 1
- 230000000361 pesticidal effect Effects 0.000 abstract 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 abstract 1
- 230000003032 phytopathogenic effect Effects 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 125000004001 thioalkyl group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
- C07D207/34—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D207/36—Oxygen or sulfur atoms
- C07D207/40—2,5-Pyrrolidine-diones
- C07D207/416—2,5-Pyrrolidine-diones with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to other ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
- C07D409/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing three or more hetero rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pyrrole Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Derivados de trifluormetilpirrolcarboxamidas plaguicidas de la formula (1), en donde: R1 es hidrogeno, halogeno, haloalquilo C1-4, o alquilo C1-4;R2 es alquilo C1-4, haloalquilo C1-4, alcoxi C1-4-alquilo C1-4, ciano, alquilo C1-4-sulfonilo, fenilsulfonilo, di(alquilo C1-4)aminosulfonilo, alquilo C1-6-carbonilo, benzoílo, o fenilsulfonilo o benzoílo sustituidos; y A es un grupo (2), en donde: R3 es alquilo C1-6, haloalquilo C1-6, alquenilo C2-6,haloalqueniloC2-6, alquinilo C2-6, alcoxi C1-6, haloalcoxi C1-6, alqueniloxi C2-6, haloalqueniloxi C2-6, alquiniloxi C2-6, cicloalquilo C3-7, alquilo C1-4-cicloalquilo C3-7, cicloalquenilo C4-7, alquilo C1-4-cicloalquenilo C4-7, cicloalquiloxi C3-7, alquilo C1-4-cicloalquiloxi C3-7, cicloalqueniloxi C5-7, alquilo C1-4-cicloalqueniloxi C5-7, fenilo, naftilo, fenoxi, naftiloxi, o fenilo o fenoxi sustituidos, en donde los sustituyentes son de 1 a 3 grupos independientementeseleccionados a partir de halogeno, alquilo C1-4, alcoxi C1-4, tioalquilo C1-4, ciano, alcoxi C1-4-carbonilo, alquilo C1-4-carbonilo, haloalquilo C1-4haloalcoxi C1-4, metilendioxi, o difluorometilendioxi, o fenilo; R4 es hidrogeno, halogeno, alquilo C1-4, haloalquilo C1-4, alcoxi C1-4, o haloalcoxi C1-4; yR5, R6 y R7, independientemente unos de otros, son alquilo C1-6, cicloalquilo C3-7, o cicloalquilo C3-7-alquilo C1-4, proceso para su preparacion, parala proteccion de plantas contra la infestacion por microorganismos fitopatogénicos, composicion para controlar microorganismos y para prevenir el ataque yla infestacion de las plantas con los mismos y método para controlar o prevenir la infestacion de plantas cultivadas por dichos microorganismos.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB9817548.2A GB9817548D0 (en) | 1998-08-12 | 1998-08-12 | Organic compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR020153A1 true AR020153A1 (es) | 2002-04-10 |
Family
ID=10837118
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP990103998A AR020153A1 (es) | 1998-08-12 | 1999-08-10 | Trifluormetilpirrolcarboxamidas, proceso para su preparacion, su uso para progeger plantas contra microorganismos fitopatogenos, composicion paracontrolar microorganismos y para prevenir el ataque y la infestacion de las plantas con los mismos y metodo para controlar o prevenir la infestacion deplan |
Country Status (26)
| Country | Link |
|---|---|
| US (1) | US6365620B2 (es) |
| EP (1) | EP1105375B1 (es) |
| JP (1) | JP4624557B2 (es) |
| KR (1) | KR20010072344A (es) |
| CN (1) | CN1166635C (es) |
| AR (1) | AR020153A1 (es) |
| AT (1) | ATE318257T1 (es) |
| AU (1) | AU756140B2 (es) |
| BR (1) | BR9912962B1 (es) |
| CR (1) | CR6079A (es) |
| DE (1) | DE69929983T2 (es) |
| DK (1) | DK1105375T3 (es) |
| ES (1) | ES2258849T3 (es) |
| GB (1) | GB9817548D0 (es) |
| GT (1) | GT199900093A (es) |
| HN (1) | HN1999000132A (es) |
| HU (1) | HUP0105067A3 (es) |
| IL (1) | IL141229A0 (es) |
| MX (1) | MXPA01001462A (es) |
| MY (1) | MY118654A (es) |
| PL (1) | PL345823A1 (es) |
| PT (1) | PT1105375E (es) |
| RU (1) | RU2264388C2 (es) |
| TR (1) | TR200100478T2 (es) |
| TW (1) | TW576831B (es) |
| WO (1) | WO2000009482A1 (es) |
Families Citing this family (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9930750D0 (en) | 1999-12-29 | 2000-02-16 | Novartis Ag | Organic compounds |
| GB0001447D0 (en) | 2000-01-21 | 2000-03-08 | Novartis Ag | Organic compounds |
| DE10122447A1 (de) * | 2000-07-24 | 2002-04-18 | Bayer Ag | Biphenylcarboxamide |
| CN1252055C (zh) * | 2000-07-24 | 2006-04-19 | 拜尔农作物科学股份公司 | 联苯甲酰胺类化合物 |
| KR20040011427A (ko) | 2000-11-08 | 2004-02-05 | 신젠타 파티서페이션즈 아게 | 피롤카르복시아미드 및 피롤카르보티오아미드 및 그의농화학적 용도 |
| GB0101996D0 (en) | 2001-01-25 | 2001-03-14 | Syngenta Participations Ag | Organtic compounds |
| GB0103258D0 (en) * | 2001-02-09 | 2001-03-28 | Syngenta Participations Ag | Organic compounds |
| DE10204390A1 (de) * | 2002-02-04 | 2003-08-14 | Bayer Cropscience Ag | Disubstituierte Thiazolylcarboxanilide |
| DE10204391A1 (de) * | 2002-02-04 | 2003-08-14 | Bayer Cropscience Ag | Difluormethylthiazolylcarboxanilide |
| GB0207253D0 (en) * | 2002-03-27 | 2002-05-08 | Syngenta Participations Ag | Chemical compounds |
| DE10219035A1 (de) * | 2002-04-29 | 2003-11-13 | Bayer Cropscience Ag | Biphenylcarboxamide |
| ATE516275T1 (de) | 2002-08-22 | 2011-07-15 | Syngenta Participations Ag | Microbiozide (z.b. fungizide) 1,2,3- triazolderivate |
| GB0224316D0 (en) * | 2002-10-18 | 2002-11-27 | Syngenta Participations Ag | Chemical compounds |
| GB0225554D0 (en) * | 2002-11-01 | 2002-12-11 | Syngenta Participations Ag | Chemical compounds |
| DE10352067A1 (de) * | 2003-10-23 | 2005-05-25 | Bayer Cropscience Ag | Isopentylcarboxanilide |
| IN2004DE01799A (es) | 2003-10-23 | 2007-01-12 | Bayer Cropscience Ag | |
| BRPI0415848B1 (pt) | 2003-10-23 | 2017-04-25 | Bayer Cropscience Ag | isopentilcarboxanilidas, seu processo de preparação, seu uso e seus intermediários, composição e seu processo de preparação, e método para controlar microorganismos indesejados |
| EP1773768B8 (en) * | 2004-07-30 | 2018-12-26 | Exelixis, Inc. | Pyrrole derivatives as pharmaceutical agents |
| KR101178747B1 (ko) | 2004-09-30 | 2012-09-03 | 다케다 야쿠힌 고교 가부시키가이샤 | 프로톤 펌프 저해제 |
| DE102004059725A1 (de) * | 2004-12-11 | 2006-06-22 | Bayer Cropscience Ag | 2-Alkyl-cycloalk(en)yl-carboxamide |
| JP2008538210A (ja) * | 2005-03-23 | 2008-10-16 | シンジェンタ パーティシペーションズ アクチェンゲゼルシャフト | 殺微生物剤としてのカルボキサニリド |
| PT1919865E (pt) * | 2005-08-30 | 2011-07-11 | Takeda Pharmaceutical | Derivados de 1h-pirrole substituídos com 1-heterociclilsulfonilo, 2-aminometilo, 5-(hetero)arilo como inibidores da secreção ácida |
| KR100698946B1 (ko) * | 2005-09-08 | 2007-03-26 | 주식회사 피엘케이 테크놀로지 | 차량 사고 정보 기록장치 |
| EA200801025A1 (ru) * | 2005-10-06 | 2008-12-30 | Юниверсити Оф Массачусетс | Композиция и синтез новых реагентов для ингибирования репликации вич |
| BRPI0713025A2 (pt) | 2006-06-16 | 2012-04-17 | Syngenta Participations Ag | compostos derivados de etenila carboxamida úteis como microbiocidas, método de controle ou prevenção de infestação de plantas úteis por microorganismo fitopatogênicos e composição para controle e prevenção dos referidos microorganismos |
| US8933105B2 (en) * | 2007-02-28 | 2015-01-13 | Takeda Pharmaceutical Company Limited | Pyrrole compounds |
| BRPI0911814A2 (pt) * | 2008-08-01 | 2018-05-29 | Bayer Cropscience Ag | "composto, composição fungicida e método para o controle do fungo fitopatogênico de culturas" |
| PT2318390E (pt) | 2008-08-27 | 2013-07-10 | Takeda Pharmaceutical | Compostos de pirrole |
| ES2475737T3 (es) | 2009-10-16 | 2014-07-11 | Syngenta Participations Ag | Nuevos microbiocidas |
| JP5712504B2 (ja) | 2010-04-27 | 2015-05-07 | 住友化学株式会社 | 有害生物防除組成物およびその用途 |
| CN102858167B (zh) | 2010-04-27 | 2016-03-16 | 住友化学株式会社 | 杀虫组合物及其用途 |
| JP5724211B2 (ja) | 2010-04-28 | 2015-05-27 | 住友化学株式会社 | 植物病害防除組成物およびその用途 |
| MX337182B (es) | 2010-04-28 | 2016-02-16 | Sumitomo Chemical Co | Composicion plaguicida y su uso. |
| CN102858172A (zh) | 2010-04-28 | 2013-01-02 | 住友化学株式会社 | 植物病害组合物及其用途 |
| MY160321A (en) * | 2010-04-28 | 2017-02-28 | Sumitomo Chemical Co | Pesticidal composition and its use |
| BR112013011936A2 (pt) * | 2010-11-15 | 2017-11-07 | Bayer Ip Gmbh | deca-hidro -1, 4-metanonaftaleno - carboxamidas |
| US9375005B2 (en) * | 2012-05-09 | 2016-06-28 | Bayer Cropscience Ag | 5-halogenopyrazole indanyl carboxamides |
| CN103145600B (zh) * | 2013-03-06 | 2015-06-03 | 东北师范大学 | 一种银催化的多取代吡咯类化合物的合成方法 |
| CN104856989B (zh) * | 2015-04-13 | 2017-04-05 | 中山大学 | 一种小分子化合物在抗流感病毒药物中的应用 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5045554A (en) * | 1988-11-29 | 1991-09-03 | Monsanto Company | Substituted thiazoles and their use as fungicides |
| JPH02157266A (ja) * | 1988-12-12 | 1990-06-18 | Mitsubishi Kasei Corp | Ｎ−インダニルカルボン酸アミド誘導体およびこれを有効成分とする農園芸用殺菌剤 |
| IL103614A (en) * | 1991-11-22 | 1998-09-24 | Basf Ag | Carboxamides for controlling botrytis and certain novel such compounds |
| EP0566138B1 (en) * | 1992-04-17 | 1998-11-18 | Hodogaya Chemical Co., Ltd. | Amino thiazole derivatives and their use as fungicides |
| DE4231517A1 (de) * | 1992-09-21 | 1994-03-24 | Basf Ag | Carbonsäureanilide, Verfahren zu ihrer Herstellung und sie enthaltende Mittel zur Bekämpfung von Schadpilzen |
| DE69618370T2 (de) * | 1995-04-11 | 2002-09-26 | Mitsui Chemicals, Inc. | Substituierte Thiophenderivate und diese als aktiver Bestandteil enthaltenden Fungizide für Land- und Gartenbauwirtschaft |
| DE19531813A1 (de) * | 1995-08-30 | 1997-03-06 | Basf Ag | Bisphenylamide |
| DE19615976A1 (de) * | 1996-04-22 | 1997-10-23 | Basf Ag | Mittel und Verfahren zur Bekämpfung von Schadpilzen |
| JPH09301974A (ja) * | 1996-05-16 | 1997-11-25 | Mitsui Toatsu Chem Inc | 置換チオフェン誘導体およびこれを有効成分とする農園芸用殺菌剤 |
-
1998
- 1998-08-12 GB GBGB9817548.2A patent/GB9817548D0/en not_active Ceased
-
1999
- 1999-05-13 TW TW088107745A patent/TW576831B/zh not_active IP Right Cessation
- 1999-06-18 GT GT199900093A patent/GT199900093A/es unknown
- 1999-07-26 CR CR6079A patent/CR6079A/es not_active Application Discontinuation
- 1999-08-10 CN CNB998094129A patent/CN1166635C/zh not_active Expired - Fee Related
- 1999-08-10 PL PL99345823A patent/PL345823A1/xx unknown
- 1999-08-10 JP JP2000564936A patent/JP4624557B2/ja not_active Expired - Fee Related
- 1999-08-10 RU RU2001105955/04A patent/RU2264388C2/ru not_active IP Right Cessation
- 1999-08-10 EP EP99941573A patent/EP1105375B1/en not_active Expired - Lifetime
- 1999-08-10 WO PCT/EP1999/005837 patent/WO2000009482A1/en not_active Ceased
- 1999-08-10 ES ES99941573T patent/ES2258849T3/es not_active Expired - Lifetime
- 1999-08-10 MX MXPA01001462A patent/MXPA01001462A/es not_active IP Right Cessation
- 1999-08-10 HU HU0105067A patent/HUP0105067A3/hu not_active Application Discontinuation
- 1999-08-10 AU AU55138/99A patent/AU756140B2/en not_active Ceased
- 1999-08-10 DE DE69929983T patent/DE69929983T2/de not_active Expired - Lifetime
- 1999-08-10 DK DK99941573T patent/DK1105375T3/da active
- 1999-08-10 KR KR1020017001680A patent/KR20010072344A/ko not_active Abandoned
- 1999-08-10 AR ARP990103998A patent/AR020153A1/es unknown
- 1999-08-10 AT AT99941573T patent/ATE318257T1/de not_active IP Right Cessation
- 1999-08-10 TR TR2001/00478T patent/TR200100478T2/xx unknown
- 1999-08-10 HN HN1999000132A patent/HN1999000132A/es unknown
- 1999-08-10 PT PT99941573T patent/PT1105375E/pt unknown
- 1999-08-10 BR BRPI9912962-0A patent/BR9912962B1/pt not_active IP Right Cessation
- 1999-08-10 IL IL14122999A patent/IL141229A0/xx not_active IP Right Cessation
- 1999-08-11 MY MYPI99003424A patent/MY118654A/en unknown
-
2001
- 2001-02-09 US US09/780,897 patent/US6365620B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US20020019541A1 (en) | 2002-02-14 |
| HUP0105067A2 (hu) | 2002-04-29 |
| DE69929983T2 (de) | 2006-09-14 |
| AU5513899A (en) | 2000-03-06 |
| DE69929983D1 (de) | 2006-04-27 |
| ATE318257T1 (de) | 2006-03-15 |
| TW576831B (en) | 2004-02-21 |
| AU756140B2 (en) | 2003-01-02 |
| CN1311774A (zh) | 2001-09-05 |
| EP1105375B1 (en) | 2006-02-22 |
| GT199900093A (es) | 2000-12-09 |
| JP4624557B2 (ja) | 2011-02-02 |
| GB9817548D0 (en) | 1998-10-07 |
| MY118654A (en) | 2004-12-31 |
| DK1105375T3 (da) | 2006-06-19 |
| CR6079A (es) | 2008-04-16 |
| BR9912962B1 (pt) | 2010-09-21 |
| PT1105375E (pt) | 2006-07-31 |
| HN1999000132A (es) | 2000-01-12 |
| WO2000009482A1 (en) | 2000-02-24 |
| JP2002522526A (ja) | 2002-07-23 |
| CN1166635C (zh) | 2004-09-15 |
| EP1105375A1 (en) | 2001-06-13 |
| TR200100478T2 (tr) | 2001-06-21 |
| KR20010072344A (ko) | 2001-07-31 |
| ES2258849T3 (es) | 2006-09-01 |
| BR9912962A (pt) | 2001-05-08 |
| RU2264388C2 (ru) | 2005-11-20 |
| PL345823A1 (en) | 2002-01-14 |
| MXPA01001462A (es) | 2002-05-08 |
| HUP0105067A3 (en) | 2004-10-28 |
| IL141229A0 (en) | 2002-03-10 |
| US6365620B2 (en) | 2002-04-02 |
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