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AR006009A1 - Un proceso para la preparacion de copolimeros de propileno aleatorios, y copolimeros de propileno - etileno aleatorios - Google Patents

Un proceso para la preparacion de copolimeros de propileno aleatorios, y copolimeros de propileno - etileno aleatorios

Info

Publication number
AR006009A1
AR006009A1 ARP970100773A ARP970100773A AR006009A1 AR 006009 A1 AR006009 A1 AR 006009A1 AR P970100773 A ARP970100773 A AR P970100773A AR P970100773 A ARP970100773 A AR P970100773A AR 006009 A1 AR006009 A1 AR 006009A1
Authority
AR
Argentina
Prior art keywords
propylene copolymers
random propylene
preparation
ethylene
electron donor
Prior art date
Application number
ARP970100773A
Other languages
English (en)
Original Assignee
Montell North America Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Montell North America Inc filed Critical Montell North America Inc
Publication of AR006009A1 publication Critical patent/AR006009A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6494—Catalysts containing a specific non-metal or metal-free compound organic containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Emergency Medicine (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)

Abstract

Un proceso para la preparación de copolímeros aleatorios del propileno con alfa-oleofinas C2-C10, llevado a cabo en presencia de un catalizador quecomprende: A) Un componente sólido que contiene un compuesto de titanio sustentado en MgCl1en forma activa y un compuesto dador de electrón; B) uncompuesto alquil-Al, y C) Un compuesto dador de electrón que se selecciona entre el grupo de los 1,3-diéteres. Los copolímeros que se obtienen mediante lautilización de dicho procesopresentan , para un contenido de alfa-oleofina equivalente, un menor contenido de fracciones solubles en xileno cuando se loscompara con aquellos copolímeros que se obtienen utilizando los catalizadores de la técnica anterior.
ARP970100773A 1996-02-27 1997-02-27 Un proceso para la preparacion de copolimeros de propileno aleatorios, y copolimeros de propileno - etileno aleatorios AR006009A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT96MI000357A IT1282691B1 (it) 1996-02-27 1996-02-27 Processo per la preparazione di copolimeri random del propilene e prodotti cosi' ottenuti

Publications (1)

Publication Number Publication Date
AR006009A1 true AR006009A1 (es) 1999-07-21

Family

ID=11373395

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP970100773A AR006009A1 (es) 1996-02-27 1997-02-27 Un proceso para la preparacion de copolimeros de propileno aleatorios, y copolimeros de propileno - etileno aleatorios

Country Status (13)

Country Link
US (2) US6365685B1 (es)
EP (1) EP0822945B1 (es)
JP (1) JPH11504679A (es)
KR (2) KR100475760B1 (es)
AR (1) AR006009A1 (es)
AT (1) ATE236199T1 (es)
AU (1) AU730331B2 (es)
BR (1) BR9702095A (es)
CA (1) CA2218997A1 (es)
DE (1) DE69720338T2 (es)
ES (1) ES2193356T3 (es)
IT (1) IT1282691B1 (es)
WO (1) WO1997031954A1 (es)

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US5968865A (en) * 1997-12-10 1999-10-19 Union Carbide Chemicals & Plastics Technology Corporation Electron donor containing compositions
US6124507A (en) * 1997-12-10 2000-09-26 Union Carbide Chemicals & Plastics Technology Corporation Electron donors
SG73622A1 (en) * 1998-03-11 2000-06-20 Sumitomo Chemical Co Solid catalyst component and catalyst for olefin polymerization and process for producing olefin polymer
MXPA02000431A (es) 2001-01-12 2005-06-06 Fina Technology Produccion de resinas de polipropileno de flujo de fundicion ultra rapido.
EP1607433B1 (en) 2001-06-27 2016-08-10 Borealis Technology Oy Polymer film comprising a propylene random copolymer
SG99976A1 (en) * 2002-03-26 2003-11-27 Sumitomo Chemical Co Propylene-based polymer and injection molded article made of the same
EP1778472A1 (en) * 2004-07-29 2007-05-02 BFS Diversified Products, LLC Construction laminates
ATE435245T1 (de) * 2005-05-12 2009-07-15 Basell Poliolefine Srl Propylen-ethylen-copolymere und herstellungsverfahren dafür
ATE437901T1 (de) * 2006-04-24 2009-08-15 Total Petrochemicals Res Feluy Verfahren zur herstellung von propylenpolymeren mit geringem aschegehalt
EP2226337A1 (en) * 2009-03-02 2010-09-08 Borealis AG Process for the production of polypropylene random copolymers for injection moulding applications
KR101235445B1 (ko) 2010-01-13 2013-02-20 삼성토탈 주식회사 프로필렌 중합용 고체촉매의 제조 방법
JP5671625B2 (ja) 2010-11-24 2015-02-18 サムスン トータル ペトロケミカルズ カンパニー リミテッド プロピレン重合用固体触媒およびその製造方法
CN103946251B (zh) 2011-09-16 2017-06-23 宾视研发公司 疏水性人工晶状体
TWI567094B (zh) 2011-10-29 2017-01-21 China Petro-Chemical Tech Dev Company Ltd Propylene random copolymers, processes for their preparation, and compositions and articles comprising the same
EP2610274A1 (en) * 2011-12-30 2013-07-03 Borealis AG Propylene random copolymer
US9522968B2 (en) * 2012-11-26 2016-12-20 Lummus Novolen Technology Gmbh High performance Ziegler-Natta catalyst systems, process for producing such MgCl2 based catalysts and use thereof
US9284392B2 (en) * 2013-03-15 2016-03-15 Basf Corporation Mixed internal donor structures for 1-olefin polymerization catalysts
US11267916B2 (en) 2014-02-07 2022-03-08 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US10696765B2 (en) 2014-02-07 2020-06-30 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer
US9399686B2 (en) 2014-02-07 2016-07-26 Eastman Chemical Company Amorphous propylene-ethylene copolymers
US10308740B2 (en) 2014-02-07 2019-06-04 Eastman Chemical Company Amorphous propylene-ethylene copolymers
US10647795B2 (en) 2014-02-07 2020-05-12 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US10723824B2 (en) 2014-02-07 2020-07-28 Eastman Chemical Company Adhesives comprising amorphous propylene-ethylene copolymers
JP6307178B2 (ja) * 2014-05-06 2018-04-04 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ ランダムプロピレン−エチレン共重合体及びその製造方法
BR112016024101B1 (pt) * 2014-05-06 2021-11-16 Basell Poliolefine Italia S.R.L. Copolímeros aleatórios de propileno e etileno com múltiplas camadas
US10155827B2 (en) * 2014-05-06 2018-12-18 Basell Poliolefine Italia S.R.L. Random propylene-ethylene copolymers
KR101836008B1 (ko) 2016-12-05 2018-03-07 한화토탈 주식회사 프로필렌 중합용 촉매 및 이를 이용한 프로필렌 중합체 또는 공중합체의 제조방법
CA3102001A1 (en) 2018-06-11 2019-12-19 W.R. Grace & Co.-Conn Propylene-ethylene random copolymers with low xs/et ratio and high mfr
US11834534B2 (en) 2018-08-22 2023-12-05 Basell Poliolefine Italia S.R.L. Random propylene-ethylene copolymers
KR102178630B1 (ko) 2018-12-20 2020-11-13 한화토탈 주식회사 프로필렌 중합용 고체 촉매 및 이를 이용한 블록 공중합체의 제조방법
EP3983456A1 (en) * 2019-06-14 2022-04-20 3D Systems, Inc. Polypropylene-based particles for additive manufacturing
KR102259306B1 (ko) 2019-10-21 2021-05-31 한화토탈 주식회사 프로필렌 중합용 고체 촉매의 제조 방법
KR102864236B1 (ko) 2022-10-24 2025-09-25 한화토탈에너지스 주식회사 프로필렌계 중합용 고체 촉매 및 이를 이용한 프로필렌계 중합체의 제조방법

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IT1098272B (it) 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
IT1221653B (it) * 1987-11-27 1990-07-12 Ausimonti Spa Copolimeri cristallini del propilene
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JP3264148B2 (ja) * 1995-08-31 2002-03-11 住友化学工業株式会社 プロピレン−エチレンランダム共重合体、その製法及びフィルム

Also Published As

Publication number Publication date
US6365685B1 (en) 2002-04-02
JPH11504679A (ja) 1999-04-27
EP0822945A1 (en) 1998-02-11
KR20040103975A (ko) 2004-12-09
ATE236199T1 (de) 2003-04-15
DE69720338T2 (de) 2004-02-12
ITMI960357A0 (es) 1996-02-27
US20020137860A1 (en) 2002-09-26
ES2193356T3 (es) 2003-11-01
EP0822945B1 (en) 2003-04-02
IT1282691B1 (it) 1998-03-31
KR100491387B1 (ko) 2005-08-31
ITMI960357A1 (it) 1997-08-27
DE69720338D1 (de) 2003-05-08
WO1997031954A1 (en) 1997-09-04
KR100475760B1 (ko) 2005-03-14
US6693161B2 (en) 2004-02-17
AU730331B2 (en) 2001-03-01
AU2039797A (en) 1997-09-16
BR9702095A (pt) 1999-07-20
CA2218997A1 (en) 1997-09-04
KR19990008107A (ko) 1999-01-25

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