NL8004153A - Werkwijze voor de bereiding van carbonzuren uit aldehyden. - Google Patents
Werkwijze voor de bereiding van carbonzuren uit aldehyden. Download PDFInfo
- Publication number
- NL8004153A NL8004153A NL8004153A NL8004153A NL8004153A NL 8004153 A NL8004153 A NL 8004153A NL 8004153 A NL8004153 A NL 8004153A NL 8004153 A NL8004153 A NL 8004153A NL 8004153 A NL8004153 A NL 8004153A
- Authority
- NL
- Netherlands
- Prior art keywords
- aldehydes
- oxidation
- oxygen
- carried out
- reaction
- Prior art date
Links
- 150000001299 aldehydes Chemical class 0.000 title claims description 25
- 238000000034 method Methods 0.000 title claims description 17
- 150000004653 carbonic acids Chemical class 0.000 title 1
- 238000006243 chemical reaction Methods 0.000 claims description 17
- 230000003647 oxidation Effects 0.000 claims description 14
- 238000007254 oxidation reaction Methods 0.000 claims description 14
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 13
- 239000001301 oxygen Substances 0.000 claims description 13
- 229910052760 oxygen Inorganic materials 0.000 claims description 13
- 239000003054 catalyst Substances 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 8
- 150000001735 carboxylic acids Chemical class 0.000 claims description 7
- 150000001450 anions Chemical class 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 239000007789 gas Substances 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 230000003197 catalytic effect Effects 0.000 claims description 2
- 150000004684 trihydrates Chemical class 0.000 claims description 2
- OOIOHEBTXPTBBE-UHFFFAOYSA-N [Na].[Fe] Chemical compound [Na].[Fe] OOIOHEBTXPTBBE-UHFFFAOYSA-N 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- AMIMRNSIRUDHCM-UHFFFAOYSA-N Isopropylaldehyde Chemical compound CC(C)C=O AMIMRNSIRUDHCM-UHFFFAOYSA-N 0.000 description 4
- -1 alkali metal salts Chemical class 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 4
- 238000006386 neutralization reaction Methods 0.000 description 4
- 230000035484 reaction time Effects 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 3
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- SRHFDJIDAXAYGO-UHFFFAOYSA-N trisodium;iron(2+);pentacyanide;hydrate Chemical compound O.[Na+].[Na+].[Na+].[Fe+2].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] SRHFDJIDAXAYGO-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- FXHGMKSSBGDXIY-UHFFFAOYSA-N heptanal Chemical compound CCCCCCC=O FXHGMKSSBGDXIY-UHFFFAOYSA-N 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 150000002506 iron compounds Chemical class 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 238000007086 side reaction Methods 0.000 description 2
- NKDGCEARZJHWFY-UHFFFAOYSA-N sodium;iron(2+) Chemical compound [Na+].[Fe+2] NKDGCEARZJHWFY-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 description 2
- IQVAERDLDAZARL-UHFFFAOYSA-N 2-phenylpropanal Chemical compound O=CC(C)C1=CC=CC=C1 IQVAERDLDAZARL-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical group N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical class [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000003934 aromatic aldehydes Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical class [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910052748 manganese Chemical class 0.000 description 1
- 239000011572 manganese Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
- C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2931154 | 1979-08-01 | ||
| DE2931154A DE2931154C2 (de) | 1979-08-01 | 1979-08-01 | Verfahren zur Herstellung von aliphatischen Carbonsäuren aus Aldehyden |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NL8004153A true NL8004153A (nl) | 1981-02-03 |
Family
ID=6077316
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NL8004153A NL8004153A (nl) | 1979-08-01 | 1980-07-18 | Werkwijze voor de bereiding van carbonzuren uit aldehyden. |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4285875A (sv) |
| JP (1) | JPS5622744A (sv) |
| AU (1) | AU533956B2 (sv) |
| CA (1) | CA1139783A (sv) |
| DE (1) | DE2931154C2 (sv) |
| FR (1) | FR2462414A1 (sv) |
| GB (1) | GB2055829B (sv) |
| NL (1) | NL8004153A (sv) |
| SE (1) | SE445638B (sv) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4347164A (en) * | 1980-12-08 | 1982-08-31 | Filtrol Corporation | Mono- and poly-metallic supported catalysts |
| JPS58140038A (ja) * | 1982-02-16 | 1983-08-19 | Kuraray Co Ltd | アゼライン酸の製造法 |
| JPS5914517A (ja) * | 1982-07-15 | 1984-01-25 | Nissan Motor Co Ltd | 車両用ドアのシ−ル構造 |
| US4511167A (en) * | 1983-03-25 | 1985-04-16 | Taiyo Sanso Kabushiki Kaisha | Detachable holder for containers |
| AT402293B (de) * | 1994-09-06 | 1997-03-25 | Chemie Linz Gmbh | Verfahren zur herstellung von mono- oder dicarbonsäuren aus aldehyden, deren vollacetalen oder halbacetalen, sowie aus gemischen davon |
| DE4435332A1 (de) * | 1994-10-01 | 1996-04-04 | Chemie Linz Deutschland | Verfahren zur Herstellung von Mono- oder Dicarbonsäuren aus Aldehyden, deren Vollacetalen oder Halbacetalen, sowie aus Gemischen davon |
| FR2791667B1 (fr) * | 1999-03-30 | 2002-05-24 | Rhone Poulenc Fibres | Procede d'oxydation d'hydrocarbures, d'alcools et/ou de cetones |
| US6300496B1 (en) | 1999-10-06 | 2001-10-09 | Union Carbide Chemicals & Plastics Technology Corporation | Processes for producing epsilon caprolactams |
| DE10010771C1 (de) * | 2000-03-04 | 2001-05-03 | Celanese Chem Europe Gmbh | Verfahren zur Herstellung aliphatischer Carbonsäuren aus Aldehyden |
| RU2272021C1 (ru) * | 2004-11-11 | 2006-03-20 | ООО "Элемент Холдинг" | Способ получения изомасляной кислоты |
| DE102004055252A1 (de) * | 2004-11-16 | 2006-05-24 | Celanese Chemicals Europe Gmbh | Verfahren zur Herstellung von aliphatischen geradkettigen und ß-alkylverzweigten Carbonsäuren |
| CN103848717B (zh) * | 2012-12-05 | 2015-07-15 | 中国科学院大连化学物理研究所 | 一种水相催化氧化脂肪醇的方法 |
| CN110372488A (zh) * | 2019-07-25 | 2019-10-25 | 润泰化学（泰兴）有限公司 | 一种甲基丙烯酸甲酯的制备方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1937528A (en) * | 1930-12-04 | 1933-12-05 | Celanese Corp | Process for the production of acetic acid |
| US2010358A (en) * | 1933-02-03 | 1935-08-06 | Shell Dev | Process for the oxidation of isoaldehydes |
| DE1618589A1 (de) * | 1967-04-01 | 1971-02-25 | Knapsack Ag | Verfahren zur Herstellung von Carbonsaeuren |
| US3816522A (en) * | 1971-10-05 | 1974-06-11 | Mobil Oil Corp | Catalytic oxidation of carbonyl compounds |
-
1979
- 1979-08-01 DE DE2931154A patent/DE2931154C2/de not_active Expired
-
1980
- 1980-07-18 NL NL8004153A patent/NL8004153A/nl not_active Application Discontinuation
- 1980-07-24 GB GB8024296A patent/GB2055829B/en not_active Expired
- 1980-07-24 FR FR8016372A patent/FR2462414A1/fr active Granted
- 1980-07-25 JP JP10144380A patent/JPS5622744A/ja active Granted
- 1980-07-25 SE SE8005389A patent/SE445638B/sv not_active IP Right Cessation
- 1980-07-28 US US06/172,620 patent/US4285875A/en not_active Expired - Lifetime
- 1980-07-29 AU AU60882/80A patent/AU533956B2/en not_active Ceased
- 1980-07-31 CA CA000357436A patent/CA1139783A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| CA1139783A (en) | 1983-01-18 |
| SE8005389L (sv) | 1981-02-02 |
| FR2462414B1 (sv) | 1984-05-04 |
| DE2931154A1 (de) | 1981-02-26 |
| GB2055829B (en) | 1983-05-11 |
| JPS5622744A (en) | 1981-03-03 |
| AU6088280A (en) | 1981-02-05 |
| US4285875A (en) | 1981-08-25 |
| AU533956B2 (en) | 1983-12-22 |
| DE2931154C2 (de) | 1985-08-01 |
| GB2055829A (en) | 1981-03-11 |
| FR2462414A1 (fr) | 1981-02-13 |
| JPS5745419B2 (sv) | 1982-09-28 |
| SE445638B (sv) | 1986-07-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A1A | A request for search or an international-type search has been filed | ||
| BB | A search report has been drawn up | ||
| BC | A request for examination has been filed | ||
| A85 | Still pending on 85-01-01 | ||
| BV | The patent application has lapsed |