MXPA04007393A - Preparacion del 4-vinilciclohexeno, el etilbenceno y el estireno. - Google Patents
Preparacion del 4-vinilciclohexeno, el etilbenceno y el estireno.Info
- Publication number
- MXPA04007393A MXPA04007393A MXPA04007393A MXPA04007393A MXPA04007393A MX PA04007393 A MXPA04007393 A MX PA04007393A MX PA04007393 A MXPA04007393 A MX PA04007393A MX PA04007393 A MXPA04007393 A MX PA04007393A MX PA04007393 A MXPA04007393 A MX PA04007393A
- Authority
- MX
- Mexico
- Prior art keywords
- butene
- butane
- vinylcyclohexene
- butadiene
- optionally
- Prior art date
Links
- BBDKZWKEPDTENS-UHFFFAOYSA-N 4-Vinylcyclohexene Chemical compound C=CC1CCC=CC1 BBDKZWKEPDTENS-UHFFFAOYSA-N 0.000 title abstract 4
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 title 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 10
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 abstract 6
- IAQRGUVFOMOMEM-UHFFFAOYSA-N but-2-ene Chemical compound CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 abstract 6
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 abstract 6
- 238000006356 dehydrogenation reaction Methods 0.000 abstract 3
- XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 abstract 3
- 239000000470 constituent Substances 0.000 abstract 2
- 238000006471 dimerization reaction Methods 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- 238000000926 separation method Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/367—Formation of an aromatic six-membered ring from an existing six-membered ring, e.g. dehydrogenation of ethylcyclohexane to ethylbenzene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/50—Diels-Alder conversion
- C07C2/52—Catalytic processes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
La invencion se refiere a un proceso para preparar el 4-vinilciclohexeno, este proceso comprende las etapas de:(A) proporcionar una corriente de gas de carga que contenga el n-butano;(B) alimentar la corriente del gas de carga que contiene el n-butano en cuando menos una zona de deshidrogenacion y deshidrogenar el n-butano al butadieno, para suministrar una corriente de producto que comprende el butadieno, n-butano, posiblemente el 1-buteno y 2-buteno y preferiblemente el vapor de agua y potros constituyentes secundarios;(C) alimentar la corriente del producto desde la deshidrogenacion, si es apropiado despues de separar el vapor de agua y los constituyentes secundarios, en una zona de dimerizacion y dimerizar cataliticamente el butadieno, para suministrar una corriente de productos que comprende el 4-vinilciclohexeno, n-butano y posiblemente el 1-buteno, 2-buteno y el butadieno sin reaccionar; y(D) separar el 4-vinilciclohexeno de la corriente del producto desde la dimerizacion y recircular el n-butano y posiblemente el 1-buteno, 2-buteno y el butadieno sin reaccionar, a la zona de deshidrogenacion.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10206954 | 2002-02-19 | ||
| DE2002131633 DE10231633A1 (de) | 2002-07-12 | 2002-07-12 | Verfahren zur Herstellung von 4-Vinylcyclohexanen, Ethylbenzol und Styrol |
| PCT/EP2003/001577 WO2003070671A1 (de) | 2002-02-19 | 2003-02-17 | Verfahren zur herstellung von 4-vinylcyclohexen, ethylbenzol und styrol |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MXPA04007393A true MXPA04007393A (es) | 2004-10-11 |
Family
ID=27758396
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MXPA04007393A MXPA04007393A (es) | 2002-02-19 | 2003-02-17 | Preparacion del 4-vinilciclohexeno, el etilbenceno y el estireno. |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US7193121B2 (es) |
| EP (1) | EP1478610B1 (es) |
| JP (1) | JP4368201B2 (es) |
| KR (2) | KR100976906B1 (es) |
| CN (1) | CN1314637C (es) |
| AT (1) | ATE420062T1 (es) |
| AU (1) | AU2003214061B2 (es) |
| BR (1) | BR0307305A (es) |
| CA (1) | CA2474762A1 (es) |
| DE (1) | DE50311049D1 (es) |
| ES (1) | ES2316735T3 (es) |
| MX (1) | MXPA04007393A (es) |
| MY (1) | MY134442A (es) |
| NO (1) | NO20043872L (es) |
| RU (1) | RU2350593C2 (es) |
| TW (1) | TWI329626B (es) |
| WO (1) | WO2003070671A1 (es) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070225536A1 (en) * | 2006-03-23 | 2007-09-27 | Eugene Frederick Lutz | Olefin conversion process and olefin recovery process |
| EP2225351A4 (en) | 2007-12-03 | 2016-11-09 | Gevo Inc | RENEWABLE COMPOSITIONS |
| CN102770397A (zh) | 2010-01-08 | 2012-11-07 | 格沃股份有限公司 | 制备可再生的化学品的整合方法 |
| US8373012B2 (en) | 2010-05-07 | 2013-02-12 | Gevo, Inc. | Renewable jet fuel blendstock from isobutanol |
| DE102011006721A1 (de) * | 2011-04-04 | 2012-10-04 | Evonik Oxeno Gmbh | Verfahren zur Herstellung von 1-Buten und einem 1,3-Butadienderivat |
| EP2699618A4 (en) | 2011-04-19 | 2014-12-17 | Gevo Inc | VARIATIONS OF A PRINS REACTION FOR THE PREPARATION OF 2,5-DIMETHYLHEXADIENE FROM ISOBUTANOL |
| US8173852B1 (en) | 2011-05-17 | 2012-05-08 | Uop Llc | Methods and apparatuses for producing styrene from ethylbenzene |
| CN113042073B (zh) * | 2021-03-24 | 2023-03-03 | 石河子大学 | 一种用于乙炔二聚反应的催化剂及其应用 |
| EP4598897A1 (en) * | 2022-11-18 | 2025-08-13 | Uop Llc | Processes and apparatuses for separating chlorides from n-butane |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US238631A (en) * | 1881-03-08 | Dynamo or magneto electric machine | ||
| US2376985A (en) * | 1942-05-23 | 1945-05-29 | Standard Oil Co | Production of styrene from butadiene |
| US2438041A (en) * | 1944-08-22 | 1948-03-16 | Phillips Petroleum Co | Process of producing styrene from butadiene |
| US3161670A (en) * | 1960-12-12 | 1964-12-15 | Shell Oil Co | Preparation of olefinic compounds |
| US3502736A (en) * | 1966-09-12 | 1970-03-24 | Maruzen Oil Co Ltd | Oxidative dehydrogenation of non-aromatic cyclic hydrocarbon having at least one unsaturated bond in side chain |
| US4029715A (en) * | 1976-08-24 | 1977-06-14 | Atlantic Richfield Company | Preparation of ethyl benzene |
| SU1616885A1 (ru) * | 1988-05-24 | 1990-12-30 | Предприятие П/Я А-7345 | Способ получени стирола |
| US5196621A (en) * | 1991-04-19 | 1993-03-23 | The Dow Chemical Company | Process for the cyclodimerization of 1,3-butadienes to 4-vinylcyclohexenes |
| US5300719A (en) | 1992-07-09 | 1994-04-05 | The Dow Chemical Company | Dehydrocyclization of unsaturated hydrocarbons to aromatic products |
| KR100271890B1 (ko) | 1992-10-22 | 2000-11-15 | 그래햄 이. 테일러 | 1,3-부타디엔을 4-비닐사이클로헥센으로 사이클로이량체화하는 방법 |
| US5321180A (en) * | 1993-05-05 | 1994-06-14 | Union Carbide Chemicals & Plastics Technology Corporation | Conversion of vinylcyclohexene to ethylbenzene |
| RU2111946C1 (ru) * | 1995-12-15 | 1998-05-27 | Товарищество с ограниченной ответственностью "Научно-исследовательский центр по нефтехимическим технологиям" | Способ получения 4-винилциклогексена-1 |
-
2003
- 2003-02-17 RU RU2004128086/04A patent/RU2350593C2/ru not_active IP Right Cessation
- 2003-02-17 DE DE50311049T patent/DE50311049D1/de not_active Expired - Lifetime
- 2003-02-17 AU AU2003214061A patent/AU2003214061B2/en not_active Ceased
- 2003-02-17 EP EP03709709A patent/EP1478610B1/de not_active Expired - Lifetime
- 2003-02-17 KR KR1020047012778A patent/KR100976906B1/ko not_active Expired - Fee Related
- 2003-02-17 MY MYPI20030539A patent/MY134442A/en unknown
- 2003-02-17 BR BR0307305-0A patent/BR0307305A/pt not_active IP Right Cessation
- 2003-02-17 US US10/501,876 patent/US7193121B2/en not_active Expired - Fee Related
- 2003-02-17 ES ES03709709T patent/ES2316735T3/es not_active Expired - Lifetime
- 2003-02-17 KR KR1020107009435A patent/KR100989208B1/ko not_active Expired - Fee Related
- 2003-02-17 CA CA002474762A patent/CA2474762A1/en not_active Abandoned
- 2003-02-17 MX MXPA04007393A patent/MXPA04007393A/es active IP Right Grant
- 2003-02-17 WO PCT/EP2003/001577 patent/WO2003070671A1/de not_active Ceased
- 2003-02-17 JP JP2003569581A patent/JP4368201B2/ja not_active Expired - Fee Related
- 2003-02-17 AT AT03709709T patent/ATE420062T1/de not_active IP Right Cessation
- 2003-02-17 CN CNB038042118A patent/CN1314637C/zh not_active Expired - Fee Related
- 2003-02-18 TW TW092103301A patent/TWI329626B/zh active
-
2004
- 2004-09-15 NO NO20043872A patent/NO20043872L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| NO20043872L (no) | 2004-09-15 |
| EP1478610A1 (de) | 2004-11-24 |
| BR0307305A (pt) | 2005-01-04 |
| KR20100051135A (ko) | 2010-05-14 |
| AU2003214061A1 (en) | 2003-09-09 |
| KR100989208B1 (ko) | 2010-10-20 |
| AU2003214061B2 (en) | 2009-03-12 |
| DE50311049D1 (de) | 2009-02-26 |
| TWI329626B (en) | 2010-09-01 |
| CN1635985A (zh) | 2005-07-06 |
| US7193121B2 (en) | 2007-03-20 |
| KR100976906B1 (ko) | 2010-08-18 |
| RU2350593C2 (ru) | 2009-03-27 |
| MY134442A (en) | 2007-12-31 |
| US20040260132A1 (en) | 2004-12-23 |
| RU2004128086A (ru) | 2005-06-10 |
| JP2005525349A (ja) | 2005-08-25 |
| EP1478610B1 (de) | 2009-01-07 |
| TW200306290A (en) | 2003-11-16 |
| WO2003070671A1 (de) | 2003-08-28 |
| CA2474762A1 (en) | 2003-08-28 |
| JP4368201B2 (ja) | 2009-11-18 |
| KR20040091640A (ko) | 2004-10-28 |
| CN1314637C (zh) | 2007-05-09 |
| ATE420062T1 (de) | 2009-01-15 |
| ES2316735T3 (es) | 2009-04-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant or registration |