MXPA02012369A - Procedimiento para la obtencion de esteres de acido hidroxifenilcarboxilico. - Google Patents
Procedimiento para la obtencion de esteres de acido hidroxifenilcarboxilico.Info
- Publication number
- MXPA02012369A MXPA02012369A MXPA02012369A MXPA02012369A MXPA02012369A MX PA02012369 A MXPA02012369 A MX PA02012369A MX PA02012369 A MXPA02012369 A MX PA02012369A MX PA02012369 A MXPA02012369 A MX PA02012369A MX PA02012369 A MXPA02012369 A MX PA02012369A
- Authority
- MX
- Mexico
- Prior art keywords
- alkali
- carboxylic acid
- cmh2m
- alkyl
- formula
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical class OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 title 1
- 150000001447 alkali salts Chemical class 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 4
- 239000003513 alkali Substances 0.000 abstract 3
- 150000001735 carboxylic acids Chemical class 0.000 abstract 3
- 239000001257 hydrogen Substances 0.000 abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 150000002431 hydrogen Chemical group 0.000 abstract 2
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 abstract 1
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 abstract 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 abstract 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 abstract 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000007935 neutral effect Effects 0.000 abstract 1
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Un procedimiento para la obtencion de compuestos de la formula (I): (ver formula) en la cual: R1 y R2 , independientemente uno del otro, significan alquilo con 1 a 8 atomos de carbono, ciclopentilo o ciclohexilo, m es 1,2 o 3, de preferencia 2, n es un numero entero de 1 a 30, y R3 es un radical de valencia n, de alquilo con 4 a 30 atomos de carbono, lineal o ramificado, el cual esta eventualmente interrumpido por uno o varios atomos de oxigeno, o (si n=1-12) un radical de valencia n, de cicloalquilo con 5 a 12 atomos de carbono, o un radical R4- [NR5 - CmH2rn- (p, R4 es hidrogeno, un radical de valencia n, de alquilo con 4 a 30 atomos de carbono, lineal o ramificado, el cual esta eventualmente interrumpido por uno o varios grupos -NR5-, o (si n=1-12) un radical de valencia n, de cicloalquilo con 5 a 12 atomos de carbono, R5 independientemente uno de otro es hidrogeno o metilo o -CmH2m-, de preferencia hidrogeno, y p concuerda con aquel numero de grupos -[NR5-Cm- H2m-], que arroje n radicales -CmH2m- por molecula, mediante la reaccion de un compuesto de la formula (II): (ver formula II) en la cual: R es alquilo con 1 a 3 atomos de carbono, con un compuesto de la formula (III): R3(OH)n (III) en la cual: R3 y n tienen el significado indicado anteriormente, caracterizado porque la reaccion tiene lugar a un valor acido (pH) practicamente neutral y en presencia de cuando menos una sal alcalina de un acido carboxilico organico, disuelta o suspendida en la mezcla de reaccion, o de una mezcla de este tipo de sales alcalinas, en donde (i) esta sal alcalina esta formada por un cation alcalino y un anion de un acido carboxilico organico, y (ii) el acido carboxilico organico es cuando menos parcialmente volatil bajo las condiciones de reaccion utilizadas. Las sales alcalinas preferidas son formiato alcalino y acetato alcalino.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH12512000 | 2000-06-23 | ||
| CH3122001 | 2001-02-22 | ||
| PCT/CH2001/000370 WO2001098249A1 (de) | 2000-06-23 | 2001-06-14 | Verfahren zur herstellung von hydroxyphenylcarbonsäureestern |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MXPA02012369A true MXPA02012369A (es) | 2003-04-25 |
Family
ID=25735909
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MXPA02012369A MXPA02012369A (es) | 2000-06-23 | 2001-06-14 | Procedimiento para la obtencion de esteres de acido hidroxifenilcarboxilico. |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US6878843B2 (es) |
| EP (1) | EP1292560B1 (es) |
| JP (1) | JP4925547B2 (es) |
| KR (1) | KR100813185B1 (es) |
| CN (1) | CN1250513C (es) |
| AT (1) | ATE320412T1 (es) |
| AU (1) | AU2001263698A1 (es) |
| BR (1) | BR0111876B1 (es) |
| CA (1) | CA2412062C (es) |
| CZ (1) | CZ301602B6 (es) |
| DE (1) | DE50109215D1 (es) |
| ES (1) | ES2259325T3 (es) |
| MX (1) | MXPA02012369A (es) |
| RU (1) | RU2272022C2 (es) |
| WO (1) | WO2001098249A1 (es) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2259413T3 (es) * | 2002-04-26 | 2006-10-01 | Ciba Specialty Chemicals Holding Inc. | Fotoiniciador incorporable. |
| GB0324964D0 (en) * | 2003-10-27 | 2003-11-26 | Great Lakes Chemical Europ | Preparation of hydroxyphenyl carboxylic acid esters |
| WO2008055832A2 (en) * | 2006-11-09 | 2008-05-15 | Ciba Holding Inc. | Process using liquid phenolic antioxidants |
| CN104334684B (zh) | 2012-07-31 | 2019-08-27 | 株式会社艾迪科 | 潜伏性添加剂以及含有该添加剂的组合物 |
| WO2015119721A1 (en) | 2014-02-07 | 2015-08-13 | C. R. Bard, Inc. | Eptfe valves |
| ES2688470T3 (es) | 2015-03-10 | 2018-11-02 | Evonik Degussa Gmbh | Antioxidantes para la preparación de sistemas de PUR de baja emisión |
| CN105294441B (zh) * | 2015-12-10 | 2017-09-15 | 中国科学院新疆理化技术研究所 | 抗氧化剂八[β‑（3,5‑二叔丁基‑4‑羟基苯基）丙酸]三季戊四醇酯的合成方法 |
| CN106674002A (zh) * | 2016-12-28 | 2017-05-17 | 天津利安隆新材料股份有限公司 | 受阻酚类抗氧剂的制备方法 |
| US20220121113A1 (en) | 2019-01-23 | 2022-04-21 | Basf Se | Oxime ester photoinitiators having a special aroyl chromophore |
| JP7703554B2 (ja) | 2020-03-04 | 2025-07-07 | ベーアーエスエフ・エスエー | オキシムエステル光開始剤 |
| CN114835991A (zh) * | 2022-06-10 | 2022-08-02 | 安徽顺彤包装材料有限公司 | 一种水性转印膜及其制备工艺 |
| EP4318166B1 (en) | 2022-08-05 | 2025-10-08 | Volocopter Technologies GmbH | Method of controlling a transition aircraft and transition aircraft |
| CN116178144A (zh) * | 2023-02-10 | 2023-05-30 | 濮阳市中原石化实业有限公司 | 一种高效合成抗氧剂245的方法 |
| WO2025011754A1 (en) | 2023-07-10 | 2025-01-16 | Basf Se | Photocurable as well as thermally curable compositions suitable for low temperature curing |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3644482A (en) * | 1961-10-30 | 1972-02-22 | Geigy Ag J R | (4-hydroxy-5-alkylphenyl) alkanoic acid esters of polyols |
| CH454171A (de) | 1964-06-02 | 1968-04-15 | Geigy Ag J R | Verfahren zur Herstellung organischer Ester |
| CH471769A (de) * | 1965-08-02 | 1969-04-30 | Geigy Ag J R | Verfahren zur Herstellung von Hydroxyphenylfettsäureestern |
| US3435065A (en) * | 1965-10-22 | 1969-03-25 | Geigy Chem Corp | N,n,n',n' - (ethylenediamine) - tetrakis (ethylene - 3 - (3',5' - di-tert-butyl-4' - hydroxyphenyl)propionate) and compositions stabilized therewith |
| SU1014213A1 (ru) * | 1981-07-15 | 1991-07-30 | Научно-исследовательский институт химикатов для полимерных материалов | Способ получени пентаэритрил-тетракис-[ @ -(3,5-дитрет-бутил-4-оксифенил)-пропионата] |
| US4536593A (en) * | 1982-07-13 | 1985-08-20 | Ciba-Geigy Corporation | Process for the preparation of sterically hindered hydroxphenylcarboxylic acid esters |
| US4594444A (en) | 1983-12-22 | 1986-06-10 | Ciba-Geigy Corporation | Process for the preparation of sterically hindered hydroxyphenylcarboxylic acid esters |
| US4716244A (en) * | 1985-05-02 | 1987-12-29 | Ciba-Geigy Corporation | Process for the preparation of sterically hindered hydroxyphenylcarboxylic acid esters |
| US5206414A (en) * | 1990-01-11 | 1993-04-27 | Ciba-Geigy Corporation | Process for the preparation of hydroxyphenylpropionic acid esters |
| US5136082A (en) | 1990-08-03 | 1992-08-04 | Himont Incorporated | Process for preparing organic esters and amides and catalyst system therefor |
| TW212790B (es) * | 1991-10-15 | 1993-09-11 | Ciba Geigy Ag | |
| EP0608089B1 (en) * | 1993-01-21 | 1997-10-15 | Sankyo Company Limited | Phenylalkanoic acid esters and their use as antioxidants |
| TW289752B (es) | 1994-03-11 | 1996-11-01 | Ciba Geigy Ag | |
| EP0808818B1 (en) * | 1996-05-23 | 2000-09-20 | Ciba SC Holding AG | Process for the preparation of substituted hydroxy-hydrocinnamate esters |
| KR20000069479A (ko) | 1996-12-20 | 2000-11-25 | 시바 스폐셜티 케미칼스 홀딩 인코포레이티드 | 고형 기재 재료상에 고정된 에스테르 교환 반응 촉매 |
-
2001
- 2001-06-14 CZ CZ20030108A patent/CZ301602B6/cs not_active IP Right Cessation
- 2001-06-14 BR BRPI0111876-5A patent/BR0111876B1/pt not_active IP Right Cessation
- 2001-06-14 JP JP2002504205A patent/JP4925547B2/ja not_active Expired - Fee Related
- 2001-06-14 US US10/311,724 patent/US6878843B2/en not_active Expired - Lifetime
- 2001-06-14 CN CNB018115365A patent/CN1250513C/zh not_active Expired - Fee Related
- 2001-06-14 EP EP01937911A patent/EP1292560B1/de not_active Expired - Lifetime
- 2001-06-14 AT AT01937911T patent/ATE320412T1/de not_active IP Right Cessation
- 2001-06-14 AU AU2001263698A patent/AU2001263698A1/en not_active Abandoned
- 2001-06-14 RU RU2003100511/04A patent/RU2272022C2/ru not_active IP Right Cessation
- 2001-06-14 CA CA2412062A patent/CA2412062C/en not_active Expired - Fee Related
- 2001-06-14 DE DE50109215T patent/DE50109215D1/de not_active Expired - Lifetime
- 2001-06-14 ES ES01937911T patent/ES2259325T3/es not_active Expired - Lifetime
- 2001-06-14 KR KR1020027016517A patent/KR100813185B1/ko not_active Expired - Fee Related
- 2001-06-14 WO PCT/CH2001/000370 patent/WO2001098249A1/de not_active Ceased
- 2001-06-14 MX MXPA02012369A patent/MXPA02012369A/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| AU2001263698A1 (en) | 2002-01-02 |
| CN1250513C (zh) | 2006-04-12 |
| ES2259325T3 (es) | 2006-10-01 |
| KR20030007861A (ko) | 2003-01-23 |
| CZ301602B6 (cs) | 2010-04-28 |
| BR0111876A (pt) | 2003-06-24 |
| CA2412062A1 (en) | 2001-12-27 |
| RU2272022C2 (ru) | 2006-03-20 |
| US6878843B2 (en) | 2005-04-12 |
| EP1292560A1 (de) | 2003-03-19 |
| EP1292560B1 (de) | 2006-03-15 |
| JP2004501128A (ja) | 2004-01-15 |
| BR0111876B1 (pt) | 2012-09-18 |
| DE50109215D1 (de) | 2006-05-11 |
| CA2412062C (en) | 2011-09-20 |
| US20030166962A1 (en) | 2003-09-04 |
| WO2001098249A1 (de) | 2001-12-27 |
| CZ2003108A3 (cs) | 2003-05-14 |
| JP4925547B2 (ja) | 2012-04-25 |
| KR100813185B1 (ko) | 2008-03-17 |
| ATE320412T1 (de) | 2006-04-15 |
| CN1437572A (zh) | 2003-08-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant or registration |