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MX9705608A - Catalizador de oxido de alquileno y proceso. - Google Patents

Catalizador de oxido de alquileno y proceso.

Info

Publication number
MX9705608A
MX9705608A MX9705608A MX9705608A MX9705608A MX 9705608 A MX9705608 A MX 9705608A MX 9705608 A MX9705608 A MX 9705608A MX 9705608 A MX9705608 A MX 9705608A MX 9705608 A MX9705608 A MX 9705608A
Authority
MX
Mexico
Prior art keywords
weight
alkylene oxide
oxide catalyst
organic polymer
parts
Prior art date
Application number
MX9705608A
Other languages
English (en)
Other versions
MX198419B (es
MXPA97005608A (es
Inventor
John Edward Buffum
Ruth Mary Kowaleski
John Robert Lockemeyer
Marek Matusz
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Publication of MX9705608A publication Critical patent/MX9705608A/es
Publication of MXPA97005608A publication Critical patent/MXPA97005608A/es
Publication of MX198419B publication Critical patent/MX198419B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/688—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • B01J27/26—Cyanides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4866—Polyethers having a low unsaturation value
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2663—Metal cyanide catalysts, i.e. DMC's

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Health & Medical Sciences (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Esta invencion se refiere a un catalizador de oxido de alquileno el cual contiene plata y uno o más promotores de metal alcalino, soportados sobre un portador preparado mediante un proceso que comprende mezclar componentes cerámicos en forma de partículas, con una cantidad de 0.5 a 50 partes en peso en base a 100 partes de los componentes cerámicos, de un polímero orgánico sintético en la forma de un polvo que tiene un tamaño promedio de partícula de menos de 400 micrometros y un contenido de ceniza de menos de 0.1 % en peso, y luego cocer u hornear a una temperatura suficiente para quemar el polímero orgánico sintético, sintetizar el componente en forma de partículas y formar un portador o soporte.
MX9705608A 1995-02-01 1996-01-31 Catalizador de oxido de alquileno y proceso. MX198419B (es)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US38302095A 1995-02-01 1995-02-01
US383020 1995-02-01
US383,020 1995-02-01
PCT/EP1996/000444 WO1996023585A1 (en) 1995-02-01 1996-01-31 Alkylene oxide catalyst and process

Publications (3)

Publication Number Publication Date
MX9705608A true MX9705608A (es) 1997-10-31
MXPA97005608A MXPA97005608A (es) 1998-07-03
MX198419B MX198419B (es) 2000-09-01

Family

ID=23511366

Family Applications (1)

Application Number Title Priority Date Filing Date
MX9705608A MX198419B (es) 1995-02-01 1996-01-31 Catalizador de oxido de alquileno y proceso.

Country Status (10)

Country Link
EP (1) EP0808215B1 (es)
JP (1) JP3953101B2 (es)
CN (1) CN1090057C (es)
AU (1) AU690809B2 (es)
CA (1) CA2211312C (es)
DE (1) DE69600628T2 (es)
ES (1) ES2120804T3 (es)
MX (1) MX198419B (es)
TW (1) TW328916B (es)
WO (1) WO1996023585A1 (es)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5801259A (en) * 1996-04-30 1998-09-01 Shell Oil Company Ethylene oxide catalyst and process
WO1997046317A1 (en) * 1996-06-05 1997-12-11 Shell Internationale Research Maatschappij B.V. Epoxidation catalyst and process
US7504525B2 (en) 1998-09-14 2009-03-17 Shell Oil Company Catalyst composition
US7232918B2 (en) 2001-11-06 2007-06-19 Shell Oil Company Catalyst composition
TR200100749T2 (tr) 1998-09-14 2001-10-22 Shell Internationale Research Maatschappij B.V. Epoksitleme katalizörü taşıyıcı, bunun hazırlanması ve kullanılması
ATE391552T1 (de) * 1998-09-14 2008-04-15 Shell Int Research Verfahren zur herstellung von katalysatoren mit verbesserten katalytischen eigenschaften
US7232786B2 (en) 1998-09-14 2007-06-19 Shell Oil Company Catalyst composition
RU2232049C2 (ru) 1998-09-14 2004-07-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ удаления ионизируемых частиц с поверхности катализатора для улучшения каталитических свойств
JP4537848B2 (ja) 2002-06-28 2010-09-08 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 触媒の選択性を改善する方法及びオレフィンのエポキシ化方法
CA2490892C (en) * 2002-06-28 2012-03-20 Shell Internationale Research Maatschappij B.V. A method for the start-up of an epoxidation process, a catalyst and a process for the epoxidation of an olefin
US20040224841A1 (en) 2003-05-07 2004-11-11 Marek Matusz Silver-containing catalysts, the manufacture of such silver-containing catalysts, and the use thereof
CA2524890C (en) 2003-05-07 2012-09-11 Shell Internationale Research Maatschappij B.V. Silver-containing catalysts, the manufacture of such silver­containing catalysts, and the use thereof
US8148555B2 (en) 2003-06-26 2012-04-03 Shell Oil Company Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin
TW200600190A (en) 2004-04-01 2006-01-01 Shell Int Research Process for preparing a silver catalyst, the catalyst, and use thereof in olefin oxidation
TW200613056A (en) * 2004-04-01 2006-05-01 Shell Int Research A process for preparing a silver catalyst, the catalyst, and a use of the catalyst for olefin oxidation
CN101405077B (zh) * 2006-02-10 2011-09-14 国际壳牌研究有限公司 制备催化剂的方法、催化剂和制备环氧烷、1，2-二醇、1，2-二醇醚或链烷醇胺的方法
US8501664B2 (en) 2006-11-20 2013-08-06 Shell Oil Company Process for treating a carrier, a process for preparing a catalyst, the catalyst, and use of the catalyst
CN103599798B (zh) 2007-05-09 2015-11-18 国际壳牌研究有限公司 环氧化催化剂及其制备方法和生产环氧烷、1,2-二醇、1,2-二醇醚、1,2-碳酸酯或烷醇胺的方法
US8187561B2 (en) * 2007-12-05 2012-05-29 Ames Goldsmith Corporation Processes and systems for recovering catalyst promoter from catalyst substrates
CN102056909B (zh) 2008-05-07 2014-03-05 国际壳牌研究有限公司 环氧化工艺的开车方法及环氧乙烷、1，2-二醇、1，2-二醇醚、1，2-碳酸酯或链烷醇胺的制备方法
PL2297125T3 (pl) 2008-05-07 2013-12-31 Shell Int Research Sposób wytwarzania tlenku olefiny, 1,2-diolu, eteru 1,2-diolu, 1,2-węglanu albo alkanoloaminy
US8933254B2 (en) 2008-07-14 2015-01-13 Basf Se Process for making ethylene oxide
US8524927B2 (en) 2009-07-13 2013-09-03 Velocys, Inc. Process for making ethylene oxide using microchannel process technology
TWI712577B (zh) 2015-06-02 2020-12-11 美商科學設計有限公司 具有增強的孔結構的多孔體
TWI774707B (zh) 2016-12-02 2022-08-21 荷蘭商蜆殼國際研究所 用於調節乙烯環氧化催化劑之方法及用於製造環氧乙烷之相關方法
US10449520B2 (en) 2017-05-15 2019-10-22 Scientific Design Company, Inc. Porous bodies with enhanced crush strength
US10676401B2 (en) 2018-04-23 2020-06-09 Scientific Design Company, Inc. Porous bodies with enhanced pore architecture prepared with oxalic acid

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4428863A (en) * 1982-07-06 1984-01-31 The Dow Chemical Company Alumina compositions of improved strength useful as catalyst supports
GB8610441D0 (en) * 1986-04-29 1986-06-04 Shell Int Research Preparation of silver-containing catalyst
CN1009437B (zh) * 1988-02-03 1990-09-05 中国石油化工总公司 乙烯氧化制环氧乙烷高效银催化剂
JP2637537B2 (ja) * 1989-01-24 1997-08-06 株式会社日本触媒 エチレンオキシド製造用銀触媒およびその製造方法
US5187140A (en) * 1989-10-18 1993-02-16 Union Carbide Chemicals & Plastics Technology Corporation Alkylene oxide catalysts containing high silver content
US5447897A (en) * 1993-05-17 1995-09-05 Shell Oil Company Ethylene oxide catalyst and process

Also Published As

Publication number Publication date
DE69600628T2 (de) 1999-02-25
DE69600628D1 (de) 1998-10-15
AU4540196A (en) 1996-08-21
ES2120804T3 (es) 1998-11-01
JPH10513106A (ja) 1998-12-15
WO1996023585A1 (en) 1996-08-08
CN1172441A (zh) 1998-02-04
EP0808215A1 (en) 1997-11-26
TW328916B (en) 1998-04-01
MX198419B (es) 2000-09-01
CA2211312C (en) 2007-07-03
CN1090057C (zh) 2002-09-04
EP0808215B1 (en) 1998-09-09
AU690809B2 (en) 1998-04-30
CA2211312A1 (en) 1996-08-08
JP3953101B2 (ja) 2007-08-08

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Legal Events

Date Code Title Description
FG Grant or registration
MM Annulment or lapse due to non-payment of fees