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MX2022011684A - Composicion novedosa de materia y sistemas de captura de dioxido de carbono. - Google Patents

Composicion novedosa de materia y sistemas de captura de dioxido de carbono.

Info

Publication number
MX2022011684A
MX2022011684A MX2022011684A MX2022011684A MX2022011684A MX 2022011684 A MX2022011684 A MX 2022011684A MX 2022011684 A MX2022011684 A MX 2022011684A MX 2022011684 A MX2022011684 A MX 2022011684A MX 2022011684 A MX2022011684 A MX 2022011684A
Authority
MX
Mexico
Prior art keywords
sub
carbon dioxide
monolith
matter
dioxide capture
Prior art date
Application number
MX2022011684A
Other languages
English (en)
Inventor
Peter Eisenberger
Eric W Ping
Miles Sakwa-Novak
Original Assignee
Global Thermostat Operations Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Global Thermostat Operations Llc filed Critical Global Thermostat Operations Llc
Publication of MX2022011684A publication Critical patent/MX2022011684A/es

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/0407—Constructional details of adsorbing systems
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B01J20/262—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon to carbon unsaturated bonds, e.g. obtained by polycondensation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/06—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/62—Carbon oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/96—Regeneration, reactivation or recycling of reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28042—Shaped bodies; Monolithic structures
    • B01J20/28045—Honeycomb or cellular structures; Solid foams or sponges
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078—Pore diameter
    • B01J20/28083—Pore diameter being in the range 2-50 nm, i.e. mesopores
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078—Pore diameter
    • B01J20/28085—Pore diameter being more than 50 nm, i.e. macropores
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28088—Pore-size distribution
    • B01J20/28092—Bimodal, polymodal, different types of pores or different pore size distributions in different parts of the sorbent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3425—Regenerating or reactivating of sorbents or filter aids comprising organic materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3483—Regenerating or reactivating by thermal treatment not covered by groups B01J20/3441 - B01J20/3475, e.g. by heating or cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/104—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/108—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20—Organic adsorbents
    • B01D2253/202—Polymeric adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20—Organic adsorbents
    • B01D2253/204—Metal organic frameworks (MOF's)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/25—Coated, impregnated or composite adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/31—Pore size distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/311—Porosity, e.g. pore volume
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
    • B01D2259/40088—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating
    • B01D2259/4009—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating using hot gas
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Nanotechnology (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Sustainable Development (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Treating Waste Gases (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Gas Separation By Absorption (AREA)
  • Separation Of Gases By Adsorption (AREA)

Abstract

Se proporciona un sustrato monolítico estructuralmente estable, adecuado para proporcionar una estructura de captura de dióxido de carbono para eliminar el dióxido de carbono del aire, que tiene dos superficies opuestas principales y que tiene además una pluralidad de canales longitudinales que se extienden entre las dos superficies opuestas principales y se abren a través de las dos superficies opuestas estructuralmente. sustrato monolítico estable; y un revestimiento macroporoso, adherido a las superficies de las paredes interiores de los canales longitudinales, que comprende un revestimiento adherente formado por partículas mesoporosas compactas y unidas, cada una de las cuales está formada por un material que es compatible con el material que forma la estructura del sustrato subyacente para adherirse al mismo cuando está recubierto. Las partículas mesoporosas son capaces de soportar en sus mesoporos un sorbente de CO2. También se proporciona un método para formar el monolito y un sistema para utilizar el monolito como parte de una estructura de captura de C02, dentro del sistema, para eliminar el CO2 de la atmósfera.
MX2022011684A 2020-03-20 2021-03-22 Composicion novedosa de materia y sistemas de captura de dioxido de carbono. MX2022011684A (es)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US202062992782P 2020-03-20 2020-03-20
US202062705061P 2020-06-09 2020-06-09
US202063198418P 2020-10-16 2020-10-16
PCT/US2021/023473 WO2021189042A1 (en) 2020-03-20 2021-03-22 Novel composition of matter & carbon dioxide capture systems

Publications (1)

Publication Number Publication Date
MX2022011684A true MX2022011684A (es) 2023-03-17

Family

ID=77771647

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2022011684A MX2022011684A (es) 2020-03-20 2021-03-22 Composicion novedosa de materia y sistemas de captura de dioxido de carbono.

Country Status (12)

Country Link
US (1) US20230149896A1 (es)
EP (1) EP4121196A4 (es)
JP (1) JP2023520609A (es)
KR (1) KR20220151703A (es)
CN (1) CN116406309A (es)
AU (1) AU2021236762A1 (es)
BR (1) BR112022018872A2 (es)
CA (1) CA3176388A1 (es)
IL (1) IL296641A (es)
MX (1) MX2022011684A (es)
WO (1) WO2021189042A1 (es)
ZA (1) ZA202210845B (es)

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MX2022015831A (es) 2020-06-09 2023-03-03 Global Thermostat Operations Llc Sistema de captura directa en aire en movimiento continuo.
EP4166215A1 (en) * 2021-10-12 2023-04-19 TotalEnergies OneTech A carbon dioxide removal installation and associated method
EP4440737A1 (en) * 2021-11-29 2024-10-09 Cormetech, Inc. Structural gas treatment bodies for carbon capture
US20230213246A1 (en) * 2022-01-02 2023-07-06 AirMyne, Inc. Using Carbon Dioxide From A Direct Air Capture System As A Low Global Warming Car And Industrial Refrigerant
CA3256296A1 (en) * 2022-05-13 2023-11-16 Shell Internationale Research Maatschappij B.V. CARBON DIOXIDE CAPTURE PROCESS
IL316964A (en) 2022-05-27 2025-01-01 Zero Carbon Systems Inc High-output moving plate direct air capture system
EP4543564A1 (en) * 2022-06-21 2025-04-30 Shell Internationale Research Maatschappij B.V. A unit design and process for direct capture of carbon dioxide from air
AU2023288718B2 (en) * 2022-06-21 2026-01-29 Shell Internationale Research Maatschappij B.V. A unit design and process for direct capture of carbon dioxide from air
US11944931B2 (en) 2022-06-24 2024-04-02 Climeworks Ag Direct air capture device
WO2023247481A1 (en) 2022-06-24 2023-12-28 Climeworks Ag Direct air capture device
KR102806233B1 (ko) * 2022-08-25 2025-05-15 주식회사 퀀텀캣 코어-쉘 구조의 복합체 입자 및 이의 제조방법
WO2025165339A2 (en) * 2022-10-27 2025-08-07 Georgia Tech Research Corporation Sorbent coated carbon fibers and their modules for reducing carbon dioxide using electrically driven temperature swing adsorption system
EP4637962A2 (en) * 2022-12-20 2025-10-29 W. L. Gore & Associates, Inc. Shelving unit with water management and integrated heating for sorbent articles in direct air capture systems
EP4658399A1 (en) 2023-02-03 2025-12-10 Shell Internationale Research Maatschappij B.V. Sorbent structures for carbon dioxide capture and methods for making thereof
WO2024160605A1 (en) 2023-02-03 2024-08-08 Shell Internationale Research Maatschappij B.V. Sorbent structures for carbon dioxide capture
WO2024188752A1 (en) * 2023-03-13 2024-09-19 Shell Internationale Research Maatschappij B.V. Processes and systems for regeneration of a sorbent
CN120826266A (zh) * 2023-03-13 2025-10-21 国际壳牌研究有限公司 用于再生吸附剂的方法和系统
NO20230416A1 (en) * 2023-04-17 2024-10-18 Knutsen Tech As Systems and methods relating to direct air capture of co2
US20250018362A1 (en) * 2023-07-14 2025-01-16 Battelle Savannah River Alliance, Llc Off-gas filter for capturing volatile elements
WO2025165710A1 (en) * 2024-01-29 2025-08-07 Siemens Energy Global GmbH & Co. KG Apparatus of robotic dac operation and method for continuous dac operation

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US9925488B2 (en) * 2010-04-30 2018-03-27 Peter Eisenberger Rotating multi-monolith bed movement system for removing CO2 from the atmosphere
US20130207034A1 (en) * 2012-02-09 2013-08-15 Corning Incorporated Substrates for carbon dioxide capture and methods for making same
WO2017095765A1 (en) * 2015-11-30 2017-06-08 Corning Incorporated Carbon dioxide capture articles and methods of making the same
ES2986300T3 (es) * 2016-11-14 2024-11-11 Georgia Tech Res Inst Material compuesto que comprende poliamina
US11298675B2 (en) * 2017-09-20 2022-04-12 The Curators Of The University Of Missouri 3D printed zeolite monoliths for CO2 removal
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CA3030416A1 (en) * 2018-01-18 2019-07-18 Research Triangle Institute Polyamine phosphorus dendrimer materials for carbon dioxide capture
CA3091524A1 (en) * 2018-02-16 2019-08-22 Carbon Sink, Inc. Fluidized bed extractors for capture of co2 from ambient air

Also Published As

Publication number Publication date
CN116406309A (zh) 2023-07-07
CA3176388A1 (en) 2021-09-23
BR112022018872A2 (pt) 2022-12-13
US20230149896A1 (en) 2023-05-18
JP2023520609A (ja) 2023-05-17
AU2021236762A1 (en) 2022-10-20
EP4121196A4 (en) 2024-12-11
EP4121196A1 (en) 2023-01-25
IL296641A (en) 2022-11-01
KR20220151703A (ko) 2022-11-15
ZA202210845B (en) 2024-01-31
WO2021189042A1 (en) 2021-09-23

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