MX2020002962A - Composiciones adhesivas acrilicas y metodos para fabricarlas. - Google Patents
Composiciones adhesivas acrilicas y metodos para fabricarlas.Info
- Publication number
- MX2020002962A MX2020002962A MX2020002962A MX2020002962A MX2020002962A MX 2020002962 A MX2020002962 A MX 2020002962A MX 2020002962 A MX2020002962 A MX 2020002962A MX 2020002962 A MX2020002962 A MX 2020002962A MX 2020002962 A MX2020002962 A MX 2020002962A
- Authority
- MX
- Mexico
- Prior art keywords
- weight
- reactor
- adhesive compositions
- weight percent
- monomer mixture
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 7
- 239000003522 acrylic cement Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000000178 monomer Substances 0.000 abstract 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 4
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000000853 adhesive Substances 0.000 abstract 2
- 230000001070 adhesive effect Effects 0.000 abstract 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 abstract 2
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 abstract 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 1
- 229920006243 acrylic copolymer Polymers 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000007870 radical polymerization initiator Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1802—C2-(meth)acrylate, e.g. ethyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
- C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/385—Acrylic polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
- C09J2203/334—Applications of adhesives in processes or use of adhesives in the form of films or foils as a label
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Se describen composiciones adhesivas que comprenden copolímeros acrílicos formados a partir de una mezcla monomérica que comprende, con base en peso total de monómeros en la mezcla monomérica, de 59 a 97.9 por ciento en peso de acrilato de 2-etilhexilo, de 0.1 a 10 por ciento en peso de estireno, de 0 a 25 por ciento en peso de metacrilato de metilo, y de 2 a 30 por ciento en peso de acrilato de etilo, en donde la relación de acrilato de etilo y estireno (en peso) es mayor que 4.5 a 1. Se describen métodos para preparar composiciones adhesivas que comprenden alimentar una carga acuosa inicial a un reactor, calentar la carga acuosa inicial de aproximadamente 30 a 110°C, alimentar gradualmente una mezcla monomérica en un reactor durante un período de tiempo (menor de 3 horas), en presencia de un iniciador de polimerización por radicales libres, formando así la composición adhesiva acrílica, en donde la cantidad del monómero libre en el reactor no excede 17 por ciento en peso, con base en peso total de los contenidos del reactor, durante la alimentación gradual.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201762563670P | 2017-09-27 | 2017-09-27 | |
| PCT/US2018/042433 WO2019067070A1 (en) | 2017-09-27 | 2018-07-17 | ADHESIVE ACRYLIC COMPOSITIONS AND METHODS OF MAKING SAME |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2020002962A true MX2020002962A (es) | 2020-07-22 |
Family
ID=63207868
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2020002962A MX2020002962A (es) | 2017-09-27 | 2018-07-17 | Composiciones adhesivas acrilicas y metodos para fabricarlas. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US11773300B2 (es) |
| EP (1) | EP3688109A1 (es) |
| JP (1) | JP7264882B2 (es) |
| CN (1) | CN111108168A (es) |
| AR (1) | AR112821A1 (es) |
| BR (1) | BR112020005228B1 (es) |
| MX (1) | MX2020002962A (es) |
| RU (1) | RU2020112746A (es) |
| TW (1) | TWI835742B (es) |
| WO (1) | WO2019067070A1 (es) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3688109A1 (en) * | 2017-09-27 | 2020-08-05 | Dow Global Technologies LLC | Acrylic adhesive compositions and methods of making same |
| JP7342507B2 (ja) * | 2019-08-08 | 2023-09-12 | Dic株式会社 | 粘着剤組成物及び粘着フィルム |
| CN112080229A (zh) * | 2020-09-01 | 2020-12-15 | 许贵真 | 一种低粘度高固含量丙烯酸压敏胶及其制备方法 |
| CN116407522A (zh) * | 2021-12-31 | 2023-07-11 | 贵州省欣紫鸿药用辅料有限公司 | 一种巴布剂中的粘着剂及其制备方法 |
| KR102670230B1 (ko) * | 2022-10-27 | 2024-05-28 | 주식회사 현대엘앤씨 | 단열 마감재 시공 분사 시스템 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3013812A1 (de) | 1980-04-10 | 1981-10-15 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von waessrigen polymer-dispersionen mit einem polymerisatgehalt bis 75 gew. prozent |
| AU638480B2 (en) * | 1989-08-14 | 1993-07-01 | Avery Dennison Corporation | Emulsion pressure-sensitive adhesive polymers exhibiting excellent room- and low-temperature performance |
| JPH06287890A (ja) | 1993-03-31 | 1994-10-11 | Nippon Paper Ind Co Ltd | 易離解性防湿紙 |
| DE19633967A1 (de) * | 1996-08-22 | 1998-02-26 | Basf Ag | Herstellung hochkonzentrierter Haftklebstoffdispersionen und deren Verwendung |
| EP1426428A1 (en) * | 2002-12-06 | 2004-06-09 | Ucb S.A. | Aqueous polymer dispersions as pressure sensitive adhesives |
| WO2008003758A1 (en) | 2006-07-07 | 2008-01-10 | Cytec Surface Specialties, S.A. | Polymer, composition and process |
| CN102056952B (zh) * | 2008-04-15 | 2013-11-13 | 巴斯夫欧洲公司 | 用于粘合剂的聚合物水分散体 |
| EP2147935B1 (en) | 2008-07-02 | 2011-12-28 | Rohm and Haas Company | Emulsion Polymer Adhesives |
| WO2011037732A2 (en) | 2009-09-17 | 2011-03-31 | Avery Dennison Corporation | Activatable adhesive, labels, and related methods |
| EP2496655B1 (de) | 2009-11-05 | 2013-10-02 | Basf Se | Haftklebstoffpolymer aus n-butylacrylat, ethylacrylat, vinylacetat und säuremonomer |
| CN102453447B (zh) | 2010-10-26 | 2014-02-26 | 罗门哈斯公司 | 可移除的胶粘贴 |
| WO2014078793A1 (en) * | 2012-11-19 | 2014-05-22 | Momentive Specialty Chemicals Inc. | Pressure sensitive adhesive compositions |
| EP3164431B1 (de) * | 2014-07-02 | 2020-02-12 | Basf Se | Verfahren zum kleben von substraten auf kalte und feuchte oberflächen |
| EP3688109A1 (en) * | 2017-09-27 | 2020-08-05 | Dow Global Technologies LLC | Acrylic adhesive compositions and methods of making same |
-
2018
- 2018-07-17 EP EP18755347.4A patent/EP3688109A1/en active Pending
- 2018-07-17 RU RU2020112746A patent/RU2020112746A/ru unknown
- 2018-07-17 BR BR112020005228-0A patent/BR112020005228B1/pt active IP Right Grant
- 2018-07-17 JP JP2020515719A patent/JP7264882B2/ja active Active
- 2018-07-17 MX MX2020002962A patent/MX2020002962A/es unknown
- 2018-07-17 WO PCT/US2018/042433 patent/WO2019067070A1/en not_active Ceased
- 2018-07-17 CN CN201880060345.2A patent/CN111108168A/zh active Pending
- 2018-07-17 US US16/643,257 patent/US11773300B2/en active Active
- 2018-08-29 TW TW107130169A patent/TWI835742B/zh active
- 2018-09-18 AR ARP180102661A patent/AR112821A1/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| TWI835742B (zh) | 2024-03-21 |
| RU2020112746A (ru) | 2021-09-30 |
| AR112821A1 (es) | 2019-12-18 |
| RU2020112746A3 (es) | 2021-11-30 |
| JP2020535244A (ja) | 2020-12-03 |
| US20200255700A1 (en) | 2020-08-13 |
| JP7264882B2 (ja) | 2023-04-25 |
| WO2019067070A1 (en) | 2019-04-04 |
| CN111108168A (zh) | 2020-05-05 |
| US11773300B2 (en) | 2023-10-03 |
| BR112020005228A2 (pt) | 2020-09-24 |
| BR112020005228B1 (pt) | 2023-11-28 |
| TW201915127A (zh) | 2019-04-16 |
| EP3688109A1 (en) | 2020-08-05 |
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