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MX2020001592A - Proceso para convertir alquilenureas ciclicas en sus alquilenaminas correspondientes. - Google Patents

Proceso para convertir alquilenureas ciclicas en sus alquilenaminas correspondientes.

Info

Publication number
MX2020001592A
MX2020001592A MX2020001592A MX2020001592A MX2020001592A MX 2020001592 A MX2020001592 A MX 2020001592A MX 2020001592 A MX2020001592 A MX 2020001592A MX 2020001592 A MX2020001592 A MX 2020001592A MX 2020001592 A MX2020001592 A MX 2020001592A
Authority
MX
Mexico
Prior art keywords
urea
derivative
derivatives
alkyleneureas
diurea
Prior art date
Application number
MX2020001592A
Other languages
English (en)
Inventor
Kate Antoon Jacob Berend Ten
Rolf Krister Edvinsson
Karl Fredrik Lake
Ina Ehlers
Eike Nicolas Kantzer
Dam Hendrik Van
Rens Veneman
Michiel Jozef Thomas Raaijmakers
Slavisa Jovic
Michael Bertil Einar Sarning
Björn Patrick SKANSEN
Stig Mikael Wernersson
Original Assignee
Nouryon Chemicals Int Bv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nouryon Chemicals Int Bv filed Critical Nouryon Chemicals Int Bv
Publication of MX2020001592A publication Critical patent/MX2020001592A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C213/02—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reactions involving the formation of amino groups from compounds containing hydroxy groups or etherified or esterified hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/62—Preparation of compounds containing amino groups bound to a carbon skeleton by cleaving carbon-to-nitrogen, sulfur-to-nitrogen, or phosphorus-to-nitrogen bonds, e.g. hydrolysis of amides, N-dealkylation of amines or quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
    • C07C211/02—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C211/09—Diamines
    • C07C211/10—Diaminoethanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La presente invención está dirigida a un proceso, para convertir alquilenureas cíclicas en sus alquilenaminas correspondientes en donde una materia prima que comprende alquilenureas cíclicas se hace reaccionar en la fase líquida con agua en una cantidad de 0.1 a 20 moles de agua por mol de la porción de urea, a una temperatura de por lo menos 230°C, con eliminación de CO2. Se ha encontrado que el proceso de acuerdo con la invención permite la conversión eficiente de alquilenureas en las alquilenaminas correspondientes. El proceso tiene un alto rendimiento y baja producción de productos secundarios. Se prefiere que la alquilenurea cíclica comprenda uno o más de EU (etilenurea, el derivado de urea de etilendiamina (EDA)), UDETA (el derivado de urea de dietilentriamina (DETA)), UTETA (el grupo de derivados de urea de trietilentetramina (TETA), DUTETA (el derivado de diurea de trietilentetramina), UTEPAs (los derivados de urea de tetraetilenpentamina (TEPA)), DUTEPAs (los derivados de diurea de TEPA), o los derivados de urea de pentaetilenhexamina (PEHA) y análogos superiores, UAEEA (el derivado de urea de aminoetiletanolamina), HE-UDETA (el derivado de urea de hidroxietil dietilentriamina), HE-UTETA (el derivado de urea de hidroxietil trietilentetramina, HE-DUTETA (el derivado de diurea de hidroxietil trietilentetramina) o cualquier mezcla de estos.
MX2020001592A 2017-08-11 2018-08-07 Proceso para convertir alquilenureas ciclicas en sus alquilenaminas correspondientes. MX2020001592A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP17185949 2017-08-11
PCT/EP2018/071321 WO2019030192A1 (en) 2017-08-11 2018-08-07 PROCESS FOR CONVERTING CYCLIC ALKYLENE UREA TO THEIR CORRESPONDING ALKYLENE AMINES

Publications (1)

Publication Number Publication Date
MX2020001592A true MX2020001592A (es) 2020-07-21

Family

ID=59592934

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2020001592A MX2020001592A (es) 2017-08-11 2018-08-07 Proceso para convertir alquilenureas ciclicas en sus alquilenaminas correspondientes.

Country Status (9)

Country Link
US (1) US10793511B2 (es)
EP (1) EP3665150A1 (es)
JP (2) JP7524053B2 (es)
KR (1) KR20200036926A (es)
CN (1) CN111032614B (es)
BR (1) BR112020002460B1 (es)
MX (1) MX2020001592A (es)
TW (1) TWI761571B (es)
WO (1) WO2019030192A1 (es)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110072841B (zh) 2016-12-15 2022-04-19 阿克苏诺贝尔化学品国际有限公司 制备羟乙基亚乙基胺的方法
WO2018108890A1 (en) * 2016-12-15 2018-06-21 Akzo Nobel Chemicals International B.V. Process for manufacturing ethylene amines
WO2019011710A1 (en) * 2017-07-10 2019-01-17 Akzo Nobel Chemicals International B.V. PROCESS FOR THE PREPARATION OF ETHYLENEAMINES AND ETHYLENEAMINE DERIVATIVES
EP3665152A1 (en) * 2017-08-11 2020-06-17 Nouryon Chemicals International B.V. Process for converting cyclic alkylene ureas into their corresponding alkylene amines
EP3665159B1 (en) * 2017-08-11 2022-12-28 Nouryon Chemicals International B.V. Process to convert the cyclic monourea of an ethylene amine compound into the ethylene amine compound
US11685673B2 (en) 2021-06-06 2023-06-27 Christopher R. Moylan Systems and methods for removal of carbon dioxide from seawater
US11407667B1 (en) 2021-06-06 2022-08-09 Christopher R. Moylan Systems and methods for removal of carbon dioxide from seawater

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2812333A (en) * 1954-09-27 1957-11-05 Union Carbide Corp Process for the preparation of 1-(2-hydroxyethyl) imidazolidine-2
US2847418A (en) 1955-05-06 1958-08-12 Union Carbide Corp Di(hydroxyethyl) imidazolidone-2 and production of n, n'-di-(2-hydroxyethyl) ethylene diamine
FR1238353A (fr) 1959-06-30 1960-08-12 Rhone Poulenc Sa Perfectionnement au procédé de préparation de la n-beta-hydroxyéthyléthylènediamine
US4503250A (en) 1981-09-30 1985-03-05 Union Carbide Corporation Preparation of polyalkylene polyamines
US4387249A (en) * 1981-12-18 1983-06-07 The Dow Chemical Company Process for the manufacture of diethylenetriamine
NL8204546A (nl) * 1982-11-23 1984-06-18 Akzo Nv Werkwijze voor het winnen van ethyleenamines uit waterige oplossing.
JPS59161338A (ja) * 1983-03-04 1984-09-12 Toyo Soda Mfg Co Ltd エチレンアミン類炭酸塩水溶液からエチレンアミン類を得る方法
JPS6065117A (ja) * 1983-09-19 1985-04-13 Unitika Ltd ゴム補強用ポリエステル繊維の製造法
JPS60120842A (ja) * 1983-12-03 1985-06-28 Toyo Soda Mfg Co Ltd エチレンアミン類炭酸塩からエチレンアミン類を得る方法
JPS60126248A (ja) * 1983-12-09 1985-07-05 Toyo Soda Mfg Co Ltd エチレンアミン類炭酸塩水溶液の脱炭酸方法
DE102004011320A1 (de) * 2004-03-09 2005-09-22 Degussa Ag Verfahren zur Herstellung von Aminen aus Carbodiimidgruppen aufweisenden Verbindungen durch Hydrolyse mit Wasser
EP2548869A1 (en) * 2011-07-20 2013-01-23 Cytec Technology Corp. Process for the Synthesis of N-substituted Cyclic Alkylene Ureas

Also Published As

Publication number Publication date
JP7524053B2 (ja) 2024-07-29
JP2020529454A (ja) 2020-10-08
JP2023022000A (ja) 2023-02-14
WO2019030192A1 (en) 2019-02-14
BR112020002460A2 (pt) 2020-07-28
TWI761571B (zh) 2022-04-21
CN111032614B (zh) 2023-04-11
EP3665150A1 (en) 2020-06-17
US10793511B2 (en) 2020-10-06
KR20200036926A (ko) 2020-04-07
BR112020002460B1 (pt) 2023-03-21
TW201920066A (zh) 2019-06-01
US20200199060A1 (en) 2020-06-25
CN111032614A (zh) 2020-04-17

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