MX2019002972A - Catalizador de oligomerizacion y procedimiento para su produccion. - Google Patents
Catalizador de oligomerizacion y procedimiento para su produccion.Info
- Publication number
- MX2019002972A MX2019002972A MX2019002972A MX2019002972A MX2019002972A MX 2019002972 A MX2019002972 A MX 2019002972A MX 2019002972 A MX2019002972 A MX 2019002972A MX 2019002972 A MX2019002972 A MX 2019002972A MX 2019002972 A MX2019002972 A MX 2019002972A
- Authority
- MX
- Mexico
- Prior art keywords
- oligomerization catalyst
- production
- oligomerization
- catalyst
- olefins
- Prior art date
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
- B01J23/04—Alkali metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/34—Mechanical properties
- B01J35/37—Crush or impact strength
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/657—Pore diameter larger than 1000 nm
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/66—Pore distribution
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/80—Catalysts, in general, characterised by their form or physical properties characterised by their amorphous structures
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0063—Granulating
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/10—Catalytic processes with metal oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
- B01J2235/05—Nuclear magnetic resonance [NMR]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/12—Silica and alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
- C07C2523/04—Alkali metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/755—Nickel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Nanotechnology (AREA)
Abstract
La invención se refiere a un catalizador de oligomerización que comprende óxido de níquel y un material de soporte de sílice-alúmina, y a un procedimiento para la oligomerización de las olefinas C3 a C6 mediante el uso del catalizador de oligomerización.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP18161757 | 2018-03-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2019002972A true MX2019002972A (es) | 2019-09-18 |
Family
ID=61691254
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2019002972A MX2019002972A (es) | 2018-03-14 | 2019-03-14 | Catalizador de oligomerizacion y procedimiento para su produccion. |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US11253844B2 (es) |
| EP (1) | EP3546065A1 (es) |
| JP (1) | JP7476437B2 (es) |
| KR (1) | KR102792203B1 (es) |
| CN (1) | CN110270335A (es) |
| AR (1) | AR116139A1 (es) |
| CA (1) | CA3036867C (es) |
| MX (1) | MX2019002972A (es) |
| MY (1) | MY203328A (es) |
| SG (1) | SG10201902134SA (es) |
| TW (1) | TWI813642B (es) |
| ZA (1) | ZA201901485B (es) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL3680224T3 (pl) | 2019-01-08 | 2023-09-11 | Evonik Operations Gmbh | Sposób usuwania wielonienasyconych węglowodorów ze strumieni węglowodorowych C4 w obecności merkaptanów, disiarczków i węglowodorów C5 |
| US11186782B2 (en) | 2019-01-08 | 2021-11-30 | Evonik Operations Gmbh | Catalyst and process for removing mercaptans from hydrocarbon streams |
| US11008275B2 (en) | 2019-06-12 | 2021-05-18 | Evonik Operations Gmbh | Process for preparing carboxylic acids or salts thereof from hydrocarbons |
| US11365171B2 (en) | 2019-06-12 | 2022-06-21 | Evonik Operations Gmbh | Process for preparing an ester by alkoxycarbonylation |
| US12064755B2 (en) | 2019-06-12 | 2024-08-20 | Evonik Oxeno Gmbh & Co. Kg | Process for separating one or more components from a mixture |
| US11440863B2 (en) | 2019-06-12 | 2022-09-13 | Evonik Operations Gmbh | Process for preparing an alcohol from hydrocarbons |
| US11332421B2 (en) | 2019-08-21 | 2022-05-17 | Evonik Operations Gmbh | Process for oligomerization of olefins with optimized distillation |
| US11254631B2 (en) | 2019-08-21 | 2022-02-22 | Evonik Operations Gmbh | Process for oligomerization of olefins with optimized distillation |
| TWI705123B (zh) * | 2019-10-29 | 2020-09-21 | 隆達電子股份有限公司 | 波長轉換物質以及發光裝置 |
| US11396488B2 (en) | 2020-07-30 | 2022-07-26 | Evonik Operations Gmbh | Process for preparing aldehydes and separation of the catalyst system by membrane separation |
| CN114425321B (zh) * | 2020-10-15 | 2024-01-30 | 中国石油化工股份有限公司 | 载体和烷烃脱氢催化剂及其制备方法和应用 |
| CN114425316B (zh) * | 2020-10-15 | 2024-01-30 | 中国石油化工股份有限公司 | 载体及其制备方法和烷烃脱氢催化剂及其制备方法和应用 |
| US12296301B2 (en) | 2020-12-22 | 2025-05-13 | Evonik Oxeno Gmbh & Co. Kg | Variable, self-regulating permeate recycling in organophilic nanofiltration |
| US11806669B2 (en) | 2020-12-22 | 2023-11-07 | Evonik Operations Gmbh | Variable and self-regulating permeate recycling in organophilic nanofiltration |
| EP4029926A1 (de) | 2021-01-15 | 2022-07-20 | Evonik Operations GmbH | Zweistufige abgaswäsche |
| EP4091712B1 (de) | 2021-05-18 | 2024-05-15 | Evonik Oxeno GmbH & Co. KG | Verfahren zur regenerierung eines katalysators für die hydroformylierung von olefinen in der gasphase |
| CA3183265A1 (en) | 2021-12-08 | 2023-06-08 | Evonik Operations Gmbh | Process for producing an oligomerization catalyst having a hydrothermal treatment step |
| US12516003B2 (en) * | 2022-03-29 | 2026-01-06 | Uop Llc | Process for converting olefins to distillate fuels |
| CN119233957A (zh) | 2022-05-18 | 2024-12-31 | 赢创奥克森诺有限责任两合公司 | 包括非均相和均相催化反应的纯化烃料流的方法 |
| WO2024037770A1 (de) | 2022-08-19 | 2024-02-22 | Evonik Oxeno Gmbh & Co. Kg | Verfahren zur behandlung eines katalysators |
Family Cites Families (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB619231A (en) * | 1945-06-15 | 1949-03-07 | Phillips Petroleum Co | Improvements in or relating to catalytic polymerization of olefins |
| GB1195307A (en) | 1968-03-04 | 1970-06-17 | Ici Ltd | Dimerisation of Olefines |
| US3658935A (en) * | 1970-06-08 | 1972-04-25 | Exxon Research Engineering Co | Dimerization and codimerization process |
| DE4339713A1 (de) | 1993-11-22 | 1995-05-24 | Basf Ag | Verfahren zur Oligomerisierung von Olefinen zu hochlinearen Oligomeren und Katalysatoren dafür |
| TW425381B (en) * | 1997-11-14 | 2001-03-11 | Basf Ag | Process for preparing essentially unbranched octenes and dodecenes by oligomerization of unbranched butenes |
| FR2819430B1 (fr) | 2001-01-15 | 2003-02-28 | Inst Francais Du Petrole | Catalyseur comportant une silice-alumine et son utilisation en hydrocraquage de charges hydrocarbonees |
| TW200417555A (en) | 2002-08-23 | 2004-09-16 | Oxeno Olefinchemie Gmbh | Catalyst and process for the oligomerization of olefins |
| DE10335510A1 (de) | 2003-07-31 | 2005-03-10 | Stockhausen Chem Fab Gmbh | Beschichteter Katalysator-Trägerkörper |
| FR2873116B1 (fr) | 2004-07-15 | 2012-11-30 | Inst Francais Du Petrole | Procede d'oligomerisation des olefines utilisant un catalyseur a base de silice-alumine |
| US20090068440A1 (en) | 2005-06-20 | 2009-03-12 | Gunther Bub | Production of acrolein, acrylic acid and water-absorbent polymer structures made from glycerine |
| EP2029511A1 (en) * | 2006-05-08 | 2009-03-04 | ExxonMobil Chemical Patents Inc. | Organic compound conversion process |
| WO2007141288A1 (de) * | 2006-06-07 | 2007-12-13 | Basf Se | Verfahren zur co-dimerisierung von olefinen |
| DE102006039203B4 (de) | 2006-08-22 | 2014-06-18 | Evonik Degussa Gmbh | Verfahren zur Herstellung von durch Kristallisation gereinigter Acrylsäure aus Hydroxypropionsäure sowie Vorrichtung dazu |
| DE102006039205A1 (de) | 2006-08-22 | 2008-03-20 | Stockhausen Gmbh | Auf nachwachsenden Rohstoffen basierende Acrylsäure und wasserabsorbierende Polymergebilde sowie Verfahren zu deren Herstellung mittels Dehydratisierung |
| FR2931818B1 (fr) * | 2008-05-28 | 2012-11-30 | Inst Francais Du Petrole | Procede d'oligomerisation des olefines legeres utilisant un catalyseur a base d'un materiau amorphe a porosite hierarchisee et organisee |
| CN102099113A (zh) * | 2008-07-23 | 2011-06-15 | 三井化学株式会社 | 乙烯低聚催化剂及其用途 |
| DE102008060888A1 (de) | 2008-12-09 | 2010-06-10 | Evonik Stockhausen Gmbh | Verfahren zur Herstellung von Acrolein umfassend die Aufarbeitung einer Rohglycerin-Phase |
| BRPI1013710A2 (pt) * | 2009-03-31 | 2016-04-05 | Uop Llc | processo para oligomerizar etileno, e, aparelho |
| MX2011013662A (es) * | 2009-06-16 | 2012-06-19 | Chevron Phillips Chemical Co | Oligomerizacion de alfa oleifinas usando sistemas de catalizador de metaloceno-ssa y uso de las polialfaolefinas resultantes para preparar mezclas lubricantes. |
| DE102009027408A1 (de) | 2009-07-01 | 2011-01-05 | Evonik Oxeno Gmbh | Regenerierung von Oligomerisierungskatalysatoren |
| FR2951164B1 (fr) * | 2009-10-08 | 2011-10-21 | Inst Francais Du Petrole | Procede d'oligomerisation d'une charge hydrocarbonee olefinique utilisant un catalyseur a base d'une silice-alumine macroporeuse |
| BR112013005598B1 (pt) * | 2010-09-16 | 2020-11-03 | Asahi Kasei Kabushiki Kaisha | material à base de sílica, processo para produzir o mesmo, material suportado com um metal nobre, processo para produzir um éster de ácido carboxílico, e, processo para produzir um ácido carboxílico |
| US9573861B2 (en) * | 2011-07-25 | 2017-02-21 | Exxonmobil Chemical Patents Inc. | Olefin oligomerization process |
| WO2013064302A1 (en) * | 2011-10-31 | 2013-05-10 | Exxonmobil Chemical Patents Inc. | Olefin oligomerization process |
| JP5978887B2 (ja) * | 2012-09-25 | 2016-08-24 | 三菱化学株式会社 | プロピレン及び直鎖ブテンの製造方法 |
| JP2014151253A (ja) | 2013-02-06 | 2014-08-25 | Jx Nippon Oil & Energy Corp | オレフィン低重合方法およびそれに用いる触媒 |
| DE102014201756A1 (de) | 2014-01-31 | 2015-08-06 | Evonik Degussa Gmbh | Reinigung chlorverschmutzter Organophosphorverbindungen |
| US10155200B2 (en) | 2015-02-18 | 2018-12-18 | Evonik Degussa Gmbh | Separation off of a homogeneous catalyst from a reaction mixture with the help of organophilic nanofiltration |
| JP6228246B2 (ja) | 2015-03-03 | 2017-11-08 | エボニック デグサ ゲーエムベーハーEvonik Degussa GmbH | エテンのオリゴマー化に使用される不均一系触媒の再生 |
| SG10201601501QA (en) | 2015-03-05 | 2016-10-28 | Evonik Degussa Gmbh | Preparation of 2,2`-biaryls in the presence of molybdenum(v) chloride |
| CN105819698B (zh) * | 2016-03-15 | 2018-09-14 | 巨石集团有限公司 | 一种高性能玻璃纤维组合物及其玻璃纤维和复合材料 |
| ES2765635T3 (es) | 2016-05-19 | 2020-06-10 | Evonik Operations Gmbh | Producción de n-pentanal a partir de mezclas de sustancias de empleo pobres en buteno |
| ES2711317T3 (es) | 2016-06-10 | 2019-05-03 | Evonik Degussa Gmbh | Oligomerización de eteno en régimen supercrítico |
| EP3266757B1 (de) | 2016-07-08 | 2019-12-25 | Evonik Operations GmbH | Herstellung von zumindest 1-hexen und octen aus ethen |
| FR3054455A1 (fr) | 2016-07-28 | 2018-02-02 | IFP Energies Nouvelles | Catalyseurs heterogenes contenant du nickel et du silicium et leur utilisation |
| US10227279B2 (en) | 2016-09-12 | 2019-03-12 | Evonik Degussa Gmbh | Dehydrogenation of LPG or NGL and flexible utilization of the olefins thus obtained |
| US10245578B2 (en) | 2016-11-09 | 2019-04-02 | Evonik Degussa Gmbh | Chromium- and nickel-free hydrogenation of hydroformylation mixtures |
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2019
- 2019-03-06 US US16/293,859 patent/US11253844B2/en active Active
- 2019-03-11 JP JP2019043536A patent/JP7476437B2/ja active Active
- 2019-03-11 ZA ZA2019/01485A patent/ZA201901485B/en unknown
- 2019-03-11 SG SG10201902134S patent/SG10201902134SA/en unknown
- 2019-03-12 TW TW108108124A patent/TWI813642B/zh active
- 2019-03-12 EP EP19162229.9A patent/EP3546065A1/de active Pending
- 2019-03-13 KR KR1020190028533A patent/KR102792203B1/ko active Active
- 2019-03-13 MY MYPI2019001326A patent/MY203328A/en unknown
- 2019-03-13 CN CN201910188621.XA patent/CN110270335A/zh active Pending
- 2019-03-14 MX MX2019002972A patent/MX2019002972A/es unknown
- 2019-03-14 AR ARP190100643A patent/AR116139A1/es active IP Right Grant
- 2019-03-14 CA CA3036867A patent/CA3036867C/en active Active
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|---|---|
| SG10201902134SA (en) | 2019-10-30 |
| TW201938267A (zh) | 2019-10-01 |
| CA3036867A1 (en) | 2019-09-14 |
| AR116139A1 (es) | 2021-04-07 |
| TWI813642B (zh) | 2023-09-01 |
| EP3546065A1 (de) | 2019-10-02 |
| ZA201901485B (en) | 2020-12-23 |
| KR20190108510A (ko) | 2019-09-24 |
| US11253844B2 (en) | 2022-02-22 |
| CN110270335A (zh) | 2019-09-24 |
| US20190283004A1 (en) | 2019-09-19 |
| JP2019171370A (ja) | 2019-10-10 |
| JP7476437B2 (ja) | 2024-05-01 |
| KR102792203B1 (ko) | 2025-04-08 |
| CA3036867C (en) | 2024-05-21 |
| MY203328A (en) | 2024-06-25 |
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