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MX2016015770A - Procatalizador para la polimerizacion de olefinas que comprende un monoester y donante interno de amidobenzoato. - Google Patents

Procatalizador para la polimerizacion de olefinas que comprende un monoester y donante interno de amidobenzoato.

Info

Publication number
MX2016015770A
MX2016015770A MX2016015770A MX2016015770A MX2016015770A MX 2016015770 A MX2016015770 A MX 2016015770A MX 2016015770 A MX2016015770 A MX 2016015770A MX 2016015770 A MX2016015770 A MX 2016015770A MX 2016015770 A MX2016015770 A MX 2016015770A
Authority
MX
Mexico
Prior art keywords
electron donor
compound
internal electron
formula
optionally
Prior art date
Application number
MX2016015770A
Other languages
English (en)
Inventor
Alexander Zuideveld Martin
Alexandra Batinas-Geurts Aurora
Meppelder Anika
Original Assignee
Sabic Global Technologies Bv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sabic Global Technologies Bv filed Critical Sabic Global Technologies Bv
Publication of MX2016015770A publication Critical patent/MX2016015770A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/656—Pretreating with metals or metal-containing compounds with silicon or compounds thereof
    • C08F4/6565—Pretreating with metals or metal-containing compounds with silicon or compounds thereof and magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12—Melt flow index or melt flow ratio
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/18—Bulk density

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

La presente invención se refiere a un procedimiento para la preparación de un procatalizador para la polimerización de olefinas, que comprende poner en contacto un soporte que contiene magnesio con un compuesto de titanio que contiene halógeno, un monoéster, un primer donante interno de electrones, en donde el donante interno de electrones está representado por un compuesto representado por la Fórmula A, por ejemplo, una proyección de Fischer de la Fórmula A, y opcionalmente un segundo donante interno de electrones seleccionado de un grupo que consiste de diésteres y diéteres, (ver Fórmula) comprendiendo dicho procedimiento las etapas de: i) poner en contacto un compuesto de Grignard de butilo con un compuesto de silano que contiene alcoxi o ariloxi para producir un primer producto de reacción intermedio; ii) activar opcionalmente el primer producto de reacción intermedio con al menos un compuesto activador para producir un segundo producto de reacción intermedio; iii) poner en contacto el primer o segundo producto de reacción intermedio, obtenido respectivamente en la etapa i) o ii), con un compuesto de Ti que contiene halógeno, el monoéster, y dicho donante interno de electrones representado por un compuesto representado por la Fórmula A, por ejemplo, una proyección de Fischer de la Fórmula A, como el primer donante interno de electrones, y, opcionalmente, el diéster o diéter como el segundo donante interno de electrones. La presente invención también se refiere a un sistema catalizador de polimerización que comprende dicho procatalizador, un cocatalizador y opcionalmente un donante externo de electrones. Además, la presente invención se refiere a una poliolefina que puede ser obtenida mediante el procedimiento de acuerdo con la presente invención y un artículo conformado de la misma.
MX2016015770A 2014-06-02 2015-06-01 Procatalizador para la polimerizacion de olefinas que comprende un monoester y donante interno de amidobenzoato. MX2016015770A (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP14170836 2014-06-02
EP15161420 2015-03-27
PCT/EP2015/062118 WO2015185490A1 (en) 2014-06-02 2015-06-01 Procatalyst for polymerization of olefins comprising a monoester and an amidobenzoate internal donor

Publications (1)

Publication Number Publication Date
MX2016015770A true MX2016015770A (es) 2017-04-25

Family

ID=53284250

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2016015770A MX2016015770A (es) 2014-06-02 2015-06-01 Procatalizador para la polimerizacion de olefinas que comprende un monoester y donante interno de amidobenzoato.

Country Status (7)

Country Link
US (1) US20170240665A1 (es)
EP (1) EP3149054A1 (es)
KR (1) KR102329438B1 (es)
CN (1) CN106414520A (es)
EA (1) EA032542B1 (es)
MX (1) MX2016015770A (es)
WO (1) WO2015185490A1 (es)

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CN107810206B (zh) 2015-06-19 2021-01-19 Sabic环球技术有限责任公司 用于烯烃聚合的包含特定比率的氨基苯甲酸酯内给体和1,3-二醚内给体的主催化剂
US10611864B2 (en) * 2015-09-22 2020-04-07 Sabic Global Technologies B.V. Synthesis of substituted amidobenzoate compounds, the compounds obtained and the use thereof as phthalate free internal electron donor for polymerization of olefins
WO2017093129A1 (en) * 2015-12-02 2017-06-08 Sabic Global Technologies B.V. Process for preparing a procatalyst for polymerization of olefins
US10836847B2 (en) 2015-12-02 2020-11-17 Sabic Global Technologies B.V. Procatalyst for polymerization of olefins
EP3383925B1 (en) * 2015-12-02 2023-10-18 SABIC Global Technologies B.V. A procatalyst for polymerization of olefins
EP3519460B1 (en) * 2016-09-29 2024-01-17 SABIC Global Technologies B.V. Procatalyst for polymerization of olefins
WO2018059955A1 (en) * 2016-09-29 2018-04-05 Sabic Global Technologies B.V. Process to prepare procatalyst for polymerization of olefins
EP3519458B1 (en) 2016-09-29 2023-08-09 SABIC Global Technologies B.V. Process to prepare procatalyst for polymerization of olefins
US11192962B2 (en) 2016-09-29 2021-12-07 Sabic Global Technologies B.V. Process to prepare procatalyst for polymerization of olefins
EP3519459B1 (en) * 2016-09-29 2023-10-11 SABIC Global Technologies B.V. Procatalyst for polymerization of olefins
RU2752084C2 (ru) * 2016-10-06 2021-07-22 У. Р. Грейс Энд Ко.-Конн. Композиция прокатализатора, полученная с комбинацией внутренних доноров электронов
CN118515799A (zh) 2016-10-12 2024-08-20 Sabic环球技术有限责任公司 制备适用于烯烃聚合的主催化剂的固体载体的方法
EP3309183A1 (en) * 2016-10-14 2018-04-18 SABIC Global Technologies B.V. Polypropylene for use in bopp applications
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WO2018167305A1 (en) 2017-03-17 2018-09-20 Sabic Global Technologies B.V. Process for preparing a procatalyst for polymerization of olefins
US10246530B2 (en) * 2017-06-27 2019-04-02 Toho Titanium Co., Ltd. Method for producing solid catalyst component for olefin polymerization, catalyst for olefin polymerization and a process for propylene polymerization
US10766854B2 (en) * 2017-10-20 2020-09-08 Sabic Global Technologies B.V. Synthesis method for the preparation of dibenzoate compounds, such as 4-[benzoyl(methyl)amino]pentane-2-yl dibenzoate
WO2019094216A1 (en) 2017-11-13 2019-05-16 W.R. Grace & Co.-Conn. Catalyst components for propylene polymerization
CN111511829B (zh) * 2017-12-22 2023-11-24 Sabic环球技术有限责任公司 用于带的丙烯组合物
EP3728460B1 (en) * 2017-12-22 2024-02-07 SABIC Global Technologies B.V. Polypropylene composition for non-pressurized pipes
EP4038108A1 (en) 2019-10-04 2022-08-10 SABIC Global Technologies, B.V. Process for polymerization of polypropylene using ziegler-natta procatalyst with novel 1,3-diether internal electron donors
CN114507303B (zh) * 2020-10-28 2023-05-05 中国石油化工股份有限公司 用于烯烃聚合的外给电子体及催化剂体系和烯烃聚合方法
CN114478870B (zh) * 2020-10-28 2023-06-06 中国石油化工股份有限公司 用于烯烃聚合的催化剂体系及烯烃聚合方法
CN116997579A (zh) * 2021-04-01 2023-11-03 Sabic环球技术有限责任公司 使用选择性控制剂和活性限制剂制造聚丙烯的方法
CN114773506A (zh) * 2022-05-31 2022-07-22 山东京博石油化工有限公司 一种用于原位成核聚丙烯的催化剂及其制备方法和应用
CN120390755A (zh) 2022-12-22 2025-07-29 Sabic环球技术有限责任公司 使用选择性控制剂和活性限制剂制备聚丙烯的方法
CN117362493B (zh) * 2023-09-26 2024-07-05 辽宁格瑞斯化工有限公司 烯烃聚合用催化体系及其应用

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Also Published As

Publication number Publication date
US20170240665A1 (en) 2017-08-24
EA201692489A1 (ru) 2017-05-31
EA032542B1 (ru) 2019-06-28
WO2015185490A1 (en) 2015-12-10
KR20170013349A (ko) 2017-02-06
CN106414520A (zh) 2017-02-15
EP3149054A1 (en) 2017-04-05
KR102329438B1 (ko) 2021-11-23

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