[go: up one dir, main page]

MX2016000765A - Preparacion de metacrilato de metilo a traves de un proceso de esterificacion oxidativa. - Google Patents

Preparacion de metacrilato de metilo a traves de un proceso de esterificacion oxidativa.

Info

Publication number
MX2016000765A
MX2016000765A MX2016000765A MX2016000765A MX2016000765A MX 2016000765 A MX2016000765 A MX 2016000765A MX 2016000765 A MX2016000765 A MX 2016000765A MX 2016000765 A MX2016000765 A MX 2016000765A MX 2016000765 A MX2016000765 A MX 2016000765A
Authority
MX
Mexico
Prior art keywords
methyl methacrylate
preparation
esterification process
oxidative esterification
methacrylate via
Prior art date
Application number
MX2016000765A
Other languages
English (en)
Inventor
Kirk Limbach
Dmitri A Kraptchetov
Christopher D Frick
Original Assignee
Rohm & Haas
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm & Haas filed Critical Rohm & Haas
Publication of MX2016000765A publication Critical patent/MX2016000765A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/624—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with germanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/644—Arsenic, antimony or bismuth
    • B01J23/6447—Bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8973—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/62—Use of additives, e.g. for stabilisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La presente invención se refiere a un proceso para producir metacrilato de metilo, el proceso comprende poner en contacto reactivos que comprenden metacroleína, metanol y un gas que contiene oxígeno, bajo condiciones de reacción en la presencia de un catalizador sólido que comprende paladio, bismuto y al menos un tercer elemento X seleccionado del grupo que consiste de Fe, Zn, Ge, y Pb, en donde el catalizador sólido comprende además un soporte seleccionado de al menos un miembro del grupo que consiste de sílice y alúmina.
MX2016000765A 2013-07-29 2014-07-29 Preparacion de metacrilato de metilo a traves de un proceso de esterificacion oxidativa. MX2016000765A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201361859544P 2013-07-29 2013-07-29
PCT/US2014/048665 WO2015017436A1 (en) 2013-07-29 2014-07-29 Preparation of methyl methacrylate via an oxidative esterification process

Publications (1)

Publication Number Publication Date
MX2016000765A true MX2016000765A (es) 2016-04-19

Family

ID=51303129

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2016000765A MX2016000765A (es) 2013-07-29 2014-07-29 Preparacion de metacrilato de metilo a traves de un proceso de esterificacion oxidativa.

Country Status (9)

Country Link
US (1) US20160207870A1 (es)
EP (1) EP2989076A1 (es)
JP (1) JP2016527267A (es)
KR (1) KR20160035591A (es)
CN (1) CN105377805A (es)
CA (1) CA2918402A1 (es)
MX (1) MX2016000765A (es)
TW (1) TW201512168A (es)
WO (1) WO2015017436A1 (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112016008906B1 (pt) 2013-10-28 2021-12-07 Rohm And Haas Company Processo para preparar metil metacrilato
KR102567215B1 (ko) * 2017-05-25 2023-08-16 롬 앤드 하아스 컴패니 메타크롤레인을 제조하는 방법
CN109694946B (zh) 2017-10-24 2020-06-23 宝山钢铁股份有限公司 快速加热冷轧带钢的装置与方法
GB201721527D0 (en) * 2017-12-21 2018-02-07 Johnson Matthey Japan Godo Kaisha Oxidation catalyst for a diesel engine exhaust
US11577225B2 (en) * 2018-01-10 2023-02-14 Dow Global Technologies Llc Heterogeneous catalyst

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997003751A1 (en) * 1995-07-18 1997-02-06 Asahi Kasei Kogyo Kabushiki Kaisha Catalyst for the preparation of carboxylic esters
JPH09216850A (ja) * 1996-02-09 1997-08-19 Mitsubishi Rayon Co Ltd カルボン酸エステルの製造方法
JP3103500B2 (ja) * 1996-02-14 2000-10-30 三菱レイヨン株式会社 カルボン酸エステルの製造方法
TW385304B (en) * 1996-09-10 2000-03-21 Asahi Chemical Ind Process for producing methacrylic acid ester or acrylic acid ester
JPH10158124A (ja) * 1996-11-25 1998-06-16 Pola Chem Ind Inc 発毛・育毛料
JP3313993B2 (ja) * 1996-11-29 2002-08-12 三菱レイヨン株式会社 カルボン酸エステルの製造法
JP3297342B2 (ja) * 1997-03-24 2002-07-02 三菱レイヨン株式会社 カルボン酸エステルの製造法
JP2002241345A (ja) * 2001-02-13 2002-08-28 Asahi Kasei Corp カルボン酸エステルの製造方法
CN101074192A (zh) * 2007-06-20 2007-11-21 天津大学 以甲醛为原料制备甲基丙烯酸甲酯的方法
CN101815579A (zh) * 2007-08-13 2010-08-25 旭化成化学株式会社 羧酸酯制造用催化剂、其制造方法、以及羧酸酯的制造方法

Also Published As

Publication number Publication date
KR20160035591A (ko) 2016-03-31
EP2989076A1 (en) 2016-03-02
US20160207870A1 (en) 2016-07-21
TW201512168A (zh) 2015-04-01
CN105377805A (zh) 2016-03-02
WO2015017436A1 (en) 2015-02-05
CA2918402A1 (en) 2015-02-05
JP2016527267A (ja) 2016-09-08

Similar Documents

Publication Publication Date Title
MX2016000765A (es) Preparacion de metacrilato de metilo a traves de un proceso de esterificacion oxidativa.
GB201000078D0 (en) Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporatng such ligands
MX2016000767A (es) Preparacion de acrilato de metilo a traves de un proceso de esterificacion oxidativa.
MX2014008253A (es) Catalizadores de hidrogenacion con soportes modificados con cobalto.
ZA201009103B (en) Process for the carbonylation of ethylenically unsaturated compounds,novel carbonylation ligands and catalyst systems incorporating such ligands
EP3471877A4 (en) DIESEL OXIDATION CATALYST WITH PALLADIUM
EP2321386A4 (en) CATALYTIC PARTIAL OXIDATION REFORMATION
EP3056482A4 (en) Method for producing unsaturated carboxylic acid, and supported catalyst
SG11201406832UA (en) Method for producing molded catalyst and method for producing diene or unsaturated aldehyde and/or unsaturated carboxylic acid using said molded catalyst
MX2010009196A (es) Metodo para producir compuestos de carbonilo olefinicamente insaturados mediante la deshidrogenacion oxidante de alcoholes.
ZA200903534B (en) Process for producing alkenes from oxygenates by using supported heteropolyacid catalysts
UA104881C2 (uk) Спосіб карбонілування з використанням зв'язаних морденітних каталізаторів, які містять срібло й/або мідь
EP2611538A4 (en) CATALYTIC COMPOSITION FOR HYDROFORMYLATION REACTION AND HYDROFORMYLATION PROCESS USING THE SAME
EA200802002A1 (ru) Каталитическая система
EP2513074A4 (en) PROCESS FOR THE PRODUCTION OF OLEFINOXIDE
EP2329881A4 (en) METHANOL DEHYDRATION CATALYST FOR THE PREPARATION OF METHYL FORMAT AND METHYL FORMAT PRODUCTION METHOD
MY167613A (en) Mathod of manufacturing magnetic recording medium and magnetic recording medium
MX2011006179A (es) Transesterificacion de una sola etapa de materia prima de alimentacion usando catalizador gaseoso.
FR2934262B1 (fr) Procede de fabrication de dialcoxyalcanes par oxydation partielle d'alcools inferieurs en presence d'un catalyseur a base d'un oxyde mixte de molybdene
MX2016000764A (es) Preparacion de metacrilato de metilo a traves de un proceso de esterificacion oxidativa.
ZA201402604B (en) A catalyst bed system for an endothermic catalytic dehydrogenation process and an endothermic dehydrogenation process
WO2009013174A3 (de) Verfahren zur herstellung von olefinen durch umsetzung von kohlenmonoxid mit wasserstoff
EA201400926A1 (ru) Платино-палладиевый катализатор на цеолитном носителе
IN2012DN02459A (es)
SI2370386T1 (sl) Postopek za oksidacijo metanola v formaldehid na mirujoči katalitski plasti