MX2012005136A - Proceso integrado para produccion de fluoro-olefina. - Google Patents
Proceso integrado para produccion de fluoro-olefina.Info
- Publication number
- MX2012005136A MX2012005136A MX2012005136A MX2012005136A MX2012005136A MX 2012005136 A MX2012005136 A MX 2012005136A MX 2012005136 A MX2012005136 A MX 2012005136A MX 2012005136 A MX2012005136 A MX 2012005136A MX 2012005136 A MX2012005136 A MX 2012005136A
- Authority
- MX
- Mexico
- Prior art keywords
- hydrofluorination
- hcfc
- vapor phase
- liquid phase
- tcp
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000007791 liquid phase Substances 0.000 abstract 4
- UMGQVBVEWTXECF-UHFFFAOYSA-N 1,1,2,3-tetrachloroprop-1-ene Chemical compound ClCC(Cl)=C(Cl)Cl UMGQVBVEWTXECF-UHFFFAOYSA-N 0.000 abstract 3
- 239000012808 vapor phase Substances 0.000 abstract 3
- FXRLMCRCYDHQFW-UHFFFAOYSA-N 2,3,3,3-tetrafluoropropene Chemical compound FC(=C)C(F)(F)F FXRLMCRCYDHQFW-UHFFFAOYSA-N 0.000 abstract 2
- SMCNZLDHTZESTK-UHFFFAOYSA-N 2-chloro-1,1,1,2-tetrafluoropropane Chemical compound CC(F)(Cl)C(F)(F)F SMCNZLDHTZESTK-UHFFFAOYSA-N 0.000 abstract 1
- 238000013019 agitation Methods 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 230000006835 compression Effects 0.000 abstract 1
- 238000007906 compression Methods 0.000 abstract 1
- 238000007033 dehydrochlorination reaction Methods 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C21/00—Acyclic unsaturated compounds containing halogen atoms
- C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
- C07C21/18—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/01—Chlorine; Hydrogen chloride
- C01B7/07—Purification ; Separation
- C01B7/0706—Purification ; Separation of hydrogen chloride
- C01B7/0718—Purification ; Separation of hydrogen chloride by adsorption
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/01—Chlorine; Hydrogen chloride
- C01B7/07—Purification ; Separation
- C01B7/0706—Purification ; Separation of hydrogen chloride
- C01B7/0731—Purification ; Separation of hydrogen chloride by extraction
- C01B7/0737—Purification ; Separation of hydrogen chloride by extraction hydrogen chloride being extracted
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/19—Fluorine; Hydrogen fluoride
- C01B7/191—Hydrogen fluoride
- C01B7/195—Separation; Purification
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/07—Preparation of halogenated hydrocarbons by addition of hydrogen halides
- C07C17/087—Preparation of halogenated hydrocarbons by addition of hydrogen halides to unsaturated halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
- C07C17/206—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being HX
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Se describe un proceso para la manufactura de HFO1234yf de TCP en tres pasos integrados que incluyen hidrofluoración de TCP (tetracloropropeno) a HCF-1233xf en la fase de vapor seguido por hidrofluoración de HCFC-1233xf a HCFC-244bb en la fase líquida que se sigue después por deshidrocloración en fase líquida o de vapor para producir HFO-1234yf. La hidrofluoración en fase de vapor se lleva a cabo a una presión superior que la hidrofluoración en fase líquida, eliminando así la necesidad de compresión y/o recuperación intermedia. También, cualquier HC1 generado de esta reacción se alimenta a la sección de hidrofluoración en fase líquida para promover agitación y mezclado. Esto da como resultado un proceso más económico de un capital inicial y costo de operación contra la conducción de los 3 pasos secuencialmente.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/611,288 US8618340B2 (en) | 2009-11-03 | 2009-11-03 | Integrated process for fluoro-olefin production |
| PCT/US2010/053486 WO2011056441A2 (en) | 2009-11-03 | 2010-10-21 | Integrated process for fluoro-olefin production |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2012005136A true MX2012005136A (es) | 2012-05-23 |
Family
ID=43926113
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2012005136A MX2012005136A (es) | 2009-11-03 | 2010-10-21 | Proceso integrado para produccion de fluoro-olefina. |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US8618340B2 (es) |
| EP (1) | EP2496541B1 (es) |
| JP (1) | JP5732062B2 (es) |
| CN (1) | CN102656132B (es) |
| ES (1) | ES2509640T3 (es) |
| MX (1) | MX2012005136A (es) |
| WO (1) | WO2011056441A2 (es) |
Families Citing this family (52)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20230150900A1 (en) * | 2004-04-29 | 2023-05-18 | Honeywell International Inc. | Method for producing fluorinated organic compounds |
| US9024092B2 (en) * | 2006-01-03 | 2015-05-05 | Honeywell International Inc. | Method for producing fluorinated organic compounds |
| US8952208B2 (en) * | 2006-01-03 | 2015-02-10 | Honeywell International Inc. | Method for prolonging a catalyst's life during hydrofluorination |
| US20170253545A1 (en) | 2007-01-03 | 2017-09-07 | Honeywell International Inc. | Process for producing 2,3,3,3-tetrafluoropropene |
| US9670117B2 (en) | 2007-01-03 | 2017-06-06 | Honeywell International Inc. | Process for producing 2,3,3,3-tetrafluoropropene |
| US8563789B2 (en) * | 2007-06-27 | 2013-10-22 | Arkema Inc. | Process for the manufacture of hydrofluoroolefins |
| US8846990B2 (en) | 2007-07-06 | 2014-09-30 | Honeywell International Inc. | Process for producing 2,3,3,3-tetrafluoropropene |
| US9493384B2 (en) | 2007-07-06 | 2016-11-15 | Honeywell International Inc. | Process for producing 2,3,3,3-tetrafluoropropene |
| US9890096B2 (en) * | 2011-01-19 | 2018-02-13 | Honeywell International Inc. | Methods of making 2,3,3,3-tetrafluoro-2-propene |
| US9000240B2 (en) | 2011-05-19 | 2015-04-07 | Honeywell International Inc. | Integrated process for the production of 1-chloro-3,3,3-trifluoropropene |
| WO2013039260A2 (en) * | 2011-09-15 | 2013-03-21 | Daikin Industries, Ltd. | Method for purifying chlorinated hydrocarbon |
| EP2760812A4 (en) * | 2011-09-30 | 2015-08-05 | Honeywell Int Inc | PROCESS FOR THE PREPARATION OF 2,3,3,3-TETRAFLUOROPROPES |
| IN2014DN02371A (es) * | 2011-09-30 | 2015-05-15 | Honeywell Int Inc | |
| EP2751058A4 (en) * | 2011-09-30 | 2015-05-20 | Honeywell Int Inc | PROCESS FOR PRODUCING 2,3,3,3-TETRAFLUOROPROPENE |
| US8796493B2 (en) * | 2011-09-30 | 2014-08-05 | Honeywell International Inc. | Methods to separate halogentated olefins from 2-chloro-1,1,1,2-tetrafluoropropane using a solid adsorbent |
| KR20140077958A (ko) * | 2011-10-14 | 2014-06-24 | 허니웰 인터내셔날 인코포레이티드 | 2,3,3,3-테트라플루오로프로펜의 제조 방법 |
| MX357840B (es) * | 2011-11-04 | 2018-07-26 | Bektesevic Selma | Proceso para producir 2,3,3,3-tetrafluoropropeno. |
| US10131597B2 (en) * | 2011-11-04 | 2018-11-20 | Honeywell International Inc. | Process for producing 2,3,3,3-tetrafluoropropene |
| US9102580B2 (en) | 2011-11-10 | 2015-08-11 | The Chemours Company Fc, Llc | Catalytic fluorination process of making hydrohaloalkane |
| US20130158250A1 (en) * | 2011-12-16 | 2013-06-20 | Honeywell International, Inc. | Method of deacidifying cellulose based materials |
| EP2812298A4 (en) * | 2012-02-10 | 2015-09-16 | Haiyou Wang | IMPROVED PROCESS FOR PRODUCING 2,3,3,3-TETRAFLUOROPROPENE |
| IN2014DN06718A (es) * | 2012-02-29 | 2015-05-22 | Honeywell Int Inc | |
| ES2568619T3 (es) * | 2012-03-22 | 2016-05-03 | Daikin Industries, Ltd. | Procedimiento para preparar 2-cloro-3,3,3-trifluoropropeno |
| US9018428B2 (en) | 2012-09-06 | 2015-04-28 | Honeywell International Inc. | Reactor and agitator useful in a process for making 1-chloro-3,3,3-trifluoropropene |
| WO2014164611A1 (en) | 2013-03-12 | 2014-10-09 | Honeywell International Inc. | A method for mitigating hfc-245cb formation during hcfo-1233xf hydrofluorination to hcfc-244bb |
| US9394217B2 (en) | 2013-03-13 | 2016-07-19 | Honeywell International, Inc. | Staged fluorination process and reactor system |
| US9353029B2 (en) * | 2013-03-14 | 2016-05-31 | Honeywell International, Inc. | Fluorination process and reactor |
| US9272968B2 (en) | 2013-03-14 | 2016-03-01 | Honeywell International Inc. | Process to suppress the formation of 3,3,3-trifluoropropyne in fluorocarbon manufacture |
| US9233895B2 (en) | 2013-03-15 | 2016-01-12 | Honeywell International, Inc. | Process to manufacture 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb) |
| US20140275651A1 (en) * | 2013-03-15 | 2014-09-18 | Honeywell International Inc. | Process for producing 2,3,3,3-tetrafluoropropene |
| US9334206B2 (en) * | 2013-03-15 | 2016-05-10 | Honeywell International Inc. | Integrated process to produce 2,3,3,3-tetrafluoropropene |
| JP2016511285A (ja) * | 2013-03-15 | 2016-04-14 | ハネウェル・インターナショナル・インコーポレーテッド | 2,3,3,3−テトラフルオロプロペン生成物中のハロゲン化エチレン不純物を除去する方法 |
| MX2015011268A (es) * | 2013-03-15 | 2015-12-03 | Honeywell Int Inc | Proceso de fabricacion de 2-cloro-1,1,1,2-tetrafluoropropano (hcfc-244bb). |
| FR3003565B1 (fr) * | 2013-03-20 | 2018-06-29 | Arkema France | Composition comprenant hf et 2,3,3,3-tetrafluoropropene |
| PT2986583T (pt) | 2013-04-18 | 2019-09-17 | Honeywell Int Inc | Sistema de reação e processo para a produção de orgânicos fluorados |
| JP5825299B2 (ja) | 2013-07-12 | 2015-12-02 | ダイキン工業株式会社 | 2,3,3,3−テトラフルオロプロペンの製造方法 |
| MX2016010294A (es) * | 2014-02-10 | 2016-10-17 | Honeywell Int Inc | Diseño de reactor para la fluoracion en fase liquida. |
| JP6210073B2 (ja) * | 2015-01-21 | 2017-10-11 | ダイキン工業株式会社 | フルオロプロペンの製造方法 |
| JP6962822B2 (ja) | 2015-05-21 | 2021-11-05 | ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー | SbF5による1233xfの244bbへのフッ化水素処理 |
| US10005705B2 (en) | 2015-11-12 | 2018-06-26 | Honeywell International Inc. | Process for the production of fluorinated cyclobutane |
| US9790151B2 (en) | 2015-11-12 | 2017-10-17 | Honeywell International Inc. | Process for making 2,3,3,3-tetrafluoropropene and/or vinylidine fluoride |
| WO2018089362A1 (en) | 2016-11-08 | 2018-05-17 | Honeywell International Inc. | A process for the production of fluorinated cyclobutane |
| US9856193B2 (en) | 2015-11-12 | 2018-01-02 | Honeywell International Inc. | Process for the production of fluorinated cyclobutane |
| WO2018231764A1 (en) * | 2017-06-12 | 2018-12-20 | Honeywell International Inc. | Method to produce hfo-1234yf from tcp by suppressing the bubble/dew point |
| CN112313199A (zh) | 2018-06-06 | 2021-02-02 | 霍尼韦尔国际公司 | 用于HCFC-244bb的脱氯化氢以制备HFO-1234yf的方法 |
| KR20250138823A (ko) | 2018-08-24 | 2025-09-22 | 허니웰 인터내셔날 인코포레이티드 | 트라이플루오로요오도메탄 및 트라이플루오로아세틸 요오다이드의 제조 방법 |
| CN113796173B (zh) | 2018-12-21 | 2025-04-08 | 霍尼韦尔国际公司 | 热传递方法、系统和流体 |
| CN109534951B (zh) * | 2018-12-30 | 2021-09-28 | 山东华安新材料有限公司 | 一种2,3,3,3-四氟丙烯混合物的分离装置及分离方法 |
| US11554956B2 (en) | 2019-04-16 | 2023-01-17 | Honeywell International Inc. | Integrated process and catalysts for manufacturing hydrogen iodide from hydrogen and iodine |
| CN113966320A (zh) * | 2019-06-04 | 2022-01-21 | 科慕埃弗西有限公司 | 2-氯-3,3,3-三氟丙烯(1233xf)组合物和用于制备和使用该组合物的方法 |
| CN113906165B (zh) * | 2019-08-30 | 2024-10-29 | 株式会社力森诺科 | 氟气的制造方法 |
| CN114599630A (zh) * | 2019-11-06 | 2022-06-07 | 霍尼韦尔国际公司 | 2-氯-1,1,1,2-四氟丙烷(hcfc-244bb)和水的共沸物或类共沸物组合物 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1972887B (zh) * | 2004-04-29 | 2010-10-13 | 霍尼韦尔国际公司 | 1,3,3,3-四氟丙烯的合成方法 |
| US8058486B2 (en) | 2004-04-29 | 2011-11-15 | Honeywell International Inc. | Integrated process to produce 2,3,3,3-tetrafluoropropene |
| US8084653B2 (en) * | 2004-04-29 | 2011-12-27 | Honeywell International, Inc. | Method for producing fluorinated organic compounds |
| US8071825B2 (en) * | 2006-01-03 | 2011-12-06 | Honeywell International Inc. | Method for producing fluorinated organic compounds |
| DK3336074T3 (da) * | 2006-01-03 | 2025-08-25 | Honeywell Int Inc | Fremgangsmåde til produktion af fluorinerede, organiske forbindelser |
| US7906693B2 (en) | 2006-10-31 | 2011-03-15 | E.I. Du Pont De Nemours And Company | Processes for producing 2,3,3,3-tetrafluoropropene, a process for producing 1-chloro-2,3,3,3-pentafluoropropane and azeotropic compositions of 1-chloro-2,3,3,3-tetrafluoropropene with HF |
| US8318992B2 (en) | 2006-10-31 | 2012-11-27 | E I Du Pont De Nemours And Company | Processes for the production of fluoropropanes and halopropenes |
| TW200837036A (en) | 2006-11-15 | 2008-09-16 | Du Pont | Process for producing 2,3,3,3-tetrafluoropropene |
| US9040759B2 (en) * | 2007-07-06 | 2015-05-26 | Honeywell International Inc. | Preparation of fluorinated olefins via catalytic dehydrohalogenation of halogenated hydrocarbons |
| US7795480B2 (en) * | 2007-07-25 | 2010-09-14 | Honeywell International Inc. | Method for producing 2-chloro-3,3,3,-trifluoropropene (HCFC-1233xf) |
| EP2185489B1 (en) | 2007-09-11 | 2013-03-20 | Daikin Industries, Ltd. | Process for producing 2,3,3,3-tetrafluoropropene |
| US9079818B2 (en) * | 2007-10-15 | 2015-07-14 | Honeywell International Inc. | Process for synthesis of fluorinated olefins |
-
2009
- 2009-11-03 US US12/611,288 patent/US8618340B2/en active Active
-
2010
- 2010-10-21 EP EP10828789.7A patent/EP2496541B1/en not_active Not-in-force
- 2010-10-21 ES ES10828789.7T patent/ES2509640T3/es active Active
- 2010-10-21 CN CN201080049776.2A patent/CN102656132B/zh active Active
- 2010-10-21 JP JP2012537902A patent/JP5732062B2/ja active Active
- 2010-10-21 WO PCT/US2010/053486 patent/WO2011056441A2/en not_active Ceased
- 2010-10-21 MX MX2012005136A patent/MX2012005136A/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| US20110105807A1 (en) | 2011-05-05 |
| WO2011056441A2 (en) | 2011-05-12 |
| EP2496541A4 (en) | 2013-03-13 |
| US8618340B2 (en) | 2013-12-31 |
| CN102656132A (zh) | 2012-09-05 |
| JP2013510148A (ja) | 2013-03-21 |
| ES2509640T3 (es) | 2014-10-17 |
| EP2496541B1 (en) | 2014-08-06 |
| EP2496541A2 (en) | 2012-09-12 |
| WO2011056441A3 (en) | 2011-09-15 |
| CN102656132B (zh) | 2014-11-26 |
| JP5732062B2 (ja) | 2015-06-10 |
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Legal Events
| Date | Code | Title | Description |
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| FG | Grant or registration |