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MX2007012985A - Procedimiento y catalizadores para la epoxidacion de compuestos olefinicos en presencia de oxigeno. - Google Patents

Procedimiento y catalizadores para la epoxidacion de compuestos olefinicos en presencia de oxigeno.

Info

Publication number
MX2007012985A
MX2007012985A MX2007012985A MX2007012985A MX2007012985A MX 2007012985 A MX2007012985 A MX 2007012985A MX 2007012985 A MX2007012985 A MX 2007012985A MX 2007012985 A MX2007012985 A MX 2007012985A MX 2007012985 A MX2007012985 A MX 2007012985A
Authority
MX
Mexico
Prior art keywords
epoxidation
oxygen
catalysts
olefinic compounds
mixtures
Prior art date
Application number
MX2007012985A
Other languages
English (en)
Inventor
Avelino Corma Canos
Marcelo Eduardo Domine
Original Assignee
Consejo Superior Investigacion
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Consejo Superior Investigacion filed Critical Consejo Superior Investigacion
Publication of MX2007012985A publication Critical patent/MX2007012985A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
    • B01J29/0316—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41 containing iron group metals, noble metals or copper
    • B01J29/0325—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/32—Reaction with silicon compounds, e.g. TEOS, siliconfluoride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/393—Metal or metal oxide crystallite size

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

La presente invencion se refiere a un procedimiento para la epoxidacion de un compuesto olefinico, caracterizado porque comprende realizar una reaccion de oxidacion de al menos un compuesto olefinico que contiene uno o mas dobles enlaces C=C, con oxigeno, en presencia de uno o mas agentes iniciadores de la reaccion, al menos un catalizador, que comprende al menos un metal seleccionado entre metal noble. un metal de transicion y mezclas de ellos, y al menos un hidrocarburo seleccionado entre uno o mas alcanos ramificados, uno o mas hidrocarburos ciclicos o alquil-ciclicos, uno o mas compuestos aromaticos o alquil-aromaticos, y mezclas de ellos.
MX2007012985A 2005-04-19 2006-04-06 Procedimiento y catalizadores para la epoxidacion de compuestos olefinicos en presencia de oxigeno. MX2007012985A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ES200500994A ES2261080B1 (es) 2005-04-19 2005-04-19 Procedimiento y catalizadores para la expoxidacion de compuestos olefinicos en presencia de oxigeno.
PCT/ES2006/070044 WO2006111600A1 (es) 2005-04-19 2006-04-06 Procedimiento y catalizadores para la epoxidación de compuestos olefínicos en presencia de oxígeno

Publications (1)

Publication Number Publication Date
MX2007012985A true MX2007012985A (es) 2008-03-13

Family

ID=37114740

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2007012985A MX2007012985A (es) 2005-04-19 2006-04-06 Procedimiento y catalizadores para la epoxidacion de compuestos olefinicos en presencia de oxigeno.

Country Status (9)

Country Link
US (1) US20090234145A1 (es)
EP (1) EP1876176A1 (es)
JP (1) JP2008536897A (es)
KR (1) KR20080003893A (es)
CN (1) CN101184740A (es)
BR (1) BRPI0612973A2 (es)
ES (1) ES2261080B1 (es)
MX (1) MX2007012985A (es)
WO (1) WO2006111600A1 (es)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101781275B (zh) * 2010-03-25 2012-04-11 中南大学 一种4,5-环氧-α-紫罗兰酮的合成方法
CN102807538B (zh) * 2011-06-02 2014-08-06 中国石油化工股份有限公司 一种制备环氧丙烷的方法
CN102875491A (zh) * 2011-07-13 2013-01-16 湖北大学 钴负载的沸石分子筛高选择性催化烯烃与空气环氧化方法
CN103288781B (zh) * 2012-02-29 2015-04-29 中国石油化工股份有限公司 一种制备环氧氯丙烷的方法
CN103288779B (zh) * 2012-02-29 2015-04-29 中国石油化工股份有限公司 一种烯丙醇氧化的方法
CN102935377A (zh) * 2012-11-22 2013-02-20 北京科技大学 一种苯乙烯催化氧化为环氧苯乙烷的催化剂的制备方法
CN104499055B (zh) * 2014-12-19 2017-01-18 中国科学技术大学先进技术研究院 一种有孪晶界的Au75Pd25二十面体纳米晶体及其制备方法和应用
EP3341123B1 (en) 2015-08-28 2019-10-30 Lyondell Chemical Technology, L.P. Epoxidation catalysts
CN105170176B (zh) * 2015-09-30 2017-05-17 万华化学集团股份有限公司 一种烯烃环氧化催化剂及其制备方法和应用
WO2018140466A1 (en) * 2017-01-24 2018-08-02 Lyondell Chemical Technology, L.P. Liquid phase selective oxidation to epoxides with molecular oxygen
CN109926098B (zh) * 2017-12-15 2021-07-13 中国科学院大连化学物理研究所 一种气体助剂改性丙烯环氧化制备环氧丙烷用催化剂及制备和应用
CN110314689A (zh) * 2018-03-29 2019-10-11 武汉纺织大学 一种棒状臭氧催化剂Cu-OMS-2的制备方法与应用
CN113840651A (zh) * 2019-05-15 2021-12-24 利安德化学技术有限公司 干燥环氧丙烷的方法
CN112791744B (zh) * 2020-12-22 2024-03-19 上海华峰新材料研发科技有限公司 一种改性钛硅分子筛及其制备方法和应用
CN115069245B (zh) * 2021-03-15 2024-03-26 中国石油化工股份有限公司 一种乙烯氧化生产环氧乙烷用银催化剂及其制备方法和应用
CN114713242A (zh) * 2022-05-11 2022-07-08 榆林学院 一种用于长链α烯烃环氧化反应金属氧化物催化剂制备方法
CN116813570B (zh) * 2023-06-29 2025-11-21 上海应用技术大学 一种改性二氧化钛光催化环己烯合成环氧环己烷的方法

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US3403193A (en) * 1965-06-28 1968-09-24 Halcon International Inc Process for the co-production of a styrene and a di-olefin
US3459810A (en) * 1965-12-30 1969-08-05 Halcon International Inc Process for the preparation of ethylbenzene hydroperoxide
FR2243169B1 (es) * 1973-09-07 1976-07-23 Anvar
US4474974A (en) * 1983-04-21 1984-10-02 Texaco Inc. Propylene oxide by direct oxidation in chlorobenzene and halocarbons with a silver catalyst
BR9710995A (pt) * 1996-07-01 2000-03-14 Dow Chemical Co Processo para preparar um óxido de olefina, processo para preparar óxido de propileno, composição de catalisador e processo para regenerar uma composição de catalisador
US6252095B1 (en) * 1998-02-24 2001-06-26 Director-General Of Agency Of Industrial Science And Technology Catalyst for partially oxidizing unsaturated hydrocarbon
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Also Published As

Publication number Publication date
WO2006111600A1 (es) 2006-10-26
JP2008536897A (ja) 2008-09-11
EP1876176A1 (en) 2008-01-09
US20090234145A1 (en) 2009-09-17
BRPI0612973A2 (pt) 2010-12-14
KR20080003893A (ko) 2008-01-08
ES2261080A1 (es) 2006-11-01
ES2261080B1 (es) 2007-12-16
CN101184740A (zh) 2008-05-21

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