WO2023148106A1 - Verfahren zur herstellung einer halbleiteranordnung und halbleiteranordnung - Google Patents
Verfahren zur herstellung einer halbleiteranordnung und halbleiteranordnung Download PDFInfo
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- WO2023148106A1 WO2023148106A1 PCT/EP2023/052082 EP2023052082W WO2023148106A1 WO 2023148106 A1 WO2023148106 A1 WO 2023148106A1 EP 2023052082 W EP2023052082 W EP 2023052082W WO 2023148106 A1 WO2023148106 A1 WO 2023148106A1
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- H—ELECTRICITY
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- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
- H10H20/80—Constructional details
- H10H20/83—Electrodes
- H10H20/832—Electrodes characterised by their material
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- H—ELECTRICITY
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- H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
- H10H20/80—Constructional details
- H10H20/85—Packages
- H10H20/857—Interconnections, e.g. lead-frames, bond wires or solder balls
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- H—ELECTRICITY
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- H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
- H10H20/80—Constructional details
- H10H20/81—Bodies
- H10H20/819—Bodies characterised by their shape, e.g. curved or truncated substrates
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- H—ELECTRICITY
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- H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
- H10H20/80—Constructional details
- H10H20/83—Electrodes
- H10H20/831—Electrodes characterised by their shape
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H29/00—Integrated devices, or assemblies of multiple devices, comprising at least one light-emitting semiconductor element covered by group H10H20/00
- H10H29/01—Manufacture or treatment
- H10H29/011—Manufacture or treatment of integrated devices comprising at least one light-emitting semiconductor component covered by group H10H20/00
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- H—ELECTRICITY
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- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H29/00—Integrated devices, or assemblies of multiple devices, comprising at least one light-emitting semiconductor element covered by group H10H20/00
- H10H29/01—Manufacture or treatment
- H10H29/036—Manufacture or treatment of packages
- H10H29/0364—Manufacture or treatment of packages of interconnections
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H29/00—Integrated devices, or assemblies of multiple devices, comprising at least one light-emitting semiconductor element covered by group H10H20/00
- H10H29/10—Integrated devices comprising at least one light-emitting semiconductor component covered by group H10H20/00
- H10H29/14—Integrated devices comprising at least one light-emitting semiconductor component covered by group H10H20/00 comprising multiple light-emitting semiconductor components
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- H—ELECTRICITY
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- H10H—INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10H20/00—Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
- H10H20/01—Manufacture or treatment
- H10H20/032—Manufacture or treatment of electrodes
Definitions
- the present invention relates to a method for producing a semiconductor arrangement comprising at least one semiconductor component, a semiconductor arrangement comprising at least one semiconductor component, a method for producing an optoelectronic device comprising a multiplicity of semiconductor components, and an optoelectronic device comprising a multiplicity of semiconductor components.
- Semiconductor components such as B. LEDs, lasers, ICs or sensors can be placed from a donor substrate onto, for example, electrical contact areas of a target substrate, for example by means of a transfer printing process.
- an electrical and, in particular, thermal coupling of the semiconductor components with the contact surfaces is also required.
- the constant development in the field of semiconductor components, and in particular a desired increasing miniaturization of semiconductor components or. the devices comprising the semiconductor components also require a very precise setting of the semiconductor components at positions provided for this purpose.
- the setting of the semiconductor components includes, for example, a transfer process and a contacting process.
- the transfer process ie the lifting of the semiconductor components from a donor substrate and the transfer of the semiconductor components onto a target substrate, can take place at room temperature.
- the semiconductor components are only deposited on the target substrate, so that only a weak mechanical coupling, preferably through sticky plastic layers on the target substrate, is achieved between the semiconductor components and the target substrate.
- the semiconductor components Only in a second step, the contacting process, are the semiconductor components pressed onto contact surfaces on the target substrate at elevated temperature in such a way that the sticky plastic layer is pierced locally by roughness points on the contact surfaces of the semiconductor components and roughness points on the contact surfaces of the target substrate, thus forming electrical contacts.
- the increased temperature and subsequent cooling causes the sticky plastic layer to harden.
- the second step not only represents an expensive additional effort due to the "additional step", but rather often leads to the dejustification of chips.
- a precise setting of the semiconductor components cannot be guaranteed, so that the type and quality of the products that are made with can be produced by such a method is limited.
- a method for producing an optoelectronic device comprising a large number of semiconductor components and an optoelectronic device comprising a large number of semiconductor components, which also counteracts at least one of the aforementioned problems.
- Claim 20 specifies the features of a method according to the invention for producing an optoelectronic device and claim 25 specifies an optoelectronic device according to the invention. Further embodiments are the subject matter of the dependent claims.
- Semiconductor components that are suitable for transfer printing processes have so far been equipped with flat metal surfaces or equipped with metal layers of essentially constant thickness as electrical contact surfaces.
- the receiving areas/electrical contact areas on the target substrate also have easily deformable metal layers.
- metal contacts allow the semiconductor components to be mechanically, thermally and electrically coupled in one step by placing them on and pressing them onto the receiver substrate.
- the easy deformability of electrical contact surfaces allows a metallic or mechanical and electrical connection of the electrical contact surfaces at or near room temperature.
- the contact surfaces are deposited on the semiconductor components in an embedded and thus safe state in a first step, and then, before the semiconductor components are removed, a sufficiently deep cavity is created under the semiconductor components with a transfer tool, such as a stamp, so that the easily deformable electrical Pads are present essentially free-floating on the semiconductor components.
- a method for producing a semiconductor arrangement comprises the steps:
- Providing a functional layer stack comprising a carrier substrate, a first layer of a first conductivity type arranged on the carrier substrate, a second layer of a second conductivity type arranged on the first layer, and an active zone lying between the first and the second layer;
- tether layer on the patterned sacrificial layer or the optional release layer, the tether layer being at least partially disposed in the at least one opening;
- Such a method can be used to produce a semiconductor arrangement comprising at least one semiconductor component, such as a micro-LED.
- the at least one semiconductor component can be grown on the basis of gallium nitride, for example, has an easily deformable electrical contact surface, for example in the form of a lawn-like metal connection surface or Nanowire layer, and is particularly suitable for a transfer printing process.
- the semiconductor arrangement or the holding layer of the semiconductor device acts as a donor substrate from which at least one semiconductor component can be removed by means of a transfer printing method, for example, and placed on a target substrate.
- a functional layer stack is deposited as usual on an epitaxial substrate, hereinafter referred to as carrier substrate. grown up and endowed and/or structured depending on the application and need.
- the functional layer stack comprises at least one first layer arranged on the carrier substrate a first conductivity type, a second layer of a second conductivity type disposed on the first layer, and an active region located between the first and second layers.
- the first conductivity type can be an n-doping of the first layer and the second conductivity type can be a p-doping of the second layer.
- doping in the reverse order is also conceivable.
- the functional layer stack can each have current spreading layers on the first or second layer include. In a later step, the semiconductor component is formed from the functional layer stack.
- a starter layer for example a 200 nm thick Au layer, is then applied over the entire surface for later formation of the nanowire layer on the side of the second layer facing away from the carrier substrate.
- the starting layer can in particular be an electrically conductive layer that allows a later galvanic deposition (electro-plating) of a metal in pores of an ion track-etched foil in order to produce the nanowires of the nanowire layer.
- Such a layer can serve to provide a better mechanical, electrical and also thermal connection between the functional layer stack and the nanowire layer, and can be formed, for example, by means of cathode sputtering.
- the nanowire layer on the side of the second layer or the starting layer before the nanowire layer on the side of the second layer or the starting layer is formed, areas in which no formation of the nanowire layer is to take place, masked, for example with a thin photoresist or silicon nitride layer.
- a structured mask is correspondingly applied to the side of the second layer or the starting layer is formed before the nanowire layer is formed this will .
- the electrically conductive nanowire layer can then then on the side facing away from the carrier substrate of the second layer or. the starting layer are formed in the areas that remain free of the structured Mas ke.
- the structured mask is formed on the side of the second layer facing away from the carrier substrate, and then the starting layer is formed or is applied, which remain free of the structured Mas ke.
- the starting layer can accordingly be present in a structured form on the carrier substrate.
- an ion track-etched film is used on the side of the second layer or layer facing away from the carrier substrate. applied to the starting layer.
- the ion track-etched film can only be applied in the areas that remain free of the structured mask.
- the ion track-etched film can also be applied to the structured mask over the entire surface.
- the film applied over the entire surface lies on the structured mask and areas that remain free from the structured mask also remain free from the ion track-etched film.
- the ion track-etched foil can be formed, for example, by a filter foil, for example made of polycarbonate (PC), polyimide (PI) or polyethylene terephthalate (PET), and can be used as a mask used for a galvanic deposition of "metal straws" or nanowires, since these have cavities or through-holes due to the ion track etching, which can then be filled with an electrically conductive material.
- PC polycarbonate
- PI polyimide
- PET polyethylene terephthalate
- a distribution of the angles that form the pores or through-holes with the film surface can differ depending on the film used.
- Such films can have a thickness of up to 25 pm or larger with cavities or through-holes with a diameter of 15 nm and larger
- a PC film with a pore or cavity diameter of 100 nm can be used in a preferred manner, so that metal straws, for example Gold (Au) straws with a diameter of 100 nm and a length of about 2 pm can be produced
- the metal straws can also be made of silver (Ag) , copper (Cu) or a correspondingly soft metal alloy
- the film can be selected in such a way that metal straws with a diameter of less than 1 pm or less than 200 nm can be produced, which have at least an 8-fold or have at least 10 times the length of the diameter.
- the application of the film to the side facing away from the carrier substrate of the second layer or the starting layer an application of a carrier material such as PC, PI or PET and subsequent etching of cavities or. Through-holes in the substrate by ion irradiation.
- the ion track-etched film can accordingly only on the second layer or. the starting layer are generated.
- an electrically conductive material is galvanically deposited on the film to form the nanowire layer. As a result, the cavities or Through-holes in the film are filled with the electrically conductive material, and the "metal straws" or nanowires are formed.
- the ion track-etched film is applied over the entire surface to a structured mask, such that areas that remain free from the structured mask remain free of the ion track-etched foil, these areas can first be filled with the electrically conductive material by electrolytic deposition of an electrically conductive material on the ion track-etched foil, before the cavities or through-holes of the foil are filled with the electrically conductive material filled, and accordingly the "metal straws" or Nanowires are formed.
- the ion track-etched film is not applied in all areas that remain free from the structured mask.
- areas of both the structured mask and the film can also remain free, which are then filled with the electrically conductive material in the course of the galvanic deposition of the latter.
- the electrically conductive material in addition to the areas of the nanowire layer, ie easily deformable areas, there are also areas that are less easily deformable, since they are formed by a more massive formation of the electrically conductive material.
- These more solid areas can then be used in the area of the at least one opening through the sacrificial layer as a fastening point for the holding layer or the separating layer serve .
- the step of forming the nanowire layer comprises a chemo-mechanical thinning or Polishing the Nanowire Layer .
- a chemo-mechanical thinning or Polishing the Nanowire Layer After the galvanic deposition, it is “polished down” chemo-mechanically down to the "metal straws" or nanowires.
- the thinning takes place in such a way that the "metal blades" or Nanowires in the nanowire layer then exist separately from each other or. are connected to each other only by the second layer or the starting layer.
- the nanowire layer can also be formed by a porous layer which has a porosity of more than 70%.
- the porous layer can be formed by galvanically depositing an electrically conductive material on a porous film.
- the nanowire layer can also be formed, for example, by a finely ramified network of electrically conductive material, with in particular local accumulations of material (pores).
- the nanowire layer can be characterized, for example, in that it can be compressed compared to a conventional electrically conductive contact layer due to its porosity.
- the film or in the case of a structured mask these are removed or etched away .
- the nanowire layer and/or the starting layer can also be removed or be etched away.
- a metal alloy for example an Au-Ag or an Ag-Cu alloy, is used to form the nanowire layer on the side of the second layer or layer facing away from the carrier substrate. the starting layer deposited. Then the less noble component of the
- Alloy for pore formation are dissolved out of the alloy, for example, a finely branched network of electrically conductive material, with in particular local accumulations of material (pores).
- the step of dissolving out the less noble component of the alloy can take place before the step of forming the sacrificial layer or after the step of removing the sacrificial layer.
- a sacrificial layer is deposited on the nanowire layer.
- the sacrificial layer can be a germanium or silicon sacrificial layer, for example.
- the sacrificial layer is either deposited in a structured manner or is subsequently structured after a continuous surface has been deposited.
- the sacrificial layer is structured in such a way that it then has at least one opening that passes through the sacrificial layer and optionally at least partially through the nanowire layer or Starting layer or the structured mask is enough.
- the at least one opening is arranged in particular in an area in which a support later formed by means of the separating layer and the retaining layer holds the at least one semiconductor component in position.
- part of the sacrificial layer is used as such instead of the foil.
- the foil forms a first part of the sacrificial layer.
- a first part of the sacrificial layer is formed on the side of the second layer or the starting layer deposited.
- an approx. 2 . 2 pm thick silicon layer on the second layer or. the starting layer are deposited and it can electrochemical cavities or.
- Through-holes or pores for example with an average diameter of 125 nm, are etched in the first part of the sacrificial layer.
- An electrically conductive material is then again galvanically deposited on the first part of the sacrificial layer and the cavities or Through holes or pores filled with the electrically conductive material.
- Such a procedure has the advantage that the sacrificial layer and the foil can be applied in just one step or an etching medium can be removed simultaneously.
- the film also forms the sacrificial layer at the same time.
- the separating layer would adhere to the nanowire layer or adjoin the film and the at least one semiconductor component corresponding to the time of removal of the sacrificial layer or. in this case keep in position from the moment of removing the film.
- a holding structure of this type merely via the nanowire layer can also be reinforced by means of additional metallic holding structures, which are reinforced by introducing larger through-holes through the film and then filling them up during the galvanic deposition.
- a separating layer that is resistant to an etching medium for later removal of the sacrificial layer for example silicon dioxide (SiO 2 ) is applied to the sacrificial layer over the entire surface.
- the separating layer serves in particular as a contact layer for the holding layer applied to the separating layer in the next step, and as a protective layer for the same in order to protect the holding layer against the etching medium for later removal of the sacrificial layer.
- the step of forming the holding layer on the separating layer comprises adhering the holding layer to the separating layer.
- the retaining layer it is also possible for the retaining layer to be formed on the separating layer by polymerization.
- divinylsiloxane-bis-benzocyclobutene in mesitylene (cyclotene) can be applied to the separating layer and polymerized to form benzocyclobutene.
- PI layers can also be used for the holding layer.
- the holding layer is at least partially arranged in the at least one opening and together with the separating layer in the area of the at least one opening forms a support which holds the at least one semiconductor component formed from the functional layer stack in subsequent steps in position.
- the holding layer serves in particular as a carrier substrate for the at least one semiconductor component and also acts as a donor substrate for a possible subsequent transfer printing process for transferring the at least one semiconductor component from the donor substrate to a target substrate.
- the layer stack that has been produced up to that point is rotated, and the epitaxial substrate or The carrier substrate of the functional layer stack, for example a sapphire substrate, is detached.
- the carrier substrate of the functional layer stack can be detached, for example by means of a laser lift-off method.
- the first layer or the side of the first layer facing away from the second layer is further processed in order to form, for example, a current spreading layer and/or an electrically conductive and in particular at least semi-transparent contact layer on the first layer.
- the functional layer stack is structured to produce at least one semiconductor component by having at least one depression in it introduced or is etched, the at least one semiconductor component from the rest of the functional layer stack or. other semiconductor components separates.
- the at least one depression extends through the entire functional layer stack to the sacrificial layer or, in the area of the at least one opening, to the optional separating layer.
- the step of structuring the functional layer stack includes a mesa etching of the functional layer stack to produce at least one semiconductor component.
- the at least one depression is produced by means of mesa etching and is correspondingly formed by at least one mesa trench.
- the at least one mesa ditch runs essentially conically or tapering towards the sacrificial or release layer .
- the resulting at least one semiconductor component correspondingly has a mesa structure.
- the step of removing the sacrificial layer takes place by means of dissolving, for example with hydrogen fluoride (HF) or with xenon difluoride (XeF2).
- HF hydrogen fluoride
- XeF2 xenon difluoride
- the removal of the sacrificial layer results between the at least one semiconductor component and the holding layer or the separating layer is a cavity, and the at least one semiconductor component is no longer on the sacrificial layer, but only in the region of the at least one opening or. Support with the optional separating layer or . connected to the holding layer.
- the foil during the step of removing the sacrificial layer removed by etching for example using chlorine trifluoride (C1F 3 ) or an organic solvent, so that the nanowire layer and in particular the "metal blades" or nanowires are at least partially exposed.
- C1F 3 chlorine trifluoride
- organic solvent for example using chlorine trifluoride (C1F 3 ) or an organic solvent
- the foil is already removed before the step of depositing the sacrificial layer on the nanowire layer.
- Metal straws of the nanowire layer are then filled—at least partially—with the material of the sacrificial layer during the step of depositing the sacrificial layer on the nanowire layer. This means that at a later point in time only one step or an etching medium is needed to remove the entire sacrificial layer and the nanowires or to expose metal stalks of the nanowire layer.
- the at least one opening through the sacrificial layer and the at least one depression through the functional layer stack are essentially directly opposite one another.
- the holding layer or Separation layer formed support in the region of at least one opening that hold at least one semiconductor component in an edge region thereof.
- the holding layer or The support formed by the separating layer holds, for example, the semiconductor components which are separated by the at least one depression and adjoin the support.
- the at least one opening through the sacrificial layer and the at least one depression through the functional layer stack are arranged offset to one another.
- each semiconductor component can be assigned its own support, which is formed in the at least one opening and holds the semiconductor component after the sacrificial layer has been removed.
- the support can for example, be arranged in the middle of the semiconductor component but also off-center from the same.
- the at least one semiconductor component or several semiconductor components in the semiconductor device can then be collectively recorded with a transfer stamp and of the semiconductor device or be detached from the support in order to then be transferred to a target substrate.
- a semiconductor arrangement which comprises at least one semiconductor component with a functional layer stack, the functional layer stack comprising a first layer of a first conductivity type, a second layer of a second conductivity type arranged on the first layer, a layer between the first and the second layer lying active zone, and having an electrically conductive nanowire layer, and wherein the electrically conductive nanowire layer is arranged at least in regions on a side facing away from the first layer of the second layer.
- the semiconductor arrangement also includes a holding layer with at least one elevation and a separating layer optionally arranged on the holding layer.
- the at least one semiconductor component is in such a way on the at least one elevation or Arranged support that there is a cavity between the at least one semiconductor component and the retaining layer and the nanowire layer is at least partially exposed.
- Such a semiconductor arrangement comprising at least one semiconductor component can serve as a donor substrate, for example, from which at least one semiconductor component can be removed by means of a transfer printing method, for example, and placed on a target substrate.
- the at least one semiconductor component can be a micro-LED, for example, which is grown on the basis of gallium nitride, for example, and which has a slightly deformed miscible electrical contact surface, for example in the form of a lawn-like metal pad or. Nanowire layer having.
- the at least one semiconductor component has a mesa structure, with at least one mesa trench or at least one depression for delimiting the at least one semiconductor component through the entire functional layer stack up to the cavity or, in the region of the at least one elevation or Support, extends up to the separating layer.
- the at least one mesa trench is essentially conical or tapering towards the cavity or the separating layer.
- the at least one semiconductor component has an electrically conductive and in particular at least semi-transparent contact layer on the side of the first layer facing away from the second layer.
- the contact layer can be formed from a material such as indium tin oxide (ITO), for example, and can provide an electrical connection surface for the at least one semiconductor component in addition to the electrically conductive nanowire layer.
- ITO indium tin oxide
- the at least one semiconductor component can correspondingly be electrically connectable to two opposite sides of the semiconductor component and correspondingly have a so-called “vertical current conduction”.
- the at least one semiconductor component is formed by a light-emitting or light-detecting component.
- the at least one semiconductor component can, for example, be an LED or be an LED chip or a photodiode.
- the LED or the LED chip can in particular also be referred to as a micro-LED, also called a pLED, or as a pLED chip, in particular if its light-emitting surface has edge lengths in a range from 100 ⁇ m to 10 ⁇ m or even significantly smaller edge lengths having .
- the LED or the LED chip can be an unpackaged semiconductor chip. Unpackaged means that the chip has no packaging around its semiconductor layers, such as e.g. B. a "chip die".
- unpackaged can mean that the chip is free of deliberately applied layers or encapsulations that comprise an organic material.
- the unpackaged device does not contain layers or encapsulations comprising organic compounds that contain carbon in covalent bonding.
- the bare device does not contain silicone, epoxy, or imide encapsulations.
- the at least one semiconductor component can be designed, for example, to emit light in the vertical direction, ie through the at least semi-transparent contact layer, or to detect light that impinges on the at least semi-transparent contact layer.
- the at least one semiconductor component is designed in the form of a volume emitter to emit light in both the vertical and lateral direction, or that the at least one semiconductor component is designed in the form of an edge emitter to emit light only in the lateral direction emit .
- the at least one semiconductor component further comprises a seed layer formed between the second layer and the nanowire layer.
- a seed layer formed between the second layer and the nanowire layer.
- Such a layer can serve to provide a better mechanical, electrical and thermal connection between the functional layer stack and the nanowire layer, and can be formed, for example, by means of cathode sputtering.
- the starting layer and the nanowire layer can be formed from the same material and merge into one another, so that the individual nanowires of the nanowire layer are essentially connected to one another via the starting layer.
- the nanowire layer of the at least one semiconductor component essentially covers the entire side of the second layer that faces away from the first layer. In this way, in particular, a particularly large-area electrical contact area can be provided on the at least one semiconductor component.
- the nanowire layer can be structured on the second layer. Structured, however, does not mean structuring in the form of individual nanowires, but that in addition to the nanowires there are areas on the second layer that remain free of the nanowire layer. Thus, for example, different electrical contact areas can be provided on one side of the at least one semiconductor component, or only material can be saved due to a reduction in the area covered with nanowires.
- the nanowire layer of the at least one semiconductor component there are a large number of "metal blades" or nanowires separate from one another. These can be arranged either periodically or randomly with respect to one another.
- the individual metal blades for example Au blades, can, for example have a diameter of 100 nm and a length of about 2 ⁇ m.
- the semiconductor device comprises at least two semiconductor components, which are formed by a depression, for example. in the form of a mesa trench, separated from each other next to each other on the at least one elevation or Support are arranged.
- the depression for delimiting the two semiconductor components extends through the entire functional layer stack to an optional separating layer arranged on the at least one elevation and runs essentially conically or. tapering towards the separating layer.
- the deepening and the elevation are essentially directly opposite one another.
- the through the holding layer or Elevation formed by the separating layer is designed to hold the at least two semiconductor components separated by the depression.
- the semiconductor device comprises at least two semiconductor components, which are formed by a depression, for example. in the form of a mesa trench, are arranged side by side, separated from one another, in each case on a separate elevation of the holding layer.
- the survey or In this case, support can in each case be arranged in the center of the semiconductor components, but also off-center from the same.
- a method for producing an optoelectronic device comprising the steps:
- a semiconductor arrangement in particular a semiconductor arrangement according to some of the aforementioned aspects, comprising at least one semiconductor component with an electrically conductive nanowire layer arranged on the side of the semiconductor component facing the holding layer.
- the at least one semiconductor component is arranged on at least one elevation of a holding layer in such a way that there is a cavity between the at least one semiconductor component and the holding layer and the nanowire layer is at least partially exposed.
- On the holding layer or an optional separating layer can also be formed between the retaining layer and the at least one half-liter component;
- At least one semiconductor component on a first contact area of a printed circuit board, the printed circuit board having a contact structure with a large number of contact areas on its upper side.
- at least the first contact area of the plurality of contact areas has an electrically conductive nanowire layer.
- the electrically conductive nanowire layer of the at least one first contact surface can be a nanowire layer, as is already the case for the semiconductor arrangement or Semiconductor component has been described. However, it can also be a porous layer or A finely ramified network of electrically conductive material, in particular with local accumulations of material (pores). Alternatively, however, it is also possible that the first contact surface zw by a conventional planar metal layer. Contact surface is formed.
- the method can be, for example, a transfer printing method for transferring at least one semiconductor component from a semiconductor arrangement comprising the semiconductor component (donor substrate) onto a printed circuit board (target substrate). Due to the nanowire layer both on the semiconductor component and on the printed circuit board, however, the process is simplified compared to the transfer printing processes currently used.
- the easily deformable electrical contact surfaces in the form of the Naonowire layers allow the semiconductor components to be mechanically, thermally and electrically coupled in one step by placing them on and pressing them onto the printed circuit board.
- the slight deformability of the electrical contact surfaces enables a metallic or mechanical and electrical connection of the electrical contact surfaces at or near room temperature.
- Semiconductor componentry is essentially accomplished in a single process step at or near room temperature.
- the at least one semiconductor component or more semiconductor components are added to a stamp and from the semiconductor assembly or. the retaining layer torn off.
- the relatively small contact area between the semiconductor component and the elevation or Support similar to a predetermined breaking point at which the semiconductor component is torn off. This ensures that only a small amount of force is required to lift off the at least one semiconductor component and that the at least one semiconductor component and in particular the nanowire layer is not damaged when it is lifted off.
- the step of depositing the at least one semiconductor component includes fixing the at least one semiconductor component on the first contact area by pressing the at least one semiconductor component onto the first contact area. Due to the turf-like structure of the nanowire layers and the easy deformability of the nanowire layers, a contact pressure of less than 1 MPa and preferably less than 0 is sufficient. 3 MPa from to produce a mechanical, thermal and electrical contact between the at least one semiconductor component and the first contact surface.
- the at least one semiconductor component is fixed essentially without a temperature-induced method, in particular by "cold welding".
- the deformation of the metal structures, which leads to “cold welding” can be carried out at or near room temperature.
- the cold welding at room temperature and low pressure succeeds better if the deformable hardly any structures or show no contamination.
- the nanowire layers cannot be stabilized with a protective lacquer for this purpose, but are only stabilized after or during the removal of the sacrificial layer or exposed by etching the cavities.
- the metal stalks or Nanowires of the nanowire layer correspondingly remain in the film in the semiconductor arrangement until after the cavities have been etched free.
- the proposed method can be used to provide a precise and nevertheless simplified assembly of at least one or more semiconductor components with large-area metallic coupling in the transfer printing process.
- an optoelectronic device comprising a printed circuit board on the upper side of which a contact structure with a multiplicity of contact surfaces is arranged.
- the optoelectronic device comprises a multiplicity of semiconductor components, each of which is based on one of the multiplicity are arranged by contact surfaces.
- the semiconductor components each have, at least in regions, an electrically conductive nanowire layer on an underside facing the contact structure, which is in an electrically conductive connection with the contact surfaces on the top side of the printed circuit board.
- the contact areas on the top side of the printed circuit board also have an electrically conductive nanowire layer. This is then in each case in an electrically conductive connection with the electrically conductive nanowire layer of the semiconductor components.
- the semiconductor components are the semiconductor components of the semiconductor arrangement or described in the context of the application. the semiconductor components produced as part of the described manufacturing method of the semiconductor arrangement, which were transferred in particular by means of the method described in this application from the semiconductor arrangement to the printed circuit board.
- the semiconductor components each have a mesa structure.
- the semiconductor components have, in particular, a functional layer stack with a first layer of a first conductivity type, a second layer of a second conductivity type arranged on the first layer, and an active zone located between the first and the second layer.
- the semiconductor components are each formed by optoelectronic semiconductor components or formed by light-emitting or light-detecting components.
- the semiconductor components can, for example, each be replaced by an LED or be formed an LED chip or a photodiode.
- the LED or the LED chip can in particular also be referred to as a micro-LED, also called pLED, or as a pLED chip, in particular in the event that its light-emitting Surface has edge lengths in a range from 100 ⁇ m to 10 ⁇ m or even significantly smaller edge lengths.
- the LED or the LED chip can be an unpackaged semiconductor chip.
- the optoelectronic semiconductor components each have an electrically conductive and in particular at least semi-transparent contact layer on a side of the semiconductor component opposite the printed circuit board.
- the semiconductor components can be designed, for example, to emit light in the vertical direction, that is to say through the at least semi-transparent contact layer, or to detect light which impinges on the at least semi-transparent contact layer.
- the semiconductor components are designed in the form of a volume emitter to emit light in both the vertical and lateral direction, or that the semiconductor components are designed in the form of an edge emitter to emit light only in the lateral direction.
- the semiconductor components each comprise a starting layer which is formed between a functional layer stack of the semiconductor component and the nanowire layer.
- the nanowire layer of the semiconductor components in each case essentially covers the entire underside of the semiconductor components, which faces the contact structure.
- Fig. 1 to 13 method steps of a method for producing a semiconductor arrangement according to some aspects of the proposed principle
- Fig. 14 to 19 method steps of a method for producing an optoelectronic device according to some aspects of the proposed principle.
- Fig. 1 to 13 show method steps of a method for manufacturing a semiconductor arrangement according to some aspects of the proposed principle.
- a functional layer stack 2 is provided.
- the functional layer stack 2 comprises a carrier substrate 3 , a first layer 4 of a first conductivity type arranged on the carrier substrate 3 , a second layer 5 of a second conductivity type arranged on the first layer 4 .
- an active zone is arranged between the first and the second layer 4 , 5 .
- the carrier substrate 3 forms an epitaxial substrate on which the first and the second layer 4, 5 are deposited or grew up .
- the functional layer stack 2 can also be doped and/or structured, depending on the application and requirements.
- the first conductivity type can be, for example, an n-doping of the first layer 4 and the second conductivity type can be a p-doping of the second layer 5 .
- the functional layer stack 2 can each have current spreading layers on the first or second layer 4, 5 and/or the active zone may have one or more quantum wells (QW). It is also possible for the functional layer stack 2 to have quantum well intermixing (QWI) at least in regions.
- a starting layer 6 is subsequently applied over the entire surface of the side of the second layer 5 facing away from the carrier substrate 3 .
- the starting layer 6 can be a thin gold, silver or copper layer, for example, which provides a better mechanical, electrical and thermal connection between the functional layer stack 2 and a nanowire layer arranged thereon in the further steps.
- a nanowire layer 9 is formed on the starting layer 6 in individual intermediate steps.
- an ion track-etched film 7 is arranged on the starting layer 6.
- the ion track-etched film 7 has cavities or through-holes due to ion track etching, which are then filled with the electrically conductive material 8.
- the electrically conductive material 8 which has been electro-deposited on the film 7 and protrudes beyond the film 7 is ground off or except for the "metal blades” or nanowires "polished down” so that the "metal blades” or nanowires in the nanowire layer 9 are then present separately from one another.
- a sacrificial layer 11 is deposited.
- the sacrificial layer 11 can be a germanium or silicon sacrificial layer, for example.
- the sacrificial layer 11 is either already deposited in a structured manner on the nanowire layer 9 or, as shown in the present example, subsequently structured after the deposition of a continuous surface (see FIG. 7).
- the sacrificial layer 11 is structured in such a way that it subsequently has at least one opening 12 which extends through the sacrificial layer 11 and through the nanowire layer 9 . The structuring of the nanowire layer 9 so that it is also shown in FIG. Having the opening shown in FIG.
- the opening 12 is arranged in particular in an area in which a support is formed in subsequent steps, which is intended to hold at least one semiconductor component of the semiconductor arrangement in position.
- a thin separating layer 13 is formed on the sacrificial layer 11 is in another, shown in FIG. 8 .
- the separating layer 13 is characterized in that it is resistant to an etching medium which is used for later removal of the sacrificial layer 11 .
- the separating layer 13 covers the entire surface of the sacrificial layer facing away from the functional layer stack 2 and also covers the inner sides of the opening 12 so that it is also partially arranged in the opening 12 .
- the separating layer 13 serves in particular as a contact layer for the holding layer 14 applied to the separating layer 13 in the next step shown in FIG.
- the holding layer 14 is formed on the separating layer 13 by polymerization.
- divinylsiloxane-bis-benzocyclobutene in mesitylene (cyclotene) can be applied to the separating layer 13 and polymerized to form benzocyclobutene.
- the holding layer 14 is at least partially arranged in the opening 12 and forms an elevation 23 in this area. Together with the separating layer 13, the elevation of the holding layer forms a support 23 which is intended to hold semiconductor components formed from the functional layer stack 2 in position in subsequent steps.
- a further auxiliary substrate 15 is applied to the holding layer, so that the stack of layers that has been produced up to that point can be rotated and further processed.
- the epitaxial substrate Carrier substrate 3 of functional layer stack 2 is also detached, which can be done, for example, by means of a laser lift-off method.
- an at least semi-transparent contact layer 16 in particular an ITO layer, is formed in a next step.
- the first layer 4 or the second layer 5 facing away from the side of the first layer 4 are processed or. eg . an additional current spreading layer can be formed on this.
- the functional layer stack 2 according to the illustration in FIG. 12 structured .
- depressions 17 are introduced or formed in the functional layer stack 2 . etched, which further separate the two semiconductor components 10 shown from one another.
- the depressions 17 extend through the entire functional layer stack 2 to the separating layer 13 or the sacrificial layer 11 .
- the depressions 17 are introduced in the course of a mesa etching for the production of the semiconductor components 10 .
- the depressions 17 form corresponding mesa trenches, which are conical or substantially. tapering towards the sacrificial or Separating layer 11, 13 run. Im in Fig .
- one of the depressions 17, more precisely the depression 17, runs between the two semiconductor components 10, centrally opposite the support 23 formed by the holding and the separating layer 13, 14.
- the semiconductor components rest on the support 23 in an edge area of the semiconductor components 10 , in particular in a comparatively small contact area.
- the sacrificial layer 13 removed or. released .
- This can be done, for example, with hydrogen fluoride (HF) or with xenon difluoride (XeF2).
- HF hydrogen fluoride
- XeF2 xenon difluoride
- the removal of the sacrificial layer 11 results between the semiconductor components 10 and the holding layer 14 or the separating layer 13 is a cavity, and the semiconductor components 10 are no longer connected via the sacrificial layer 11, but only in the region of the support 23 with the separating layer or connected to the holding layer 13 , 14 .
- the foil 7 is also removed by etching, for example using chlorine trifluoride (CIF3) or an organic solvent, so that the nanowire layer 9 and in particular the "metal blades" or nanowires of the nanowire layer 9 exposed .
- CCF3 chlorine trifluoride
- FIG. 2B shows an embodiment of a possible at the in FIG. 2A shown step subsequent method step.
- a structured mask 22 is applied to the starting layer 6 .
- the mask can be formed, for example, by a thin layer of photoresist or silicon nitride.
- the mask defines areas in which no formation of a nanowire layer 9 is to take place in the further process.
- FIGS. 3.1 to 13.1 also show method steps for producing at least one semiconductor arrangement 10 that follow the method step illustrated in FIG. 2B.
- the method steps illustrated in FIGS. 3.1 to 13.1 essentially correspond to the steps illustrated in FIGS. 3 to 13, with the difference that that the electrically conductive nanowire layer 9 is formed only in areas that remain free of the structured mask 22 .
- the nanowire layer 9 accordingly has a further structure in addition to the nanowires or metal straws. While the nanowires or metal straws can be understood as a type of structuring at the microscopic level, the superordinate structuring of the nanowire layer 9 at the macroscopic level should be understood as a structuring.
- the sacrificial layer 11 and the electrically conductive nanowire layer 9 or structured mask 22 are structured or the opening 12 is introduced into them in such a way that the opening 12 extends through the sacrificial layer 11 and the structured mask 22 and not directly through the nanowire layer 9.
- FIG. 13.1 shows a further embodiment of the semiconductor arrangement 1 corresponding to FIG. 13.
- Figure 3.2 shows an alternative to the step shown in Figure 3.1 and differs from Figure 3.1 in that the ion track-etched film 7 is not only in the areas that remain free from the structured mask but is applied to the structured mask 22 over the entire surface. This results in cavities between the starting layer 6 and the film 7 which are filled in a subsequent step, see FIG.
- This step, shown in FIG. 4.2, can then be followed by the steps shown in FIGS. 5 to 13 or 5.1 to 13.1.
- Figure 3.3 shows another alternative to the steps shown in Figures 3.1 and 3.2.
- the ion track-etched film 7 is also applied to the entire surface of the structured mask 22, but this is designed in such a way that it hugs the contour of the structured mask 22 and is therefore in contact with the starting layer in the areas that remain free of the structured mask 6 stands.
- FIG. 13.2 shows a further exemplary embodiment of a semiconductor arrangement 1. Contrary to the other two exemplary embodiments, this has two supports 23, which are each arranged centrally opposite the half-liter components 10 and hold them in position. The depression 17 between the two semiconductor components 10 is arranged correspondingly offset to the two supports 23 .
- the semiconductor components 10 in the semiconductor arrangement 1 produced by means of the method steps shown can then be picked up with a transfer die, for example, and detached from the semiconductor arrangement 1 or the supports 23 in order to then be transferred to a target substrate.
- the semiconductor arrangement 10 can serve as a donor substrate, from which the semiconductor components 10 are transferred to a target substrate.
- 14 to 19 show method steps of such a method for producing an optoelectronic device 100 according to some aspects of the proposed principle.
- a first step as shown in FIG. 14 shown to a as shown in FIG. 13 illustrated semiconductor arrangement 1 comprising two semiconductor components 10, a transfer stamp 18 placed on the contact layer 16.
- the semiconductor components are then, as shown in Figure 15, from the semiconductor device or. lifted from the supports 23 of the semiconductor device 1 or. demolished, and the transfer stamp 18 with the semiconductor components 10 is positioned over a printed circuit board 19, as shown in FIG.
- the printed circuit board 19 has a contact structure 20 with a multiplicity of slightly raised contact surfaces 21 arranged on its upper side. Like the semiconductor components 1, the contact areas 21 on the upper side of the printed circuit board 19 have an electrically conductive nanowire layer, which can be formed in accordance with the proposed aspects.
- the transfer stamp 18 with the semiconductor components 10 is positioned over the printed circuit board 19 in such a way that the nanowire layer 9 of a semiconductor component 10 with a contact surface 21 on the upper side of the printed circuit board 19 is opposite.
- the transfer die 18 with the semiconductor components 10 is lowered in the direction of the circuit board 19 and onto the circuit board 19 or the contact structure 20 is pressed. Due to the fact that the contact surfaces 21 protrude somewhat beyond the surface of the circuit board 19, when the transfer die 18 is lowered, the opposite nanowire layer 9 and the first touch contact surface 21 . In contrast, the nanowire layer 9 of the adjacent semiconductor component does not touch the upper side of the printed circuit board.
- the semiconductor component 10 is fixed on the contact surface 21 by the semiconductor component 10 being set down and pressed onto the contact surface 21 . Due to the turf-like structure of the nanowire layers and the easy deformability of the nanowire layers, a relatively small contact pressure is sufficient to produce a mechanical, thermal and electrical contact between the semiconductor component 10 and the contact surface 21 . This results in the structures or Nanowires of the nanowire layers hook and slide into each other, creating a mechanical, thermal and electrical connection.
- the deposition and pressing of the semiconductor component 10 on the contact surface 21 takes place essentially without a temperature-induced process, which is why one can also speak of "cold welding” without an arc.
- the deformation of the metal structures, which leads to "cold welding" can occur at or near room temperature to be executed .
- the transfer stamp 18 can be raised or lowered again. are lifted off, and the fixed semiconductor component 10 remains on the contact surface 21 . Then, as shown in Fig. 18, the transfer stamp 18 with the remaining semiconductor components 10 or in the illustrated case, the remaining semiconductor component 10 is positioned opposite the printed circuit board 19 in such a way that the nanowire layer 9 of the remaining semiconductor component 10 is opposite a further contact surface 21 . The transfer stamp 18 is then lowered in the direction of the printed circuit board 19 and placed on the printed circuit board 19 or pressed the contact structure 20 so that the remaining Semiconductor component 10 is fixed on the further contact area 21 .
Landscapes
- Electrodes Of Semiconductors (AREA)
- Led Devices (AREA)
Abstract
Description
Claims
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE112023000762.4T DE112023000762A5 (de) | 2022-02-01 | 2023-01-27 | Verfahren zur herstellung einer halbleiteranordnung und halbleiteranordnung |
| US18/834,575 US20250113680A1 (en) | 2022-02-01 | 2023-01-27 | Method for manufacturing a semiconductor arrangement and semiconductor arrangement |
| CN202380019639.1A CN118633172A (zh) | 2022-02-01 | 2023-01-27 | 用于制造半导体装置的方法和半导体装置 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102022102362.1 | 2022-02-01 | ||
| DE102022102362.1A DE102022102362A1 (de) | 2022-02-01 | 2022-02-01 | Verfahren zur herstellung einer halbleiteranordnung und halbleiteranordnung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2023148106A1 true WO2023148106A1 (de) | 2023-08-10 |
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ID=85150857
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP2023/052082 Ceased WO2023148106A1 (de) | 2022-02-01 | 2023-01-27 | Verfahren zur herstellung einer halbleiteranordnung und halbleiteranordnung |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US20250113680A1 (de) |
| CN (1) | CN118633172A (de) |
| DE (2) | DE102022102362A1 (de) |
| WO (1) | WO2023148106A1 (de) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102023133304A1 (de) * | 2023-11-28 | 2025-05-28 | Ams-Osram International Gmbh | VERFAHREN ZUR WAFER-FÜLLFAKTORERHÖHUNG UND ZUR UNIVERSELLEN EINSATZMÖGLICHKEIT VON µLED BASISSTRUKTUREN |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1727217A2 (de) * | 2005-05-24 | 2006-11-29 | LG Electronics, Inc. | Lichtemittierende Vorrichtung mit Nanostrukturen für Lichtauskopplung |
| CN1949554A (zh) * | 2006-11-02 | 2007-04-18 | 浙江大学 | 一种ZnO基纳米线发光二极管及其制备方法 |
| EP1798780A2 (de) * | 2005-12-15 | 2007-06-20 | LG Electronics Inc. | Verfahren zur Herstellung eines Substrats mit Nanostrukturen, lichtemittierende Vorrichtung und Verfahren zu deren Herstellung |
| KR20100002485A (ko) * | 2008-06-30 | 2010-01-07 | 서울옵토디바이스주식회사 | 나노 로드 또는 나노 홀을 포함하는 투명 전극층을구비하는 발광다이오드 및 그 제조방법 |
| EP2365547A2 (de) * | 2010-03-09 | 2011-09-14 | LG Innotek Co., Ltd. | Lichtemittierende Vorrichtung und Gehäuse für lichtemittierende Vorrichtung |
| US20120273756A1 (en) * | 2011-04-29 | 2012-11-01 | Hon Hai Precision Industry Co., Ltd. | Light emitting diode |
| EP2722889A2 (de) * | 2012-10-18 | 2014-04-23 | LG Innotek Co., Ltd. | Leuchtdiode mit verbesserter Effizienz durch Stromaufweitung |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102014106634B4 (de) | 2014-05-12 | 2019-08-14 | Osram Oled Gmbh | Beleuchtungsvorrichtung, Verfahren zum Herstellen einer Beleuchtungsvorrichtung |
| CN108886073B (zh) | 2015-12-24 | 2022-01-11 | 维耶尔公司 | 竖直固态器件 |
| DE102019115479A1 (de) | 2019-06-07 | 2020-12-10 | OSRAM Opto Semiconductors Gesellschaft mit beschränkter Haftung | Versorgungsschaltung und verfahren zum versorgen eines bauelements, insbesondere eines opto-elektronischen bauelements |
-
2022
- 2022-02-01 DE DE102022102362.1A patent/DE102022102362A1/de not_active Withdrawn
-
2023
- 2023-01-27 WO PCT/EP2023/052082 patent/WO2023148106A1/de not_active Ceased
- 2023-01-27 DE DE112023000762.4T patent/DE112023000762A5/de active Pending
- 2023-01-27 CN CN202380019639.1A patent/CN118633172A/zh active Pending
- 2023-01-27 US US18/834,575 patent/US20250113680A1/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1727217A2 (de) * | 2005-05-24 | 2006-11-29 | LG Electronics, Inc. | Lichtemittierende Vorrichtung mit Nanostrukturen für Lichtauskopplung |
| EP1798780A2 (de) * | 2005-12-15 | 2007-06-20 | LG Electronics Inc. | Verfahren zur Herstellung eines Substrats mit Nanostrukturen, lichtemittierende Vorrichtung und Verfahren zu deren Herstellung |
| CN1949554A (zh) * | 2006-11-02 | 2007-04-18 | 浙江大学 | 一种ZnO基纳米线发光二极管及其制备方法 |
| KR20100002485A (ko) * | 2008-06-30 | 2010-01-07 | 서울옵토디바이스주식회사 | 나노 로드 또는 나노 홀을 포함하는 투명 전극층을구비하는 발광다이오드 및 그 제조방법 |
| EP2365547A2 (de) * | 2010-03-09 | 2011-09-14 | LG Innotek Co., Ltd. | Lichtemittierende Vorrichtung und Gehäuse für lichtemittierende Vorrichtung |
| US20120273756A1 (en) * | 2011-04-29 | 2012-11-01 | Hon Hai Precision Industry Co., Ltd. | Light emitting diode |
| EP2722889A2 (de) * | 2012-10-18 | 2014-04-23 | LG Innotek Co., Ltd. | Leuchtdiode mit verbesserter Effizienz durch Stromaufweitung |
Also Published As
| Publication number | Publication date |
|---|---|
| CN118633172A (zh) | 2024-09-10 |
| DE102022102362A1 (de) | 2023-08-03 |
| US20250113680A1 (en) | 2025-04-03 |
| DE112023000762A5 (de) | 2024-11-21 |
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