WO2021074980A1 - パワーモジュール - Google Patents
パワーモジュール Download PDFInfo
- Publication number
- WO2021074980A1 WO2021074980A1 PCT/JP2019/040555 JP2019040555W WO2021074980A1 WO 2021074980 A1 WO2021074980 A1 WO 2021074980A1 JP 2019040555 W JP2019040555 W JP 2019040555W WO 2021074980 A1 WO2021074980 A1 WO 2021074980A1
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- Prior art keywords
- metal wire
- power module
- semiconductor chip
- sheet
- metal
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- H10W40/25—
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- H10W72/50—
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- H10W40/22—
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- H10W40/255—
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- H10W72/00—
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- H10W90/00—
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- H10W40/10—
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- H10W72/07554—
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- H10W72/534—
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- H10W72/5438—
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- H10W72/5445—
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- H10W72/5449—
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- H10W72/5453—
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- H10W72/5475—
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- H10W72/552—
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- H10W74/114—
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- H10W76/15—
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- H10W76/47—
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- H10W90/753—
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- H10W90/754—
Definitions
- the present invention relates to an improvement in heat dissipation in a power module.
- wiring on a semiconductor chip is performed by bonding using a metal wire. If a metal wire is used for wiring on a semiconductor chip, it is possible to develop a variety of products in which the size or electrode shape of the semiconductor chip is changed in the same package by changing the wiring shape.
- Patent Document 1 discloses a technique for improving heat dissipation in the bonding of the lower side of a semiconductor chip.
- Patent Document 2 discloses a technique for improving the heat dissipation of the encapsulant.
- the temperature of the wire wiring when the power module is energized rises.
- the life of the semiconductor chip and the wire bond joint is shortened due to the temperature cycle of heat generation and cooling, or the wire wiring itself is blown.
- the present invention has been made to solve the above problems, and an object of the present invention is to improve the heat dissipation of a metal wire on a semiconductor chip in a power module.
- the power module of the present invention includes a base plate, an insulating substrate provided on the base plate and having a circuit pattern, at least one semiconductor chip mounted on the circuit pattern of the insulating substrate, and a plurality of connected to the surface of the semiconductor chip.
- the metal wire comprises a metal wire and a heat conductive sheet that contacts the metal wire from above, and the metal wire includes at least one first metal wire that connects the surface of the semiconductor chip and the circuit pattern, and two on the surface of the semiconductor chip. It comprises at least one second metal wire, which connects the points and has the same potential as the first metal wire, the heat conductive sheet comprises a graphite sheet, and the sheet surface of the heat conductive sheet is at least one first metal.
- the wire is in contact with at least one second metal wire.
- the sheet surface of the heat conductive sheet containing the graphite sheet comes into contact with at least one first metal wire and at least one second metal wire. Therefore, the heat of the second metal wire is transferred to the first metal wire through the graphite sheet and radiated from the first metal wire to the circuit pattern, so that the temperature rise of the second metal wire can be prevented. In this way, the heat dissipation of the metal wire on the semiconductor chip is improved.
- FIG. It is sectional drawing of the power module of Embodiment 1.
- FIG. It is an isometric view of the power module of Embodiment 2.
- FIG. It is a top view of the power module of Embodiment 2.
- FIG. 1 is a cross-sectional view of the power module 101 of the first embodiment.
- the power module 101 includes a base plate 1, an insulating substrate 7, a diode chip 81, transistor chips 9a1, 9b1, metal wires 10a, 10b, 10c, a graphite sheet 11, a case 12, and a sealing material 13.
- the insulating substrate 7 is formed on the upper surface of the base plate 1.
- the insulating substrate 7 is composed of an insulating base material 4, a lower surface pattern 2 made of a metal bonded to the lower surface of the insulating base material 4 with a bonding material 3, and a metal bonded to the upper surface of the insulating base material 4 with a bonding material 5. It is configured to include circuit patterns 6a, 6b, and 6c.
- the lower surface pattern 2 of the insulating substrate 7 is formed on the upper surface of the base plate 1.
- the diode chip 81 and the transistor chips 9a1 and 9b1 are bonded to the circuit pattern 6b by a bonding material such as solder or a sintered material.
- the diode chip 81 functions as a freewheeling diode for the transistor chips 9a1 and 9b1.
- the diode chip 81 and the transistor chips 9a1 and 9b1 are examples of semiconductor chips. In place of these semiconductor chips, another semiconductor chip may be mounted on the power module 101, or one semiconductor chip may be mounted.
- Wire wiring with metal wires is applied to the upper surface of the semiconductor chip.
- the metal wire connecting the diode chip 81 and the circuit pattern 6a is referred to as a metal wire 10a.
- the metal wire 10a is also referred to as a first metal wire.
- metal wires connecting two places on the diode chip 81, two places on the diode chip 81 and the transistor chip 9a1, two places on the transistor chip 9a1, and two places on the transistor chip 9a1 and the transistor chip 9a2, and the transistor 9a2 are connected. Let it be a metal wire 10b.
- the metal wire 10b is also referred to as a second metal wire.
- the transistor chip 9a2 and the circuit pattern 6c are connected by a metal wire 10c.
- the metal wire 10c is a gate wire that connects the gate electrode of the transistor chip 9a2 and the circuit pattern 6c, and has the same potential as the gate electrode (hereinafter, also referred to as “gate potential”).
- the metal wire 10a and the metal wire 10b have the same potential as the emitter electrode of the transistor chip 9a2 (hereinafter, also referred to as “emitter potential”).
- the graphite sheet 11 is provided on the metal wires 10a and 10b connected to the upper surface of the semiconductor chip, with the sheet surface in contact with the metal wires 10a and 10b.
- the graphite sheet 11 is an anisotropic heat conductive material having a low thermal conductivity of 1 W / mK in the thickness direction and a high thermal conductivity of 500 W / mK or more in the plane direction. Therefore, the heat of the metal wire 10b is transferred to the metal wire 10a by the graphite sheet 11, and is further dissipated from the metal wire 10a to the circuit pattern 6a. Thereby, the temperature of the metal wire 10b can be lowered.
- the graphite sheet 11 functions as a heat conductive sheet that conducts the heat of the metal wire 10b in the plane direction.
- the graphite sheet 11 does not come into contact with the metal wire 10c because the metal wire 10c has a different potential than the metal wires 10a and 10b.
- the base plate 1 is fitted to the case 12, and the case 12 accommodates the base plate 1, the insulating substrate 7, the diode chip 81, the transistor chips 9a1, 9b1, the metal wires 10a, 10b, 10c, and the graphite sheet 11. ing.
- the inside of the case 12 is filled with a sealing material 13 made of gel or epoxy resin, and the diode chip 81, the transistor chips 9a1, 9b1, the metal wires 10a, 10b, 10c, and the graphite sheet 11 are sealed by the sealing material 13. Has been done.
- the graphite sheet 11 is in contact with all the metal wires 10b, but as long as it is in contact with the metal wire 10a and at least one metal wire 10b having the same potential as the metal wire 10a, the above heat dissipation effect can be obtained. Obtainable. However, the larger the number of metal wires 10b that the graphite sheet 11 contacts, the more heat of the metal wires 10b can be dissipated to the circuit pattern 6a.
- the heat generated on the semiconductor chip of the power module is transmitted to the base plate 1 through the bonding under the semiconductor chip, and is dissipated from the base plate 1 to the cooling fins.
- the temperature of the metal wire becomes high due to heat transfer from the semiconductor chip or heat generated by the energizing current of the metal wire itself.
- the heat of the metal wire 10b is dissipated by the graphite sheet 11 in the direction parallel to the surface of the base plate 1, so that the temperature rise of the metal wire 10b is alleviated. ..
- the power module 101 of the first embodiment includes a base plate 1, an insulating substrate 7 provided on the base plate 1 and having circuit patterns 6a, 6b, 6c, and a circuit pattern 6b of the insulating substrate 7. It includes a diode chip 81 and transistor chips 9a1 and 9b1 which are semiconductor chips mounted on the semiconductor chip, a plurality of metal wires connected to the surface of the semiconductor chip, and a heat conductive sheet which comes into contact with the metal wires from above.
- the metal wire connects the metal wire 10a, which is at least one first metal wire connecting the surface of the diode chip 81 and the circuit pattern 6a, and two points on the surface of the semiconductor chip, and has the same potential as the metal wire 10a.
- the metal wire 10b which is at least one second metal wire, is provided.
- the heat conductive sheet includes a graphite sheet 11, and the sheet surface of the heat conductive sheet is in contact with at least one metal wire 10a and at least one metal wire 10b. Therefore, the heat of the metal wire 10b is transferred to the metal wire 10a through the graphite sheet 11 and radiated from the metal wire 10a to the circuit pattern 6a, so that the temperature rise of the metal wire 10b can be prevented.
- FIG. 2 is an isometric view of the power module 102 of the second embodiment.
- FIG. 3 is a top view of the power module 102.
- FIG. 4 is an isometric view showing a state before the graphite sheet 11 of the power module 102 is installed.
- the power module 102 includes a diode chip 82-88 and transistor chips 9a2-9a8 and 9b2-9b8 in addition to the configuration of the power module 101 of the first embodiment.
- the power module 102 is mounted in parallel with a set of eight semiconductor chips including one diode chip 8n and two transistor chips 9an and 9bn. Note that n is a natural number from 1 to 8.
- the connection status of the metal wires in each set of semiconductor chips is the same.
- the transistor chip is arranged in the region 14 of FIG. 3, and the diode chip is arranged in the region 15.
- metal wires 10a and 10b are shown as ribbon wires in FIGS. 2 to 4, they may be single wire wires.
- a wire wire has less restrictions on the chip size than a ribbon wire, and can be bonded in an oblique direction.
- the diode chip 8n functions as a freewheeling diode of the transistor chips 9an and 9bn.
- the fact that the semiconductor chips are mounted in parallel is shown in FIG. 4 that the metal wire 10c, which is a gate wire, is connected to each of the transistor chips 9a1-9a8 from the same circuit pattern 6c. ..
- a plurality of semiconductor chips mounted in parallel are connected by a metal wire to form an electric circuit.
- the transistor chip 9b1 and the transistor chip 9b2 are connected by a metal wire 10b1
- the transistor chip 9b2 and the transistor chip 9a3 are connected by a metal wire 10b1.
- These metal wires 10b1 have the same potential as the metal wire 10a, and are also referred to as a second metal wire like the metal wire 10b.
- the plurality of semiconductor chips mounted in parallel are energized at the same time, and a large current of the power module 102 is realized.
- the bond point since the semiconductor chips at both ends of the metal wire 10b1 are energized at the same time, the bond point generates heat, and when the metal wire 10b1 itself is energized, the temperature becomes higher than that on the semiconductor chip. turn into.
- the graphite sheet 11 connects a set of transistor chips 9a1, 9b1, diode chips 81 and a set of transistor chips 9a2, 9b2, diode chips 82, in addition to the features of the first embodiment. It is formed on the upper portion of the metal wire 10b1 so as to come into contact with the metal wire 10b1.
- the power module 102 of the second embodiment has transistor chips 9b1-9b8, which are a plurality of semiconductor chips in which a gate terminal as a control terminal is connected to the same circuit pattern 6a or a circuit pattern having the same potential. Including, the sheet surface of the heat conductive sheet comes into contact with the metal wire 10b1, which is the second metal wire connecting the transistor chips 9b1-9b8. Since the semiconductor chips 9b1-9b8 at both ends of the metal wire 10b1 are simultaneously energized and generate heat, the metal wire 10b1 may have a higher temperature than that on the semiconductor chip 9b1-9b8. By conducting the wire 10a and dissipating heat from the metal wire 10a to the circuit pattern 6a, it is possible to suppress an increase in the temperature of the metal wire 10b1. This makes it possible to extend the product life of the power module 102.
- the heat conductive sheet is composed of the graphite sheet 11 alone.
- a heat conductive sheet is formed by a clad material in which a graphite sheet 11 and a metal thin film 16 are laminated.
- the metal thin film 16 is shown as a lower layer and the graphite sheet 11 is shown as an upper layer, but the graphite sheet 11 may be a lower layer and the metal thin film 16 may be an upper layer.
- the configuration of the power module of the third embodiment other than the heat conductive sheet is the same as that of the power modules 101 and 102 of the first embodiment or the second embodiment.
- the graphite sheet 11 Since the graphite sheet 11 has low strength and is brittle, if the graphite sheet 11 alone constitutes a heat conductive sheet, the state will change due to the handling during shape processing or assembly, and the yield in product assembly will deteriorate. I am concerned. Therefore, by forming the heat conductive sheet with a clad material in which the graphite sheet 11 and the metal thin film 16 are superposed, it is possible to process or assemble the shape of the heat conductive sheet while having the high strength of the metal thin film 16. .. Further, the high thermal conductivity in the surface direction of the graphite sheet 11 suppresses heat generation of the metal wires 10b and 10b1.
- the thickness of the metal thin film 16 is 100 ⁇ m and the thickness of the graphite sheet 11 is 100 ⁇ m or more and 400 ⁇ m or less. As described above, when the heat conductive sheet has an appropriate thickness, it is possible to easily change the shape or install the heat conductive sheet according to the wiring material.
- FIG. 6 is a top view of the power module 104 of the fourth embodiment.
- the power module 104 of the fourth embodiment is different from the configuration of the power module 102 of the second embodiment in that the graphite sheet 11 is formed with a hole 15 penetrating the sheet surface. Although eight holes 15 are formed in FIG. 6, it is sufficient that at least one hole 15 is formed.
- the case 12 is filled with the sealing material 13 as shown in FIG. If air bubbles are contained inside the cured encapsulant, the insulation quality of the power module deteriorates depending on the place where the air bubbles are generated.
- the holes 15 of the graphite sheet 11 allow bubbles generated between the graphite sheet 11 and the semiconductor chip to be extracted above the graphite sheet 11 and further extracted from the sealing material 13.
- the diameter of the hole 15 is preferably 1.0 mm or more in order to remove air bubbles. Further, it is desirable that the outer circumference of the hole 15 is 1.0 mm or more away from the place where the graphite sheet 11 comes into contact with the metal wires 10a and 10b. If the hole 15 is installed in a place where air bubbles are likely to remain, the effect of removing air bubbles can be easily obtained.
- the present embodiment may be combined with the third embodiment. That is, in the present embodiment, the heat conductive sheet is composed of the graphite sheet 11 and the clad material of the metal thin film 16, and the holes 15 penetrating the graphite sheet 11 and the metal thin film 16 are formed on the sheet surface of the heat conductive sheet. Is also good. In this case, since the heat conductive sheet has high strength due to the metal thin film 16, the holes 15 can be easily machined, and defects of the member itself can be reduced.
- the power module 104 of the fourth embodiment is fitted to the base plate 1 and houses the insulating substrate 7, the semiconductor chips 81, 9a1, 9b1, the metal wires 10a, 10b, and the heat conductive sheet, and the case 12 and the case 12. It is filled inside and includes a semiconductor chip, metal wires 10a and 10b, and a sealing material 13 for sealing the heat conductive sheet, and penetrates the sheet surface at a position not overlapping with the metal wires 10a and 10b of the heat conductive sheet. The hole 15 is formed. As a result, bubbles that affect the insulation quality of the power module generated between the graphite sheet 11 and the semiconductor chip can be extracted above the graphite sheet 11 and further extracted from the sealing material 13.
- each embodiment can be freely combined, and each embodiment can be appropriately modified or omitted within the scope of the invention.
- the present invention has been described in detail, the above description is exemplary in all embodiments and the invention is not limited thereto. It is understood that innumerable variations not illustrated can be assumed without departing from the scope of the present invention.
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- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Chemical & Material Sciences (AREA)
- Power Engineering (AREA)
- Materials Engineering (AREA)
- Cooling Or The Like Of Semiconductors Or Solid State Devices (AREA)
- Ceramic Engineering (AREA)
- Connection Or Junction Boxes (AREA)
- Multi-Conductor Connections (AREA)
- Coupling Device And Connection With Printed Circuit (AREA)
Abstract
Description
図1は、実施の形態1のパワーモジュール101の断面図である。パワーモジュール101は、ベース板1、絶縁基板7、ダイオードチップ81、トランジスタチップ9a1,9b1、金属ワイヤ10a,10b,10c、グラファイトシート11、ケース12、および封止材13を備えて構成される。
図2は、実施の形態2のパワーモジュール102の等角投影図である。図3は、パワーモジュール102の上面図である。図4は、パワーモジュール102のグラファイトシート11を設置する前の状態を示した等角投影図である。
実施の形態1,2のパワーモジュール101,102において、熱伝導シートはグラファイトシート11単体で構成された。これに対して実施の形態3のパワーモジュールでは、図5に示すように、グラファイトシート11と金属薄膜16が重ねあわされたクラッド材によって熱伝導シートが構成される。図5では、金属薄膜16を下層、グラファイトシート11を上層として示しているが、グラファイトシート11が下層、金属薄膜16が上層であっても良い。熱伝導シート以外の実施の形態3のパワーモジュールの構成は、実施の形態1または実施の形態2のパワーモジュール101,102と同様である。
図6は、実施の形態4のパワーモジュール104の上面図である。実施の形態4のパワーモジュール104は、実施の形態2のパワーモジュール102の構成と比較すると、グラファイトシート11に、そのシート面を貫通する穴15が形成されている点が異なる。図6には、8個の穴15が形成されているが、穴15は少なくとも1つ形成されていれば良い。
Claims (5)
- ベース板と、
前記ベース板上に設けられ回路パターンを有する絶縁基板と、
前記絶縁基板の前記回路パターンに搭載された少なくとも1つの半導体チップと、
前記半導体チップの表面に接続される複数の金属ワイヤと、
前記金属ワイヤに上方から接触する熱伝導シートと、を備え、
前記金属ワイヤは、
前記半導体チップの表面と前記回路パターンを接続する少なくとも1つの第1金属ワイヤと、
前記半導体チップの表面上の2点を接続し、前記第1金属ワイヤと同電位である、少なくとも1つの第2金属ワイヤと、を備え、
前記熱伝導シートはグラファイトシートを含み、
前記熱伝導シートのシート面は、少なくとも1つの前記第1金属ワイヤと、少なくとも1つの前記第2金属ワイヤとに接触する、
パワーモジュール。 - 前記半導体チップは、同じ前記回路パターンまたは同電位の前記回路パターンに制御端子が接続された複数の半導体チップを含み、
前記熱伝導シートのシート面は、前記複数の半導体チップを接続する前記第2金属ワイヤに接触する、
請求項1に記載のパワーモジュール。 - 前記熱伝導シートは、金属薄膜と前記グラファイトシートが重なったクラッド材である、
請求項1または請求項2に記載のパワーモジュール。 - 前記金属薄膜の厚みは100μmであり、
前記グラファイトシートの厚みは100μm以上400μm以下である、
請求項3に記載のパワーモジュール。 - 前記ベース板に嵌合し、前記絶縁基板、前記半導体チップ、前記金属ワイヤ、前記熱伝導シートを収容するケースと、
前記ケース内部に充填され、前記半導体チップ、前記金属ワイヤ、前記熱伝導シートを封止する封止材と、をさらに備え、
前記熱伝導シートの、前記金属ワイヤと重ならない位置に、シート面を貫通する穴が形成されている、
請求項1から請求項4のいずれか1項に記載のパワーモジュール。
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US17/632,164 US12051636B2 (en) | 2019-10-16 | 2019-10-16 | Power module |
| JP2021552025A JP7106014B2 (ja) | 2019-10-16 | 2019-10-16 | パワーモジュール |
| DE112019007832.1T DE112019007832T5 (de) | 2019-10-16 | 2019-10-16 | Leistungsmodul |
| CN201980101259.6A CN114556548B (zh) | 2019-10-16 | 2019-10-16 | 功率模块 |
| PCT/JP2019/040555 WO2021074980A1 (ja) | 2019-10-16 | 2019-10-16 | パワーモジュール |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/JP2019/040555 WO2021074980A1 (ja) | 2019-10-16 | 2019-10-16 | パワーモジュール |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2021074980A1 true WO2021074980A1 (ja) | 2021-04-22 |
Family
ID=75538043
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2019/040555 Ceased WO2021074980A1 (ja) | 2019-10-16 | 2019-10-16 | パワーモジュール |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US12051636B2 (ja) |
| JP (1) | JP7106014B2 (ja) |
| CN (1) | CN114556548B (ja) |
| DE (1) | DE112019007832T5 (ja) |
| WO (1) | WO2021074980A1 (ja) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003249607A (ja) * | 2002-02-26 | 2003-09-05 | Seiko Epson Corp | 半導体装置及びその製造方法、回路基板並びに電子機器 |
| JP2008235492A (ja) * | 2007-03-20 | 2008-10-02 | Matsushita Electric Ind Co Ltd | 半導体装置および半導体装置の製造方法 |
| JP2018166184A (ja) * | 2017-03-28 | 2018-10-25 | 株式会社ケーヒン | パワーモジュール |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08139234A (ja) * | 1994-11-11 | 1996-05-31 | Mitsubishi Electric Corp | 半導体装置 |
| JP3878869B2 (ja) * | 2002-03-06 | 2007-02-07 | 浜松ホトニクス株式会社 | 半導体発光装置 |
| JP2004103936A (ja) * | 2002-09-11 | 2004-04-02 | Mitsubishi Electric Corp | 電力半導体装置およびその製造方法 |
| JP4697025B2 (ja) * | 2006-04-19 | 2011-06-08 | 富士電機ホールディングス株式会社 | 電力用半導体モジュール |
| JP5028907B2 (ja) * | 2006-08-11 | 2012-09-19 | 日産自動車株式会社 | 半導体装置及び電力変換装置 |
| US20120032350A1 (en) * | 2010-08-06 | 2012-02-09 | Conexant Systems, Inc. | Systems and Methods for Heat Dissipation Using Thermal Conduits |
| KR20120026909A (ko) * | 2010-09-10 | 2012-03-20 | 삼성전자주식회사 | 반도체 패키지 및 그의 제조 방법 |
| JP6265693B2 (ja) * | 2013-11-12 | 2018-01-24 | 三菱電機株式会社 | 半導体装置およびその製造方法 |
| JP6406190B2 (ja) | 2015-09-15 | 2018-10-17 | トヨタ自動車株式会社 | 半導体装置 |
| JP2017108046A (ja) | 2015-12-11 | 2017-06-15 | ルネサスエレクトロニクス株式会社 | 半導体装置 |
| US10804253B2 (en) * | 2016-08-10 | 2020-10-13 | Mitsubishi Electric Corporation | Semiconductor device |
| JP2019096731A (ja) | 2017-11-22 | 2019-06-20 | トヨタ自動車株式会社 | 半導体装置 |
-
2019
- 2019-10-16 CN CN201980101259.6A patent/CN114556548B/zh active Active
- 2019-10-16 JP JP2021552025A patent/JP7106014B2/ja active Active
- 2019-10-16 DE DE112019007832.1T patent/DE112019007832T5/de active Pending
- 2019-10-16 WO PCT/JP2019/040555 patent/WO2021074980A1/ja not_active Ceased
- 2019-10-16 US US17/632,164 patent/US12051636B2/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003249607A (ja) * | 2002-02-26 | 2003-09-05 | Seiko Epson Corp | 半導体装置及びその製造方法、回路基板並びに電子機器 |
| JP2008235492A (ja) * | 2007-03-20 | 2008-10-02 | Matsushita Electric Ind Co Ltd | 半導体装置および半導体装置の製造方法 |
| JP2018166184A (ja) * | 2017-03-28 | 2018-10-25 | 株式会社ケーヒン | パワーモジュール |
Also Published As
| Publication number | Publication date |
|---|---|
| JP7106014B2 (ja) | 2022-07-25 |
| CN114556548B (zh) | 2025-01-10 |
| US12051636B2 (en) | 2024-07-30 |
| US20220285243A1 (en) | 2022-09-08 |
| DE112019007832T5 (de) | 2022-06-30 |
| JPWO2021074980A1 (ja) | 2021-04-22 |
| CN114556548A (zh) | 2022-05-27 |
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