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WO2020005151A1 - Heating device and heating foil - Google Patents

Heating device and heating foil Download PDF

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Publication number
WO2020005151A1
WO2020005151A1 PCT/SG2018/050306 SG2018050306W WO2020005151A1 WO 2020005151 A1 WO2020005151 A1 WO 2020005151A1 SG 2018050306 W SG2018050306 W SG 2018050306W WO 2020005151 A1 WO2020005151 A1 WO 2020005151A1
Authority
WO
WIPO (PCT)
Prior art keywords
heating
conducting
layer
foil
areas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/SG2018/050306
Other languages
French (fr)
Inventor
Cheok Pui YUEN
Song Lin LIU
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pelen Pte Ltd
Original Assignee
Pelen Pte Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pelen Pte Ltd filed Critical Pelen Pte Ltd
Priority to PCT/SG2018/050306 priority Critical patent/WO2020005151A1/en
Priority to SG11202010819QA priority patent/SG11202010819QA/en
Publication of WO2020005151A1 publication Critical patent/WO2020005151A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/10Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
    • H05B3/12Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
    • H05B3/14Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material the material being non-metallic
    • H05B3/145Carbon only, e.g. carbon black, graphite
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00Ohmic-resistance heating
    • H05B3/20Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater
    • H05B3/22Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible
    • H05B3/28Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible heating conductor embedded in insulating material
    • H05B3/30Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible heating conductor embedded in insulating material on or between metallic plates
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B2203/00Aspects relating to Ohmic resistive heating covered by group H05B3/00
    • H05B2203/009Heaters using conductive material in contact with opposing surfaces of the resistive element or resistive layer
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B2214/00Aspects relating to resistive heating, induction heating and heating using microwaves, covered by groups H05B3/00, H05B6/00
    • H05B2214/04Heating means manufactured by using nanotechnology

Definitions

  • the present invention relates to a heating device and a foil.
  • Ohmic-resistance heating devices are well known. E specially wire resistance is commonly used. To heat a surface the wire is often disposed on a foil or tape in a side to side and/or zigzag-shaped fashion.
  • WO 2017/176208 A self-adhesive heating tape is described that at each edge of a thin conductive carbon ink layer a stripe of conductive paste is disposed. The whole layer is laminated with two insulating polymer layers. T he thickness of the heating tape is in the regime of 120 pm to 300 pm.
  • F urthermore, materials with a positive temperature coefficient (PTC materials) are often used for heating devices as well.
  • T he advantage of such a material is that point-wise self-regulating and self-limiting devices can be realized.
  • ceramics are used as PTC materials.
  • T he disadvantage of ceramic lies in the rigid nature of the material.
  • T o use the silicone rubber as a heating element the contacting electrodes are placed on one side of the material to ensure the minimal gap between the electrodes, which is needed to ensure the necessary field strength of minimum 30 V/mm. This field strength is necessary to enable the PTC effect in silicone rubber.
  • a heating element having a PTC material.
  • the PTC material is a siloxane elastomer, also known as silicone elastomer, with carbon blacks of PTC type.
  • the PTC layer has a thickness of 10 - 300 i m is placed on top of an insulating layer.
  • a third layer, which provide the electrode contacts, is placed on top of the PTC layer.
  • a conductive polymer composition and an electric device is described.
  • the conductive polymer composition is a mixture of an essentially amorphous thermoplastic resin and a thermosetting resin.
  • the conductive polymer composition can be used e.g. for heaters. In the electric device the conductive polymer composition is placed between two electrodes.
  • a heater which prevents temperature overshoots. Between two electrodes three layers a re disposed. Two layers, those, which are close to the electrodes, are constant wattage layer to prevent an overshoot A third layer in the middle is a PTC heating layer.
  • the PTC material is, for example, a doped ceramic or a doped thermoplastic polymer.
  • US 4,774,397 A discloses a heater including a substrate, a longitudinal conductor contact portions or stripes and regularly space semiconductor heating portions or bars extending between the stripes.
  • AU 8524575 A also published as DE 2543907 A1 shows another flexible heater comprising a pair of electrode and sheets of an electrically conductive resistive material as heating layer.
  • This elastic material comprises a mixture of rubber and graphite.
  • Another flexible heating means shown in US 6,172,344 B1 comprises electrodes and a heating layer.
  • the electrodes are positioned at the edges of a thin heating film.
  • the above mentioned prior art comprises flexible heating tapes, thin heating films and inflexible heating devices.
  • F lexible heating tapes comprise a conductive heating layer and at the edges electrodes so that heating current is applied alongside the heating layer.
  • S uch heating tapes are disclosed in WO 2017/176208 A, US 4,774,397 A, AU 8524575 A and US 6,172,344 B1. These heating tapes are usually cuttable in a direction perpendicular to the edges at which the electrodes are arranged.
  • Thin heating films comprise a substrate on which a very thin heating film is disposed. On top of the heating film two electrodes are provided. S uch thin heating films are shown in US 9,392,645 B2.
  • These heating devices are very flexible, and the heating material is only cuttable before the electrodes are attached. After the electrodes are placed onto the heating film, the heating device is not cuttable anymore.
  • Inflexible heating devices comprises at least one hard inflexible layer. They are often using a hard heating layer made of ceramics or thermoplastic. S uch inflexible heating devices are described in US 5,250,228 A, US 4,616,125 A and US
  • the heating device is not flexible and not cuttable.
  • US 2016/01 13065 A1 discloses an electric heater comprising a heating element disposed between a first and a second conductor, wherein the heating element comprises an electric conductive material distributed within an ethylene acetate or ethylene acrylate copolymer, and wherein the heating element has a first thickness in a first region and a different thickness in a second region.
  • a fabric comprising two main conductors and a plurality of heating conductors.
  • the main conductors are arranged in parallel to each other and along one edge of the fabric.
  • T he heating conductors extend a lso parallel to the main conductors and are distributed over the whole fabric.
  • the heating conductors are connected by means of thin conductive wires with the main conductors so that always certain sections of the heating conductors are supplied with electricity from the main conductors.
  • T his kind of fabric provides a homogenous heating and can be cut freely, wherein the heating function is maintained.
  • the main conductors cannot be cut and there is a complex structure of main conductors, heating conductors and conductive wires to achieve the cutta bility.
  • the object of the invention is to provide a heating foil, which comprises a simple structure, which is readily manufactured, which is flexible and cuttable without significant geometric limitations and without any special treatment
  • a heating foil comprises:
  • heating layer made of a silicone or polyurethane polymer with embedded conducting particles that are distributed in the heating layer
  • the current for heating the heating layer is crossing the heating layer from one to the other side, wherein the current is distributed over the area of the surface electrode. This provides a homogeneous heating in this area.
  • both conducting layers form a surface electrode.
  • the conducting layers are preferably opposing each other, wherein also a certain offset is possible.
  • This heating foil comprises a very simple structure as it comprises a heating layer and electrodes, the conducting layers, on both sides of the heating layer.
  • the heating foil it is preferable flexible. Therefore, the heating foil can adjust to an object, e.g. the sole of a foot; to be comfortable and to heat it efficiently.
  • the heating layer is preferable not compressible. If the heating layer is pinched, the pressed material of the heating layer will elude. After the heating layer is pinched, the material of the heating layer will recapture its form. This allows to cut the heating foil in the regions where a conducting layer is disposed, because due to the incompressibility of the heating layer the conducting layers are kept apart and do not cause a short circuit
  • the heating layer is completely or nearly completely covered on both sides by the conducting layer. This allows to cut the heating foil in any shape, because then it is secured that the surfaces on each side of the heating layer are sufficiently covered by a conducting layer which forms an electrode.
  • C ompletely covered does not mean that the conducting layer has to be a continuous layer without any openings.
  • T he conducting layer can be e.g. a mesh or formed with a pattern having one or more openings.
  • the openings shall be so small that a homogeneous current distribution is still possible.
  • the size of the openings is preferably not larger than 10 times of the squared thickness of the heating layer and particularly not larger than 2 times of the squared thickness of the heating layer.
  • the bulk modulus of the compressibility of silicone is about 1.5 to 2 PGa, which is close to the compressibility of water, which has a bulk modulus of 2.1 to 2.7 PGa. If the heating foil is cut or cropped, e.g. by means of a scissors, the silicone returns to its original position immediately after the clipping, whereby the electrodes remain at a distance from each other. T his allows the heating foil to be cropped as desired.
  • cut edges do not need to be further supported or treated afterwards.
  • defect areas of the heating foil can be easily cut out without replacing the whole heating foil or treating the cut edges further.
  • the heating foil is cuttable along a separation area, as long as the separation area is not parallel to one of the layers
  • heating layer with embedded conducting particles thick heating layers are feasible, i.e. layers with a thickness of 1 mm and more are achievable, although smaller thickness than 1 mm are possible, too.
  • thick layers made out of silicone or polyurethane the heater will act like a thermic insulator as well.
  • this thick heating layer will be more comfortable in direct contact with human skin, than for example hard ceramic heating foils.
  • the heating foil is especially suitable for e.g.
  • active winter clothing active seat heater, or active storage box for food.
  • the heating foil can be perforated so that it is permeable for gas and vapor even if the heating layer is completely covered by the conducting layer or made of a non- permeable polymer.
  • the perforation can be laser cut or punched.
  • the heating layer has a thickness of at least 0.05 mm, 0.1 mm or 0.3 mm. If the heating layer is thin then the electrical resistance is low and the generated heat is accordingly small or there is a significant risk that the heating layer is deteriorated by the heat.
  • the maximum thickness is preferably not more than 1 mm, particularly not more than 2 mm or 10 mm.
  • the electrical resistance is the larger the thicker the layer is.
  • the conducting particles are composed of carbon. Carbon is a relatively nonhazardous cheap material, which is easily to fabricate. Carbon can withstand high temperatures and strong electric currents.
  • the carbon particles can be also carbon nano tubes, carbon black, graphite, or carbon fibers.
  • the conducting particles are homogenously distributed. They can also be randomly distributed.
  • the conducting particles have a concentration in weight relative to the silicone of at least 1 %, 10% or 20% and/or preferably not more than 70%, 80% or 95%
  • the heating layer has specific electrical resistance of minimum 5 Witi, 10 Om or 20 Om and maximum 1 kQm, 10 kQm or 100 kQm
  • a favorable setting is, that the conducting layer is a metal mesh.
  • the inventors have realized that a non-continuous conducting layer maintains a stronger connection to the silicone layer, if the heating foil is bent. Continuous conducting layer might break or getting more easily detached from the heating layer.
  • the metal mesh consists of conductor stripes or wires with a width or diameter of at least 0.05 mm, 0.1 mm or 0.5 mm and/or preferably not more than 1 mm, 1.5 mm or 2 mm.
  • the metal mesh can be printed onto the heating layer.
  • the metal mesh has an aperture with a maximum diameter of at least 0.05 mm, 0.5 mm or 1 mm and/or preferably not more than 5 mm, 10 mm or 15 mm.
  • the apertures can be in the form of a circle or any other form. If the aperture deviates from the form of the circle then it comprises different diameters.
  • the conducting layers are covered with an insulator layer, which isolates the heating foil electronically and/or thermally. Therefore, the heating foil can be touched without risking an electric shock.
  • the insulator layer made out of e.g. a polymer, protects the other layer from harm like e.g. sharp objects or liquids.
  • using a thermally isolation will direct the heating to one side mainly. This is beneficially in clothing. On the side towards a human body is needed to be heated. The other side can be insulated, which will increase the heating on the preferred side.
  • thermoly insulator on one side of the heating foil a thermally insulator is provided.
  • an insulator structure comprising several insulating layers. It can also make sense to provide on one side of the heating foil an insulating layer which forms a good electrically and thermally insulator and on the other side an insulating layer which forms a good electrically but not so good thermally insulator. T his can be e.g. achieved by applying on one side a thick layer of insulating material and on the other side a thin layer of insulating material of the same or different insulating material.
  • the concentration of the embedded conducting particles may be heterogeneous.
  • a heterogeneous concentration is defined as a certain concentration of embedded conducting particles at a certain area and another concentration of embedded conducting particles at another, different area.
  • the change of the concentration between these areas may be continuous. T his will result in different heating areas of heating. For example, an area with higher concentration will results in a higher temperature.
  • An area with a certain concentration might follow a specific shape.
  • the heating foil can comprise several separated conducting areas in the heating layer, wherein the non-conducting areas in between the separated conducting areas are embodied so that they do not conduct significant amounts of electrical current and do therefore not contribute to the heating of the heating foil.
  • the conducting areas can be composed of silicone with embedded conducting particles and the non conducting areas can be composed of a polymer without embedded conducting pa rticles.
  • the conducting areas can be defined by the shape of the conducting layer and the non-conducting areas can be defined by omitting the conducting layers in these areas.
  • E ach segment of the conduction layer in a certain conducting area shall to be in electrically contact with the other segments of the conducting layer.
  • These electrical connections can be e.g. embodied by thin conducting paths of the conducting layer in between the individual segments.
  • heating foils which have e.g. a size of one or more m/l Even with such a size a reasonable power consumption can be achieved.
  • Large heating foils with one single continuous heating area would need a conducting layer with a very small electric resistance due to the large size of the heating layer. This makes it difficult to control the electrical power and thus the heating behavior of the heating foil. If a plurality of heating areas are provided a homogeneous temperature distribution can be easily achieved, particularly if the conducting layer is completely covering the heating layer, because electrically conducting materials are mostly also good heat conductors.
  • the conducting area can be shaped like circles in the plain view. P referably, the conducting areas are equally distributed.
  • a heating device comprising:
  • heating foil comprises:
  • heating layer made of a not compressible polymer with embedded conducting particles that are distributed in the heating layer
  • the electric wire can be used to connect the heating device to an electric circuit.
  • the punctiform electric contact is, for example, a soldering point.
  • P unctiform means that the area of the electric contact is significantly smaller than the area of the conductive area.
  • the heating foil can be cut everywhere, as long as the conducting layers of the remaining areas have a punctiform electric contact.
  • the heating foil corresponds to the above mentioned heating foil.
  • F igure 1 an embodiment of the inventive heating device in isometric view
  • F igure 4 an alternative of a section of the heating device of F ig. 1 ,
  • F igure 5 a second embodiment of the inventive heating device with separated conducting areas in shown with cut layers
  • F igure 6 a section of a heating device with insulating layers
  • F igure 7 an implementation in an electric circuit of the inventive heating device in isometric view.
  • a heating device for a heating shoe forms a first exemplary embodiment of the present invention (figure 1 to 4).
  • the heating device comprises a heating foil 1 and at least one electric wire 10 connecting the heating foil 1 by means of a punctiform electric contact 1 1 to an electric circuit 9.
  • the heating foil 1 is a flexible sheet, i.e. width W and length L is larger than thickness T.
  • the area A of the heating foil 1 in plain view is about 200 cn 4
  • This heating foil 1 comprises a heating layer 2 with embedded conducting particles 3 for heating, two cover layers 4a and 4b to cover the heating layer 2.
  • the cover layer 4 comprise a conducting layer 5 to connect the heating foil 1 to an external electric circuit 9 and an insulating layer 6.
  • the cover layer 4 comprise only a conducting layer 5.
  • the external electric circuit 9 is connected to the conducting layers 5a and 5b by the electric wire 10.
  • the contact between the external electric circuit 9 and one of the conducting layers 5 is a punctiform electric contact 1 1 , which comprises for example, a soldering point.
  • the heating layer 2 is placed between the two conducting layers 5a and 5b and has in this embodiment a thickness tn of 1 mm.
  • the specific electric resistance p is 240
  • the material of the embedded conducting particles 3 is carbon.
  • the carbon concentration in weight relative to the silicone of resistance of 4%.T he size of on carbon particle 3 is between 0.1 i m and 100 i m.
  • the conducting layers 5a and 5b consist of a woven metallic mash, which comprises wires with a diameter of 0.1 mm and has an aperture with a maximum diameter of about 1 mm.
  • the conducting layers 5a and 5b are attached to the silicon layer, e.g. by gluing (with conductive glue) or melting.
  • the insulating layers 6a and 6b covers each conducting layer 5a and 5b and are attached to them.
  • the insulating layer 6a is the layer on the top side, which is close to the human body (foot). It is an electrically insulator to prevent the human from an electric shock.
  • the material of the insulation layer 6a is in this embodiment
  • the thickness of this insulating layer 6a is about 0.1 mm.
  • the insulating layer 6b is attached to the downside of the heating foil 1 . It is insulating electrically and thermally. Therefore, the heating is directed towards the human body.
  • the material of the insulation layer 6b is in this embodiment P ET.
  • the thickness of this insulating layer 6b is about 2 mm.
  • a heating power of 12 W is desired, which is a reasonable value for a heating shoe sheet. In other embodiments other heating power are feasible.
  • the heating foil is connected at the conducting layers 5a and 5b to an electric circuit 9.
  • the electric circuit 9 has a voltage supply of 12 V. In other embodiments other voltages are feasible.
  • the resulting power P corresponds to the desired 12 W.
  • a heating device comprises a heating foil 1 and at least one electric wire 10 connecting the heating foil 1 by means of a punctiform electric contact 1 1 to an electric circuit 9.
  • the heating foil is a flexible sheet, i.e. width W and length L is larger than thickness T.
  • width W width W
  • length L is larger than thickness T.
  • the area A of the heating foil 1 in plain view is about 200 cn 4
  • This heating foil 1 comprises a heating layer 2 with embedded conducting particles 3 for heating, two cover layers 4a and 4b to cover the heating layer 2.
  • the cover layer 4 comprise a conducting layer 5 to connect the heating foil 1 to an external electric circuit 9 and an insulating layer 6.
  • the cover layer 4 comprise only a conducting layer 5.
  • the external electric circuit 9 is connected to the conducting layers 5a and 5b by an electric wire 10.
  • the contact between the external electric circuit 9 and one of the conducting layers 5 is a punctiform electric contact 1 1 , which comprises for example, a soldering point.
  • the heating layer 2 is placed between the two conducting layers 5a and 5b and has in this embodiment a thickness tn of 1 mm.
  • the heating layer 2 consist of two different areas:
  • conducting areas 7 for heating which are embedded in a non-conducting area 8. Both areas are made out of silicone, while the conducting areas 7 comprises embedded conducting particles 3 and the non-conducting area 8 are mostly free of embedded conducting particles 3. E ach area is connected to both conducting layers 5a and 5b.
  • the non-conducting area 8 is spread over the whole heating layer, while the conducting area 7 are equally distributed.
  • the conducting area 7 are circle shaped in plain view.
  • T he thickness tn is 1 mm.
  • One circle plane has a radius of 0.56 mm.
  • the area of the circle is 1 mnr ⁇ T he volume of the cylinder is therefore 1 mmE
  • the total number of conducting areas 7 are 1600, which results in a circle density of 2 per 25 mn 4at the connection of the heating layer 2 to one of the conducting layers 5a and 5b.
  • T he total volume of the conducting area 7 is 1700 mmE
  • the material of the embedded conducting particles 3 is carbon.
  • the size of on carbon particle 3 is between 0.1 i m and 100 i m.
  • the conducting layers 5a and 5b consist of a woven metallic mash 5, which consist of wires with a diameter of 0.1 mm and has an aperture with a maximum diameter of about 1 mm.
  • the conducting layers 5a and 5b are attached to the silicon layer, e.g. by gluing (with conductive glue) or melting.
  • the insulating layers 6a and 6b covers each conducting layer 5a and 5b and are attached to them.
  • the insulating layer 6a is the layer on the top side, which is close to the human body (foot). It is only an electrically insulator to prevent the human from an electric shock.
  • the material of the insulation layer 6a is in this embodiment Polyethylenterephthalat (P ET).
  • P ET Polyethylenterephthalat
  • the thickness of this insulating layer 6a is about 0.1 mm.
  • the insulating layer 6b is attached to the downside of the heating foil 1 . It is insulating electrically and thermally. Therefore, the heating is directed towards the human body.
  • T he material of the insulation layer 6b is in this embodiment P ET.
  • the thickness of this insulating layer 6b is about 2 mm.
  • the heating foil is connected at the conducting layers to an electric circuit 9.
  • the electric circuit 9 has a voltage supply of 12 V. In other embodiments other voltages are feasible.
  • the resulting power P corresponds to the desired 12 W.
  • the conducting areas 7 can be defined by the shape of the conducting layer 5 and the non-conducting areas 8 can be defined by omitting the conducting layers 5a and 5b in these areas.
  • Each segment of the conduction layer 5 in a certain conducting area is in electrically contact with the other segments of the conducting layer 7.
  • These electrical connections can be e.g. embodied by thin conducting paths of the conducting layer 7 in between the individual segments. For example, small electrode dots can be glued on each side of the heating layer 2. Afterwards they are connected via small wires, which can be performed by bonding machines.
  • the insulating layer 6 can be attached in liquid form on each side. This will fix the arrangement and isolate the electric circuit 9 at the same time.
  • the temperature can be adjusted by a control unit, which control the electric power by adjusting the voltage and/or the current. By changing the power, the final temperature will change as well.
  • the conducting layer 5 is applied on the heating layer 2 with a material sputter device, similar to e.g. metallized boP ET films. This will result in a thin conducting layer 5 with a very high flexibility and strong connection to the heating layer.
  • the heating layer 2 is transparent by using e.g. transparent silicone.
  • the embedded conducting particles 3 might tarnish the heating layer 2, but nevertheless light will be go through the layer.
  • a translucent heating foil 1 is feasible.
  • the heating foil 1 is controlled with a sensor.
  • One option is to measure the current which flows through the heating foil, as long as the power supply is a voltage supply.
  • the heating layer has a low temperature dependence, this dependence can be used to determine the temperature.
  • S imila rly the temperature depending resistance can be measured using a four-point- measurement.
  • a temperature sensor can be attached to the heating foil 1 directly.
  • a control unit can adjust the power due to the measured temperature and the desired temperature.
  • the concentration of embedded conducting particles 3 in the heating layer 2 can vary. T his will result in different heating areas of heating. For example, the form of the area with higher concentration, which results a higher temperature, might follow a specific shape. In an alternative embodiment the variation of concentration between two areas of the heating layer 2 change continuously. For example, the concentration might follow a linear, squared or exponential local dependence. In an alternative embodiment the thickness of the heating layer tn can vary. This will result in different heating areas of heating.

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  • Surface Heating Bodies (AREA)

Abstract

Heating device comprising: - a heating foil (1), and - at least one electric wire (10) connecting a conducting layer (4) of the heating foil (1) by means of a punctiform electric contact (11), wherein the heating foil (1) comprises: - a heating layer (2) made of a not compressible polymer with embedded conducting particles (3) that are distributed in the heating layer (2), and - conducting layers (5) disposed on each side of the heating layer (2), wherein at least one of the conducting layers (5) forms a surface electrode.

Description

Heating device and heating foil
The present invention relates to a heating device and a foil.
Ohmic-resistance heating devices are well known. E specially wire resistance is commonly used. To heat a surface the wire is often disposed on a foil or tape in a side to side and/or zigzag-shaped fashion.
Besides several heating tapes are known, where a flat tape-shaped ohmic-resistor is in contact with electrodes at the edges.
For example, in WO 2017/176208 A self-adhesive heating tape is described that at each edge of a thin conductive carbon ink layer a stripe of conductive paste is disposed. The whole layer is laminated with two insulating polymer layers. T he thickness of the heating tape is in the regime of 120 pm to 300 pm.
F urthermore, materials with a positive temperature coefficient (PTC materials) are often used for heating devices as well. T he advantage of such a material is that point-wise self-regulating and self-limiting devices can be realized. Often ceramics are used as PTC materials. T he disadvantage of ceramic lies in the rigid nature of the material.
R ecent developments use often silicone rubber as a PTC material. T o use the silicone rubber as a heating element the contacting electrodes are placed on one side of the material to ensure the minimal gap between the electrodes, which is needed to ensure the necessary field strength of minimum 30 V/mm. This field strength is necessary to enable the PTC effect in silicone rubber.
For example, in US 9,392,645 B2 a heating element is disclosed having a PTC material. In one embodiment the PTC material is a siloxane elastomer, also known as silicone elastomer, with carbon blacks of PTC type. The PTC layer has a thickness of 10 - 300 i m is placed on top of an insulating layer. A third layer, which provide the electrode contacts, is placed on top of the PTC layer. In US 5,250,228 A conductive polymer composition and an electric device is described. The conductive polymer composition is a mixture of an essentially amorphous thermoplastic resin and a thermosetting resin. The conductive polymer composition can be used e.g. for heaters. In the electric device the conductive polymer composition is placed between two electrodes.
In AT 274965 a method to manufacture silicone rubber with homogeneously distributed, electrically conductive or semiconducting particles is disclosed.
In US 4,017,715 A a heater is described, which prevents temperature overshoots. Between two electrodes three layers a re disposed. Two layers, those, which are close to the electrodes, are constant wattage layer to prevent an overshoot A third layer in the middle is a PTC heating layer. The PTC material is, for example, a doped ceramic or a doped thermoplastic polymer.
US 4,774,397 A discloses a heater including a substrate, a longitudinal conductor contact portions or stripes and regularly space semiconductor heating portions or bars extending between the stripes.
AU 8524575 A, also published as DE 2543907 A1 shows another flexible heater comprising a pair of electrode and sheets of an electrically conductive resistive material as heating layer. This elastic material comprises a mixture of rubber and graphite.
Another flexible heating means shown in US 6,172,344 B1 comprises electrodes and a heating layer. The electrodes are positioned at the edges of a thin heating film.
The above mentioned prior art comprises flexible heating tapes, thin heating films and inflexible heating devices.
F lexible heating tapes comprise a conductive heating layer and at the edges electrodes so that heating current is applied alongside the heating layer. S uch heating tapes are disclosed in WO 2017/176208 A, US 4,774,397 A, AU 8524575 A and US 6,172,344 B1. These heating tapes are usually cuttable in a direction perpendicular to the edges at which the electrodes are arranged.
Thin heating films comprise a substrate on which a very thin heating film is disposed. On top of the heating film two electrodes are provided. S uch thin heating films are shown in US 9,392,645 B2.
These heating devices are very flexible, and the heating material is only cuttable before the electrodes are attached. After the electrodes are placed onto the heating film, the heating device is not cuttable anymore.
Inflexible heating devices comprises at least one hard inflexible layer. They are often using a hard heating layer made of ceramics or thermoplastic. S uch inflexible heating devices are described in US 5,250,228 A, US 4,616,125 A and US
4,017,715 A. Due to the hard heating material, like ceramic or thermoplastic, the heating device is not flexible and not cuttable.
In US 3,397,302 a flexible sheet-like electric heater for aircraft wings is disclosed. Two thin sheets are of electrically conductive metal foil is in on either side of a thin electric resistance layer of polytetrafluoroethylene impregnated with carbon particles. Two current conducting lead wires extend along the entire length of said the sheets.
US 2016/01 13065 A1 discloses an electric heater comprising a heating element disposed between a first and a second conductor, wherein the heating element comprises an electric conductive material distributed within an ethylene acetate or ethylene acrylate copolymer, and wherein the heating element has a first thickness in a first region and a different thickness in a second region.
F rom DE 10 2008 035 057 A1 a fabric is known comprising two main conductors and a plurality of heating conductors. The main conductors are arranged in parallel to each other and along one edge of the fabric. T he heating conductors extend a lso parallel to the main conductors and are distributed over the whole fabric. The heating conductors are connected by means of thin conductive wires with the main conductors so that always certain sections of the heating conductors are supplied with electricity from the main conductors. T his kind of fabric provides a homogenous heating and can be cut freely, wherein the heating function is maintained. However, the main conductors cannot be cut and there is a complex structure of main conductors, heating conductors and conductive wires to achieve the cutta bility.
The object of the invention is to provide a heating foil, which comprises a simple structure, which is readily manufactured, which is flexible and cuttable without significant geometric limitations and without any special treatment
The above-mentioned object is solved by the subject matter of one of the independent claims. Advantageous developments and preferred embodiments from the subject of the corresponding sub claims.
A heating foil comprises:
- a heating layer made of a silicone or polyurethane polymer with embedded conducting particles that are distributed in the heating layer, and
- conducting layers disposed on each side of the heating layer, wherein at least one of the conducting layers forms a surface electrode.
As at least one of the conducting layers forms a surface electrode the current for heating the heating layer is crossing the heating layer from one to the other side, wherein the current is distributed over the area of the surface electrode. This provides a homogeneous heating in this area.
P referably, both conducting layers form a surface electrode.
F urthermore, the conducting layers are preferably opposing each other, wherein also a certain offset is possible.
This heating foil comprises a very simple structure as it comprises a heating layer and electrodes, the conducting layers, on both sides of the heating layer.
The heating foil it is preferable flexible. Therefore, the heating foil can adjust to an object, e.g. the sole of a foot; to be comfortable and to heat it efficiently. The heating layer is preferable not compressible. If the heating layer is pinched, the pressed material of the heating layer will elude. After the heating layer is pinched, the material of the heating layer will recapture its form. This allows to cut the heating foil in the regions where a conducting layer is disposed, because due to the incompressibility of the heating layer the conducting layers are kept apart and do not cause a short circuit
As long as a sufficient section of the conducting layers is maintained on the heating layer after cutting the heating foil it is possible to use the cut heating layer without the need of applying an electrode to the heating layer as it is needed in the prior art according to US 9,392,645 B2 after cutting the heating layer.
P referably, the heating layer is completely or nearly completely covered on both sides by the conducting layer. This allows to cut the heating foil in any shape, because then it is secured that the surfaces on each side of the heating layer are sufficiently covered by a conducting layer which forms an electrode.
C ompletely covered does not mean that the conducting layer has to be a continuous layer without any openings. T he conducting layer can be e.g. a mesh or formed with a pattern having one or more openings. The openings shall be so small that a homogeneous current distribution is still possible. The size of the openings is preferably not larger than 10 times of the squared thickness of the heating layer and particularly not larger than 2 times of the squared thickness of the heating layer.
The bulk modulus of the compressibility of silicone is about 1.5 to 2 PGa, which is close to the compressibility of water, which has a bulk modulus of 2.1 to 2.7 PGa. If the heating foil is cut or cropped, e.g. by means of a scissors, the silicone returns to its original position immediately after the clipping, whereby the electrodes remain at a distance from each other. T his allows the heating foil to be cropped as desired.
The cut edges do not need to be further supported or treated afterwards.
As a further advantage defect areas of the heating foil can be easily cut out without replacing the whole heating foil or treating the cut edges further. The heating foil is cuttable along a separation area, as long as the separation area is not parallel to one of the layers
Moreover, using an heating layer with embedded conducting particles thick heating layers are feasible, i.e. layers with a thickness of 1 mm and more are achievable, although smaller thickness than 1 mm are possible, too. By using such thick layers made out of silicone or polyurethane the heater will act like a thermic insulator as well.
Additionally, due to the flexibility of silicone or polyurethane this thick heating layer will be more comfortable in direct contact with human skin, than for example hard ceramic heating foils.
F urthermore, the mechanical properties of silicone change only slightly with temperature changes.
Due to gas permeability of silicone the heating foil is especially suitable for e.g.
active winter clothing, active seat heater, or active storage box for food.
The heating foil can be perforated so that it is permeable for gas and vapor even if the heating layer is completely covered by the conducting layer or made of a non- permeable polymer. The perforation can be laser cut or punched.
P referable, the heating layer has a thickness of at least 0.05 mm, 0.1 mm or 0.3 mm. If the heating layer is thin then the electrical resistance is low and the generated heat is accordingly small or there is a significant risk that the heating layer is deteriorated by the heat.
The maximum thickness is preferably not more than 1 mm, particularly not more than 2 mm or 10 mm. The electrical resistance is the larger the thicker the layer is.
It is advantageous that the conducting particles are composed of carbon. Carbon is a relatively nonhazardous cheap material, which is easily to fabricate. Carbon can withstand high temperatures and strong electric currents. The carbon particles can be also carbon nano tubes, carbon black, graphite, or carbon fibers.
P referably, the conducting particles are homogenously distributed. They can also be randomly distributed.
Favorably, the conducting particles have a concentration in weight relative to the silicone of at least 1 %, 10% or 20% and/or preferably not more than 70%, 80% or 95%
It is beneficial that the heating layer has specific electrical resistance of minimum 5 Witi, 10 Om or 20 Om and maximum 1 kQm, 10 kQm or 100 kQm
A favorable setting is, that the conducting layer is a metal mesh. The inventors have realized that a non-continuous conducting layer maintains a stronger connection to the silicone layer, if the heating foil is bent. Continuous conducting layer might break or getting more easily detached from the heating layer.
P referably, the metal mesh consists of conductor stripes or wires with a width or diameter of at least 0.05 mm, 0.1 mm or 0.5 mm and/or preferably not more than 1 mm, 1.5 mm or 2 mm.
The metal mesh can be printed onto the heating layer.
Favorably, the metal mesh has an aperture with a maximum diameter of at least 0.05 mm, 0.5 mm or 1 mm and/or preferably not more than 5 mm, 10 mm or 15 mm. The apertures can be in the form of a circle or any other form. If the aperture deviates from the form of the circle then it comprises different diameters.
It is advantageous, that the conducting layers are covered with an insulator layer, which isolates the heating foil electronically and/or thermally. Therefore, the heating foil can be touched without risking an electric shock. F urthermore, the insulator layer, made out of e.g. a polymer, protects the other layer from harm like e.g. sharp objects or liquids. Additionally, using a thermally isolation will direct the heating to one side mainly. This is beneficially in clothing. On the side towards a human body is needed to be heated. The other side can be insulated, which will increase the heating on the preferred side.
P referably, on both sides of the heating foil an electrical insulator is provided.
It is advantageous, that on one side of the heating foil a thermally insulator is provided.
There can be an insulator structure comprising several insulating layers. It can also make sense to provide on one side of the heating foil an insulating layer which forms a good electrically and thermally insulator and on the other side an insulating layer which forms a good electrically but not so good thermally insulator. T his can be e.g. achieved by applying on one side a thick layer of insulating material and on the other side a thin layer of insulating material of the same or different insulating material.
The concentration of the embedded conducting particles may be heterogeneous. A heterogeneous concentration is defined as a certain concentration of embedded conducting particles at a certain area and another concentration of embedded conducting particles at another, different area. The change of the concentration between these areas may be continuous. T his will result in different heating areas of heating. For example, an area with higher concentration will results in a higher temperature.
An area with a certain concentration might follow a specific shape.
The heating foil can comprise several separated conducting areas in the heating layer, wherein the non-conducting areas in between the separated conducting areas are embodied so that they do not conduct significant amounts of electrical current and do therefore not contribute to the heating of the heating foil. The conducting areas can be composed of silicone with embedded conducting particles and the non conducting areas can be composed of a polymer without embedded conducting pa rticles.
The conducting areas can be defined by the shape of the conducting layer and the non-conducting areas can be defined by omitting the conducting layers in these areas. E ach segment of the conduction layer in a certain conducting area shall to be in electrically contact with the other segments of the conducting layer. These electrical connections can be e.g. embodied by thin conducting paths of the conducting layer in between the individual segments.
With this separation in conducting areas and non-conducting areas it is possible to use large heating foils which have e.g. a size of one or more m/l Even with such a size a reasonable power consumption can be achieved. Large heating foils with one single continuous heating area would need a conducting layer with a very small electric resistance due to the large size of the heating layer. This makes it difficult to control the electrical power and thus the heating behavior of the heating foil. If a plurality of heating areas are provided a homogeneous temperature distribution can be easily achieved, particularly if the conducting layer is completely covering the heating layer, because electrically conducting materials are mostly also good heat conductors.
For example, the conducting area can be shaped like circles in the plain view. P referably, the conducting areas are equally distributed.
A heating device comprising:
- a heating foil, and
- at least one electric wire connecting a conducting layer of the heating foil by means of a punctiform electric contact
wherein the heating foil comprises:
- a heating layer made of a not compressible polymer with embedded conducting particles that are distributed in the heating layer, and
- conducting layers disposed on each side of the heating layer, wherein at least one of the conducting layers forms a surface electrode.
The electric wire can be used to connect the heating device to an electric circuit.
The punctiform electric contact is, for example, a soldering point. P unctiform means that the area of the electric contact is significantly smaller than the area of the conductive area. The heating foil can be cut everywhere, as long as the conducting layers of the remaining areas have a punctiform electric contact.
P referably, the heating foil corresponds to the above mentioned heating foil.
S ubsequently, exemplarily two embodiments of the invention will be described by reference to the illustrations.
The illustrations show schematically in:
F igure 1 an embodiment of the inventive heating device in isometric view,
F igure 2 a section 12 of the heating device in F ig. 1 ,
F igure 3 the section 12 of the heating device of F ig. 2 with cut layers,
F igure 4 an alternative of a section of the heating device of F ig. 1 ,
F igure 5 a second embodiment of the inventive heating device with separated conducting areas in shown with cut layers,
F igure 6 a section of a heating device with insulating layers, and
F igure 7 an implementation in an electric circuit of the inventive heating device in isometric view.
A heating device for a heating shoe forms a first exemplary embodiment of the present invention (figure 1 to 4).
The heating device comprises a heating foil 1 and at least one electric wire 10 connecting the heating foil 1 by means of a punctiform electric contact 1 1 to an electric circuit 9.
The heating foil 1 is a flexible sheet, i.e. width W and length L is larger than thickness T. In this embodiment the shape of the inventive heating foil follows the shape of the shoe in plain view with a maximum width W = 10 cm and the length L is 25 cm. The area A of the heating foil 1 in plain view is about 200 cn 4
This heating foil 1 comprises a heating layer 2 with embedded conducting particles 3 for heating, two cover layers 4a and 4b to cover the heating layer 2. The cover layer 4 comprise a conducting layer 5 to connect the heating foil 1 to an external electric circuit 9 and an insulating layer 6.
Alternatively, the cover layer 4 comprise only a conducting layer 5.
The external electric circuit 9 is connected to the conducting layers 5a and 5b by the electric wire 10. The contact between the external electric circuit 9 and one of the conducting layers 5 is a punctiform electric contact 1 1 , which comprises for example, a soldering point.
The heating layer 2 is placed between the two conducting layers 5a and 5b and has in this embodiment a thickness tn of 1 mm. The specific electric resistance p is 240
Qm. With a specific electric resistance p = 240 Qm the total electric resistance R can be calculated:
R = p . tH / A = 12 n.
In this embodiment the material of the embedded conducting particles 3 is carbon. The carbon concentration in weight relative to the silicone of resistance of 4%.T he size of on carbon particle 3 is between 0.1 i m and 100 i m.
In this embodiment the conducting layers 5a and 5b consist of a woven metallic mash, which comprises wires with a diameter of 0.1 mm and has an aperture with a maximum diameter of about 1 mm. The conducting layers 5a and 5b are attached to the silicon layer, e.g. by gluing (with conductive glue) or melting.
The insulating layers 6a and 6b covers each conducting layer 5a and 5b and are attached to them. The insulating layer 6a is the layer on the top side, which is close to the human body (foot). It is an electrically insulator to prevent the human from an electric shock. The material of the insulation layer 6a is in this embodiment
Polyethylenterephthalat (P ET). The thickness of this insulating layer 6a is about 0.1 mm. The insulating layer 6b is attached to the downside of the heating foil 1 . It is insulating electrically and thermally. Therefore, the heating is directed towards the human body. The material of the insulation layer 6b is in this embodiment P ET. The thickness of this insulating layer 6b is about 2 mm.
Hereinafter, the use of an inventive heating foil is described (figure 6).
In this embodiment a heating power of 12 W is desired, which is a reasonable value for a heating shoe sheet. In other embodiments other heating power are feasible.
To create heat the heating foil is connected at the conducting layers 5a and 5b to an electric circuit 9. In this embodiment of a heating shoe sheet the electric circuit 9 has a voltage supply of 12 V. In other embodiments other voltages are feasible.
With a given resistance R = 12 W of the heating layer 2, the current can be calculated:
I = U / R = 12 V / 12 W = 1 A.
Therefore, the power P is:
P = U I = 12 V - 1 A = 12 W.
The resulting power P corresponds to the desired 12 W.
Hereinafter, a second embodiment of the invention is described, wherein same elements are provided with the same reference numbers as in the first embodiment The above description applies to the same elements unless otherwise stated below (F ig. 1 and 5).
Again, a heating device comprises a heating foil 1 and at least one electric wire 10 connecting the heating foil 1 by means of a punctiform electric contact 1 1 to an electric circuit 9. The heating foil is a flexible sheet, i.e. width W and length L is larger than thickness T. In this embodiment the shape of the inventive heating foil follows the shape of the shoe in plain view with a maximum width W = 10 cm and the length L is 25 cm. The area A of the heating foil 1 in plain view is about 200 cn 4
This heating foil 1 comprises a heating layer 2 with embedded conducting particles 3 for heating, two cover layers 4a and 4b to cover the heating layer 2.
The cover layer 4 comprise a conducting layer 5 to connect the heating foil 1 to an external electric circuit 9 and an insulating layer 6.
Alternatively, the cover layer 4 comprise only a conducting layer 5.
The external electric circuit 9 is connected to the conducting layers 5a and 5b by an electric wire 10. The contact between the external electric circuit 9 and one of the conducting layers 5 is a punctiform electric contact 1 1 , which comprises for example, a soldering point.
The heating layer 2 is placed between the two conducting layers 5a and 5b and has in this embodiment a thickness tn of 1 mm.
Unlike the first embodiment the heating layer 2 consist of two different areas:
conducting areas 7 for heating, which are embedded in a non-conducting area 8. Both areas are made out of silicone, while the conducting areas 7 comprises embedded conducting particles 3 and the non-conducting area 8 are mostly free of embedded conducting particles 3. E ach area is connected to both conducting layers 5a and 5b.
The non-conducting area 8 is spread over the whole heating layer, while the conducting area 7 are equally distributed.
In this embodiment, the conducting area 7 are circle shaped in plain view. T he thickness tn is 1 mm. One circle plane has a radius of 0.56 mm. The area of the circle is 1 mnr^ T he volume of the cylinder is therefore 1 mmE In this embodiment the total number of conducting areas 7 are 1600, which results in a circle density of 2 per 25 mn 4at the connection of the heating layer 2 to one of the conducting layers 5a and 5b. T he total volume of the conducting area 7 is 1700 mmE The total area Ac ire le IS 1700 mn 4
The specific electric resistance p is here 20.4 Qm. With a specific electric resistance p = 20.4 Om the total electric resistance R can be calculated:
R = p tn / Acircle = 12 W.
In this embodiment the material of the embedded conducting particles 3 is carbon. The carbon concentration in weight relative to the silicone of resistance of 6%. The size of on carbon particle 3 is between 0.1 i m and 100 i m.
In this embodiment the conducting layers 5a and 5b consist of a woven metallic mash 5, which consist of wires with a diameter of 0.1 mm and has an aperture with a maximum diameter of about 1 mm. The conducting layers 5a and 5b are attached to the silicon layer, e.g. by gluing (with conductive glue) or melting.
The insulating layers 6a and 6b covers each conducting layer 5a and 5b and are attached to them. The insulating layer 6a is the layer on the top side, which is close to the human body (foot). It is only an electrically insulator to prevent the human from an electric shock. The material of the insulation layer 6a is in this embodiment Polyethylenterephthalat (P ET). The thickness of this insulating layer 6a is about 0.1 mm.
The insulating layer 6b is attached to the downside of the heating foil 1 . It is insulating electrically and thermally. Therefore, the heating is directed towards the human body. T he material of the insulation layer 6b is in this embodiment P ET. The thickness of this insulating layer 6b is about 2 mm.
Hereinafter, the use of an inventive heating foil is described (figure 6). In this embodiment a heating power of 12 W is desired, which is a reasonable value for a heating shoe sheet In other embodiments other heating power are feasible.
To create heat the heating foil is connected at the conducting layers to an electric circuit 9. In this embodiment of a heating shoe sheet the electric circuit 9 has a voltage supply of 12 V. In other embodiments other voltages are feasible.
With a given resistance R = 12 W of the heating layer 2, the current can be
calculated:
I = U / R = 12 V / 12 W = 1 A.
Therefore, the power P is:
P = U I = 12 V - 1 A = 12 W.
The resulting power P corresponds to the desired 12 W.
In an alternative embodiment the conducting areas 7 can be defined by the shape of the conducting layer 5 and the non-conducting areas 8 can be defined by omitting the conducting layers 5a and 5b in these areas. Each segment of the conduction layer 5 in a certain conducting area is in electrically contact with the other segments of the conducting layer 7. These electrical connections can be e.g. embodied by thin conducting paths of the conducting layer 7 in between the individual segments. For example, small electrode dots can be glued on each side of the heating layer 2. Afterwards they are connected via small wires, which can be performed by bonding machines.
To stabilize this arrangement of electrode dots and bonding wires, the insulating layer 6 can be attached in liquid form on each side. This will fix the arrangement and isolate the electric circuit 9 at the same time. Beneficially, the temperature can be adjusted by a control unit, which control the electric power by adjusting the voltage and/or the current. By changing the power, the final temperature will change as well.
In an alternative embodiment the conducting layer 5 is applied on the heating layer 2 with a material sputter device, similar to e.g. metallized boP ET films. This will result in a thin conducting layer 5 with a very high flexibility and strong connection to the heating layer.
Alternatively, instead of a single heating layer 2 in between two conducting layers 5a and 5b, it might be advantageously to stack several heating 2 and conducting layers 5a and 5b a Ite rnatingly.
Beneficially, the heating layer 2 is transparent by using e.g. transparent silicone. The embedded conducting particles 3 might tarnish the heating layer 2, but nevertheless light will be go through the layer. In combination with a metal mash 5, a translucent heating foil 1 is feasible.
In an alternative embodiment the heating foil 1 is controlled with a sensor. One option is to measure the current which flows through the heating foil, as long as the power supply is a voltage supply. Although the heating layer has a low temperature dependence, this dependence can be used to determine the temperature. S imila rly, the temperature depending resistance can be measured using a four-point- measurement. Alternatively, a temperature sensor can be attached to the heating foil 1 directly. A control unit can adjust the power due to the measured temperature and the desired temperature.
Alternatively, the concentration of embedded conducting particles 3 in the heating layer 2 can vary. T his will result in different heating areas of heating. For example, the form of the area with higher concentration, which results a higher temperature, might follow a specific shape. In an alternative embodiment the variation of concentration between two areas of the heating layer 2 change continuously. For example, the concentration might follow a linear, squared or exponential local dependence. In an alternative embodiment the thickness of the heating layer tn can vary. This will result in different heating areas of heating.
List of reference numbers
1 Heating foil
2 heating layer
3 embedded conducting particles
4 cover layer
5 conducting layer
6 insulator layer
7 conducting area
8 non-conducting area
9 electric circuit
10 electric wire
1 1 punctiform electric contact
12 section of heating foil p specific electric resistance
R total electric resistance
I current
V voltage
P power
W width
L length
T thickness of heating foil
tH thickness of heating layer
tc thickness of conducting layer
A plane area

Claims

C laims
1. Heating foil (1 ) comprising:
- a heating layer (2) made of silicone or polyurethane polymer with embedded conducting particles (3) that are distributed in the heating layer (2), and
- conducting layers (5) disposed on each side of the heating layer (2), wherein at least one of the conducting layers (5) forms a surface electrode.
2. Heating foil (1 ) according to claim 1 ,
characterized in that
the conducting particles (3) are composed of carbon, carbon black, graphite, carbon fibres or carbon nano tubes.
3. Heating foil (1 ) according to claim 1 or 2,
characterized in that
the conducting particles (3) has a concentration in weight relative to the not compressible polymer of resistance of at least 1 %, 10% or 20% and/or preferably not more than 70%, 80% or 95%.
4. Heating foil (1 ) according to one of the claims 1 to 3,
characterized in that
the heating layer (2) has specific electrical resistance of at least 5 Om, 10 Qm or 20 Dm and/or preferably not more than 1 kQm, 10 kQm or 100 kQm.
5. Heating foil (1 ) according to one of the claims 1 to 4,
characterized in that
the conducting layer (5) is a metal mesh.
6. Heating foil (1 ) according to claim 5,
characterized in that
the metal mesh consists of wires with a diameter of at least 0.05 mm, 0.1 mm or 0.5 mm and/or preferably not more than 1 mm, 1 .5 mm or 2 mm.
7. Heating foil (1 ) according to claim 5 or 6,
characterized in that
the metal mesh (5) has an aperture with a maximum diameter of at least 0.05 mm, 0.5 mm or 1 mm and/or preferably not more than 5 mm, 10 mm or 15 mm.
8. Heating foil (1 ) according to one of the claims 1 to 7,
characterized in that
the conducting layers (4) are covered with an additional insulator layer (6), which insulated the heating electronically a nd/or thermally.
9. Heating foil (1 ) according to one of the claims 1 to 8,
characterized in that
the concentration of the embedded conducting particles (3) is heterogeneous.
10. Heating foil (1 ) according to one of the claims 1 to 9,
characterized in that
several separated conducting areas (7) of the heating layer (2) are comprised, wherein non-conducting (8) of the heating layer (2) areas in between the separated conducting areas (7) are embodied so that they do not conduct significant amounts of electrical current and do therefore not contribute to the heating of the heating foil (1 ).
11. Heating foil (1 ) according to claim 10,
characterized in that
the conducting areas (7) can be composed of silicone with embedded conducting particles (3) and the non-conducting areas (8) can be composed of a polymer without embedded conducting particles (3).
12. Heating foil (1 ) according to claim 10 or 11 ,
characterized in that
the conducting areas (7) can be defined by the shape of the conducting layer (5) and the non-conducting areas (8) can be defined by omitting the conducting layers (5) in these areas.
13. Heating device comprising:
- a heating foil (1 ), and
- at least one electric wire (10) connecting a conducting layer (5) of the heating f o i I ( 1 ) by means of a punctiform electric contact (1 1 ),
wherein the heating foil (1 ) comprises:
- a heating layer (2) made of a not compressible polymer with embedded conducting particles (3) that are distributed in the heating layer (2), and
- conducting layers (5) disposed on each side of the heating layer (2), wherein at least one of the conducting layers (5) forms a surface electrode.
14. Heating device according to claim 13,
characterized in that
the heating foil (1 ) correspond to one of the claims 1 to 12.
PCT/SG2018/050306 2018-06-25 2018-06-25 Heating device and heating foil Ceased WO2020005151A1 (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20210023327A1 (en) * 2013-05-17 2021-01-28 Paul Barghouth Humidification of Ventilator Gases
US20220078890A1 (en) * 2020-09-05 2022-03-10 Young Fast Optoelectronics Co., Ltd. Transparent heating film

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4743321A (en) * 1985-10-04 1988-05-10 Raychem Corporation Devices comprising PTC conductive polymers
US4783587A (en) * 1984-12-18 1988-11-08 Matsushita Electric Industrial Co., Ltd. Self-regulating heating article having electrodes directly connected to a PTC layer
US4833305A (en) * 1986-08-12 1989-05-23 Mitsuboshi Belting Limited Thermally self-regulating elastomeric composition and heating element utilizing such composition
US20060000823A1 (en) * 2003-11-19 2006-01-05 Surgrx, Inc. Polymer compositions exhibiting a PTC property and methods of fabrication
US20100320191A1 (en) * 2006-10-17 2010-12-23 Conflux Ab Heating element
CN103572453A (en) * 2012-08-12 2014-02-12 泰根索路科技股份有限公司 Conductive silicone rubber heating element and manufacturing method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4783587A (en) * 1984-12-18 1988-11-08 Matsushita Electric Industrial Co., Ltd. Self-regulating heating article having electrodes directly connected to a PTC layer
US4743321A (en) * 1985-10-04 1988-05-10 Raychem Corporation Devices comprising PTC conductive polymers
US4833305A (en) * 1986-08-12 1989-05-23 Mitsuboshi Belting Limited Thermally self-regulating elastomeric composition and heating element utilizing such composition
US20060000823A1 (en) * 2003-11-19 2006-01-05 Surgrx, Inc. Polymer compositions exhibiting a PTC property and methods of fabrication
US20100320191A1 (en) * 2006-10-17 2010-12-23 Conflux Ab Heating element
CN103572453A (en) * 2012-08-12 2014-02-12 泰根索路科技股份有限公司 Conductive silicone rubber heating element and manufacturing method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20210023327A1 (en) * 2013-05-17 2021-01-28 Paul Barghouth Humidification of Ventilator Gases
US12390614B2 (en) * 2013-05-17 2025-08-19 Sahamed Technologies, Llc Humidification of ventilator gases
US20220078890A1 (en) * 2020-09-05 2022-03-10 Young Fast Optoelectronics Co., Ltd. Transparent heating film

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