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WO2019186681A1 - Substrate processing device and semiconductor device production method - Google Patents

Substrate processing device and semiconductor device production method Download PDF

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Publication number
WO2019186681A1
WO2019186681A1 PCT/JP2018/012337 JP2018012337W WO2019186681A1 WO 2019186681 A1 WO2019186681 A1 WO 2019186681A1 JP 2018012337 W JP2018012337 W JP 2018012337W WO 2019186681 A1 WO2019186681 A1 WO 2019186681A1
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WO
WIPO (PCT)
Prior art keywords
tube
reaction tube
substrate processing
processing apparatus
pipe
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2018/012337
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French (fr)
Japanese (ja)
Inventor
優作 岡嶋
周平 西堂
吉田 秀成
隆史 佐々木
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kokusai Electric Corp
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Kokusai Electric Corp
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Filing date
Publication date
Application filed by Kokusai Electric Corp filed Critical Kokusai Electric Corp
Priority to JP2020510225A priority Critical patent/JP6918211B2/en
Priority to PCT/JP2018/012337 priority patent/WO2019186681A1/en
Publication of WO2019186681A1 publication Critical patent/WO2019186681A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • H10P72/0441
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/67005Apparatus not specifically provided for elsewhere
    • H01L21/67011Apparatus for manufacture or treatment
    • H01L21/67126Apparatus for sealing, encapsulating, glassing, decapsulating or the like
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • H10P14/60
    • H10P32/00
    • H10P72/0402
    • H10P72/0432

Definitions

  • the present invention relates to a furnace port portion structure of a substrate processing apparatus, and more particularly, to a heat resistance countermeasure technique for the furnace port portion.
  • a reaction tube has a boat as a substrate holding member for holding wafers, that is, substrates in multiple stages, and the substrate is processed in a processing chamber in the reaction tube while holding the plurality of substrates. It is known that there is something to do.
  • a plurality of substrates are vertically arranged and held by a substrate holding member and are carried into a processing chamber. Thereafter, a processing gas is introduced into the processing chamber while the substrate is heated by a superheater such as a heater installed outside the processing chamber, and a thin film forming process or the like is performed on the substrate.
  • Patent Document 1 such a substrate processing apparatus is formed of opaque quartz for reducing the influence of heat from the substrate, the substrate holding member, and the heating device and preventing the seal member such as an O-ring from being burned out.
  • a structure has been proposed in which the cylindrical heat shield ring is disposed obliquely above the O-ring.
  • a reaction tube fixing ring is used when connecting to a furnace port part.
  • the reaction tube fixing ring is provided with a flow path of cooling water, and the reaction tube and the furnace port part are connected to each other. It performs the cooling function for the O-ring part installed in between.
  • the diameter of the exhaust pipe of the reaction tube is increased for the purpose of improving the exhaust efficiency in the reaction tube, the flange on the bottom surface and the exhaust pipe are close to each other, and the reaction tube fixing ring may not be provided below the exhaust pipe. is there. In this case, the cooling function of the O-ring below the exhaust pipe is lowered, and it becomes necessary to limit the temperature. It is difficult to provide a cylindrical shielding ring as described in Patent Document 1 even below the exhaust pipe.
  • An object of the present invention is to solve the above-described problems and to provide a configuration capable of suppressing the temperature rise of the O-ring portion below the exhaust pipe even when the diameter of the exhaust pipe is widened.
  • a substrate holder for arranging and holding a plurality of substrates, a cylindrical inner tube having an opening through which a substrate holder can be taken in and out, and an upper end that is closed to the outer periphery of the lower end
  • a reaction tube having a cylindrical outer tube provided with a flange and configured to surround the inner tube; a furnace body that surrounds the top and sides of the reaction tube; a heater that heats the inside of the furnace body; and a flange, A mating member connected via a seal member, a heat insulating structure disposed between the substrate holder and the mating member, and a gas supply mechanism for supplying gas to a plurality of substrates held in the reaction tube
  • the reaction tube is provided near the flange in a position facing the exhaust pipe along the outer surface of the inner pipe, and an exhaust pipe that fluidly communicates the space between the inner pipe and the outer pipe with the outside of the outer pipe.
  • a configuration having a diffuser plate provided is provided.
  • FIG. 1 It is a figure which shows one structural example of the vertical heat processing apparatus with which this invention is applied. It is a schematic diagram for demonstrating the subject of the substrate processing apparatus of this invention. It is a figure which shows the principal part of the substrate processing apparatus based on Example 1. FIG. It is a figure which shows the principal part of the substrate processing apparatus based on Example 2. FIG.
  • the substrate processing apparatus 1 is configured as a vertical heat treatment apparatus that performs a heat treatment process in the manufacture of a semiconductor integrated circuit, and includes a processing furnace 2.
  • the processing furnace 2 has a heater 3 in order to heat it uniformly.
  • the heater 3 has a cylindrical shape and is installed perpendicular to the installation floor of the substrate processing apparatus 1 by being supported by a heater base as a holding plate.
  • the heater 3 also functions as an activation mechanism that excites the gas with heat.
  • the reaction tube 4 constituting a reaction vessel is disposed inside the heater 3, a reaction tube 4 constituting a reaction vessel is disposed.
  • the reaction tube 4 is made of a heat-resistant material such as quartz (SiO 2) or silicon carbide (SiC), and has a cylindrical shape with the upper end closed and the lower end opened.
  • the reaction tube 4 has a double-pipe structure having an outer tube 4A and an inner tube 4B that are coupled to each other at a flange 4C at the lower end. The upper ends of the outer tube 4A and the inner tube 4B are closed, and the lower end of the inner tube 4B is open.
  • the flange 4C has a larger outer diameter than the outer tube 4A and protrudes outward.
  • An exhaust port 4D communicating with the inside of the outer tube 4A is provided near the lower end of the reaction tube 4, and the entire reaction tube 4 is integrally formed of a single material such as quartz.
  • the double structure including the outer tube 4A and the inner tube 4B is not limited to an integral structure in which both are coupled to each other, and may be a separable structure.
  • the manifold 5 has a cylindrical or truncated cone shape, is made of metal or quartz, and is provided to support the lower end of the reaction tube 4.
  • the inner diameter of the manifold 5 is formed larger than the inner diameter of the reaction tube 4, that is, the inner diameter of the flange 4C.
  • an annular space is formed between the flange 4 ⁇ / b> C at the lower end of the reaction tube 4 and the seal cap 19. This space or its surrounding members are collectively referred to as the furnace opening.
  • the inner pipe 4B has a main exhaust port 4E that communicates the inside and the outside on the side of the reaction tube at the back side of the exhaust port 4D, and a supply slit 4F at a position opposite to the main exhaust port 4E.
  • the main exhaust port 4E is a single vertically long opening that opens to a region where the wafer 7 is disposed.
  • the supply slits 4 ⁇ / b> F are slits extending in the circumferential direction, and a plurality of supply slits 4 ⁇ / b> F are provided in the vertical direction so as to correspond to the respective wafers 7.
  • one or more nozzles 8 for supplying a processing gas such as a raw material gas are provided in correspondence with the position of the supply slit 4F. It has been.
  • a gas supply pipe 9 for supplying a processing gas is connected to the nozzle 8 through the manifold 5.
  • the inner pipe 4B is further provided with a plurality of sub exhaust ports 4G that allow the processing chamber 6 and the exhaust space S to communicate with each other at a position farther behind the reaction tube 4 than the exhaust port 4D and more open than the main exhaust port 4E. It is done.
  • the flange 4C is also formed with a plurality of bottom exhaust ports 4H and the like for communicating the processing chamber 6 and the lower end of the exhaust space S. In other words, the lower end of the exhaust space S is closed by the flange 4C except for the bottom exhaust port 4H and the like.
  • the sub exhaust port 4G and the bottom exhaust port 4H mainly function to exhaust a shaft purge gas described later.
  • a mass flow controller (MFC) 10 that is a flow rate controller and a valve 11 that is an on-off valve are provided on the flow path of the gas supply pipe 9 in order from the upstream direction.
  • a gas supply pipe 12 that supplies an inert gas is connected to the gas supply pipe 9 on the downstream side of the valve 11.
  • the gas supply pipe 12 is provided with an MFC 13 and a valve 14 in order from the upstream direction.
  • a processing gas supply unit that is a processing gas supply system is mainly configured by the gas supply pipe 9, the MFC 10, and the valve 11. As described above, the substrate processing apparatus shown in FIG. 1 uses the gas supply mechanism including the nozzle 8, the gas supply pipes 9 and 12, the MFCs 10 and 13, the valves 11 and 14, and the like.
  • the substrate processing is performed by sequentially repeating the fourth step to be supplied to the substrate.
  • the nozzle 8 is provided in the gas supply space 4 so as to rise from the lower part of the reaction tube 4.
  • One or a plurality of nozzle holes 8H for supplying gas are provided on the side surface and upper end of the nozzle 8.
  • the plurality of nozzle holes 8H correspond to the respective openings of the supply slit 4F, and are opened so as to face the center of the reaction tube 4, so that gas can be injected toward the wafer 7 through the inner tube 4B. it can.
  • An exhaust pipe 15 that exhausts the atmosphere in the processing chamber 6 is connected to the exhaust port 4D.
  • a vacuum pump 18 as a vacuum exhaust device is connected to the exhaust pipe 15 via a pressure sensor 16 as a pressure detector for detecting the pressure in the processing chamber 6 and an APC (Auto Pressure Controller) valve 17 as a pressure adjusting unit. It is connected.
  • the APC valve 17 can perform evacuation in the processing chamber 6 and stop evacuation by opening and closing the valve while the vacuum pump 18 is operated. Further, the pressure in the processing chamber 6 can be adjusted by adjusting the valve opening degree based on the pressure information detected by the pressure sensor 16 in a state where the vacuum pump 18 is operated. .
  • a seal cap 19 is provided as a furnace port lid that can airtightly close the lower end opening of the manifold 5.
  • the seal cap 19 is made of, for example, a metal such as stainless steel or a nickel-based alloy, and is formed in a disk shape.
  • An O-ring 19 ⁇ / b> A is provided on the upper surface of the seal cap 19 as a seal member that comes into contact with the lower end of the manifold 5.
  • the O-ring as the seal member can be installed on the upper surface of the manifold 5 so as to contact the lower end of the flange 4C.
  • a cover plate 20 that protects the seal cap 19 is provided on the upper surface of the seal cap 19 with respect to a portion inside the lower end inner periphery of the manifold 5.
  • the cover plate 20 is made of a heat and corrosion resistant material such as quartz, sapphire, or SiC, and is formed in a disk shape.
  • the boat 21 as a substrate holder supports a plurality of, for example, 25 to 200, wafers 7 in a multi-stage by aligning them vertically in a horizontal posture and with their centers aligned. In this case, the wafers 7 are arranged at regular intervals.
  • the boat 21 is made of a heat resistant material such as quartz or SiC. It may be desirable for the reaction tube 4 to have a minimum inner diameter that allows the boat 21 to be safely carried in and out.
  • a heat insulation assembly 22 is disposed at the bottom of the boat 21.
  • the heat insulation assembly 22 has a structure that reduces heat conduction or transmission in the vertical direction, and usually has a cavity inside. The interior can be purged with a shaft purge gas.
  • a processing region A an upper portion where the boat 21 is disposed
  • a lower portion where the heat insulating assembly 22 is disposed is referred to as a heat insulating region B.
  • Rotating mechanism 23 for rotating boat 21 is installed on the side of seal cap 19 opposite to processing chamber 6.
  • a gas supply pipe 24 for shaft purge gas is connected to the rotation mechanism 23.
  • the gas supply pipe 44c is provided with an MFC 25 and a valve 26 in order from the upstream direction.
  • the boat elevator 27 is provided vertically below the reaction tube 4 and operates as an elevating / lowering mechanism for moving the seal cap 19 up and down. Thereby, the boat 21 and the wafer 7 supported by the seal cap 19 are carried into and out of the processing chamber 6. Note that a shutter that closes the lower end opening of the reaction tube 4 may be provided instead of the seal cap 19 while the seal cap 19 is lowered to the lowest position.
  • a temperature detector 28 is installed on the outer wall of the outer tube 4A.
  • the temperature detector 28 can be configured by a plurality of thermocouples arranged side by side. By adjusting the power supply to the heater 3 based on the temperature information detected by the temperature detector 28, the temperature in the processing chamber 6 becomes a desired temperature distribution.
  • the controller 29 is a computer that controls the entire substrate processing apparatus 1, and includes MFCs 10 and 13, valves 11 and 14, pressure sensor 16, APC valve 17, vacuum pump 18, heater 3, temperature detector 28, rotating mechanism 23, boat It is electrically connected to the elevator 27 and the like, and receives signals from them and controls them.
  • a furnace port that forms an annular space between the reaction tube 4, a flange 4 ⁇ / b> C at the lower end thereof, and a seal cap 19 that is a lid of the furnace port part.
  • a reaction tube fixing ring is used to connect the parts.
  • 2A and 2B schematically show the substrate processing apparatus 1 using the reaction tube fixing ring 29 as a longitudinal sectional view and a transverse sectional view thereof.
  • the O-ring installed between the lower end of the flange and the manifold of the furnace opening portion at this time becomes high temperature.
  • a cooling water flow path (not shown) is provided inside the reaction tube fixing ring 29 to perform a cooling function for the O-ring portion installed between the flange and the manifold.
  • the exhaust port diameter of the reaction tube 4 that is, the diameter of the exhaust tube 15 is increased for the purpose of improving the exhaust efficiency in the reaction tube
  • the seal cap 19 and the exhaust tube 15 are close as shown schematically in FIG.
  • the reaction tube fixing ring 29 cannot be provided up to the bottom of the exhaust pipe 15 at the exhaust port.
  • the cooling function of the O-ring located below the exhaust port, that is, the exhaust pipe 15, is lowered, it is necessary to limit the temperature of heating by the heater.
  • various embodiments of the present invention for solving this problem will be described.
  • a substrate holder for arranging and holding a plurality of substrates, a cylindrical inner tube having an opening through which the substrate holder can be taken in and out, a flange on the outer periphery of the lower end, which is closed at the upper end, are provided.
  • a reaction tube having a cylindrical outer tube configured to surround the inner tube, a furnace body that surrounds the top and sides of the reaction tube, a heater that heats the inside of the furnace body, and a flange through a seal member
  • a mating member connected to each other, a heat insulating structure disposed between the substrate holder and the mating member, and a gas supply mechanism for supplying gas to a plurality of substrates held in the reaction tube.
  • An exhaust pipe that fluidly communicates the space between the inner pipe and the outer pipe with the outside of the outer pipe in the vicinity of the flange, and a scattering plate provided at a position facing the exhaust pipe along the outer surface of the inner pipe It is an Example of the substrate processing apparatus which has.
  • FIG. 3 is a schematic diagram showing a configuration of a main part of the first embodiment.
  • the principal part of the substrate processing apparatus which has the scattering plate 30 provided only in the position which opposes the exhaust pipe 15 along the outer surface of the inner pipe 4B of the reaction tube of a present Example was shown typically.
  • the scattering plate 30 made of a radiation net that scatters radiation (light rays such as infrared rays) is a position substantially facing the exhaust pipe 15 so as to scatter and reflect radiation directly reaching the O-ring 19B below the exhaust pipe. And installed so as to cover the height between the straight line drawn from the upper part of the heater to the O-ring 19B and the straight line drawn from the lower part of the heater to the O-ring. As shown in FIGS.
  • the scattering plate 30 is provided at a position that takes into account the direction of arrival of thermal radiation, but the scattering plate 30 has an opening so as not to block the intermediate exhaust port.
  • 30A is formed. That is, since the inner pipe 4B has a sub exhaust port (intermediate exhaust port) 4G that fluidly communicates the inner side and the outer side of the inner pipe at a position facing the exhaust pipe 15, a newly installed scattering plate 30 is configured to have an opening 30A having the same shape as the sub exhaust port 4G so as not to block the sub exhaust port 4G.
  • quartz that is made opaque by forming a large number of minute cavities and voids that are inner bubbles. This type of opaque quartz remains opaque even when fired. Since the wavelength transmittance varies depending on the size of the void, it is preferable to select a void having an appropriate size according to the temperature of the reactor, 600 to 1000 ° C.
  • the insertion-side hinges 31 are provided at the upper and lower ends of the scattering plate 30 at a total of four locations, a total of four locations, and the outer surface of the reaction tube inner tube 4B. It is inserted from above into a receiving-side hinge 32 corresponding to the above, and fitted and fitted. In FIG. 3, four hinges are used. However, it is desirable to use a minimum of three hinges and design so that there is as little play as possible in consideration of manufacturing intersections.
  • the scattering plate 30 is attached to the inner tube 4B by being hooked with three or more hinges.
  • the back surface of the mounted scattering plate 30, that is, the inner surface to be mounted is installed in a state slightly lifted from the outer surface of the inner tube of the reaction tube.
  • the scattering plate 30 may absorb heat.
  • a reflection plate having a structure in which a metal film is sandwiched between quartz or the like may be used.
  • you may comprise integrally with a reaction tube.
  • a metal film or a dielectric multilayer film including TiO 2 or TaO 3
  • a quartz or other ceramic thick film may be placed thereon to protect it.
  • these plate-like structures having a scattering function are collectively referred to as a scattering plate.
  • a scattering plate that suppresses radiation from the heater is installed at a position facing the exhaust port of the inner tube of the reaction tube without using a cylindrical heat shield ring.
  • a scattering plate that suppresses radiation from the heater is installed at a position facing the exhaust port of the inner tube of the reaction tube without using a cylindrical heat shield ring.
  • a substrate holder for arranging and holding a plurality of substrates, a cylindrical inner tube having an opening through which the substrate holder can be taken in and out, a flange on the outer periphery of the lower end, which is closed at the upper end, are provided.
  • a reaction tube having a cylindrical outer tube configured to surround the inner tube, a furnace body that surrounds the upper and sides of the reaction tube, a heater that heats the inside of the furnace body, and a flange that serves as a sealing member
  • a reaction tube comprising: a mating member connected via the substrate holder; a heat insulating structure disposed between the substrate holder and the mating member; and a gas supply mechanism for supplying gas to the plurality of substrates held by the reaction tube.
  • FIG. 4 is a schematic diagram showing a configuration of a main part of the second embodiment.
  • the exhaust port diameter of the reaction tube 4 that is, the exhaust tube 15 is increased for the purpose of improving the exhaust efficiency in the reaction tube, the seal cap 19 and the exhaust tube 15 become closer, The reaction tube fixing ring 29 cannot be provided under the exhaust port. Therefore, in this embodiment, a structure in which a partial cooling block is cut into the lower portion of the exhaust pipe 15 is adopted.
  • a notch 33 is provided in the built-up portion 34 below the exhaust port of the reaction tube 4 so that there is no problem in strength.
  • the partial cooling block 36 made of a metal such as stainless steel, which extends from the cooling block 35 through which the cooling water can circulate, is configured to partially enter.
  • the installation position of the cooling block 35 corresponds to a portion where the reaction tube fixing ring 29 below the exhaust tube 15 shown in FIG.
  • the exhaust pipe 15 is provided with a built-up portion 34 in order to maintain the strength near the base of the reaction tube 4.
  • the build-up portion 34 is partially connected to the furnace port flange 4C.
  • a portion having no problem in strength that is, a notch 33 is formed obliquely below, and the partial cooling block 36 enters the notch 33. It has a shape.
  • the partial cooling block 36 it is configured to partially cover the upper portion of the O-ring 19B installed on the upper surface of the manifold 5 which is the counterpart member, so that it also has a radiation reflection effect.
  • the reaction tube 15 is provided by the partial cooling block 36 extended into the notch 33 at the lower portion of the exhaust pipe 15.
  • the temperature rise of the O-ring 19B which is a seal member in the lower portion of the exhaust port, can be efficiently suppressed.
  • An elastic member 38 shown in FIG. 3C is an elastic member made of a fluororesin sheet or a heat conductive sheet that closely contacts the partial cooling block 36 and the flange portion of the reaction tube.
  • the heat conductive sheet is obtained by dispersing a high heat conductive filler such as aluminum nitride in a resin.
  • a cooling water channel 37 that goes around inside the manifold 15 below the O-ring 19B installed on the upper surface of the manifold 5 is installed separately from the cooling block 35,
  • the O-ring 19B can also be cooled by the cooling water flowing through.
  • the partial cooling block under the exhaust port of the reaction tube, it is possible to efficiently suppress the temperature rise of the seal member in the lower portion of the exhaust port.
  • this invention is not limited to the above-mentioned Example, Various modifications are included.
  • the above-described embodiments have been described in detail for better understanding of the present invention, and are not necessarily limited to those having all the configurations described.
  • a part of the configuration of one embodiment can be replaced with the configuration of another embodiment, and the configuration of another embodiment can be added to the configuration of one embodiment.
  • the reaction tube has been described as a type in which the inner tube and the outer tube are integrated.
  • the present invention is not limited to this, and a separable type reaction tube is provided. Needless to say, the present invention can also be applied to a substrate processing apparatus.
  • deposition such as CVD, PVD, ALD, epitaxial growth, or processing for forming an oxide film or a nitride film on the surface It can be applied to diffusion treatment and etching treatment.

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Abstract

In one embodiment of the present invention, a substrate processing device is provided that can suppress a rise in the temperature of an O-ring part below an exhaust tube, even if the opening diameter of the exhaust tube 15 has been widened. Provided is a configuration comprising: a reaction tube comprising a substrate holding tool for holding a plurality of substrates, a cylindrical inner tube 4B having, at a lower side thereof, an opening wherethrough the substrate holding tool can exit and enter, and a cylindrical outer tube whereof the upper end is closed, provided with a flange in the outer periphery of the lower end, and constituted in such a manner as to surround the inner tube; a heater for heating the inner side of an oven body that surrounds the top and the side of the reaction tube; a counterpart-side member whereto the flange is connected via the O-ring 19B; and a gas supply mechanism for supplying a gas to the plurality of substrates held in the reaction tube. The reaction tube comprises an exhaust tube 15 near the flange, establishing fluid communication between the exterior of the outer tube and the space between the inner tube and the outer tube, and a scattering plate 30 provided along the outer surface of the inner tube at a position facing the exhaust tube 15. Note: selected drawing is FIG. 3.

Description

基板処理装置及び半導体装置の製造方法Substrate processing apparatus and semiconductor device manufacturing method

 本発明は、基板処理装置の炉口部構造に係り、特に炉口部の耐熱対策技術に関する。 The present invention relates to a furnace port portion structure of a substrate processing apparatus, and more particularly, to a heat resistance countermeasure technique for the furnace port portion.

 基板処理装置の一例として半導体製造装置があり、さらに半導体製造装置の一例として縦型装置があることが知られている。この種の基板処理装置として、反応管内に、ウエハ、すなわち基板を多段に保持する基板保持部材としてのボートを有し、この複数の基板を保持した状態で反応管内の処理室にて基板を処理するものがあることが知られている。縦型装置では基板保持部材によって複数の基板を垂直方向に配列して保持し、処理室内に搬入する。その後、処理室外に設置されたヒータなどの過熱装置によって基板を加熱した状態で処理室内に処理ガスを導入し、基板に対して薄膜形成処理等が行われる。 It is known that there is a semiconductor manufacturing apparatus as an example of a substrate processing apparatus, and there is a vertical apparatus as an example of a semiconductor manufacturing apparatus. As a substrate processing apparatus of this type, a reaction tube has a boat as a substrate holding member for holding wafers, that is, substrates in multiple stages, and the substrate is processed in a processing chamber in the reaction tube while holding the plurality of substrates. It is known that there is something to do. In the vertical apparatus, a plurality of substrates are vertically arranged and held by a substrate holding member and are carried into a processing chamber. Thereafter, a processing gas is introduced into the processing chamber while the substrate is heated by a superheater such as a heater installed outside the processing chamber, and a thin film forming process or the like is performed on the substrate.

 なお、特許文献1には、このような基板処理装置で、基板や基板保持部材や加熱装置からの熱の影響を低減させ、Oリング等のシール部材の焼損を防止するための不透明石英で形成された円筒形状の遮熱リングを、Oリングの斜め上方に配置する構造が提案されている。 In Patent Document 1, such a substrate processing apparatus is formed of opaque quartz for reducing the influence of heat from the substrate, the substrate holding member, and the heating device and preventing the seal member such as an O-ring from being burned out. A structure has been proposed in which the cylindrical heat shield ring is disposed obliquely above the O-ring.

特開2011-3689号公報Japanese Patent Application Laid-Open No. 2011-3687

 基板処理装置の反応管では、炉口部品と連結する際に反応管固定リングを使用しており、この反応管固定リングには、冷却水の流路が設けられ、反応管と炉口部の間に設置しているOリング部分に対する冷却機能を果たしている。しかしながら、反応管内の排気効率を向上させる目的で、反応管の排気管の口径を大きくした場合、底面のフランジと排気管が近くなり、反応管固定リングを排気管下まで設けることができない場合がある。この場合、排気管下のOリングの冷却機能が低下し、温度制限を行う必要が出てくる。特許文献1に記載のような円筒形状の遮蔽リングも排気管下まで設けることは困難である。 In the reaction tube of the substrate processing apparatus, a reaction tube fixing ring is used when connecting to a furnace port part. The reaction tube fixing ring is provided with a flow path of cooling water, and the reaction tube and the furnace port part are connected to each other. It performs the cooling function for the O-ring part installed in between. However, if the diameter of the exhaust pipe of the reaction tube is increased for the purpose of improving the exhaust efficiency in the reaction tube, the flange on the bottom surface and the exhaust pipe are close to each other, and the reaction tube fixing ring may not be provided below the exhaust pipe. is there. In this case, the cooling function of the O-ring below the exhaust pipe is lowered, and it becomes necessary to limit the temperature. It is difficult to provide a cylindrical shielding ring as described in Patent Document 1 even below the exhaust pipe.

 本発明の目的は、上記の課題を解決し、排気管の口径を広げた場合においても、排気管下のOリング部分の温度上昇を抑えることが可能な構成を提供することにある。 An object of the present invention is to solve the above-described problems and to provide a configuration capable of suppressing the temperature rise of the O-ring portion below the exhaust pipe even when the diameter of the exhaust pipe is widened.

 本発明の一態様によれば、複数の基板を配列させて保持する基板保持具と、下方に基板保持具を出し入れ可能な開口を有する筒状の内管と、上端を塞がれ下端外周にフランジが設けられ内管を囲むように構成された筒状の外管とを有する反応管と、反応管の上方及び側方を取り囲む炉体と、炉体の内側を加熱するヒータと、フランジがシール部材を介して接続する相手側部材と、基板保持具と相手側部材の間に配置される断熱構造体と、反応管内で保持された複数の基板にガスを供給するガス供給機構と、を備え、反応管は、フランジ付近において、内管と外管の間の空間と外管の外とを流体的に連通させる排気管と、内管の外面に沿って排気管に対向する位置に設けられた散乱板を有する構成が提供される。 According to one aspect of the present invention, a substrate holder for arranging and holding a plurality of substrates, a cylindrical inner tube having an opening through which a substrate holder can be taken in and out, and an upper end that is closed to the outer periphery of the lower end A reaction tube having a cylindrical outer tube provided with a flange and configured to surround the inner tube; a furnace body that surrounds the top and sides of the reaction tube; a heater that heats the inside of the furnace body; and a flange, A mating member connected via a seal member, a heat insulating structure disposed between the substrate holder and the mating member, and a gas supply mechanism for supplying gas to a plurality of substrates held in the reaction tube, The reaction tube is provided near the flange in a position facing the exhaust pipe along the outer surface of the inner pipe, and an exhaust pipe that fluidly communicates the space between the inner pipe and the outer pipe with the outside of the outer pipe. A configuration having a diffuser plate provided is provided.

 ヒータからの輻射を抑える散乱板の設置により、石英反応管と炉口部下に配置しているシール部材の排気管下部分の温度上昇を効率よく抑えることができる。 By installing a scattering plate that suppresses radiation from the heater, it is possible to efficiently suppress the temperature rise of the quartz reaction tube and the lower part of the exhaust pipe of the seal member arranged under the furnace port.

本発明が適用される縦型熱処理装置の一構成例を示す図である。It is a figure which shows one structural example of the vertical heat processing apparatus with which this invention is applied. 本発明の基板処理装置の課題を説明するための模式図である。It is a schematic diagram for demonstrating the subject of the substrate processing apparatus of this invention. 実施例1に係る、基板処理装置の要部を示す図である。It is a figure which shows the principal part of the substrate processing apparatus based on Example 1. FIG. 実施例2に係る、基板処理装置の要部を示す図である。It is a figure which shows the principal part of the substrate processing apparatus based on Example 2. FIG.

 以下本発明を実施するための形態を図面に従い順次説明するが、まず本発明が適用される基板処理装置の一例として、縦型熱処理装置の一構成とその課題を図1、図2を使って説明する。 DESCRIPTION OF THE PREFERRED EMBODIMENTS Embodiments for carrying out the present invention will be described in order with reference to the drawings. First, as an example of a substrate processing apparatus to which the present invention is applied, a configuration of a vertical heat treatment apparatus and its problems will be described with reference to FIGS. explain.

 図1に示すように、基板処理装置1は、半導体集積回路の製造における熱処理工程を実施する縦型熱処理装置として構成され、処理炉2を備えている。処理炉2は、それを均一に加熱するために、ヒータ3を有する。ヒータ3は円筒形状であり、保持板としてのヒータベースに支持されることにより、基板処理装置1の設置床に対して垂直に据え付けられている。ヒータ3は、ガスを熱で励起させる活性化機構としても機能する。 As shown in FIG. 1, the substrate processing apparatus 1 is configured as a vertical heat treatment apparatus that performs a heat treatment process in the manufacture of a semiconductor integrated circuit, and includes a processing furnace 2. The processing furnace 2 has a heater 3 in order to heat it uniformly. The heater 3 has a cylindrical shape and is installed perpendicular to the installation floor of the substrate processing apparatus 1 by being supported by a heater base as a holding plate. The heater 3 also functions as an activation mechanism that excites the gas with heat.

 ヒータ3の内側に、反応容器を構成する反応管4が配設されている。反応管4は、例えば石英(SiO2)または炭化シリコン(SiC)等の耐熱性材料からなり、上端が閉塞し下端が開口した円筒形状に形成されている。反応管4は、下端のフランジ4Cにおいて互いに結合した外管4Aと内管4Bとを有する2重管構造を有する。外管4Aと内管4Bの上端は閉じられ、内管4Bの下端は開口している。そのフランジ4Cは、外管4Aよりも大きな外径を有し、外側へ突出している。反応管4の下端寄りには、外管4A内と連通する排気ポート4Dが設けられ、反応管4全体は石英などの単一の材料で一体に形成される。なお、外管4Aと内管4Bからなる2重構造は、両者が互いに結合した一体構造のものに限らず、分離可能な構造のものであっても良い。 Inside the heater 3, a reaction tube 4 constituting a reaction vessel is disposed. The reaction tube 4 is made of a heat-resistant material such as quartz (SiO 2) or silicon carbide (SiC), and has a cylindrical shape with the upper end closed and the lower end opened. The reaction tube 4 has a double-pipe structure having an outer tube 4A and an inner tube 4B that are coupled to each other at a flange 4C at the lower end. The upper ends of the outer tube 4A and the inner tube 4B are closed, and the lower end of the inner tube 4B is open. The flange 4C has a larger outer diameter than the outer tube 4A and protrudes outward. An exhaust port 4D communicating with the inside of the outer tube 4A is provided near the lower end of the reaction tube 4, and the entire reaction tube 4 is integrally formed of a single material such as quartz. Note that the double structure including the outer tube 4A and the inner tube 4B is not limited to an integral structure in which both are coupled to each other, and may be a separable structure.

 マニホールド5は、円筒又は円錐台形状で金属製又は石英製であり、反応管4の下端を支えるように設けられる。マニホールド5の内径は、反応管4の内径、すなわち、フランジ4Cの内径よりも大きく形成されている。これにより、反応管4の下端のフランジ4Cとシールキャップ19との間に円環状の空間が形成される。この空間もしくはその周辺の部材を炉口部と総称する。 The manifold 5 has a cylindrical or truncated cone shape, is made of metal or quartz, and is provided to support the lower end of the reaction tube 4. The inner diameter of the manifold 5 is formed larger than the inner diameter of the reaction tube 4, that is, the inner diameter of the flange 4C. Thereby, an annular space is formed between the flange 4 </ b> C at the lower end of the reaction tube 4 and the seal cap 19. This space or its surrounding members are collectively referred to as the furnace opening.

 内管4Bは、排気ポート4Dよりも反応管の奥側で、その側面において内側と外側を連通させる主排気口4Eを有し、また、主排気口4Eと反対の位置において供給スリット4Fを有する。主排気口4Eは、ウエハ7が配置されている領域に対して開口する単一の縦長の開口である。供給スリット4Fは、円周方向に伸びたスリットであり、各ウエハ7に対応するように垂直方向に複数並んで設けられている。外管4Aと内管4Bの間の空間(以後、排気空間Sと呼ぶ)には、供給スリット4Fの位置に対応させて、原料ガス等の処理ガスを供給する1本以上のノズル8が設けられている。ノズル8には、処理ガスを供給するガス供給管9がマニホールド5を貫通してそれぞれ接続されている。 The inner pipe 4B has a main exhaust port 4E that communicates the inside and the outside on the side of the reaction tube at the back side of the exhaust port 4D, and a supply slit 4F at a position opposite to the main exhaust port 4E. . The main exhaust port 4E is a single vertically long opening that opens to a region where the wafer 7 is disposed. The supply slits 4 </ b> F are slits extending in the circumferential direction, and a plurality of supply slits 4 </ b> F are provided in the vertical direction so as to correspond to the respective wafers 7. In a space between the outer tube 4A and the inner tube 4B (hereinafter referred to as an exhaust space S), one or more nozzles 8 for supplying a processing gas such as a raw material gas are provided in correspondence with the position of the supply slit 4F. It has been. A gas supply pipe 9 for supplying a processing gas is connected to the nozzle 8 through the manifold 5.

 内管4Bは更に、排気ポート4Dよりも反応管4の奥側で且つ主排気口4Eよりも開口側の位置に、処理室6と排気空間Sとを連通させる複数の副排気口4Gが設けられる。また、フランジ4Cにも、処理室6と排気空間S下端とを連通させる複数の底排気口4H等が形成される。言い換えれば、排気空間Sの下端は、フランジ4Cによって底排気口4H等を除き閉塞されている。副排気口4G、底排気口4Hは、主に後述の軸パージガスを排気するように機能する。 The inner pipe 4B is further provided with a plurality of sub exhaust ports 4G that allow the processing chamber 6 and the exhaust space S to communicate with each other at a position farther behind the reaction tube 4 than the exhaust port 4D and more open than the main exhaust port 4E. It is done. The flange 4C is also formed with a plurality of bottom exhaust ports 4H and the like for communicating the processing chamber 6 and the lower end of the exhaust space S. In other words, the lower end of the exhaust space S is closed by the flange 4C except for the bottom exhaust port 4H and the like. The sub exhaust port 4G and the bottom exhaust port 4H mainly function to exhaust a shaft purge gas described later.

 ガス供給管9の流路上には、上流方向から順に、流量制御器であるマスフローコントローラ(MFC)10および開閉弁であるバルブ11が設けられている。バルブ11よりも下流側では、不活性ガスを供給するガス供給管12がガス供給管9に接続されている。ガス供給管12には、上流方向から順に、MFC13およびバルブ14が設けられている。主に、ガス供給管9、MFC10、バルブ11により、処理ガス供給系である処理ガス供給部が構成される。このように、ノズル8、ガス供給管9、12、MFC10、13、バルブ11、14等で構成されるガス供給機構を用いて、図1に示した基板処理装置は、第1の原料ガスを前記複数の基板に供給する第1工程と、パージガスを前記複数の基板に供給する第2工程と、第2の原料ガスを前記複数の基板に供給する第3工程と、パージガスを前記複数の基板に供給する第4工程と、を順次繰り返すことにより、基板処理を実行する。 A mass flow controller (MFC) 10 that is a flow rate controller and a valve 11 that is an on-off valve are provided on the flow path of the gas supply pipe 9 in order from the upstream direction. A gas supply pipe 12 that supplies an inert gas is connected to the gas supply pipe 9 on the downstream side of the valve 11. The gas supply pipe 12 is provided with an MFC 13 and a valve 14 in order from the upstream direction. A processing gas supply unit that is a processing gas supply system is mainly configured by the gas supply pipe 9, the MFC 10, and the valve 11. As described above, the substrate processing apparatus shown in FIG. 1 uses the gas supply mechanism including the nozzle 8, the gas supply pipes 9 and 12, the MFCs 10 and 13, the valves 11 and 14, and the like. A first step for supplying the plurality of substrates; a second step for supplying a purge gas to the plurality of substrates; a third step for supplying a second source gas to the plurality of substrates; and a purge gas for the plurality of substrates. The substrate processing is performed by sequentially repeating the fourth step to be supplied to the substrate.

 ノズル8は、ガス供給空間4内に、反応管4の下部から立ち上がるように設けられている。ノズル8の側面や上端には、ガスを供給する1ないし複数のノズル孔8Hが設けられている。複数のノズル孔8Hは、供給スリット4Fのそれぞれの開口に対応させて、反応管4の中心を向くように開口させることで、内管4Bを通り抜けてウエハ7に向けてガスを噴射することができる。 The nozzle 8 is provided in the gas supply space 4 so as to rise from the lower part of the reaction tube 4. One or a plurality of nozzle holes 8H for supplying gas are provided on the side surface and upper end of the nozzle 8. The plurality of nozzle holes 8H correspond to the respective openings of the supply slit 4F, and are opened so as to face the center of the reaction tube 4, so that gas can be injected toward the wafer 7 through the inner tube 4B. it can.

 排気ポート4Dには、処理室6内の雰囲気を排気する排気管15が接続されている。排気管15には、処理室6内の圧力を検出する圧力検出器としての圧力センサ16および圧力調整部としてのAPC(Auto Pressure Controller)バルブ17を介して、真空排気装置としての真空ポンプ18が接続されている。APCバルブ17は、真空ポンプ18を作動させた状態で弁を開閉することで、処理室6内の真空排気および真空排気停止を行うことができる。更に、真空ポンプ18を作動させた状態で、圧力センサ16により検出された圧力情報に基づいて弁開度を調節することで、処理室6内の圧力を調整することができるように構成される。 An exhaust pipe 15 that exhausts the atmosphere in the processing chamber 6 is connected to the exhaust port 4D. A vacuum pump 18 as a vacuum exhaust device is connected to the exhaust pipe 15 via a pressure sensor 16 as a pressure detector for detecting the pressure in the processing chamber 6 and an APC (Auto Pressure Controller) valve 17 as a pressure adjusting unit. It is connected. The APC valve 17 can perform evacuation in the processing chamber 6 and stop evacuation by opening and closing the valve while the vacuum pump 18 is operated. Further, the pressure in the processing chamber 6 can be adjusted by adjusting the valve opening degree based on the pressure information detected by the pressure sensor 16 in a state where the vacuum pump 18 is operated. .

 マニホールド5の下方には、マニホールド5の下端開口を気密に閉塞可能な炉口蓋体としてのシールキャップ19が設けられている。シールキャップ19は、例えばステンレスやニッケル基合金等の金属からなり、円盤状に形成されている。シールキャップ19の上面には、マニホールド5の下端と当接するシール部材としてのOリング19Aが設けられている。このシール部材としてOリングは、マニホールド5の上面に、フランジ4Cの下端と当接するよう設置することもできる。シールキャップ19上面には、マニホールド5の下端内周より内側の部分に対し、シールキャップ19を保護するカバープレート20が設置されている。カバープレート20は、例えば、石英、サファイヤ、またはSiC等の耐熱耐蝕性材料からなり、円盤状に形成されている。 Below the manifold 5, a seal cap 19 is provided as a furnace port lid that can airtightly close the lower end opening of the manifold 5. The seal cap 19 is made of, for example, a metal such as stainless steel or a nickel-based alloy, and is formed in a disk shape. An O-ring 19 </ b> A is provided on the upper surface of the seal cap 19 as a seal member that comes into contact with the lower end of the manifold 5. The O-ring as the seal member can be installed on the upper surface of the manifold 5 so as to contact the lower end of the flange 4C. A cover plate 20 that protects the seal cap 19 is provided on the upper surface of the seal cap 19 with respect to a portion inside the lower end inner periphery of the manifold 5. The cover plate 20 is made of a heat and corrosion resistant material such as quartz, sapphire, or SiC, and is formed in a disk shape.

 基板保持具としてのボート21は、複数枚、例えば25~200枚のウエハ7を、水平姿勢で、かつ、互いに中心を揃えた状態で垂直方向に整列させて多段に支持する。そこではウエハ7は、一定の間隔を空けて配列させる。ボート21は、例えば石英やSiC等の耐熱性材料からなる。反応管4は、ボート21を安全に搬入出可能な最小限の内径を有することが望ましい場合がある。 The boat 21 as a substrate holder supports a plurality of, for example, 25 to 200, wafers 7 in a multi-stage by aligning them vertically in a horizontal posture and with their centers aligned. In this case, the wafers 7 are arranged at regular intervals. The boat 21 is made of a heat resistant material such as quartz or SiC. It may be desirable for the reaction tube 4 to have a minimum inner diameter that allows the boat 21 to be safely carried in and out.

 ボート21の下部には断熱アセンブリ22が配設されている。断熱アセンブリ22は、上下方向の熱の伝導或いは伝達が小さくなるような構造を有し、通常、内部に空洞を有する。内部は軸パージガスによってパージされうる。反応管4において、ボート21が配置されている上部分を処理領域A、断熱アセンブリ22が配置されている下部分を断熱領域Bと呼ぶ。 A heat insulation assembly 22 is disposed at the bottom of the boat 21. The heat insulation assembly 22 has a structure that reduces heat conduction or transmission in the vertical direction, and usually has a cavity inside. The interior can be purged with a shaft purge gas. In the reaction tube 4, an upper portion where the boat 21 is disposed is referred to as a processing region A, and a lower portion where the heat insulating assembly 22 is disposed is referred to as a heat insulating region B.

 シールキャップ19の処理室6と反対側には、ボート21を回転させる回転機構23が設置されている。回転機構23には、軸パージガスのガス供給管24が接続されている。ガス供給管44cには、上流方向から順に、MFC25およびバルブ26が設けられている。 Rotating mechanism 23 for rotating boat 21 is installed on the side of seal cap 19 opposite to processing chamber 6. A gas supply pipe 24 for shaft purge gas is connected to the rotation mechanism 23. The gas supply pipe 44c is provided with an MFC 25 and a valve 26 in order from the upstream direction.

 ボートエレベータ27は、反応管4の外部下方に垂直に備えられ、シールキャップ19を昇降させる昇降、搬送機構として動作する。これにより、シールキャップ19に支えられたボート21およびウエハ7が、処理室6内外に搬入出される。なお、シールキャップ19が最下位置に降りている間、シールキャップ19の代わりに反応管4の下端開口を塞ぐシャッタが設けられうる。 The boat elevator 27 is provided vertically below the reaction tube 4 and operates as an elevating / lowering mechanism for moving the seal cap 19 up and down. Thereby, the boat 21 and the wafer 7 supported by the seal cap 19 are carried into and out of the processing chamber 6. Note that a shutter that closes the lower end opening of the reaction tube 4 may be provided instead of the seal cap 19 while the seal cap 19 is lowered to the lowest position.

 外管4Aの外壁には、温度検出器28が設置されている。温度検出器28は、上下に並んで配列された複数の熱電対によって構成されうる。温度検出器28により検出された温度情報に基づきヒータ3への通電具合を調整することで、処理室6内の温度が所望の温度分布となる。 A temperature detector 28 is installed on the outer wall of the outer tube 4A. The temperature detector 28 can be configured by a plurality of thermocouples arranged side by side. By adjusting the power supply to the heater 3 based on the temperature information detected by the temperature detector 28, the temperature in the processing chamber 6 becomes a desired temperature distribution.

 コントローラ29は、基板処理装置1全体を制御するコンピュータであり、MFC10,13、バルブ11,14、圧力センサ16、APCバルブ17、真空ポンプ18、ヒータ3、温度検出器28、回転機構23、ボートエレベータ27等と電気的に接続され、それらから信号を受け取ったり、それらを制御したりする。 The controller 29 is a computer that controls the entire substrate processing apparatus 1, and includes MFCs 10 and 13, valves 11 and 14, pressure sensor 16, APC valve 17, vacuum pump 18, heater 3, temperature detector 28, rotating mechanism 23, boat It is electrically connected to the elevator 27 and the like, and receives signals from them and controls them.

 図1では図示を省略したが、基板処理装置1において、反応管4と、その下端のフランジ4Cと炉口部の蓋体であるシールキャップ19との間の円環状の空間を構成する炉口部品とを連結するため反応管固定リングが使用される。図2の(a)、(b)にその縦断面図、横断面図として、反応管固定リング29を使用する基板処理装置1を模式的に示した。基板処理装置1において、ヒータ3を使って加熱を行うと、フランジの下端と、当節する炉口部のマニホールドの間に設置されたOリングが高温になる。そのため、反応管固定リング29の内部には図示を省略した冷却水の流路が設けられており、フランジとマニホールドの間などに設置しているOリング部分に対する冷却機能を果たしている。しかしながら、反応管内の排気効率を向上させる目的で、反応管4の排気口径、すなわち排気管15の口径を大きくした場合、図2に模式的に示すように、シールキャップ19と排気管15が近くなり、排気口の排気管15の下まで反応管固定リング29を設けることができない。この場合、排気口、すなわち排気管15の下に位置するOリングの冷却機能が低下するため、ヒータによる加熱の温度制限を行うことが必要になる。以下、この課題を解決するための本発明の各種の実施例について説明する。 Although not shown in FIG. 1, in the substrate processing apparatus 1, a furnace port that forms an annular space between the reaction tube 4, a flange 4 </ b> C at the lower end thereof, and a seal cap 19 that is a lid of the furnace port part. A reaction tube fixing ring is used to connect the parts. 2A and 2B schematically show the substrate processing apparatus 1 using the reaction tube fixing ring 29 as a longitudinal sectional view and a transverse sectional view thereof. In the substrate processing apparatus 1, when heating is performed using the heater 3, the O-ring installed between the lower end of the flange and the manifold of the furnace opening portion at this time becomes high temperature. For this reason, a cooling water flow path (not shown) is provided inside the reaction tube fixing ring 29 to perform a cooling function for the O-ring portion installed between the flange and the manifold. However, when the exhaust port diameter of the reaction tube 4, that is, the diameter of the exhaust tube 15 is increased for the purpose of improving the exhaust efficiency in the reaction tube, the seal cap 19 and the exhaust tube 15 are close as shown schematically in FIG. Thus, the reaction tube fixing ring 29 cannot be provided up to the bottom of the exhaust pipe 15 at the exhaust port. In this case, since the cooling function of the O-ring located below the exhaust port, that is, the exhaust pipe 15, is lowered, it is necessary to limit the temperature of heating by the heater. Hereinafter, various embodiments of the present invention for solving this problem will be described.

 本実施例は、複数の基板を配列させて保持する基板保持具と、下方に基板保持具を出し入れ可能な開口を有する筒状の内管と、上端を塞がれ下端外周にフランジが設けられ内管を囲むように構成された筒状の外管とを有する反応管と、反応管の上方及び側方を取り囲む炉体と、炉体の内側を加熱するヒータと、フランジがシール部材を介して接続する相手側部材と、基板保持具と相手側部材の間に配置される断熱構造体と、反応管内で保持された複数の基板にガスを供給するガス供給機構とを備え、反応管は、フランジ付近において、内管と外管の間の空間と外管の外とを流体的に連通させる排気管と、内管の外面に沿って排気管に対向する位置に設けられた散乱板を有する基板処理装置の実施例である。 In this embodiment, a substrate holder for arranging and holding a plurality of substrates, a cylindrical inner tube having an opening through which the substrate holder can be taken in and out, a flange on the outer periphery of the lower end, which is closed at the upper end, are provided. A reaction tube having a cylindrical outer tube configured to surround the inner tube, a furnace body that surrounds the top and sides of the reaction tube, a heater that heats the inside of the furnace body, and a flange through a seal member A mating member connected to each other, a heat insulating structure disposed between the substrate holder and the mating member, and a gas supply mechanism for supplying gas to a plurality of substrates held in the reaction tube. An exhaust pipe that fluidly communicates the space between the inner pipe and the outer pipe with the outside of the outer pipe in the vicinity of the flange, and a scattering plate provided at a position facing the exhaust pipe along the outer surface of the inner pipe It is an Example of the substrate processing apparatus which has.

 図3は実施例1の要部の構成を示す模式図である。本実施例の反応管の内管4Bの外面に沿って、排気管15に対向する位置にのみ設けられる散乱板30を有する基板処理装置の要部を模式的に示した。輻射(赤外線等の光線)を散乱する輻射ネットからなる散乱板30は、排気管15に略対面する位置であって、ヒータから排気管下のOリング19Bへ直接届く輻射を散乱、反射させるように、ヒータ上部からOリング19Bへ引いた直線と、ヒータ下部からOリングへ引いた直線の間の高さを覆うように設置する。なお、図3の(a)、(b)に示す通り、散乱板30は、熱輻射の到来方向を考慮した位置に設けられるが、中間排気口を塞がないように散乱板30には開口30Aを形成しておく。すなわち、内管4Bは、排気管15に対向する位置に、内管の内側と外側を流体的に連通させる副排気口(中間排気口)4Gを有しているため、新たに設置した散乱板30は、この副排気口4Gを塞がないように副排気口4Gと同形の開口30Aを有するよう構成する。 FIG. 3 is a schematic diagram showing a configuration of a main part of the first embodiment. The principal part of the substrate processing apparatus which has the scattering plate 30 provided only in the position which opposes the exhaust pipe 15 along the outer surface of the inner pipe 4B of the reaction tube of a present Example was shown typically. The scattering plate 30 made of a radiation net that scatters radiation (light rays such as infrared rays) is a position substantially facing the exhaust pipe 15 so as to scatter and reflect radiation directly reaching the O-ring 19B below the exhaust pipe. And installed so as to cover the height between the straight line drawn from the upper part of the heater to the O-ring 19B and the straight line drawn from the lower part of the heater to the O-ring. As shown in FIGS. 3 (a) and 3 (b), the scattering plate 30 is provided at a position that takes into account the direction of arrival of thermal radiation, but the scattering plate 30 has an opening so as not to block the intermediate exhaust port. 30A is formed. That is, since the inner pipe 4B has a sub exhaust port (intermediate exhaust port) 4G that fluidly communicates the inner side and the outer side of the inner pipe at a position facing the exhaust pipe 15, a newly installed scattering plate 30 is configured to have an opening 30A having the same shape as the sub exhaust port 4G so as not to block the sub exhaust port 4G.

 本実施例の散乱板30は、内部に微小な空洞、内泡であるボイドが多数形成されることで不透明化された石英を用いることが望ましい。この種の不透明石英は、火加工を行っても不透明性が保たれる。ボイドのサイズによって波長透過率が変わるため、反応炉の温度である600-1000℃に応じて適切なサイズのボイドを選ぶと良い。 For the scattering plate 30 of the present embodiment, it is desirable to use quartz that is made opaque by forming a large number of minute cavities and voids that are inner bubbles. This type of opaque quartz remains opaque even when fired. Since the wavelength transmittance varies depending on the size of the void, it is preferable to select a void having an appropriate size according to the temperature of the reactor, 600 to 1000 ° C.

 また、散乱板30は、反応管内管と面で接触すると、パーティクル発生原因となるため、接触箇所を極力少なくする必要がある。本実施例では、図3の(a)、(b)に示すように、差込側の蝶番31を散乱板30の両側端に上下2箇所の計4箇所に設け、反応管内管4Bの外面に対応させて設けた受け側の蝶番32に上方から差込み、嵌合させて装着する。図3では、4箇所の蝶番を使ったが、最低3個の蝶番を使い、製造上の交差を考慮した上でガタができるだけ少なくなるように設計することが望ましい。すなわち、散乱板30は、3つ以上の複数の蝶番で引っ掛けて内管4Bに装着される。なお、装着された散乱板30の裏面、すなわち装着される内側面は、反応管内管の外面からわずかに浮かせた状態で設置する。 In addition, if the scattering plate 30 comes into contact with the inner tube of the reaction tube on the surface, it causes generation of particles, so that the number of contact portions needs to be reduced as much as possible. In this embodiment, as shown in FIGS. 3 (a) and 3 (b), the insertion-side hinges 31 are provided at the upper and lower ends of the scattering plate 30 at a total of four locations, a total of four locations, and the outer surface of the reaction tube inner tube 4B. It is inserted from above into a receiving-side hinge 32 corresponding to the above, and fitted and fitted. In FIG. 3, four hinges are used. However, it is desirable to use a minimum of three hinges and design so that there is as little play as possible in consideration of manufacturing intersections. In other words, the scattering plate 30 is attached to the inner tube 4B by being hooked with three or more hinges. The back surface of the mounted scattering plate 30, that is, the inner surface to be mounted is installed in a state slightly lifted from the outer surface of the inner tube of the reaction tube.

 散乱板30は熱を吸収するものであっても良い。また、散乱板30に変えて、金属膜を石英等で挟み込んだ構造の反射板でも良い。また反応管と一体に構成しても良い。例えば反応管の内管4Bに直接、金属膜や誘電体多層膜(TiO2やTaO3を含む)を形成し、その上に石英その他のセラミックの厚膜をかぶせて保護する構成としても良い。本明細書においては、これら散乱機能を有する板状構成物を散乱板と総称する。 The scattering plate 30 may absorb heat. Further, instead of the scattering plate 30, a reflection plate having a structure in which a metal film is sandwiched between quartz or the like may be used. Moreover, you may comprise integrally with a reaction tube. For example, a metal film or a dielectric multilayer film (including TiO 2 or TaO 3) may be directly formed on the inner tube 4 B of the reaction tube, and a quartz or other ceramic thick film may be placed thereon to protect it. In the present specification, these plate-like structures having a scattering function are collectively referred to as a scattering plate.

 本実施例によれば、円筒形状の遮熱リングを用いることなく、反応管内管の排気口に対向する位置にヒータからの輻射を抑える散乱板を設置することにより、フランジと相手側部材の間などに設置されるシール部材の排気口下部分の温度上昇を効率よく抑えることが可能となる。 According to the present embodiment, a scattering plate that suppresses radiation from the heater is installed at a position facing the exhaust port of the inner tube of the reaction tube without using a cylindrical heat shield ring. Thus, it is possible to efficiently suppress the temperature rise in the lower portion of the exhaust port of the seal member installed.

 本実施例は、複数の基板を配列させて保持する基板保持具と、下方に基板保持具を出し入れ可能な開口を有する筒状の内管と、上端を塞がれ下端外周にフランジが設けられ、内管を囲むように構成された筒状の外管とを有する反応管と、反応管の上方及び側方を取り囲む炉体と、炉体の内側を加熱するヒータと、フランジがシール部材を介して接続する相手側部材と、基板保持具と相手側部材の間に配置される断熱構造体と、反応管で保持された複数の基板にガスを供給するガス供給機構とを備え、反応管は、フランジ付近において、内管と外管の間の空間と外管の外とを流体的に連通させる排気管と、相手側部材の上面であって、排気管下部に設けられた部分冷却ブロックとを有する基板処理装置の実施例である。 In this embodiment, a substrate holder for arranging and holding a plurality of substrates, a cylindrical inner tube having an opening through which the substrate holder can be taken in and out, a flange on the outer periphery of the lower end, which is closed at the upper end, are provided. A reaction tube having a cylindrical outer tube configured to surround the inner tube, a furnace body that surrounds the upper and sides of the reaction tube, a heater that heats the inside of the furnace body, and a flange that serves as a sealing member A reaction tube comprising: a mating member connected via the substrate holder; a heat insulating structure disposed between the substrate holder and the mating member; and a gas supply mechanism for supplying gas to the plurality of substrates held by the reaction tube. Is an exhaust pipe that fluidly communicates the space between the inner pipe and the outer pipe and the outside of the outer pipe in the vicinity of the flange, and a partial cooling block provided on the upper surface of the mating member and below the exhaust pipe Is an embodiment of a substrate processing apparatus having the following.

 図4は実施例2の要部の構成を示す模式図である。図2を用いて説明したように、反応管内の排気効率を向上させる目的で、反応管4の排気口径、すなわち排気管15の口径を大きくした場合、シールキャップ19と排気管15が近くなり、排気口下まで反応管固定リング29を設けることができない。そこで、本実施例においては、排気管15下部に部分冷却ブロックを食い込ませた構造とする。 FIG. 4 is a schematic diagram showing a configuration of a main part of the second embodiment. As described with reference to FIG. 2, when the exhaust port diameter of the reaction tube 4, that is, the exhaust tube 15 is increased for the purpose of improving the exhaust efficiency in the reaction tube, the seal cap 19 and the exhaust tube 15 become closer, The reaction tube fixing ring 29 cannot be provided under the exhaust port. Therefore, in this embodiment, a structure in which a partial cooling block is cut into the lower portion of the exhaust pipe 15 is adopted.

 すなわち、図4の(a)、(b)に示すように、反応管4の排気口下の肉盛り部34に強度的に問題ない程度の切欠き部33を設け、この切欠き部33に、冷却水が循環可能な冷却ブロック35から伸びる、ステンレス鋼などの金属で構成した部分冷却ブロック36が部分的に入り込む形状とする。冷却ブロック35の設置位置は、図2で示した排気管15の下部の反応管固定リング29が存在しない部分に対応させる。 That is, as shown in FIGS. 4 (a) and 4 (b), a notch 33 is provided in the built-up portion 34 below the exhaust port of the reaction tube 4 so that there is no problem in strength. The partial cooling block 36 made of a metal such as stainless steel, which extends from the cooling block 35 through which the cooling water can circulate, is configured to partially enter. The installation position of the cooling block 35 corresponds to a portion where the reaction tube fixing ring 29 below the exhaust tube 15 shown in FIG.

 図4の(a)、(b)に示すように、排気管15は反応管4への付け根付近における強度維持のため、肉盛り部34が設けられている。一方、排気管15はできるだけ反応管4の下方である炉口フランジ寄りに設けることが望ましいため、肉盛り部34は炉口フランジ4Cと一部繋がっている。本実施例では、この肉盛り部34の下部分において、強度的に問題が無い部分、すなわち斜め下に切欠き部33を形成し、その切欠き部33の内部に、部分冷却ブロック36が入り込む形状としている。この部分冷却ブロック36の設置により、相手側部材であるマニホールド5の上面に設置されたOリング19Bの上部を一部覆うように構成することで、輻射の反射効果も有している。 4 (a) and 4 (b), the exhaust pipe 15 is provided with a built-up portion 34 in order to maintain the strength near the base of the reaction tube 4. On the other hand, since it is desirable to provide the exhaust pipe 15 as close to the furnace port flange as possible below the reaction tube 4, the build-up portion 34 is partially connected to the furnace port flange 4C. In the present embodiment, in the lower portion of the build-up portion 34, a portion having no problem in strength, that is, a notch 33 is formed obliquely below, and the partial cooling block 36 enters the notch 33. It has a shape. By providing the partial cooling block 36, it is configured to partially cover the upper portion of the O-ring 19B installed on the upper surface of the manifold 5 which is the counterpart member, so that it also has a radiation reflection effect.

 図4の(c)、(d)に示すように、本実施例の構成にあっては、排気管15の下部の切欠き部33の内部に伸ばされた部分冷却ブロック36によって、反応管15の排気口下部分のシール部材であるOリング19Bの温度上昇を効率よく抑えることができる。同図の(c)に示す弾性部材38は、部分冷却ブロック36と反応管のフランジ部分とを密着させるふっ素樹脂シート又は熱伝導シートからなる弾性部材である。熱伝導シートは、例えば窒化アルミ等の高熱伝導性フィラーが樹脂に分散されたものである。 また、同図の(c)に示すように、マニホールド5の上面に設置されたOリング19Bの下にマニホールド15の内部で一周する冷却水路37を、冷却ブロック35とは別途に設置し、内部を流れる冷却水によってOリング19Bの冷却を行うよう構成することもできる。 As shown in FIGS. 4C and 4D, in the configuration of the present embodiment, the reaction tube 15 is provided by the partial cooling block 36 extended into the notch 33 at the lower portion of the exhaust pipe 15. The temperature rise of the O-ring 19B, which is a seal member in the lower portion of the exhaust port, can be efficiently suppressed. An elastic member 38 shown in FIG. 3C is an elastic member made of a fluororesin sheet or a heat conductive sheet that closely contacts the partial cooling block 36 and the flange portion of the reaction tube. The heat conductive sheet is obtained by dispersing a high heat conductive filler such as aluminum nitride in a resin. In addition, as shown in FIG. 5C, a cooling water channel 37 that goes around inside the manifold 15 below the O-ring 19B installed on the upper surface of the manifold 5 is installed separately from the cooling block 35, The O-ring 19B can also be cooled by the cooling water flowing through.

 本実施例によれば、反応管の排気口下に部分冷却ブロックを配置することにより、排気口下部分のシール部材の温度上昇を効率よく抑えることができる。 According to the present embodiment, by arranging the partial cooling block under the exhaust port of the reaction tube, it is possible to efficiently suppress the temperature rise of the seal member in the lower portion of the exhaust port.

 なお、本発明は上記した実施例に限定されるものではなく、様々な変形例が含まれる。例えば、上記した実施例は本発明のより良い理解のために詳細に説明したのであり、必ずしも説明の全ての構成を備えるものに限定されるものではない。また、ある実施例の構成の一部を他の実施例の構成に置き換えることが可能であり、また、ある実施例の構成に他の実施例の構成を加えることが可能である。また、各実施例の構成の一部について、他の構成の追加・削除・置換をすることが可能である。上述した本発明の実施例の説明においては、反応管の内管と外管が一体になっているタイプのもので説明したが、これに限定されず、分離可能なタイプの反応管を備えた基板処理装置などにも適用できることは言うまでもない。 In addition, this invention is not limited to the above-mentioned Example, Various modifications are included. For example, the above-described embodiments have been described in detail for better understanding of the present invention, and are not necessarily limited to those having all the configurations described. Further, a part of the configuration of one embodiment can be replaced with the configuration of another embodiment, and the configuration of another embodiment can be added to the configuration of one embodiment. Further, it is possible to add, delete, and replace other configurations for a part of the configuration of each embodiment. In the above description of the embodiments of the present invention, the reaction tube has been described as a type in which the inner tube and the outer tube are integrated. However, the present invention is not limited to this, and a separable type reaction tube is provided. Needless to say, the present invention can also be applied to a substrate processing apparatus.

 半導体基板等に対して、減圧下若しくは処理ガス雰囲気下或いは高温下で処理する装置に適用でき、例えば、CVD、PVD、ALD、エピタキシャル成長等の堆積や、表面に酸化膜、窒化膜を形成する処理、拡散処理、エッチング処理に適用できる。 It can be applied to an apparatus for processing a semiconductor substrate or the like under reduced pressure, in a processing gas atmosphere or at a high temperature. For example, deposition such as CVD, PVD, ALD, epitaxial growth, or processing for forming an oxide film or a nitride film on the surface It can be applied to diffusion treatment and etching treatment.

1 基板処理装置、    2 処理炉
3 ヒータ、       4 反応管
5 マニホールド、    6 処理室
7 ウエハ、       8 ノズル
9、12 ガス供給管、  10、13 MFC
11、14 バルブ
15 排気管、      16 圧力センサ
17 APCバルブ、   18 真空ポンプ
19 シールキャップ、  19A、19B Oリング
30 散乱板、      31、32 蝶番
33 切欠き部、     34 肉盛り部
35 冷却ブロック、   36 部分冷却ブロック
37 冷却水流路、    38 弾性部材
DESCRIPTION OF SYMBOLS 1 Substrate processing apparatus, 2 Processing furnace 3 Heater, 4 Reaction tube 5 Manifold, 6 Processing chamber 7 Wafer, 8 Nozzle 9, 12 Gas supply tube, 10, 13 MFC
11, 14 Valve 15 Exhaust pipe, 16 Pressure sensor 17 APC valve, 18 Vacuum pump 19 Seal cap, 19A, 19B O-ring 30 Scatter plate, 31, 32 Hinge 33 Notch part, 34 Overlay part 35 Cooling block, 36 part Cooling block 37 Cooling water flow path 38 Elastic member

Claims (8)

複数の基板を配列させて保持する基板保持具と、
下方に前記基板保持具を出し入れ可能な開口を有する筒状の内管と、上端を塞がれ下端外周にフランジが設けられ、前記内管を囲むように構成された筒状の外管とを有する反応管と、
前記反応管の上方及び側方を取り囲む炉体と、
前記炉体の内側を加熱するヒータと、
前記フランジがシール部材を介して接続する相手側部材と、
前記基板保持具と前記相手側部材の間に配置される断熱構造体と、
前記反応管内で前記基板保持具に保持された前記複数の基板にガスを供給するガス供給機構と、を備え、
前記反応管は、前記フランジの付近において、前記内管と前記外管の間の空間と前記外管の外とを流体的に連通させる排気管と、前記内管の外面に沿って前記排気管に対向する位置に設けられた光線散乱板とを有するように構成されている基板処理装置。
A substrate holder for arranging and holding a plurality of substrates;
A cylindrical inner tube having an opening through which the substrate holder can be taken in and out, and a cylindrical outer tube that is closed at the upper end and provided with a flange at the outer periphery of the lower end and configured to surround the inner tube A reaction tube having,
A furnace body surrounding the top and sides of the reaction tube;
A heater for heating the inside of the furnace body;
A mating member to which the flange is connected via a seal member;
A heat insulating structure disposed between the substrate holder and the mating member;
A gas supply mechanism for supplying gas to the plurality of substrates held by the substrate holder in the reaction tube,
In the vicinity of the flange, the reaction tube includes an exhaust pipe that fluidly communicates a space between the inner pipe and the outer pipe and the outside of the outer pipe, and the exhaust pipe along an outer surface of the inner pipe. The substrate processing apparatus comprised so that it might have a light-scattering plate provided in the position which opposes.
請求項1に記載の基板処理装置であって、
前記光線散乱板が、前記内管の外面上に浮かせて設置されるように構成されている基板処理装置。
The substrate processing apparatus according to claim 1,
A substrate processing apparatus, wherein the light scattering plate is configured to float on an outer surface of the inner tube.
請求項1に記載の基板処理装置であって、
前記内管は、前記排気管に対向する位置に、前記内管の内側と外側を流体的に連通させる中間排気口を有し、
前記光線散乱板は、前記中間排気口と同形の開口を有するように構成されている基板処理装置。
The substrate processing apparatus according to claim 1,
The inner pipe has an intermediate exhaust port for fluidly communicating the inner side and the outer side of the inner pipe at a position facing the exhaust pipe,
The substrate processing apparatus, wherein the light scattering plate is configured to have an opening having the same shape as the intermediate exhaust port.
請求項1に記載の基板処理装置であって、
前記光線散乱板は、内部に形成された複数のボイドによって不透明化されるように構成される基板処理装置。
The substrate processing apparatus according to claim 1,
The substrate processing apparatus, wherein the light scattering plate is made opaque by a plurality of voids formed therein.
請求項2に記載の基板処理装置であって、
前記光線散乱板は、前記光線散乱板が有する3つ以上の複数の蝶番が、前記複数の蝶番とそれぞれ対を成すように前記内管に形成された複数の蝶番に嵌合することで、前記内管に装着される基板処理装置。
The substrate processing apparatus according to claim 2,
The light scattering plate is fitted with a plurality of hinges formed on the inner tube such that three or more hinges of the light scattering plate are paired with the hinges, respectively. A substrate processing apparatus mounted on the inner tube.
請求項1に記載の基板処理装置であって、
前記反応管は、前記相手側部材の上面であって、前記排気管の下部に設けられた部分冷却ブロックを有する基板処理装置。
The substrate processing apparatus according to claim 1,
The substrate processing apparatus, wherein the reaction tube has a partial cooling block provided on the upper surface of the counterpart member and below the exhaust pipe.
請求項6に記載の基板処理装置であって、
前記部分冷却ブロックは、前記フランジと前記排気管の間に食い込む部分冷却部を有し、部分冷却部の少なくとも一部は、シール部材の上に重なるように構成される基板処理装置。
The substrate processing apparatus according to claim 6,
The partial cooling block includes a partial cooling unit that bites between the flange and the exhaust pipe, and at least a part of the partial cooling unit is configured to overlap the seal member.
 複数の基板を配列させて保持する基板保持具と、下方に前記基板保持具を出し入れ可能な開口を有する筒状の内管と、上端を塞がれ下端外周にフランジが設けられ、前記内管を囲むように構成された筒状の外管と、前記フランジの付近において、前記内管と前記外管の間の空間と前記外管の外とを流体的に連通させる排気管と、前記内管の外面に沿って前記排気管に対向する位置に設けられた散乱板とを有する反応管内に、前記反応管の前記反応管の上方及び側方を取り囲む炉体の内側をヒータで加熱しつつ、前記基板を処理する半導体装置の製造方法。 A substrate holder for arranging and holding a plurality of substrates, a cylindrical inner tube having an opening through which the substrate holder can be taken in and out, a top end closed and a flange provided at the outer periphery of the lower end, and the inner tube A cylindrical outer pipe configured to surround the exhaust pipe, an exhaust pipe that fluidly communicates a space between the inner pipe and the outer pipe and the outside of the outer pipe in the vicinity of the flange; In a reaction tube having a scattering plate provided at a position facing the exhaust pipe along the outer surface of the tube, while heating the inside of the furnace body surrounding the upper side and the side of the reaction tube with a heater A method of manufacturing a semiconductor device for processing the substrate.
PCT/JP2018/012337 2018-03-27 2018-03-27 Substrate processing device and semiconductor device production method Ceased WO2019186681A1 (en)

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