WO2019035595A1 - Infrared transmitting ink composition for ink jet, method for forming bezel pattern by using same, bezel pattern formed thereby, and display substrate comprising same - Google Patents

Abstract

Disclosed are an infrared transmitting ink composition for an ink jet, a method for forming a bezel pattern by using the same, a bezel pattern formed thereby, and a display substrate comprising the same, wherein the infrared transmitting ink composition enables the check of align markers through an infrared camera and the detection of pressure marks through non-destructive inspection even after the bezel pattern is printed on the display substrate, has excellent storage stability, curing sensitivity, and adhesion with a basic material, and can improve an ink jet process performance. The infrared transmitting ink composition for an ink jet comprises: a lactam black pigment, a perylene black pigment, or a combination thereof; a dispersant; an epoxy compound; an oxetane compound; a photo-polymerization initiator; and an organic solvent.

Description

An infrared ray transmitting ink composition for ink jet, a method of forming a bezel pattern using the same, a bezel pattern manufactured thereby, and a display substrate

This application claims the benefit of priority based on Korean Patent Application No. 10-2017-0104616, dated August 18, 2017, and Korean Patent Application No. 10-2018-0084684, dated July 20, 2018, The entire contents of which are incorporated herein by reference.

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an infrared ray transmitting ink composition for ink jet, a method of forming a bezel pattern using the same, a bezel pattern and a display substrate including the same, and more particularly, It is possible to detect the mark mark by the camera and to detect the indentation mark by the non-destructive inspection, and it has excellent storage stability, excellent curing sensitivity, excellent adhesion with the substrate, and improved ink jet process performance A method of forming a bezel pattern using the same, a bezel pattern manufactured thereby, and a display substrate including the same.

Display devices, such as TVs and smart phones, such as mobile devices, have been developed differently from the originality and convenience. In addition to this growth, there are also a number of demands and problems to be solved for improved convenience , And studies for solving this are continuing. As a means for improving the user's screen immersion level, a narrow bezel that reduces unnecessary edges is applied to secure a more extended screen. As a result, the case of the display panel becomes unnecessary, Research has been continued to obscure the outside of the display display area and to further reduce the difference in viewing between the display area and the non-display area. In addition, development of an ink which is improved in storage stability, excellent in curing sensitivity, capable of exhibiting excellent adhesion to a substrate, and capable of improving inkjet process performance is also desired.

[Prior Art Literature]

[Patent Literature]

(Patent Document 1) Korean Patent Laid-open Publication No. 10-2013-0016460

As described above, for application of a narrow bezel for securing a more extended screen of a display device, it is necessary not only to cover the electrodes outside the display display area, but also to reduce the difference in viewing between the display area and the non- In addition, studies have been made for the development of inks which can improve storage stability, have excellent curing sensitivity, exhibit excellent adhesion with a substrate, and can improve the performance of an inkjet process.

As a part of this research, various ink compositions have been developed. However, in the case of a black ink containing carbon black, an align marker for a post-process must be emptied and printed, In order to detect the indentation (Mark), there is a problem that the sample must be destroyed and then inspected. In addition, most of the ink has a disadvantage that the ink can be adhered to the substrate only after the heat treatment process is performed have.

SUMMARY OF THE INVENTION It is therefore an object of the present invention to provide an apparatus and a method for confirming an align marker using an infrared camera even after printing a bezel pattern on a display substrate and detecting a pressure mark by a nondestructive inspection after ACF bonding A method of forming a bezel pattern using the same, a bezel pattern manufactured thereby, and a display substrate including the same.

Another object of the present invention is to provide an infrared ray transmitting ink composition for an ink jet, which is improved in storage stability, excellent in curing sensitivity, excellent in adhesion with a base material and capable of improving the performance of an inkjet process, And a display substrate including the bezel pattern.

In order to accomplish the above object, the present invention provides a pigment dispersion comprising a lactam black pigment or a perylene black pigment or a combination thereof; Dispersing agent; Epoxy compounds; Oxetane compounds; A photopolymerization initiator; And an organic solvent.

Further, the present invention provides a method of manufacturing an inkjet inkjet ink composition, comprising the steps of: a) forming a bezel pattern by inkjet printing the inkjet infrared ray transmitting ink composition on a substrate; And b) irradiating the bezel pattern with radiation to cure the bezel pattern. The present invention also provides a method of forming a bezel pattern using the ink composition.

The present invention also provides a bezel pattern manufactured according to the method of forming the bezel pattern.

Further, the present invention provides a display substrate including the bezel pattern.

INDUSTRIAL APPLICABILITY By using the infrared ray transmitting ink composition for ink jet according to the present invention, the method of forming a bezel pattern using the same, the bezel pattern thus formed and the display substrate including the same, It is possible to identify an align marker, and it is also possible to detect a pressure mark by nondestructive inspection after ACF bonding. In addition, the infrared ray transmitting ink composition for ink jet according to the present invention has excellent storage stability, excellent curing sensitivity, excellent adhesion to a substrate, and improved ink jet process performance.

Hereinafter, the present invention will be described in detail.

The present invention is capable of various modifications and various embodiments and is intended to illustrate certain embodiments. It should be understood, however, that the present invention is not intended to be limited to any particular embodiment, but is intended to cover all modifications, equivalents, and alternatives falling within the spirit and scope of the present invention. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.

The infrared ray transmitting ink composition for ink jet according to the present invention comprises a Lactam Black pigment or a Perylene Black pigment or a combination thereof, a dispersant, an epoxy compound, an oxetane compound, a photopolymerization initiator and an organic solvent.

The lactam black pigment or perylene black pigment is an infrared ray transmitting pigment and is a coloring agent for determining the infrared transmittance of a coating layer formed by curing the ink composition according to the present invention. When the above-mentioned lactam black pigment or perylene black pigment or a combination thereof is used in contrast to a pigment such as carbon black or aniline black which can not be used because the transmittance is very low due to blocking (light shielding) of light of all wavelengths, Even when the bezel pattern is printed on the display substrate, the non-destructive infrared ray detector such as an infrared camera can be used to detect the alignment mark and the pressure mark of the substrate appearing under the bezel pattern. Detection is possible.

Examples of the perylene black pigment include, but are not limited to, Paliogen Black L 0086 (BASF, Germany) and Paliogen Black S 0084 (BASF, Germany).

The content of the infrared ray transmitting pigment is 5 to 15% by weight, preferably 10 to 12% by weight, more preferably about 12% by weight based on the total ink composition, and the content of the infrared ray transmitting pigment is 5 When the content is less than 15% by weight, the viscosity of the ink becomes excessively high, or the infrared transmittance is low, so that the sensitivity of the infrared sensor The function may be degraded.

The dispersant is used to make the infrared transmitting pigment into particles of uniform size and also to shorten the production time of the ink. The dispersing agent may be a polymeric, nonionic, anionic or cationic dispersing agent. Examples of the dispersing agent include acrylic type, polyalkylene glycol and its esters, polyoxyalkylene polyhydric alcohol, ester alkylene oxide adduct, alcohol Alkylene oxide adducts, sulfonic acid esters, sulfonate salts, carboxylic acid esters, carboxylic acid salts, alkylamide alkylene oxide adducts and alkyl amines, which may be used alone or in combination of two or more thereof , Storage stability of ink, and the like are preferably used.

The content of the dispersing agent is 0.5 to 5% by weight, preferably 1 to 3% by weight, more preferably about 2% by weight based on the total ink composition. When the content of the dispersing agent is less than 0.5% , There is a fear that the pigment is not evenly dispersed. When the content exceeds 5% by weight, the pigment may aggregate and the curing sensitivity may be lowered.

The epoxy compound is cationic polymerization type and may be a mixture of one or two selected from alicyclic epoxy compounds containing a cationic polymerizable alicyclic epoxy monomer. Such an alicyclic epoxy compound may contain one or two epoxidized aliphatic cyclic groups, wherein the epoxidized aliphatic cyclic group may be, for example, a compound having an epoxy group formed in an alicyclic ring, The hydrogen atom of the formula ring may be substituted by a substituent such as an alkyl group.

Examples of the alicyclic epoxy compound, that is, the epoxy compound include dicyclopentadiene dioxide, limonene dioxide, (3,4-epoxycyclohexyl) methyl-3,4-epoxycyclohexanecarboxylate, 3- Vinyl cyclohexene oxide, bis (2,3-epoxycyclopentyl) ether, bis (3,4-epoxycyclohexylmethyl) adipate, bis (3,4-epoxy-6-methylcyclohexylmethyl) adipate, (3,4-epoxycyclohexyl) methyl-3,4-epoxy-6-methylcyclohexanecarboxylate, ethylene glycol bis (3,4-epoxy Cyclohexyl) ether, 3,4-epoxycyclohexene carboxylic acid ethylene glycol diester and (3,4-epoxycyclohexyl) ethyltrimethoxysilane, but are not limited thereto.

The content of the epoxy compound is 5 to 25% by weight, preferably 7 to 15% by weight, more preferably about 10% by weight based on the total ink composition, and the content of the epoxy compound is 5% By weight, the curing sensitivity is deteriorated. If it exceeds 25% by weight, the viscosity of the ink may increase and the performance of the ink-jet process may be deteriorated.

The oxetane compound is a compound having a quaternary cyclic ether group in the molecular structure and is used for lowering the viscosity of the cationic polymerizable ink composition. Examples thereof include 3-ethyl-3-hydroxymethyloxetane, 1,4- (3-ethyl-3-oxetanyl) methyl] ether, bis [(3-ethyl-3-oxetanyl) methoxymethyl] 3-ethyl-3-cyclohexyloxymethyloxetane, phenol novolak oxetane and the like, and trade names such as 3-ethyl-3- (2-ethylhexyloxymethyl) oxetane, 3- Examples thereof include OXT-101, Aronoxetan OXT-121, Aronoxetan OXT-211, Aronoxetan OXT-221 and Aronoxetan OXT-212. Two or more of them may be used in combination.

The content of the oxetane compound is 25 to 50% by weight, preferably 30 to 45% by weight, and more preferably 34 to 40% by weight with respect to the total ink composition, When the amount is less than 25% by weight, the viscosity may increase and the inkjet processability may be deteriorated. When the amount is more than 50% by weight, the curing sensitivity may be lowered.

The organic solvent may be used without particular limitation as long as it has excellent curing sensitivity even after printing the bezel pattern on the display substrate using the ink composition according to the present invention. However, in order to improve the performance of the inkjet process, , And has a viscosity of 1 to 5 cP, preferably 3 cP or less at 25 캜.

That is, when the infrared transmitting pigment is contained in the total ink composition at a low content of less than 10% (especially 7% or less), even if an organic solvent such as ethylene glycol monobutyl ether acetate (BCSA) having a boiling point of less than 200 ° C is used There is no serious problem in the performance of the inkjet process, but if the ink composition contains the above-mentioned infrared ray-transmitting pigment in a relatively high content of 10% or more, the inkjet process performance is degraded.

Therefore, in the present invention, the use of an organic solvent capable of improving or improving the performance of the inkjet process is required. The inkjet process performance is determined by the conditions of high boiling point and low viscosity (boiling point is 200 ° C or higher, The viscosity is 1 to 5 cP, especially 3 cP or less). Therefore, an organic solvent satisfying such conditions, for example, butyl diglyme or diethylene glycol di Butyl ether), dipropylene glycol methyl ether acetate, ethylene glycol dibutyrate, diethyl succinate, gamma-butyrolactone (GBL) and ethyl caprolactone An organic solvent such as ethyl caprate should be used, and it is most preferable to use butyl diglyme and diethyl succinic acid.

The content of the organic solvent is 10 to 40% by weight, preferably 20 to 35% by weight, more preferably 25 to 35% by weight based on the total ink composition. When the content of the organic solvent is less than 10% by weight, Or the thickness of the bezel layer may become thick. When it exceeds 40% by weight, the curing sensitivity may be lowered.

The photopolymerization initiator is a cationic polymerizable initiator. Specifically, the photopolymerization initiator includes at least one of a compound capable of forming a cationic species or a Bronsted acid by irradiation with ultraviolet rays, for example, an iodonium salt and a sulfonium salt . The iodonium salt or sulfonium salt causes a curing reaction in which monomers having an unsaturated double bond contained in the ink react with each other to form a polymer in an ultraviolet curing process. For example, the photopolymerization initiator may be an anion represented by SbF ₆ -, AsF ₆ -, BF ₆ -, (C ₆ F ₅ ) ₄ B-, PF ₆ - or RfnF ₆ -n, Irgacure 250, Irgacure 270, Irgacure 290, CPI-100P, CPI-101A, CPI-210S, Omnicat 440, Omnicat 550 and Omnicat 650. These photopolymerization initiators may be used alone or in combination of two or more. Two or more of them may be used in combination. In particular, in one aspect of the present invention, in order to improve the storage stability of the ink jet infrared transmitting ink composition, the photopolymerization initiator may be a sulfonium salt, more preferably Omnicat 550. [

The content of the photopolymerization initiator is 1 to 10% by weight, preferably 2 to 7% by weight, more preferably 3 to 5% by weight based on the total ink composition. When the content of the photopolymerization initiator is less than 1% The reaction may be insufficient, and if it exceeds 10% by weight, it may not be dissolved completely or the viscosity may be increased and the inkjet processability may be deteriorated.

On the other hand, the ink composition according to the present invention may further include at least one of a reactive diluent, an adhesion promoting agent, and a surfactant, if necessary.

The reactive diluent may be included to improve the ink jet processability by lowering the viscosity of the ink. A glycidyl ether-based epoxy compound capable of cationic polymerization may be used. Examples of the glycidyl ether-based epoxy compound include N-butyl N-butyl glycidyl ether, and neopentyl glycol diglycidyl ether (LD203). One or more of them may be used.

The content of the reactive diluent is preferably 0 to 30% by weight, more preferably 0.1 to 20% by weight based on the total weight of the ultraviolet curable ink composition. If it is more than 30% by weight, the curing sensitivity is lowered.

The adhesion-promoting agent may improve adhesion of the substrate and the print layer, and may include at least one selected from the group consisting of an alkoxysilane compound and a phosphate-based acrylate such as phosphate acrylate, Examples of the silane compound include 3-glycidoxypropyl trimethoxysilane, KBM-403 (Shin-Etsu Co., USA), 3-glycidoxypropyl methyldimethoxysilane KBM-402), 2- (3,4 epoxycyclohexyl) ethyltrimethoxysilane, KBM-303, 3-glycidoxypropylmethyldiethoxysilane (3- Glycidoxypropyl methyldiethoxysilane, KBE-402), 3-glycidoxypropyl triethoxysilane (KBE-403), and 3-methacryloxypropyl trimethoxysilane ane, KBM-503), and one or more of them can be used.

When the adhesion promoting agent is used, the content thereof is 1 to 5% by weight, preferably 2 to 4% by weight based on the total ink composition. When the content of the adhesion promoting agent is less than 1% by weight, If it is more than 5% by weight, it may become difficult to rework the printed layer in the substrate.

The surface active agent controls the surface tension of the ink to smoothly jetting the ink, and also allows the ink to properly spread on the substrate. The surfactant is commercially available from Dai Nippon Ink & Chemicals, Megafack F-444, F-475 , Surflon S-111, S-112 of F-478, F-479, F-484, F-550, F-552, F-553, F- , Fluorad FC-93, FC-95, FC-98, FC-129 and FC-135 of Sumitomo 3M, S-113, S-121, S-131, S- 310, BYK-320, BYK-320, BYK-330, BYK-300, FSN, FSN-100 and FSO from DuPont, 361, BYK-381, BYK-370, BYK-371, BYK-331, BYK-333, BYK-342, BYK-350, BYK-354, BYK-355, BYK- BYK-388, BYK-392, BYK-394, BYK-399, BYK-3440, BYK-3441, BYK-UV3500, BYK-UV3530, BYK-UV3570, BYKETOL-AQ, BYK-DYNWET 800, BYK -SILCLEAN 3700 and BYK-UV 3570, or Rad 2100, Rad 2011, Glide 100, Glide 410, Glide 450 from Tego Corporation , Flow 370 and Flow 425, and the like, and those selected from the group consisting of these may be used singly or in combination of two or more.

When the surfactant is included in the ink composition, the content thereof is 0.1 to 5% by weight, preferably 0.5 to 3% by weight based on the total ink composition. When the content of the surfactant is less than 0.1% by weight, The effect of lowering the tensile force is insufficient and coating failure phenomenon occurs when the composition is coated on the substrate. When the amount of the surfactant is more than 5% by weight, the surfactant is used in an excess amount and the compatibility and defoaming property of the composition is rather reduced Problems may arise.

On the other hand, the inkjet infrared transmitting ink composition according to the present invention (or the ink) has a curing dose of 20 to 5,000 mJ / cm ² , preferably 100 to 3,000 mJ / cm ² and a wavelength of 250 to 410 nm, Is cured by absorbing radiation in the wavelength range of 360 to 410 nm and has a viscosity of 1 to 30 cP at 25 ° C, preferably 2 to 20 cP at 25 ° C, preferably 2 to 20 cP, suitable for ink jet processes, The adhesion force with the substrate in the state that the heat treatment is excluded is cross cut test 4B or more.

Further, the inkjet infrared ray transmitting ink composition according to the present invention (or the ink) has a viscosity of not less than 20 days, preferably not less than 40 days, more preferably not less than 60 days, Time, and achieves excellent ink stability without precipitation of the photoinitiating polymer after ink production.

As described above, the infrared ray transmitting ink composition for ink jet according to the present invention is capable of curing in a long wavelength ultraviolet ray, and has a light transmittance similar to that of a conventional carbon black pigment, but has a transmittance of 80% at an infrared wavelength of 850 to 940 nm, Even after the bezel pattern is printed on the display substrate by using a high lactam black pigment or a perylene black pigment or a combination thereof, it is possible to confirm an align marker using an infrared camera, Can be detected.

It is possible to detect an align marker and a pressure mark by a nondestructive inspection using an infrared camera. On the other hand, in order to improve the light shielding property by using a lactam black pigment or a perylene black pigment or a combination thereof, the inkjet process performance may be deteriorated by setting the content of the pigment to 10% by weight or more based on the total ink composition, In order to prevent this, the present invention improves the performance of an inkjet process by using an organic solvent satisfying a specific condition. In addition, the use of the infrared ray transmitting ink composition for ink jet according to the present invention has excellent curing sensitivity of the ink of 2,000 mJ / cm ² @ 1.8 占 퐉, and even when the post-process (heat treatment) Is excellent. Finally, there is an advantage in that the reworkability of reusing the defective display panel by removing the printed bezel pattern is excellent, while the adhesion to the substrate is excellent.

Next, a method of forming a bezel pattern using the inkjet infrared transmitting ink composition according to the present invention will be described. The method for forming a bezel pattern using the inkjet infrared ray transmitting ink composition includes the steps of: a) forming a bezel pattern by inkjet printing the inkjet infrared ray transmitting ink composition on a substrate; and b) irradiating the bezel pattern with radiation to cure . Here, the thickness of the cured bezel pattern may be 1 to 3 占 퐉, and a detailed description thereof is based on the method described in the ink composition item and the method of forming the bezel pattern using a conventional cationic polymerization ink composition.

Meanwhile, the present invention provides a bezel pattern manufactured using the inkjet infrared ray transmitting ink composition, or a bezel pattern manufactured according to the method of forming the bezel pattern.

The present invention also provides a display substrate including the bezel pattern. Here, the display may be a plasma display panel (PDP), a light emitting diode (LED), an organic light emitting diode (OLED), a liquid crystal display A liquid crystal display (LCD), a liquid crystal display (LCD), and a cathode ray tube (CRT).

It will be apparent to those skilled in the art that various modifications and variations can be made in the present invention without departing from the spirit or scope of the invention as set forth in the appended claims. Such changes and modifications are intended to be within the scope of the appended claims.

Example

[Example 1] Preparation of infrared ray transmitting ink composition for ink jet

12% by weight of lactam black (trade name: S0100CF, BASF, Germany) as a pigment, 2% by weight of an acrylic dispersant as a dispersing agent, 10% by weight of an epoxy compound as an epoxy compound, (OXT-221, TOAGOSEI, Japan) as an oxetane compound and 5 wt% of N-butyl glycidyl ether (hubei) as a diluent (DAICEL Co., 25% by weight butyl diglyme and 6% by weight gamma butyrolactone (GBL) as an organic solvent, 3% by weight of KBM-403 as an adhesion promoter (Shin-Etsu Silicone Co., ) And 3% by weight of Omnicat 550 (IHT, China) as a photopolymerization initiator were mixed and stirred for 5 hours to prepare an inkjet infrared transmitting ink composition.

[Example 2] Preparation of infrared ray transmitting ink composition for ink jet

An infrared ray transmitting ink composition for ink jet printing was prepared by the same composition and method as in Example 1 except that diethyl succinate was used instead of butyl diglyme as a solvent as shown in the following Table 1 .

[Example 3] Preparation of infrared ray transmitting ink composition for ink jet

As shown in the following Table 1, the content of OXT-221 used as an oxetane compound was changed to 39 wt% instead of 34 wt%, the content of butyl diglyme used as a solvent was changed to 20 wt% instead of 25 wt% , An infrared ray transmitting ink composition for ink jet printing was prepared by the same composition and method as in Example 1.

[Example 4] Preparation of infrared ray transmitting ink composition for ink jet

The content of lactam black used as a pigment was changed to 10 wt% instead of 12 wt% and the content of OXT-221 used as an oxetane compound was changed to 36 wt% instead of 34 wt%, as shown in the following Table 1 , An infrared ray transmitting ink composition for an ink jet was prepared by the same composition and method as in Example 1.

[Example 5] Preparation of infrared ray transmitting ink composition for ink jet

The composition shown in the following Table 1 was prepared in the same manner as in Example 1, except that 12 weight% of perylene black (trade name: Paliogen Black L 0086, BASF, Germany) was used, .

* Celloxide 2021p: (3 ', 4'-epoxycyclohexane) Methyl 3,4-epoxycyclohexyl carboxylate

* OXT-221: bis [1-ethyl (3-oxetanyl)] methyl ether

* N-BUTYL GLYCIDYL ETHER: N-butyl glycidyl ether

KBM-403: 3-glycidoxypropyltrimethoxysilane

* Omnicat 550: 10- [1,1'-biphenyl] -4-yl-2- (1-methylethyl) -9-oxo-9H-thioxanetetanium hexafluorophosphate

[Comparative Example 1] Preparation of ink composition

(OXT-221) and OXT-212 (TOAGOSEI, Japan) as an oxetane compound and 10 wt% of 1,4-cyclohexanedimethanol di (Butyl diglyme) as an organic solvent, 4 wt% of Irgacure 250 (Basf, Germany) as a photopolymerization initiator, and 1 wt% of a photoinitiator as a photosensitizer, Of ITX (IHT, China) was used instead of ITX (IHT, China).

[Comparative Example 2] Preparation of ink composition

An ink composition was prepared by the same composition and method as in Example 2, except that ethylene glycol monobutyl ether acetate (BCSA) was used instead of diethyl succinic acid as an organic solvent as shown in the following Table 2.

[Comparative Example 3] Preparation of ink composition

(Butyl diglyme) as an organic solvent, 3 wt% of CPI-210S (SAN-APRO, Japan) as a photopolymerization initiator, 1 wt% of An ink composition was prepared by the same composition and method as in Example 3 except that DBA (KAWASAKI KASEI, Japan) was used.

[Comparative Example 4] Preparation of ink composition

As shown in Table 2 below, 25% by weight of butyl diglyme was used as an organic solvent, 29% by weight of OXT-221 was used as an oxetane compound, 10% by weight of 1,4-cyclohexane di An ink composition was prepared by the same composition and method as in Example 1 except that methanol divinyl ether, 3 wt% of CPI-210S as a photopolymerization initiator, and 1 wt% of DBA as a photosensitizer were used.

[Comparative Example 5] Preparation of ink composition

An ink composition was prepared by the same composition and method as in Comparative Example 4, except that UV-692S (Tetrachem, China) was used instead of CPI-210S as a photopolymerization initiator as shown in the following Table 2.

[Comparative Example 6] Preparation of ink composition

An ink composition was prepared by the same composition and method as in Comparative Example 4 except that Irgacure 290 (BASF, Germany) was used instead of CPI-210S as a photopolymerization initiator as shown in the following Table 2.

[Examples 1 to 5 and Comparative Examples 1 to 6] Evaluation of physical properties of a specimen made of an ink composition

The ink composition prepared in Examples 1 to 5 and Comparative Examples 1 to 6 was applied to a square glass having a size of 50 mm in width, 50 mm in length and 0.5 m in thickness using X-rite 341C After the sample was prepared by inkjet printing at an optical density (OD) of 0.9, the thickness of the sample, curing sensitivity, storage stability, ink stability, inkjet process idle time, ) Performance and infrared transmittance (@ 850 nm) were evaluated, and the results are shown in Tables 3 and 4 below.

The curing sensitivity was evaluated by measuring the UV energy at a tack free point using a UV LED lamp having a wavelength of 395 nm. The storage stability of the ink was measured by storing the ink in an oven at 35 ° C. and measuring the viscosity at 10 The ink stability was evaluated by whether or not the photopolymerization initiator was precipitated after ink production. The ink jet process performance was evaluated by measuring the short purse (3s) and the idle time after wiping in the state where all the nozzles were ejected, (ASTM D3002, D3359). The rework performance was evaluated by the Abrasion & rubbing tester with wiper (CF-909 ), And then acetone was supplied to it to check whether the bezel layer was removed within 20 round trips (feed rate: 30 reciprocations / min). The infrared transmittance was measured with a UV-VIS spectrometer and the transmittance at 850 nm is shown in Tables 3 and 4 (the transmittance of the glass itself without printing the ink composition is taken as 100%). Further, in the evaluation of ink stability and reworkability in the following Tables 3 and 4, it means that the display is excellent and the X display is not excellent.

Example 1 Example 2 Example 3 Example 4 Example 5 Optical Density 0.9 0.9 0.9 0.9 0.9 Thickness (탆) 1.9 1.9 2.2 2.3 1.9 Curing sensitivity (UV energy, mJ / cm2) 1500 1500 1500 1500 1500 Storage stability (Storage point at 35 ℃, 10% or more) 60 60 60 60 60 Ink stability ○ ○ ○ ○ ○ Inkjet process performance (idle time) 20 minutes 20 minutes 20 minutes 20 minutes 20 minutes Lower adhesion 5B 5B 5B 5B 5B Rework performance ○ ○ ○ ○ ○ Transmittance (@ 850 mm) 80% 80% 80% 80% 80%

Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Comparative Example 6 Optical Density 0.9 0.9 0.9 0.9 0.9 0.9 Thickness (탆) 1.9 1.9 1.9 1.9 1.9 1.9 Curing sensitivity (UV energy, mJ / cm2) 1000 1500 5000 4000 4000 5000 Storage stability (Storage point at 35 ℃, 10% or more) 10 60 60 60 50 50 Ink stability ○ ○ ○ ○ ○ ○ Inkjet process performance (idle time) 20 minutes 3 minutes 20 minutes 20 minutes 20 minutes 20 minutes Lower adhesion 5B 5B 5B 5B 5B 5B Rework performance ○ ○ ○ ○ ○ ○ Transmittance (@ 850 mm) 80% 80% 80% 80% 80% 80%

[Experimental Example 1] Evaluation of thickness

Unlike Examples 1 and 2, in which the content of the lactam black pigment was 12% by weight, in Example 4 in which the content of the lactam black pigment was lowered to 10% by weight, the thickness of the sample (i.e., bezel) , Which is 3 mu m or less and is suitable for the present invention. Other physical properties were the same as in Examples 1 and 2, confirming that there was no problem in reliability. Unlike Examples 1 and 2 in which the content of the organic solvent was 25 wt%, in Example 3 where the content of the organic solvent was lowered to 20 wt%, the thickness of the sample (i.e., the bezel) , Which is 3 mu m or less and is suitable for the present invention. Other physical properties were the same as in Examples 1 and 2, confirming that there was no problem in reliability.

[Experimental Example 2] Evaluation of inkjet process performance and curing sensitivity

In Examples 1 to 5 using butyl diglyme or diethyl succinate as an organic solvent, the idle time was 20 minutes and the inkjet process performance was excellent. However, ethylene glycol monobutyl ether acetate ( BCSA) was used as an organic solvent, it was confirmed that the performance of the ink jet process was insufficient because the dwell time was 5 minutes or less.

Further, Examples 1 to 5 using Omnicat 550 as a photopolymerization initiator exhibited excellent curing sensitivity without using a photosensitizer, whereas Comparative Examples 3 to 6 using CPI-210S, UV-692S or Irgacure 290 instead of Omnicat 550 6 had poor curing sensitivity despite the use of a photosensitizer (1 wt% DBA).

[Experimental Example 3] Evaluation of storage stability

In the case of Examples 1 to 5 using Ominicat 550 as a photopolymerization initiator, excellent storage stability was observed at 60% in the case of 10% or more of storage at 35 ° C in an oven, whereas Irgacure 250, CPI- Comparative Examples 1 and 3 to 6 using 692S or Irgacure 290 showed poor storage stability.

[Experimental Example 4] Evaluation of ink stability

The ink compositions according to Examples 1 to 5 did not cause precipitation of the initiator after ink production, and showed good ink stability.

[Experimental Example 5] Evaluation of lower adhesion force

The ink compositions according to Examples 1 to 5 using 3% by weight of KBM-403 as an adhesion promoter showed excellent adhesion at a level of 5B as measured by a cross cut test.

[Experimental Example 6] Rework performance evaluation

It was confirmed that the ink compositions according to Examples 1 to 5 using 3 wt% of KBM-403 as an adhesion promoter were not easily removed even after 20 reciprocations.

[Experimental Example 7] Evaluation of Infrared Transmittance

It was confirmed that the ink compositions according to Examples 1 to 5 exhibited an infrared transmittance of 80% at 850 nm.

While the present invention has been particularly shown and described with reference to particular embodiments thereof, those skilled in the art will appreciate that such specific embodiments are merely preferred embodiments, It will be clear that it is not. Accordingly, the actual scope of the present invention will be defined by the appended claims and their equivalents.

Claims (26)

A lactam black pigment or a perylene black pigment or a combination thereof, Dispersants, Epoxy compounds, Oxetane compounds, A photopolymerization initiator and An infrared ray transmitting ink composition for an inkjet comprising an organic solvent. The infrared ray transmitting ink composition for inkjet according to claim 1, wherein the organic solvent has a boiling point of 200 ° C or higher and a viscosity of 1 to 5 cP at 25 ° C. The organic solvent according to claim 1, wherein the organic solvent is selected from the group consisting of butyl diglyme, dipropylene glycol methyl ether acetate, ethylene glycol dibutyrate, diethyl succinate, , Gamma-butyrolactone, and ethyl caprate. The ink composition according to any one of claims 1 to 7, wherein the at least one ink composition is at least one selected from the group consisting of gamma-butyrolactone and ethyl caprate. The infrared ray transmitting ink composition for ink jet according to claim 1, wherein the ink composition has a transmittance of 80% or more at a wavelength of 850 to 940 nm. The infrared ray transmitting ink composition for ink jet according to claim 1, wherein the content of the lactam black pigment or the perylene black pigment or a combination thereof is 5 to 15% by weight based on the total ink composition. The infrared ray transmitting ink composition for inkjet according to claim 1, wherein the content of the dispersing agent is 0.5 to 5% by weight based on the total ink composition. The infrared ray transmitting ink composition for ink jet according to claim 1, wherein the content of the epoxy compound is 5 to 25% by weight based on the total ink composition. The infrared ray transmitting ink composition for inkjet according to claim 1, wherein the content of the oxetane compound is 25 to 50% by weight based on the total ink composition. The ink composition according to claim 1, wherein the content of the organic solvent is 20 to 35% by weight based on the total ink composition. The infrared ray transmitting ink composition for inkjet according to claim 1, wherein the content of the photopolymerization initiator is 1 to 10% by weight based on the total ink composition. The method of claim 1, wherein the dispersing agent is selected from the group consisting of acrylic series, polyalkylene glycols and esters thereof, polyoxyalkylene polyhydric alcohols, ester alkylene oxide adducts, alcohol alkylene oxide adducts, sulfonic acid esters, sulfonates, Wherein the surfactant is selected from the group consisting of an acid ester, a carboxylate, an alkylamide alkylene oxide adduct, an alkylamine, and a mixture thereof. The infrared ray transmitting ink composition for inkjet according to claim 1, wherein the epoxy compound is an alicyclic epoxy compound containing one or two epoxidized aliphatic cyclic groups. The epoxy resin composition according to claim 1, wherein the epoxy compound is selected from the group consisting of dicyclopentadiene dioxide, limonene dioxide, (3,4-epoxycyclohexyl) methyl-3,4-epoxycyclohexanecarboxylate, 3-vinylcyclohexene oxide, bis Epoxycyclohexylmethyl) adipate, bis (3,4-epoxycyclohexylmethyl) adipate, bis (3,4-epoxycyclohexylmethyl) 3, 4-epoxy-6-methylcyclohexanecarboxylate, ethylene glycol bis (3,4-epoxycyclohexyl) ether, 4-epoxycyclohexene carboxylic acid ethylene glycol diester, and (3,4-epoxycyclohexyl) ethyltrimethoxysilane. The process of claim 1, wherein the oxetane compound is selected from the group consisting of 3-ethyl-3-hydroxymethyloxetane, 1,4-bis [(3-ethyl- Ethyl-3- (2-ethylhexyloxymethyl) oxetane, 3-ethyl-3-oxetanyl) Cyclohexyloxymethyl oxetane, and phenol novolak oxetane. The ink composition according to claim 1, The infrared ray transmitting ink composition for ink jet according to claim 1, wherein the photopolymerization initiator comprises at least one of an iodonium salt and a sulfonium salt. The infrared ray transmitting ink composition for inkjet according to claim 1, wherein the photopolymerization initiator comprises a sulfonium salt. The photopolymerization initiator according to claim 1, wherein the photopolymerization initiator is at least one selected from the group consisting of Omnicat 550 (10- [1,1'-biphenyl] -4-yl-2- (1-methylethyl) -9-oxo-9H-thioxanetetanium hexafluoro Phosphate). ≪ / RTI > The ink composition according to claim 1, wherein the ink composition further comprises an adhesion promoting agent in an amount of 1 to 5% by weight based on the total ink composition. 19. The method of claim 18, wherein the adhesion promoter is selected from the group consisting of 3-glycidoxypropyltrimethoxysilane, 3-glycidoxypropylmethyldimethoxysilane, 2- (3,4 epoxycyclohexyl) ethyltrimethoxysilane, 3- Alkoxysilane compounds selected from the group consisting of glycidoxypropylmethyldiethoxysilane, 3-glycidoxypropyltriethoxysilane, and 3-methacryloxypropyltrimethoxysilane, and phosphate-based acrylates. Wherein at least one of the ink composition and the ink composition is an inkjet ink composition. The infrared ray transmitting ink composition for inkjet according to claim 1, wherein the ink composition has a curing dose of 100 to 3,000 mJ / cm ² and is cured by absorbing radiation in a wavelength range of 250 to 410 nm. The ink composition according to claim 1, wherein the ink composition has a viscosity of 1 to 30 cP at 25 캜, and an adhesion force with a substrate is not less than 4 B as a cross cut test. The infrared ray transmitting ink composition for inkjet according to claim 1, wherein the ink composition is at a point in time at which the ink composition has a viscosity of 10% or more when stored at 35 DEG C for at least 60 days. a) forming a bezel pattern by inkjet printing the inkjet infrared ray transmitting ink composition of claim 1 on a substrate; And b) irradiating the bezel pattern with radiation to cure the bezel pattern. 24. The method of claim 23, wherein the cured bezel pattern has a thickness of 1 to 3 占 퐉. A bezel pattern produced using the ink jet infrared transmitting ink composition of claim 1. 26. A display substrate comprising the bezel pattern of claim 25.