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WO2018164463A1 - Élément décoratif et procédé de fabrication d'élément décoratif - Google Patents

Élément décoratif et procédé de fabrication d'élément décoratif Download PDF

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Publication number
WO2018164463A1
WO2018164463A1 PCT/KR2018/002671 KR2018002671W WO2018164463A1 WO 2018164463 A1 WO2018164463 A1 WO 2018164463A1 KR 2018002671 W KR2018002671 W KR 2018002671W WO 2018164463 A1 WO2018164463 A1 WO 2018164463A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
decorative member
degrees
convex portion
pattern layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2018/002671
Other languages
English (en)
Korean (ko)
Inventor
조은별
김용찬
손정우
조필성
허난슬아
송진숙
한상철
장성호
김기환
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LG Chem Ltd
Original Assignee
LG Chem Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020170136790A external-priority patent/KR101966851B1/ko
Application filed by LG Chem Ltd filed Critical LG Chem Ltd
Priority to US16/465,106 priority Critical patent/US11376888B2/en
Priority to JP2019524888A priority patent/JP6870815B2/ja
Priority to CN201880013619.2A priority patent/CN110382253B/zh
Priority to EP18763746.7A priority patent/EP3594016A4/fr
Publication of WO2018164463A1 publication Critical patent/WO2018164463A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/263—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer having non-uniform thickness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/16—Layered products comprising a layer of synthetic resin specially treated, e.g. irradiated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/30—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/02—Physical, chemical or physicochemical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/02—Physical, chemical or physicochemical properties
    • B32B7/023—Optical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44F—SPECIAL DESIGNS OR PICTURES
    • B44F1/00—Designs or pictures characterised by special or unusual light effects
    • B44F1/08—Designs or pictures characterised by special or unusual light effects characterised by colour effects
    • B44F1/10—Changing, amusing, or secret pictures
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/20—Inorganic coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2451/00—Decorative or ornamental articles

Definitions

  • the present application relates to a decorative member and a method for manufacturing the decorative member.
  • Patent document 1 relates to the manufacturing method of the decorative member for electronic devices which applied the pattern.
  • decorative members to which a pattern is applied have one color, and interest in decorative members having dichroism showing different colors is increasing according to the viewing direction.
  • Patent Document 1 Republic of Korea Patent Publication No. 10-1652875
  • the present application provides a decorative member and a method of manufacturing the decorative member having dichroism showing different colors depending on the viewing direction and improving the visibility of the dichroic.
  • the present application relates to a decorative member.
  • the decorative member according to the exemplary embodiment of the present specification includes a pattern layer including a convex or concave-shaped surface having a cross section of an asymmetric structure; And an inorganic layer provided on the convex or concave-shaped surface.
  • the term "layer” means covering 70% or more of the area in which the layer exists. It means preferably covering at least 75%, more preferably at least 80%.
  • a cross section means the surface at the time of cut
  • the cross section may mean a surface when the convex portion or the concave portion is cut in a direction parallel to the ground or perpendicular to the ground when the decorative member is placed on the ground.
  • the convex or concave-shaped surface of the pattern layer of the decorative member according to the embodiment is characterized in that at least one of the cross sections in the direction perpendicular to the ground has an asymmetrical structure.
  • the cross section of the asymmetric structure means that the figure composed of the edge of the cross section is a structure having no line symmetry or point symmetry.
  • Line symmetry refers to the property of overlapping when a figure is symmetric about a straight line.
  • Point symmetry means that when a figure is rotated 180 degrees around a point, it has a symmetrical property that completely overlaps the original figure.
  • the edge of the cross section of the asymmetric structure may be a straight line, a curve or a combination thereof.
  • the said decorative member can express dichroism by the convex part or concave part which has the cross section of the asymmetric structure contained in the surface of a pattern layer.
  • Dichroism means that different colors are observed depending on the viewing angle.
  • the color can be represented by CIE L * a * b *, and the color difference can be defined using a distance ( ⁇ E * ab) in L * a * b * space. Specifically, the color difference is In the range 0 ⁇ E * ab ⁇ 1, the observer cannot perceive the color difference (Ref. Machine Graphics and Vision 20 (4): 383-411). Therefore, in the present specification, dichroism may be defined as ⁇ E * ab> 1.
  • the surface of the convex portion or the concave portion includes two or more of the convex portion or the concave portion shape.
  • dichroism can be made larger by having two or more convex or recessed surfaces.
  • two or more convex portions or concave portions may have the same shape, but different shapes may be included.
  • the convex portion or the concave portion having the cross section of the asymmetric structure includes two or more sides having at least one cross section having different inclination angles, different degrees of bending, or different sides.
  • the convex portions or concave portions have an asymmetrical structure.
  • the shape of the convex portion or the concave portion includes a first inclined side and a second inclined side of at least one cross-section is different from each other.
  • side may be a straight line, but is not limited thereto, and all or part of the curve may be curved.
  • the sides may include a portion of an arc of a circle or ellipse, a wave structure, a zigzag structure, or the like.
  • the circle or ellipse may have a radius of curvature.
  • the radius of curvature may be defined as the radius of the arc when the extremely short section of the curve is converted into an arc.
  • the term "inclined side” means the side of the angle when the decorative member is placed on the ground is more than 0 degrees and less than 90 degrees. At this time, when the side is a straight line, the angle between the straight line and the ground can be measured. When the side includes a curve, when the decorative member is placed on the ground, the angle formed by the straight line connecting the point closest to the ground and the furthest point from the ground among the sides at the shortest distance can be measured. Can be.
  • an inclination angle is an angle which the surface or side which comprises the said pattern layer with the ground when the said decoration member is placed on the ground, is more than 0 degree and 90 degrees or less.
  • a line segment (a'-b ') generated when the point (a') where the face or side of the pattern layer is in contact with the ground and the point (b ') farthest from the face or side of the pattern layer are connected to each other. ) May mean an angle formed by the ground.
  • the degree of curvature refers to the degree of change in the slope of the tangent at successive points on the side or face. The greater the change in the slope of the tangent at successive points on the side or face, the greater the degree of curvature.
  • An angle a1 formed between the first inclined side L1 and the second inclined side L2 may be in a range of 80 degrees to 100 degrees.
  • the angle a1 may be specifically 80 degrees or more, 83 degrees or more, 86 degrees or more, or 89 degrees or more, and 100 degrees or less, 97 degrees or less, 94 degrees or less, or 91 degrees or less.
  • the angle may refer to the angle of the vertex consisting of the first inclined side and the second inclined side.
  • the first inclined side and the second inclined side do not form a vertex with each other, the first inclined side and the second inclined side may mean an angle of a vertex in a state in which a vertex is formed.
  • the difference between the inclination angle a2 of the first inclined side of the convex portion P1 and the inclination angle a3 of the second inclined side may be in a range of 30 degrees to 70 degrees.
  • the difference between the inclination angle a2 of the first inclined side and the inclination angle a3 of the second inclined side may be, for example, 30 degrees or more, 35 degrees or more, 40 degrees or more, or 45 degrees or more, 70 degrees or less, 65 degrees or less. , 60 degrees or less or 55 degrees or less.
  • the shape of the convex portion or the concave portion of the surface of the pattern layer may be a convex portion of the cone shape protruding out of the surface of the pattern layer or the shape of a cone recessed into the surface of the pattern layer. It may be a recess of.
  • Cone forms include cones, ellipses, or polygonal cones.
  • the shape of the bottom surface of the polygonal pyramid includes a triangle, a square, and a star shape having five or more protruding points.
  • the decorative member when the decorative member is placed on the ground, when the surface of the pattern layer has a cone-shaped convex shape, at least one of the vertical cross-sections of the convex shape with respect to the ground may be triangular in shape.
  • the decorative member when the decorative member is placed on the ground, when the surface of the pattern layer has a concave shape of a cone, at least one of the vertical cross-sections of the concave shape with respect to the ground is an inverted triangle shape. Can be.
  • the cone-shaped convex portion or the cone-shaped concave portion may have at least one cross section of an asymmetric structure.
  • the convex portion or the concave portion of the cone shape is observed from the surface side of the convex portion or the concave portion, when two or less identical forms exist when rotating 360 degrees from the vertex of the cone, the dichroism is It is advantageous to be expressed.
  • Fig. 7 shows the convex shape of the cone shape observed from the surface side of the convex shape, (a) shows the cone shape of the symmetrical structure, and (b) shows the cone shape of the asymmetric structure. It is illustrated.
  • the cone shape of the symmetrical structure When the decorative member is placed on the ground, the cone shape of the symmetrical structure has a circular cross section (hereinafter referred to as a horizontal cross section) in a direction horizontal to the ground, or a regular polygon having the same length of each side, and the vertex of the cone is on the ground. It is a structure existing on a line perpendicular to the cross section of the center of gravity of the horizontal cross section for.
  • a cone shape having a cross section of an asymmetric structure is located on the vertical line of the point where the vertex position of the cone is not the center of gravity of the horizontal cross section of the cone when observed from the surface side of the shape of the convex portion or the recess portion of the cone shape.
  • the horizontal cross section of the cone is a polygon or ellipse of an asymmetric structure.
  • the horizontal cross section of the cone is a polygon of an asymmetric structure, at least one of the sides or angles of the polygon may be designed differently from the rest.
  • the position of the vertex of the cone can be changed.
  • the vertex of the cone when the vertex of the cone is designed to be positioned on the vertical line of the center of gravity (01) of the horizontal cross section with respect to the ground of the cone when viewed from the surface side of the convex shape of the cone shape, Four identical structures can be obtained at 360 degrees of rotation from the vertex of the cone (4 fold symmetry).
  • the symmetrical structure is broken by designing the vertices of the cone at position 02, not the center of gravity 01 of the horizontal cross section with respect to the ground.
  • the pattern layer has a surface of a convex portion having a linear point or a concave portion having a linear point.
  • 10 to 12 show photographs of an example of implementing a convex portion having a line shape.
  • the linear shape may be a straight line, a curved line, may include both a curved line and a straight line, or may be zigzag.
  • the center of gravity of the horizontal cross section with respect to the ground surface of the convex portion or the concave portion is observed when the surface of the convex portion having the highest point is linear or the concave portion having the lowest point is observed from the surface side of the convex portion or the concave portion.
  • Fig. 9 shows a surface having the shape of a convex portion having a peak at a line
  • (a) illustrates a pattern having convex portions that do not express dichroism
  • (b) has convex portions expressing dichroism. The pattern is illustrated.
  • X-X 'cross section of FIG. 9 (a) is an isosceles triangle or equilateral triangle
  • Y-Y' cross section of FIG. 9 (b) is a triangle from which the side length differs.
  • the pattern layer has a convex or concave-shaped surface of the structure in which the tip of the cone shape is cut off.
  • FIG. 13 when the decorative member is placed on the ground, a photograph embodying an inverted trapezoidal recess having an asymmetrical cross section perpendicular to the ground is shown.
  • Such asymmetric cross sections may be trapezoidal or inverted trapezoidal in shape.
  • dichroism can be expressed by the cross section of an asymmetric structure.
  • the shape of the convex portion or the concave portion includes a first inclined surface and a second inclined surface different from each other.
  • the "face” may be a plane, but is not limited thereto, and all or part of the surface may be curved.
  • the shape of the cross section in a direction perpendicular to the plane may include a portion of an arc of a circle or ellipse, a wave structure, a zigzag structure, or the like.
  • the term "inclined surface” means a surface of which the angle formed by the surface with respect to the ground is greater than 0 degrees and less than 90 degrees when the decorative member is placed on the ground. At this time, when the plane is a plane, the angle between the plane and the ground can be measured. When the surface includes a curved surface, when the decorative member is placed on the ground, an angle formed by a straight line connecting the point closest to the ground and the farthest point among the surface with the ground is measured. Can be.
  • 1 to 3 exemplarily illustrate a decorative member including a pattern layer and an inorganic layer (not shown) each including a surface having a convex portion P1 shape.
  • the inclination angles a2 and a3 of the convex portion P1 may mean an angle formed between the inclined surfaces S1 and S2 of the convex portion P1 and the horizontal plane of the pattern layer.
  • the first inclined plane may be defined as a left inclined plane of the convex portion
  • the second inclined plane may mean a right inclined plane of the convex portion.
  • the convex portion P1 of the pattern layer may have a polygonal cross section and have a pillar shape extending in one direction.
  • the cross section of the convex portion P1 may be triangular or have a shape further including a small concave portion at the tip (a pointed portion or a vertex portion) of the triangle.
  • An angle a1 formed between the first inclined surface S1 and the second inclined surface S2 may be in a range of 80 degrees to 100 degrees.
  • the angle a1 may be specifically 80 degrees or more, 83 degrees or more, 86 degrees or more, or 89 degrees or more, and 100 degrees or less, 97 degrees or less, 94 degrees or less, or 91 degrees or less.
  • the angle may refer to the angle of the vertex consisting of the first slope and the second slope.
  • the first inclined surface and the second inclined surface do not form a vertex with each other, the first inclined surface and the second inclined surface may mean an angle of a vertex in a state of forming a vertex.
  • the difference between the inclination angle a2 of the first inclined surface of the convex portion P1 and the inclination angle a3 of the second inclined surface may be in a range of 30 degrees to 70 degrees.
  • the difference between the inclination angle a2 of the first inclined surface and the inclination angle a3 of the second inclined surface may be, for example, 30 degrees or more, 35 degrees or more, 40 degrees or more, or 45 degrees or more, 70 degrees or less, 65 degrees or less. , 60 degrees or less or 55 degrees or less.
  • the height H1 of the convex portion P1 may be 5 ⁇ m to 30 ⁇ m. If the height of the convex portion is within the above range, it may be advantageous in terms of production process. In the present specification, the height of the convex portion may mean the shortest distance between the highest portion and the lowest portion of the convex portion with respect to the horizontal plane of the pattern layer. In the description relating to the height of the convex portion, the same numerical range may be applied to the depth of the concave portion described above.
  • the width W1 of the convex portion P1 may be 10 ⁇ m to 90 ⁇ m. If the width of the convex portion is within the above range, it may be advantageous in terms of process for processing and forming the pattern.
  • the width W1 of the convex portion P1 may be, for example, 10 ⁇ m or more, 15 ⁇ m or more, 20 ⁇ m or more, or 25 ⁇ m or more, 90 ⁇ m or less, 80 ⁇ m or less, 70 ⁇ m or less, 60 ⁇ m or less, 50. It may be up to 40 ⁇ m, or up to 35 ⁇ m. Descriptions relating to this width may apply not only to the convex portions, but also to the concave portions described above.
  • An interval between the convex portions P1 may be 0 ⁇ m to 20 ⁇ m.
  • the distance between the convex portions may mean the shortest distance between two adjacent convex portions, at which one convex portion ends and another convex portion starts. If the spacing between the convex portions is properly maintained, the decorative member should have a relatively bright color when viewed from the side of the inclined surface where the inclination angle of the convex portion is larger, thereby improving the phenomenon that the reflection area is dark due to shading. As described later, a second convex portion having a smaller height than the convex portion may exist between the convex portions. The description relating to this spacing can be applied not only to the convex portion but also to the concave portion described above.
  • the pattern layer may have a flat portion on a surface opposite to the surface on which the convex portion is formed, and the flat portion may be formed on the base layer.
  • a plastic substrate can be used as the substrate layer.
  • the plastic substrate include triacetyl cellulose (TAC); COP (cyclo olefin copolymer) such as norbornene derivatives; Poly (methyl methacrylate); PC (polycarbonate); PE (polyethylene); PP (polypropylene); PVA (polyvinyl alcohol); DAC (diacetyl cellulose); Pac (Polyacrylate); PES (poly ether sulfone); PEEK (polyetheretherketon Polyphenylsulfone (PPS), polyetherimide (PEI); polyethylenemaphthatlate (PEN); polyethyleneterephtalate (PET); polyimide (PI); polysulfone (PSF); polyarylate (PAR) or amorphous fluorocarbon resin, but is not limited there
  • the pattern layer may include a curable resin.
  • Photocurable resin or thermosetting resin can be used as said curable resin.
  • Ultraviolet curable resin can be used as said photocurable resin.
  • thermosetting resin for example, silicone resin, silicon resin, fran resin, polyurethane resin, epoxy resin, amino resin, phenol resin, urea resin, polyester resin, melamine resin, etc. may be used, but is not limited thereto.
  • UV curable resins typically include acrylic polymers such as polyester acrylate polymers, polystyrene acrylate polymers, epoxy acrylate polymers, polyurethane acrylate polymers or polybutadiene acrylate polymers, silicone acrylate polymers or alkyl acrylates. Polymers and the like may be used, but are not limited thereto.
  • the said pattern layer can be manufactured by apply
  • the mold may for example have a flat form or a roll form.
  • a soft mold or a hard mold may be used.
  • a color dye may be further included on at least one surface of the pattern layer.
  • the inclusion of a colored dye on at least one surface of the pattern layer may mean, for example, a case where the colored dye is included in the above-described base layer provided on the flat portion side of the pattern layer.
  • the colored dyes include anthraquinone-based dyes, phthalocyanine-based dyes, thioindigo-based dyes, perinone-based dyes, isoxindigo-based dyes, and methane-based dyes. Dyes, monoazo-based dyes and 1: 2 metal complex dyes.
  • the pattern layer When the pattern layer includes a colored dye therein, it may be applied by adding a dye to the curable resin. When further comprising a colored dye in the lower portion of the pattern layer, it may be applied by coating a layer containing the dye on the upper or lower portion of the base layer.
  • the content of the colored dye may be 0 to 50 wt%, for example.
  • the content of the colored dye may determine the transmittance and haze range of the pattern layer to the decorative member, the transmittance may be, for example, 20% to 90%, and the haze may be, for example, 1% to 40%.
  • the inorganic layer may give a metallic texture and depth of color when looking at the decorative member.
  • the inorganic layer may be viewed in various colors according to the viewing angle of the image of the decorative member. This is because the wavelength of the light passing through the pattern layer and reflected from the surface of the inorganic layer changes according to the wavelength of the incident light.
  • the inorganic layer may have the same convex portion or concave portion as the surface of the pattern layer described above.
  • the inorganic layer may have the same slope as the surface of the pattern layer described above.
  • the inorganic layer may include a metal.
  • the inorganic layer include indium (In), titanium (Ti), tin (Sn), silicon (Si), germanium (Ge), aluminum (Al), copper (Cu), nickel (Ni), and vanadium. (V), tungsten (W), tantalum (Ta), molybdenum (Mo), neodymium (Nb), iron (Fe), chromium (Cr), cobalt (Co), gold (Au) and silver (Ag) It may include one or two or more of the materials, oxides, nitrides or oxynitrides thereof, carbon and carbon composites.
  • the inorganic layer may be a single layer or multiple layers including the material.
  • the inorganic layer may have a refractive index of 0 to 8 with respect to light having a wavelength of 400 nm. When the refractive index of the inorganic layer is out of the range, the reflected light decreases and may not be appropriate.
  • the refractive index of the inorganic layer may be specifically 0 or more, 1 or more, 2 or more, 3 or more, 4 or more, or 4.5 or more, 8 or less, 7 or less, 6 or less, or 6.5 or less.
  • the inorganic layer may have a thickness of, for example, 10 nm to 1 ⁇ m. When the thickness of the inorganic layer is within the above range, it may be advantageous to provide a decorative member having dichroism showing a different color depending on the viewing direction and improving the dichroic visibility.
  • the inorganic layer may have a thickness of, for example, 10 nm or more, 50 nm or more, or 100 nm or more, and may be 1 ⁇ m or less, 800 nm or less, 600 nm or less, 400 nm or less, or 300 nm or less.
  • the decorative member may exhibit dichroism showing different colors depending on the viewing direction. The decorative member can improve the dichroic visibility by modifying the surface shape of the pattern layer.
  • the "thickness" of a layer means the shortest distance from the lower surface of the layer to the upper surface.
  • the surface of the pattern layer may have a shape in which the second convex portion P2 having a smaller height than the convex portion is disposed between the convex portions P1.
  • the convex part named before the second convex part may be referred to as the first convex part.
  • the height H2 of the second convex portion P2 may have a range of 1/5 to 1/4 of the height H1 of the first convex portion P1.
  • the difference between the heights H1-H2 of the first convex portion and the second convex portion may be 10 ⁇ m to 30 ⁇ m.
  • the width W2 of the second convex portion may be 1 ⁇ m to 10 ⁇ m.
  • the width W2 of the second convex portion may be specifically 1 ⁇ m or more, 2 ⁇ m or more, 3 ⁇ m or more, 4 ⁇ m or more, or 4.5 ⁇ m or more, 10 ⁇ m or less, 9 ⁇ m or less, 8 ⁇ m or less, 7 ⁇ m or less, 6 ⁇ m or less or 5.5 ⁇ m or less.
  • the second convex portion may have two inclined surfaces S3 and S4 having different inclination angles.
  • An angle a4 formed by the two inclined surfaces of the second convex portion may be 20 degrees to 100 degrees.
  • the angle a4 may be specifically 20 degrees or more, 30 degrees or more, 40 degrees or more, 50 degrees or more, 60 degrees or more, 70 degrees or more, 80 degrees or more, or 85 degrees or more, and 100 degrees or less or 95 degrees or less. have.
  • the difference a6-a5 of the inclination angles of both inclined surfaces of the second convex portion may be 0 to 60 degrees.
  • the difference a6-a5 of the inclination angle may be 0 degrees or more, 10 degrees or more, 20 degrees or more, 30 degrees or more, 40 degrees or more, or 45 degrees or more, and 60 degrees or less or 55 degrees or less.
  • the dimension of the second convex portion is within the above range, it may be advantageous in terms of increasing the inflow of light from the side having a large inclined plane angle to form a bright color.
  • the surface of the pattern layer may have a shape further including a concave portion P3 having a smaller height than the convex portion at the tip portion (pointed portion) of the convex portion P1.
  • Such a decorative member may have an effect that the image color is slightly changed depending on the viewing angle.
  • the height H3 of the recess P3 may be 3 ⁇ m to 15 ⁇ m.
  • the height H3 of the recess P3 may be specifically 3 ⁇ m or more, and may be 15 ⁇ m or less, 10 ⁇ m or less, or 5 ⁇ m or less.
  • the concave portion may have two inclined surfaces S5 and S6 having different inclination angles.
  • An angle a7 formed by the two inclined surfaces of the recess may be 20 degrees to 100 degrees.
  • the angle a7 may be specifically 20 degrees or more, 30 degrees or more, 40 degrees or more, 50 degrees or more, 60 degrees or more, 70 degrees or more, 80 degrees or more, or 85 degrees or more, and 100 degrees or less or 95 degrees or less. have.
  • the difference a9-a8 between the inclination angles of both inclined surfaces of the recess may be 0 to 60 degrees.
  • the difference (a9-a8) of the inclination angle may be 0 degrees or more, 10 degrees or more, 20 degrees or more, 30 degrees or more, 40 degrees or more, or 45 degrees or more, and 60 degrees or less or 55 degrees or less.
  • the size of the concave portion is in the above range it may be advantageous in terms of adding color in the mirror surface.
  • the surface of the pattern layer may have a shape in which a plurality of convex portions are arranged in an inverted structure of 180 degrees.
  • the surface of the pattern layer may include a first region C1 having a larger inclination angle of the second inclined surface than a first inclined surface and a second region C2 having a larger inclination angle of the second inclined surface than the first inclined surface.
  • the convex portion included in the first region may be referred to as a first convex portion P1
  • the convex portion included in the second region may be referred to as a fourth convex portion P4.
  • the height, width, inclination angle, and angle formed by the first and second inclined surfaces of the first convex portion P1 and the fourth convex portion P4 may be the same as those described in the items of the convex portion P1. have.
  • one of the first area and the second area may correspond to an image or a logo
  • the other area may correspond to a background part.
  • Such a decorative member may have an effect that the image or logo color is softly changed depending on the viewing angle.
  • the color may change depending on the direction in which the image or logo portion and the background portion look.
  • the first region and the second region may each include a plurality of convex portions.
  • the width and the number of the convex portions of the first region and the second region may be appropriately adjusted in consideration of the size of the desired image or logo.
  • the cross section of the pattern layer has a convex portion shape
  • the cross section of the convex portion shape includes a first region D1 including a first inclined side and a second including a second inclined side. Area D2 is included.
  • the first slope and the second slope are straight.
  • An angle c3 formed between the first inclined side and the second inclined side may be 75 degrees to 105 degrees.
  • the angle c1 between the first inclined side and the ground and the angle c2 between the second inclined side and the ground are different.
  • the combination of c1 and c2 may be 20 degrees / 80 degrees, 10 degrees / 70 degrees or 30 degrees / 70 degrees.
  • a cross section of the pattern layer has a convex portion shape
  • a cross section of the convex portion shape includes a first region E1 including a first inclined side and a second including a second inclined side.
  • Region E2 At least one of the first slope and the second slope may have a curved shape.
  • both the first slope and the second slope may be curved, the first slope may be straight, and the second slope may be curved.
  • the angle between the inclined side having a curved shape and the ground can be calculated from the angle formed by the straight line and the ground when an arbitrary straight line is drawn from a point where the inclined side and the ground meets to a point where the first inclined side and the second inclined side meet.
  • the curved second slope may have a different degree of curvature according to the height of the pattern layer, and the curved line may have a radius of curvature.
  • the radius of curvature may be 10 times or less than the pitch E1 + E2 of the convex shape.
  • FIG. 33A shows that the radius of curvature of the curve is twice the pitch of the convex portion, and FIG.
  • 33B shows that the radius of curvature of the curve is one times the pitch of the convex portion.
  • the ratio of the curvature portion E2 to the pitch E1 + E2 of the convex portion may be 90% or less.
  • 33 (a) and 33 (b) show that the ratio of the curvature portion E2 to the pitch E1 + E2 of the convex portion is 60%.
  • the cross section of the pattern layer may have a convex portion shape
  • the cross section of the convex portion shape may have a quadrangular shape.
  • the rectangular shape may be a general rectangular shape, and is not particularly limited as long as the inclination angles of the inclined sides are different from each other.
  • the quadrangular shape may be a form in which a triangle is partially cut off.
  • the pair may have a trapezoid in which parallel pairs of quadrilaterals are parallel, or a quadrangle in which pairs of parallel pairs do not exist.
  • the convex-shaped cross section includes a first region F1 including a first inclined side, a second region F2 including a second inclined side, and a third region F3 including a third inclined side.
  • the third inclined side may or may not be parallel to the ground.
  • the third slope is parallel to the ground.
  • At least one of the first to third slopes may have a curved shape, and the details of the curved shape are the same as those described in the fifth embodiment.
  • the length of the sum of F1 + F2 + F3 may be defined as the pitch of the convex pattern, and the details of the pitch are as described above.
  • a flat portion may be included between each convex portion of the pattern layer.
  • the flat portion means a region where no convex portion exists.
  • the pattern layer further includes a flat portion, the description of the remaining components D1, D2, c1, c2, c3, the first inclined side and the second inclined side is the same as that described in the fourth embodiment.
  • a configuration (D1 + D2 + G1) including one convex portion and one flat portion adjacent to the convex portion may be referred to as a unit pattern.
  • the ratio of the area D1 + D2 of the convex portion to the area D1 + D2 + G1 of the unit pattern may be 10% or more and 100% or less. In FIG. 35A, the ratio is 83%, and in FIG. 35B, the ratio is 50%.
  • the cross section of the pattern layer may have a convex portion shape
  • the cross section of the convex portion may have a shape in which a specific region of the ABO1 triangle shape is removed.
  • the method of determining the specific region to be removed is as follows. The contents of the inclination angles c1 and c2 are the same as described above.
  • L1: L2, m1: m2, n1: n2 and o1: o2 ratio may be the same or different from each other, and each independently 1: 1000 to 1000: 1.
  • ABP2P3P1 The shape formed by the polygon is defined as the cross section of the convex portion.
  • the pattern layer according to the eighth embodiment may be modified in various forms by adjusting the ratios L1: L2, m1: m2, n1: n2, and o1: o2.
  • L1 and m1 increases, the height of the pattern may increase, and when the o1 increases, the height of the concave portion formed on the convex portion may decrease, and the convex portion may be formed by adjusting the ratio of n1.
  • the position of the lowest point of the concave portion can be adjusted close to either of the inclined sides of the convex portion.
  • FIG. 37 exemplarily shows a pattern layer of the decorative member according to the eighth embodiment of the present specification.
  • the cross section may have a trapezoidal shape.
  • the height (ha, hb) of the trapezoid can be varied by adjusting the ratio of L1: L2.
  • FIG. 37 (a) shows a pattern layer manufactured when the ratio of L1: L2 is 1: 1
  • FIG. 37 (b) shows the ratio of L1: L2 is 2: 1.
  • the ratio of l1: l2 represents a pattern layer prepared when the ratio of 1: 2, m1: m2 is 1: 1, the ratio of n1: n2 is 1: 5, and the ratio of o1: o2 is 1: 1.
  • FIG. 39A illustrates an example of a pattern layer of a decoration member according to an eighth embodiment of the present specification.
  • the ratio of o1: o2 is greater than 1: 1 and less than or equal to 1000: 1
  • the P1P3 and P2P3 segments are curved rather than straight lines.
  • the P1P3 and P2P3 segments are connected by one curve, have a constant radius of curvature, and the details of the radius of curvature are as described above.
  • the ratio of o1: o2 is greater than 1: 1 and less than or equal to 1: 1000, and the P1P3 and P2P3 segments are not straight lines.
  • the P1P3 and P2P3 segments are connected by one curve, have a constant radius of curvature, and the details of the radius of curvature are as described above.
  • the pattern layer is prepared when the ratio of L1: L2 is 2: 1, the ratio of m1: m2 is 1: 1, and the ratio of o1: o2 is 1: 8.
  • the light absorption layer and the light reflection layer are named according to their function.
  • a layer that reflects light relatively much may be represented by a light reflection layer
  • a layer that reflects light relatively little may be represented by a light absorption layer.
  • each layer is laminated in the order of L i-1 layer, L i layer, and L i + 1 layer with respect to the direction of light input, and between the L i-1 layer and the L i layer.
  • the interface (interface) i i is located, and the interface i i + 1 located between the layer L i and L i + 1 layer.
  • the reflectance at the interface Ii may be expressed by Equation 1 below.
  • Equation 1 n i ( ⁇ ) denotes a refractive index according to the wavelength ⁇ of the i-th layer, and k i ( ⁇ ) denotes an extinction coefficient according to the wavelength ⁇ of the i-th layer. Means.
  • the extinction coefficient is a measure that can define how strongly the target material absorbs light at a particular wavelength, as defined above.
  • Equation 2 when the sum of reflectances for each wavelength at the interface I i calculated at each wavelength is R i , R i is represented by Equation 2 below.
  • the contact surface Ii when in the interface between the layered product Ii R i is the larger, and the contact surface Ii, can be defined as the light-reflecting light-absorbing layer and the other layer in the layer opposite to a direction in which the light entering the interface between Ii.
  • the layer L i + 1 layer when the sum of the wavelength specific reflectivity of the interface I i + 1 the largest, in contact with I i + 1, the interface I i + 1 and the light is located opposite to the incoming direction
  • the layer L i + 1 layer may be defined as a light reflection layer, the remaining layers L i-1 and L i layers as light absorbing layers.
  • the present application also relates to a method of manufacturing a decorative member.
  • 4 exemplarily shows a method of manufacturing a decorative member of the present specification.
  • Exemplary manufacturing methods include preparing a pattern layer comprising a convex or concave-shaped surface having a cross-section of an asymmetric structure; And forming an inorganic layer on the surface of the convex or concave portion having the cross section of the asymmetric structure of the pattern layer.
  • the manufacturing method may deposit the first and second inorganic layers on the first and second inclined surfaces of the pattern layer including the convex-shaped surfaces including the first and second inclined surfaces having different inclination angles, respectively. It may include doing.
  • An exemplary manufacturing method deposits an inorganic layer on each of the two inclined surfaces of the pattern layer, so that the thickness and type of the inorganic layer may be adjusted on each inclined surface, thereby broadening the dichroic spectrum. Unless otherwise described with respect to the manufacturing method, the contents described in the items of the decorative member may be equally applied.
  • the first and second inorganic layers are respectively formed on the first and second slopes by sputtering, evaporation, evaporation, chemical vapor deposition, wet coating, and the like. Can be formed.
  • the sputtering method is straight, it is possible to maximize the difference in deposition thickness of both inclined surfaces by tilting the position of the target.
  • the first inorganic layer 201 is tilted toward the smaller slope of the first and second slopes of the pattern layer 10 to deposit the first inorganic layer 201 (S1). 2 inorganic layer 202 may be deposited (S2).
  • the order of the process (S1 and S2) may be reversed, it may be advantageous in terms of depositing inorganic materials of different thickness on both inclined surfaces.
  • the first and second inorganic layers may be deposited on the first and second inclined surfaces with different thicknesses.
  • the thicknesses of the first and second inorganic layers may be appropriately adjusted in consideration of the desired luminous characteristics within the range described in the items of the decorative member, respectively.
  • the first and second inorganic layers may be deposited on the first and second inclined surfaces with different materials.
  • the materials of the first and second inorganic layers may be appropriately adjusted in consideration of the desired visibility characteristics in the material in the items of the decorative member, respectively.
  • the inorganic layer may be composed of a single layer, it may be composed of a multilayer of two or more layers.
  • the inorganic material layer may include a third inorganic material layer and a fourth inorganic material layer sequentially stacked on the convex or concave-shaped surface.
  • the inorganic material layer may include a fourth inorganic material layer and a third inorganic material layer sequentially stacked on the convex or concave-shaped surface.
  • the materials included in each layer may be the same or different from each other.
  • the material of the third and fourth inorganic material layer may include the material of the inorganic material layer described above.
  • the third inorganic layer may be represented by a light absorption layer
  • the fourth inorganic layer may be represented by a light reflection layer.
  • the inorganic layer may include a light absorption layer and a light reflection layer sequentially stacked on the convex or concave-shaped surface, or the inorganic layer may be a light reflection layer sequentially stacked on the convex or concave-shaped surface. It may include a light absorbing layer.
  • the light absorbing layer and the light reflecting layer is a layer having relative properties to each other, the light absorbing layer means a layer having a higher light absorption than the light reflecting layer, the light reflecting layer is a light reflectivity compared to the light absorbing layer It can mean a high layer.
  • the light absorption layer and the light reflection layer may each be composed of a single layer, or may be composed of two or more layers.
  • the light absorbing layer In the light absorbing layer, light is absorbed at the incident path and the reflecting path of the light, and the light is reflected at the surface of the light absorbing layer and at the interface between the light absorbing layer and the light reflecting layer, respectively, so that the two reflected light beams reinforce or cancel each other.
  • the light reflected from the surface of the light absorbing layer may be represented by the surface reflected light, the light reflected from the interface between the light absorbing layer and the light reflecting layer.
  • Figure 15 shows a schematic diagram of such a principle of action. 15 illustrates a structure in which the substrate 101, the light reflection layer 201, and the light absorption layer 301 are stacked in this order, but the substrate is located below the light reflection layer, but is not essential.
  • the light reflected from the surface of the light absorbing layer may be represented by the surface reflected light, and the light reflected from the interface between the light absorbing layer and the light reflecting layer may be represented as interface reflected light.
  • the inorganic material layer represents a decorative member having a multilayer structure.
  • the light absorption layer 401 and the light reflection layer 501 sequentially formed on the surface of the convex portion of the pattern layer may be included.
  • the thickness t1 of the light reflection layer in the region E of the pattern layer including the first inclined surface and the thickness t2 of the light reflection layer in the region F of the pattern layer including the second inclined surface may be the same or different.
  • Figure 6 relates to a light absorption layer having a structure in which the inclined surfaces facing each other, that is, the cross section is triangular.
  • the thickness of the light absorption layer may be different on the two surfaces of the triangular structure. Accordingly, the light absorption layer having two or more regions having different thicknesses can be formed by only one process. As a result, the expression color is different depending on the thickness of the light absorption layer. At this time, if the thickness of the light reflection layer is more than a certain amount does not affect the color change.
  • the light reflecting layer is not particularly limited as long as it is a material capable of reflecting light, but the light reflectance may be determined depending on the material, for example, color is easily implemented at 50% or more. Light reflectance can be measured using an ellipsometer.
  • the light absorption layer preferably has a refractive index n of 0 to 8 at 400 nm, may be 0 to 7, may be 0.01 to 3, and may be 2 to 2.5.
  • the refractive index n may be calculated as sin ⁇ 1 / sin ⁇ 2 ( ⁇ 1 is the angle of light incident on the surface of the light absorption layer, and ⁇ 2 is the angle of refraction of light inside the light absorption layer).
  • the light absorption layer has an extinction coefficient k of 400 nm and greater than 0 and 4 or less, preferably 0.01 to 4, 0.01 to 3.5, 0.01 to 3, and 0.1 to 1.
  • the extinction coefficient (k) is-(l / 4pI) (dI / dx), where the path unit length in the light absorbing layer (dx), e.g., the fraction of dI / I of light intensity per meter multiplied by l / 4p Value, where l is the wavelength of light.
  • the light absorption layer has an extinction coefficient k of 380 to 780 nm greater than 0 and 4 or less, preferably 0.01 to 4, 0.01 to 3.5, 0.01 to 3, and 0.1 to 1. Since the extinction coefficient k is in the above range in the entire visible light wavelength range of 400 nm, preferably 380 to 780 nm, it may serve as a light absorbing layer within the visible light range.
  • the light reflection layer may be a metal layer, a metal oxynitride layer, or an inorganic layer.
  • the light reflection layer may be composed of a single layer, or may be composed of two or more multilayers.
  • the light reflection layer may be formed of indium (In), titanium (Ti), tin (Sn), silicon (Si), germanium (Ge), aluminum (Al), copper (Cu), nickel (Ni), vanadium ( V), tungsten (W), tantalum (Ta), molybdenum (Mo), neodymium (Nb), iron (Fe), chromium (Cr), cobalt (Co), gold (Au) and silver (Ag) It may be a single layer or multiple layers comprising one or two or more materials, oxides, nitrides or oxynitrides thereof, one or two or more of carbon and carbon composites.
  • the light reflection layer may include two or more alloys selected from the above materials, oxides, nitrides or oxynitrides thereof.
  • the light reflection layer may include two or more alloys selected from the metals. More specifically, the light reflection layer may include molybdenum, aluminum or copper.
  • the light reflection layer may be manufactured using an ink containing carbon or a carbon composite to implement a high resistance reflective layer. Carbon or carbon composites include carbon black and CNT.
  • the ink containing the carbon or carbon composite material may include the above-described materials or oxides, nitrides or oxynitrides thereof, such as indium (In), titanium (Ti), tin (Sn), silicon (Si), germanium ( Ge).
  • Aluminum (Al), Copper (Cu), Nickel (Ni), Vanadium (V), Tungsten (W), Tantalum (Ta), Molybdenum (Mo), Neodymium (Nb), Iron (Fe), Chromium (Cr), One or two or more oxides selected from cobalt (Co), gold (Au), and silver (Ag) may be included.
  • a curing process may be further performed.
  • the light reflection layer includes two or more kinds of materials
  • two or more kinds of materials may be formed using a single process, for example, a method of deposition or printing.
  • a method of forming a layer thereon from one or more materials can be used.
  • the ink containing carbon may be printed and cured to form a light reflection layer.
  • the ink may further include an oxide such as titanium oxide and silicon oxide.
  • the light absorption layer may be a single layer or a multilayer of two or more layers.
  • the light absorption layer may be made of a material having an extinction coefficient k at 380 to 780 nm, that is, a material having an extinction coefficient greater than 0 and 4 or less, preferably 0.01-4.
  • the light absorption layer may include one or two or more selected from the group consisting of metals, metalloids, and oxides, nitrides, oxynitrides and carbides of metals or metalloids. Oxides, nitrides, oxynitrides or carbides of the metal or metalloid can be formed by deposition conditions set by those skilled in the art.
  • the light absorption layer may include the same metal, metalloid, two or more alloys or oxynitrides as the light reflection layer.
  • the light absorption layer may include indium (In), titanium (Ti), tin (Sn), silicon (Si), germanium (Ge), aluminum (Al), copper (Cu), nickel (Ni), vanadium (V). , Tungsten (W), tantalum (Ta), molybdenum (Mo), neodymium (Nb), iron (Fe), chromium (Cr), cobalt (Co), gold (Au) and silver (Ag) Or a single layer or multiple layers comprising two or more materials or oxides, nitrides or oxynitrides thereof.
  • the light absorption layer may include one or two or more selected from copper oxide, copper nitride, copper oxynitride, aluminum oxide, aluminum nitride, aluminum oxynitride, and molybdenum titanium oxynitride.
  • the light absorbing layer includes silicon (Si) or germanium (Ge).
  • the light absorption layer made of silicon (Si) or germanium (Ge) has a refractive index (n) of 0 to 8 and may be 0 to 7 at 400 nm, and an extinction coefficient (k) of more than 0 to 4 or less, preferably 0.01 to 4, and may be 0.01 to 3 or 0.01 to 1.
  • the light absorption layer is AlOxNy (x> 0, y> 0).
  • the light absorption layer may be AlOxNy (0 ⁇ x ⁇ 1.5, 0 ⁇ y ⁇ 1).
  • the light absorption layer is AlOxNy (x> 0, y> 0), the number of each atom satisfies the following equation for the total number of atoms 100%.
  • the light absorption layer may be made of a material having an extinction coefficient (k) at 400 nm, preferably 380 to 780 nm.
  • the light absorption layer / light reflection layer may be formed of CuO / Cu, CuON / Cu, CuON / It may be formed of a material such as Al, AlON / Al, AlN / AL / AlON / Cu, AlN / Cu.
  • the thickness of the light reflection layer can be determined according to the desired color in the final structure, for example 1 nm or more, preferably 25 nm or more, such as 50 nm or more, preferably 70 nm or more.
  • the thickness of the light absorption layer may be 5 to 500 nm, for example, 30 to 500 nm.
  • the decorative member according to another embodiment of the present application is between the pattern layer and the inorganic layer; An opposite surface of the surface of the pattern layer that faces the inorganic layer; Or it may further include a color film provided on the opposite side of the surface of the inorganic layer facing the pattern layer.
  • the inorganic layer includes a light absorption layer and a light reflection layer, and between the pattern layer and the inorganic layer; Between the light absorption layer and the light reflection layer; An opposite surface of the surface of the pattern layer that faces the inorganic layer; It further comprises a color film provided on the opposite side of the surface of the inorganic layer facing the pattern layer.
  • the color film is a color difference ⁇ E which is a distance in a space of L * a * b * on the color coordinate CIE L * a * b * of the color expression layer when the color film is present, as compared with the case where the color film is not provided.
  • * Ab is not particularly limited as long as it exceeds 1.
  • the color can be represented by CIE L * a * b *, and the color difference can be defined using a distance ( ⁇ E * ab) in L * a * b * space. Specifically, And within the range of 0 ⁇ E * ab ⁇ 1 the observer cannot perceive the color difference (Ref. Machine Graphics and Vision 20 (4): 383-411). Therefore, in the present specification, the color difference according to the addition of the color film may be defined as ⁇ E * ab> 1.
  • the color change width according to the addition of the color film may be defined as a color difference ( ⁇ E * ab), which is a difference between L * a * b * before and after applying the color film.
  • FIG. 22A illustrates a structure in which a color film 401 is provided on the opposite side of the light reflection layer 201 side of the light absorption layer 301
  • the color film 401 includes a light absorption layer 301
  • a structure provided between the light reflection layer 201 a structure in which the color film 401 is provided between the light reflection layer 201 and the pattern layer 101 in FIG. 22C, and a color in FIG. 22D.
  • the structure in which the film 401 is provided on the opposite side of the light reflection layer 201 side of the pattern layer 101.
  • the color films 401a, 401b, 401c, and 401d respectively have light.
  • the structure provided on the opposite side of the 201 side is illustrated, but not limited thereto, and one to three of the color films 401a, 401b, 401c, and 401d may be omitted.
  • the arrangement position of the color film in the structure in which the light reflection layer 301 and the light absorption layer 201 are sequentially provided on the pattern layer 101 is illustrated in FIG. 23 (pattern layer Omission of convex or concave portions on the surface of 101).
  • the color film 401 is provided on the opposite side of the light absorption layer 301 side of the pattern layer 101, and in FIG. 23B, the color film 401 is the pattern layer 101.
  • the structure of the color film 401 is provided between the light absorbing layer 301 and the light reflection layer 201, (d) in Figure 23, (d) The structure of the color film 401 is provided on the opposite side of the light absorption layer 301 side of the light reflection layer 201.
  • the color films 401a, 401b, 401c, and 401d are disposed on the opposite side of the light absorbing layer 301 side of the pattern layer 101, between the pattern layer 101 and the light absorbing layer 301, respectively.
  • the structure provided between the light absorption layer 301 and the light reflection layer 201 and on the opposite side of the light absorption layer 301 side of the light reflection layer 201 is illustrated, but is not limited thereto, and color films 401a and 401b. , 1 to 3 of 401c and 401d may be omitted.
  • 22 (b) and 23 (c) have a structure in which the light incident layer can reflect light incident through the color film when the visible light transmittance of the color film is greater than 0%. Color can be implemented accordingly.
  • the transmittance is at least 1%, preferably at least 3%, more preferably at least 5%. This is because the light transmitted in the visible light transmittance range may be mixed with the color by the color film.
  • the color film may be provided in a state where one or two or more of the same kind or different kinds are stacked.
  • the color film may be used in combination with the color expressed from the laminated structure of the light reflection layer and the light absorption layer described above to express a desired color.
  • a color film in which one or two or more of pigments and dyes are dispersed in a matrix resin and exhibit color can be used.
  • the color film as described above may be formed by coating the color film-forming composition directly to the position where the color film may be provided as shown in Figures 1 to 3, or coating the color film-forming composition on a separate substrate, or casting After manufacturing the color film using a known molding method such as extrusion, a method of arranging or attaching the color film at a position where the color film may be provided as shown in FIGS. 1 to 3 may be used.
  • the coating method may be wet coating or dry coating.
  • Pigments and dyes that may be included in the color film may be selected from those known in the art as to achieve the desired color from the final decorative sub-material, red, yellow, purple, blue, pink 1 type, or 2 or more types of pigments and dyes, such as a series, can be used.
  • perinone-based red dye, anthraquinone-based red dye, methine-based yellow dye, anthraquinone-based yellow dye, anthraquinone-based violet dye, phthalocyanine-based blue dye, thioindigo-based pink dye, iso Dyes such as isoxindigo-based pink dyes may be used alone or in combination.
  • Pigment Blue 15: 3 C.I. Pigments such as Pigment Red 112, Pigment blue, and Isoindoline yellow may be used alone or in combination.
  • the dye or pigment as described above commercially available ones may be used, and for example, a material such as Ciba ORACET Co., Ltd. and Kwang Paint Co., Ltd. may be used.
  • the types of dyes or pigments and their colors are only examples, and various known dyes or pigments may be used, thereby realizing more various colors.
  • materials known as materials such as a transparent film, a primer layer, an adhesive layer, and a coating layer may be used, and are not particularly limited thereto.
  • various materials such as acrylic resins, polyethylene terephthalate resins, urethane resins, linear olefin resins, cycloolefin resins, epoxy resins, triacetyl cellulose resins, and the like may be selected, and copolymers of the above exemplified materials or Mixtures may also be used.
  • the color film When the color film is disposed closer to the position for observing the decorative member than the light reflection layer or the light absorption layer, for example, (a), (b), (a), (b) and (c) of FIGS.
  • the color film has a light transmittance of 1% or more, preferably 3% or more, and more preferably 5% or more of the color expressed from the light reflection layer, the light absorption layer, or the laminated structure of the light reflection layer and the light absorption layer. desirable.
  • the color expressed from the color film and the color expressed from the light reflection layer, the light absorbing layer, or a laminated structure thereof may be combined together to achieve a desired color.
  • the thickness of the color film is not particularly limited, and if the desired color can be represented, one of ordinary skill in the art can select and set the thickness.
  • the thickness of the color film may be 500 nm to 1 mm.
  • Exemplary decorative members and methods of manufacturing the decorative members can be applied to known objects in need of application of decorative members.
  • the present invention may be applied without limitation to portable electronic devices, electronic products, cosmetic containers, furniture, building materials, and the like.
  • the method of applying the decorative member to a portable electronic device, an electronic product, a cosmetic container, a furniture, a building material, etc. is not particularly limited, and a known method known as a method of applying a decor film in the art may be applied.
  • the decorative member may further include an adhesive layer as necessary.
  • the decorative member may be applied by direct coating to a portable electronic device or an electronic product. In this case, a separate adhesive layer for attaching the decorative member to a portable electronic device or an electronic product may not be necessary.
  • the decorative member may be attached to a portable electronic device or an electronic product through the adhesive layer.
  • the adhesive layer may use an optically clear adhesive tape (OCA tape) or an adhesive resin.
  • OCA tape or adhesive resin may be applied without limitation OCA tape or adhesive resin known in the art. If necessary, a release liner for protecting the adhesive layer may be further provided.
  • the present specification comprises the steps of preparing a pattern layer including a convex or concave-shaped surface having a cross section of an asymmetric structure; And forming an inorganic layer on the surface of the convex portion or the concave portion having the cross section of the asymmetric structure of the pattern layer.
  • the present application provides a decorative member and a method of manufacturing the decorative member having dichroism showing different colors depending on the viewing direction and improving the visibility of the dichroic.
  • 3 exemplarily shows a decorative member and left and right views of the present specification.
  • FIG. 5 is a dichroic luminous evaluation result of Example 1.
  • FIG. 6 illustrates a laminated structure of a decorative member according to an exemplary embodiment of the present specification.
  • 10-14 are examples of convex or concave-shaped surfaces of a patterned layer in accordance with some embodiments.
  • 15 is a schematic diagram of an optical path according to a laminated structure of a light absorption layer and a light reflection layer.
  • FIG. 18 shows n and k values of the aluminum oxynitride layer of Example 5.
  • Figure 21 shows the structure and color of the decorative member prepared in Examples 8 and 9 and Comparative Example 2.
  • 22 and 23 illustrate a laminated structure of a decorative member including a color film.
  • 25 and 26 show the physical properties of the color film used in Examples 10 to 28.
  • 41 is a view showing a method of distinguishing a light absorption layer and a light reflection layer.
  • FIG. 42 to 54 show experimental results according to Evaluation Example 3.
  • the hard mold was processed to have a pattern of the structure of FIG. 1.
  • the pattern layer having the structure of FIG. 1 was formed by applying a composition containing an epoxy resin and a phthalocyanine dye on the substrate layer, pressing the hard mold, and curing the same with ultraviolet rays.
  • Aluminum was deposited to a thickness of 200 nm on the upper part of the pattern layer to form an inorganic layer to prepare a decorative member.
  • the inorganic layer has a refractive index of 5 for light having a wavelength of 400 nm.
  • Both inclination angles of the first convex portions of the manufactured decorative members were 20 degrees (a2) and 70 degrees (a3), respectively, and the width was 30 ⁇ m, and both inclination angles of the second convex portions were 20 degrees (a5) and 70 degrees (a6), respectively. ) And the width is 5 ⁇ m.
  • the heights H1 and H2 of the first and second convex portions are determined from the width and the inclination angle, respectively.
  • a decorative member was manufactured in the same manner as in Example 1 except that the soft and hard molds were processed to have the pattern of the structure of FIG. 2.
  • Both inclination angles of the convex portions of the manufactured decorative members were 20 degrees and 70 degrees, respectively, and the width was 30 ⁇ m, and both inclination angles of the concave portions were 20 degrees (a8) and 70 degrees (a9), respectively, and the height H3 was 3 ⁇ m. to be.
  • the height of the convex portion is determined from the width and the inclination angle
  • the width of the concave portion is determined from the height and the inclination angle.
  • a decorative member was manufactured in the same manner as in Example 1, except that the soft and hard molds were processed to have the pattern of FIG. 3.
  • Both inclination angles of the first convex portion P1 of the convex portion of the first region of the manufactured decorative member are 20 degrees and 70 degrees, respectively, and the width is 30 ⁇ m, and the convex portion P4 of the second region is formed of the first region. It has a 180 degree reverse phase structure with the convex portion, and both inclination angles have 70 degrees and 20 degrees, respectively.
  • the decorative member was manufactured in the method of FIG. 4 by the sputter method.
  • a pattern layer was manufactured in the same manner as in Example 1, and the molybdenum was deposited to a thickness of 100 nm by tilting toward the first inclined surface of the pattern layer to form a first inorganic layer 201, and then tilted toward the second inclined surface to form aluminum by 300 nm. By depositing to form a second inorganic layer 202.
  • the pattern layer was formed in a structure in which the asymmetric prism structure was repeated as shown in FIG. 16, and the inclination angle of one side of the pattern was 60 °, and the inclination angles of the opposite side were 40 ° (Example 5) and 30 ° (Example 6) A sample was prepared at 20 ° (Example 7). At this time, the pitch of the patterns was 100 micrometers and the height of the pattern was 25 micrometers. Light is incident on the substrate side of the obtained sample, and the light passing through the light absorption layer and reflected by the light reflection layer can be observed on the substrate side. The thickness and color of the light absorption layer observed from the obtained sample are shown in FIG. 17. The n and k values of the aluminum oxynitride layer are described in FIG. 18.
  • the pattern layer was formed in a structure in which a symmetrical prism structure was repeated.
  • the inclination angle of one side of the pattern was 45 °, and the same inclination was performed as in Example 5 except that the opposite inclination angle was 45 °. .
  • the pattern was formed of a structure in which a symmetrical prism structure was repeated.
  • the inclination angle of one side of the pattern was 45 ° and the inclination angle of the opposite side was 45 °.
  • the pitch of the patterns was 100 micrometers and the height of the pattern was 25 micrometers.
  • the deposition thickness of the light absorption layer on the left slope was 19.0 nm and the deposition thickness of the light absorption layer on the right slope was 12.2 nm based on the vertex of the triangle of the cross section of the light absorption layer.
  • the photograph of the color of the direction perpendicular to the inclined surface of the obtained sample is shown in FIG.
  • the pattern was formed in the same manner as in Example 8 except that the shape of the pattern was formed to have a symmetrical inclined surface having a double-sided symmetry, and the deposition thickness of the light absorbing layer on the inclined surface of the light absorbing layer was uniformed to 6.3 nm.
  • the photograph of the color of the direction perpendicular to the inclined surface of the obtained sample is shown in FIG.
  • the dichroic luminous evaluation was evaluated about the Examples 1-4 and the comparative example 1 by visual inspection.
  • 5 (a) and 5 (b) are photographs of the right view and the left view of Example 1, respectively.
  • FIG. 30 is a view showing a color change according to a viewing angle of a decorative member according to Example 1 and a decorative member according to Comparative Example 1.
  • FIG. 30 is a view showing a color change according to a viewing angle of a decorative member according to Example 1 and a decorative member according to Comparative Example 1.
  • the decorative member according to Example 1 exhibits dichroism showing different colors depending on the viewing angle, whereas the decorative member according to Comparative Example 1 shows only one color.
  • FIG. 31 shows brightness values (L *), color values (* a), and saturation values (*) according to viewing angles in the CIE L * a * b color space of the decorative member according to Example 1 and the decorative member according to Comparative Example 1.
  • FIG. b) measured and compared.
  • Example 1 In the case of Example 1, it was confirmed that the brightness value (L *) and the saturation value (* b) change greatly as the viewing angle changes.
  • the color visually recognized through the air of the decorative members manufactured in these examples was calculated using the reflectance in the visible region (SCI, Specular Component Included) measured by Konica Minolta's CM-2600d equipment. Specific color conversion conditions were based on D65 light source and 10 ° observer. The calculated result is shown in FIG. In this case, the thicknesses of the light absorbing layer at the low angle and at the high angle were 30 nm and 10 nm in Example 10, and 80 nm and 30 nm in Example 11, respectively. 140 nm / 50 nm, respectively.
  • Example 27 shows the result of calculating the color visually recognized through the air of the decorative member manufactured in these Examples as in Example 10.
  • the thickness of the side visible at the low angle and the side of the light absorption layer was 30 nm and 10 nm in Example 13, respectively
  • Example 14 was 80 nm and 30 nm, respectively
  • Example 15 was 140 nm and 50 nm, respectively.
  • Example 26 shows the result of calculating the color visually recognized through the air of the decorative member manufactured in these examples as in Example 10.
  • the thicknesses of the light absorbing layer at the low angle and at the high angle were 30 nm and 10 nm in Example 16, and 80 nm and 30 nm in Example 17, respectively. 140 nm and 50 nm, respectively.
  • the solution in which the red pigment was dispersed on the glass was formed in the same manner as in Examples 10 to 12 except that the red color film was formed by a wet coating process before the light absorption layer was formed, not on the light absorption layer. .
  • Example 10 The color visually recognized through the glass of the decorative member manufactured by these Examples was calculated like Example 10, and is shown in FIG.
  • the thicknesses of the light absorbing layer at the low angle and at the high angle were 30 nm and 10 nm in Example 19 and 80 nm and 30 nm in Example 20, respectively. 140 nm and 50 nm, respectively.
  • Example 10 The color visually recognized through the glass of the decorative member manufactured in Examples 13-15 was calculated as in Example 10, and is shown in FIG. 28.
  • the thicknesses of the light absorbing layer at the low angle and at the high angle were 30 nm and 10 nm in Example 22 and 80 nm and 30 nm in Example 23, respectively. 140 nm and 50 nm, respectively.
  • Example 10 The color visually recognized through the glass of the decorative member manufactured in Examples 16-18 was calculated as in Example 10, and is shown in FIG. 28.
  • the thickness of the light absorbing layer at the low angle and the side at the high angle was 30 nm and 10 nm in Example 25 and 80 nm and 30 nm in Example 26, respectively. 140 nm and 50 nm, respectively.
  • an aluminum oxynitride layer was formed as a light absorption layer by using reactive sputtering deposition.
  • the deposition process was performed under a base pressure of 3 ⁇ 10 ⁇ 6 Torr and a process pressure of 3 mTorr vacuum, Ar gas was adjusted to 100 sccm, and reactive gas N 2 was adjusted to 14 sccm.
  • An aluminum layer was deposited to a thickness of 100 nm on the light absorption layer as a light reflection layer. 29 shows the result of comparing the color observed through the glass for the decorative member thus prepared.
  • the hard mold was processed to have the pattern of the structure of FIG.
  • a pattern layer having the structure of FIG. 32 was formed by coating a composition including an acrylic resin on a polyethylene terephthalate (PET) substrate layer, pressing the hard mold, and curing the UV mold with ultraviolet rays.
  • PET polyethylene terephthalate
  • Aluminum was deposited to a thickness of 200 nm on the upper part of the pattern layer to form an inorganic layer to prepare a decorative member.
  • Both inclination angles of the convex portions of the decorative member of each embodiment are 20 degrees and 70 degrees (Example 29), 10 degrees and 70 degrees (Example 30), 20 degrees and 80 degrees (Example 31), 30 degrees and 70 degrees, respectively. (Example 32), 30 degrees, and 60 degrees (Example 33), and width is 30 micrometers.
  • FIG. 42 (Example 29), FIG. 43 (Example 30), FIG. 44 (Example 31), and FIG. 45 (Example 32) by measuring the values of L *, a *, and b * according to the viewing angle of each example.
  • FIG. 46 (Example 33).
  • the hard mold was processed so as to have patterns of the structures of FIGS. 33A and 33B, respectively.
  • the cross section of the convex portion included a first inclined side and a second inclined side having different inclination angles, the first inclined side includes a straight line, and the second inclined side has a curved shape.
  • the inclination angle between the first inclined side and the ground was 70 degrees, and the line segment and the ground angle were 20 degrees when the top point of the second inclined side and the point where the second inclined side were in contact with the ground were connected.
  • the details of the shape of the curve and the radius of curvature are as described above.
  • the hard mold was processed to have a pattern of the structure of FIGS. 34 and 36.
  • the cross section of the convex portion has a trapezoidal shape in which a pair of opposite sides are parallel and include a first inclined side and a second inclined side.
  • the cross-sectional shape may have a trapezoidal shape.
  • Example 36 shows a pattern layer prepared when the ratio of L1: L2 is 1: 1, and Example 37 is the ratio of L1: L2 is 2: 1.
  • the inclination angle between the first inclination edge and the ground was 20 degrees, and the angle between the second inclination edge and the ground was 70 degrees.
  • the values of L *, a * and b * according to the viewing angle of each example were measured and shown in FIGS. 49 (Example 36) and 50 (Example 37).
  • the hard mold was processed to have a pattern of the structure of Figs. 35 (a) and (b).
  • Example 38 showed the form of the pattern of FIG. 35 (a), and Example 39 (b).
  • the inclination angle c1 was 70 degrees and c2 was 20 degrees. Details of D1 to D3 are as described above.
  • the hard mold was processed to have a pattern of the structure of FIG. 40.
  • C1 was 20 degrees and c2 was 70 degrees.
  • the values of L *, a *, and b * according to the viewing angle of Example 40 were measured and shown in FIG. 53.
  • FIGS. 42 to 54 shows the values of L *, a *, and b * according to the viewing angle of Comparative Example 3.
  • FIG. 54 shows the values of L *, a *, and b * according to the viewing angle of Comparative Example 3.
  • the color difference E * ab in the L * a * b * space can be greatly expressed by largely changing any one or more of L *, a *, and b *.
  • Coordinates may be represented by ( ⁇ , ⁇ ).
  • the x-axis is perpendicular to the plane direction of the decorative member and the y-axis is any one of the plane direction of the decorative member
  • the angle formed by the x-axis and the viewing direction is ⁇
  • the angle formed by the y-axis and the viewing direction is ⁇ . It is called.
  • phi was 0 degrees ( ⁇ , 0)
  • the L *, a * and b * values according to the change of ⁇ were measured.
  • IES type B Reference [IES-LM-75-01 Goniophotometer Types and Photometric Coordinates (title), IES (author), (Illuminating Engineering Society of North America, 2001)]. This is illustrated in FIG. 55.
  • P1 Convex portion or first convex portion
  • P2 Second convex portion
  • P3 Concave portion
  • P4 Third convex portion 10: Pattern layer 201: First inorganic layer 202: Second inorganic layer H1, H2, H3: Height W1 , W2, W3: Width, S1, S2, S3, S4, S5, S6: Inclined surface, a1, a4, a7: Vertex angle, a2, a3, a5, a6, a8, a9: Inclined angle
  • C1 First area
  • C2 First 2 zones

Landscapes

  • Laminated Bodies (AREA)
  • Finishing Walls (AREA)

Abstract

La présente invention concerne un élément décoratif et un procédé de fabrication de l'élément décoratif. La présente invention concerne : un élément décoratif ayant un dichroïsme dans lequel différentes couleurs dichroïques sont présentées selon les directions de visualisation de l'élément décoratif, les couleurs dichroïques ayant une visibilité améliorée ; et un procédé de fabrication de l'élément décoratif.
PCT/KR2018/002671 2017-03-06 2018-03-06 Élément décoratif et procédé de fabrication d'élément décoratif Ceased WO2018164463A1 (fr)

Priority Applications (4)

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US16/465,106 US11376888B2 (en) 2017-03-06 2018-03-06 Decorative member and method for manufacturing decorative member
JP2019524888A JP6870815B2 (ja) 2017-03-06 2018-03-06 装飾部材および装飾部材の製造方法
CN201880013619.2A CN110382253B (zh) 2017-03-06 2018-03-06 装饰构件及装饰构件的制造方法
EP18763746.7A EP3594016A4 (fr) 2017-03-06 2018-03-06 Élément décoratif et procédé de fabrication d'élément décoratif

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KR10-2017-0028261 2017-03-06
KR20170028261 2017-03-06
KR10-2017-0136790 2017-10-20
KR1020170136790A KR101966851B1 (ko) 2017-03-06 2017-10-20 장식 부재 및 이의 제조방법
KR10-2017-0160298 2017-11-28
KR20170160298 2017-11-28

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JP7777987B2 (ja) 2020-02-04 2025-12-01 三井金属株式会社 キャリア付金属箔

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KR102306984B1 (ko) * 2018-09-28 2021-09-29 주식회사 엘지화학 장식 부재
KR102332417B1 (ko) * 2020-12-30 2021-12-01 에스케이씨하이테크앤마케팅(주) 컬러 가변형 데코레이션 시트 및 이의 제조방법

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JP7777987B2 (ja) 2020-02-04 2025-12-01 三井金属株式会社 キャリア付金属箔
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