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WO2018012595A1 - Composition répulsive contre des organismes nuisibles et procédé pour repousser des organismes nuisibles - Google Patents

Composition répulsive contre des organismes nuisibles et procédé pour repousser des organismes nuisibles Download PDF

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Publication number
WO2018012595A1
WO2018012595A1 PCT/JP2017/025574 JP2017025574W WO2018012595A1 WO 2018012595 A1 WO2018012595 A1 WO 2018012595A1 JP 2017025574 W JP2017025574 W JP 2017025574W WO 2018012595 A1 WO2018012595 A1 WO 2018012595A1
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WIPO (PCT)
Prior art keywords
component
pest repellent
repellent composition
mass
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
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PCT/JP2017/025574
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English (en)
Japanese (ja)
Inventor
昇子 中嶋
耕平 松本
達也 亀澤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lion Corp
Original Assignee
Lion Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lion Corp filed Critical Lion Corp
Priority to KR1020187026884A priority Critical patent/KR102387616B1/ko
Priority to MYPI2018003014A priority patent/MY199207A/en
Priority to CN201780031755.XA priority patent/CN109310079A/zh
Priority to JP2018527665A priority patent/JP6971983B2/ja
Publication of WO2018012595A1 publication Critical patent/WO2018012595A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M29/00—Scaring or repelling devices, e.g. bird-scaring apparatus
    • A01M29/12—Scaring or repelling devices, e.g. bird-scaring apparatus using odoriferous substances, e.g. aromas, pheromones or chemical agents
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A01N25/10—Macromolecular compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/24—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients to enhance the sticking of the active ingredients
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02—Amines; Quaternary ammonium compounds
    • A01N33/12—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/16—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof the nitrogen atom being part of a heterocyclic ring

Definitions

  • the present invention relates to a pest repellent composition and a pest repellent method.
  • This application claims priority on July 15, 2016 based on Japanese Patent Application No. 2016-140794 for which it applied to Japan, and uses the content here.
  • Patent Document 1 proposes a pest repellent composition containing an antibacterial compound and a repellent active ingredient. According to the invention described in Patent Document 1, the repellent efficacy of the repellent active ingredient is enhanced by the antibacterial compound.
  • An object of the present invention is to provide a pest repellent composition having an excellent pest repellent effect and a pest repellent method using the same.
  • a pest repellent composition comprising (A) component and at least one component selected from the group consisting of (B) component, (C) component, and (D) component,
  • the component (A) is a repellent active ingredient
  • the component (B) is an antioxidant component
  • the component (C) is a chelating agent
  • the pest repellent composition wherein the component (D) is at least one polymer compound selected from the group consisting of polyvinyl pyrrolidone and a vinyl acetate / vinyl pyrrolidone copolymer.
  • a pest repellent composition having an excellent pest repellent effect and a pest repellent method using the same can be provided.
  • connection cage used in the Example.
  • the pest repellent composition of the present invention includes (A) component and at least one component selected from the group consisting of (B) component, (C) component, and (D) component.
  • the component (A) is a component having a pest repellent effect.
  • the component (A) is not particularly limited, and examples thereof include icaridin (1-methylpropyl 2- (2-hydroxyethyl) -1-piperidinecarboxylate), diet (N, N-diethyl-3-methylbenzamide), 3 -(Nn-butyl-N-acetyl) aminopropionic acid ethyl ester (IR3535), p-menthane-3,8-diol, lemon eucalyptus oil, citronella oil and the like.
  • icaridin is preferable in terms of skin feel and odor when applied to the skin.
  • a component may be used individually by 1 type and may be used in combination of 2 or more type.
  • the content of the component (A) is preferably 1 to 80% by mass, more preferably 5 to 30% by mass with respect to the total mass of the pest repellent composition.
  • it is preferably 1 to 30% by mass, more preferably 5 to 20% by mass, based on the total mass of the pest repellent composition.
  • it is preferably 5 to 50% by mass, more preferably 10 to 30% by mass, based on the total mass of the pest repellent composition.
  • antioxidant component is an antioxidant component and enhances the repellent effect.
  • Antioxidant components include sugars or sugar alcohols such as trehalose, xylitol, sorbitol, maltitol, xylose, mannitol; vitamins such as vitamin A, vitamin E, vitamin C and their derivatives; amino acids such as tyrosine, tryptophan, methionine, histidine And peptides. Among these, trehalose, sorbitol, and maltitol are preferable.
  • a component may be used individually by 1 type and may be used in combination of 2 or more type.
  • the content of the component (B) is preferably 0.1 to 10% by mass with respect to the total mass of the pest repellent composition, and 0.5 to 5%. More preferably, it is more preferably 1 to 3% by mass.
  • content of a component is below the said upper limit, there is no stickiness and a usability
  • the mass ratio represented by the component (A) / the component (B) (hereinafter also referred to as A / B ratio) is preferably 0.1 to 800. 0.1 to 100 is more preferable, and 0.5 to 30 is more preferable. If the A / B ratio is within the above range, the repellent effect is easily exhibited.
  • the component (C) is a chelating component and enhances the repellent effect.
  • an ethylenediamine acetic acid chelating agent, an organic acid chelating agent, and a phosphoric acid chelating agent are preferable.
  • the ethylenediamineacetic acid type chelating agent include ethylenediamineacetic acid derivatives or salts thereof.
  • edetic acid ethylenediaminetetraacetic acid, EDTA
  • EDDA ethylenediaminediacetic acid
  • DTPA diethylenetriaminepentaacetic acid
  • HEDTA N- (2-hydroxyethyl) ethylenediaminetriacetic acid
  • physiologically acceptable salt for example, sodium salt such as sodium ethylenediaminetetraacetate, potassium salt, magnesium salt, calcium salt, etc.
  • ethylenediaminetetraacetic acid or a salt thereof is preferable, and specific examples include disodium ethylenediaminetetraacetic acid, disodium ethylenediaminetetraacetic acid dihydrate (hereinafter also referred to as sodium edetate), and the like.
  • the organic acid type chelating agent include maleic acid, tartaric acid, citric acid, succinic acid, gluconic acid and the like, and may be used as a pharmacologically or physiologically acceptable salt.
  • the phosphoric acid chelating agent include phosphoric acid, sodium polyphosphate, metaphosphoric acid and the like, and may be used as a pharmacologically or physiologically acceptable salt. Of these, citric acid and sodium citrate are preferable.
  • a component may be used individually by 1 type and may be used in combination of 2 or more type.
  • the component (C) is a counter ion salt (monosodium salt, trisodium salt, tripotassium salt, etc.) or a hydrate (monohydrate etc.), the mass fluctuation becomes large. Therefore, in this application, it describes with the content converted into “anhydrate” (henceforth "acid conversion") in the state of the "acid” which is not neutralized.
  • the content of the component (C) is “acid conversion” and is 0.01 to 3% by mass with respect to the total mass of the pest repellent composition. Preferably, 0.05 to 2% by mass is more preferable. It is easy to suppress that (C) component precipitates or skin irritation arises as content of (C) component is below the above-mentioned upper limit. When it is at least the lower limit, the effect of component (C) can be easily obtained.
  • the content of citric acid or sodium citrate is “acid equivalent” and is 0.01 to about the total mass of the pest repellent composition. 3% by mass is preferred, 0.1-2% by mass is more preferred, and 0.2-1% by mass is even more preferred. It can suppress that citric acid or sodium citrate precipitates, and skin irritation arises that content of a citric acid or sodium citrate is below the said upper limit. When it is at least the above lower limit value, the repelling effect is easily exhibited.
  • the content of EDTA or a salt thereof is “acid conversion” and is 0.03 to 0.5 mass relative to the total mass of the pest repellent composition. % Is preferable, and 0.05 to 0.3% by mass is more preferable. It can suppress that EDTA or its salt precipitates, or skin irritation arises that EDTA or its salt is below the said upper limit. When it is at least the above lower limit value, the repelling effect is easily enhanced.
  • the component (C) is “acid-converted” and the mass ratio represented by the component (A) / component (C) (hereinafter referred to as A / C ratio). Is also preferably from 0.1 to 8000, more preferably from 1 to 1000, and even more preferably from 5 to 200. If the A / C ratio is within the above range, the repellent effect is easily exhibited.
  • the (C) component is “acid-converted” and the mass ratio represented by (B) component / (C) component (
  • the ratio (hereinafter also referred to as B / C ratio) is preferably 0.01 to 1000, more preferably 0.1 to 200, and further preferably 1 to 50. If the B / C ratio is within the above range, the repellent effect is easily exhibited.
  • ⁇ (D) component at least one polymer compound selected from the group consisting of polyvinylpyrrolidone and vinyl acetate / vinylpyrrolidone copolymer>
  • the component (D) include at least one polymer compound selected from the group consisting of polyvinyl pyrrolidone and vinyl acetate / vinyl pyrrolidone copolymers.
  • polyvinylpyrrolidone those having a weight average molecular weight of 8,000 to 3,000,000 can be used. Particularly, those having a weight average molecular weight of 2,000,000 or less are soluble, feel in use, and have a long-lasting deodorizing effect. Is preferable.
  • the weight average molecular weight is obtained by converting the K value defined in the United States Pharmacopeia USP into the weight average molecular weight measured by the light scattering method.
  • Rubiscol K17 weight average molecular weight: about 9,000
  • Rubiscol K30 weight average molecular weight: about 45,000
  • Rubiscol K90 weight average molecular weight: about 1,600,000
  • BASF BASF
  • PVPK-15 weight average molecular weight: 8,000
  • PVPK-30 weight average molecular weight: 60,000
  • PVPK-60 weight average molecular weight: 400,000
  • PVPK-90 weight average) Molecular weight: 1,300,000
  • PVPK-120 weight average molecular weight: 3,000,000
  • the copolymerization molar ratio (VP / VA) of vinyl pyrrolidone and vinyl acetate in the vinyl acetate / vinyl pyrrolidone copolymer is preferably in the range of 7/3 to 3/7.
  • those having a copolymerization molar ratio (VP / VA) of 7/3 or 6/4 are preferable from the viewpoints of solubility, feeling of use, and sustainability of the deodorizing effect.
  • Commercially available products include PVP / VA S-630 (VP / VA molar ratio 6/4), PVP / VA E-735 (VP / VA molar ratio 7/3), PVP / VA E-535 (VP / VA molar ratio).
  • a component may be used individually by 1 type and may be used in combination of 2 or more type.
  • the weight average molecular weight of the vinyl acetate / vinyl pyrrolidone copolymer is preferably 200 to 80,000, and more preferably 40,000 to 70,000.
  • the weight average molecular weight is obtained by converting the K value defined in the United States Pharmacopeia USP into the weight average molecular weight measured by the light scattering method.
  • the content of the component (D) is preferably 0.1 to 3% by mass with respect to the total mass of the pest repellent composition, 0.2 to 1 The mass% is more preferable.
  • the content of the component (D) is within the above range, the repellent effect is highly durable and there is no stickiness and the feeling of use is good.
  • the mass ratio represented by the component (A) / (D) component is preferably 0.1 to 800. 1 to 200 is more preferable, and 5 to 50 is more preferable. If the A / D ratio is within the above range, the repellent effect is easily exhibited.
  • the mass ratio represented by the component (B) / (D) component (hereinafter also referred to as B / D ratio) is 0. 0.01 to 200 is preferable, 1 to 100 is more preferable, and 1 to 30 is more preferable. If the B / D ratio is within the above range, the repellent effect is easily exhibited.
  • the (C) component is “acid-converted” and the mass ratio represented by (C) component / (D) component (
  • the C / D ratio is preferably 0.001 to 50, more preferably 0.005 to 30, and still more preferably 0.1 to 10. If the C / D ratio is within the above range, the repellent effect is easily exhibited.
  • the other components excluding the components (A) to (D) include, for example, an antibacterial compound (hereinafter also referred to as the (E) component), a surfactant (hereinafter also referred to as the (F) component), a solvent, and a moisturizing agent. And additives such as agents, thickeners, dyes, pH adjusters, fragrances, ultraviolet absorbers, and ultraviolet scattering agents.
  • the phenolic antibacterial component include isopropylmethylphenol (3-methyl-4-isopropylphenol), ortho-phenylphenol, and the like.
  • the quaternary ammonium salt antibacterial component include benzalkonium chloride and benzethonium chloride.
  • Examples of the biguanide antibacterial component include chlorhexidine hydrochloride and polyhexamethylene biguanide hydrochloride.
  • Organic nitrogen sulfur antibacterial components include 5-chloro-2-methyl-4-isothiazolin-3-one, 2-methyl-4-isothiazolin-3-one, 2-mercaptobenzothiazole, 2-n-octyl-4- Examples thereof include isothiazoline-3-one and 1,2-benzisothiazolin-3-one.
  • other component (E) include triclosan, diclosan, 2-bromo-2-nitropropane-1,3-diol, lichlorocarbanilide, piroctone olamine, and clara extract.
  • a phenolic antibacterial component and a quaternary ammonium salt antibacterial component are preferable, and isopropylmethylphenol and benzalkonium chloride are more preferable.
  • the antibacterial compound may be used alone or in combination of two or more, and it is preferable to use a phenolic antibacterial component and a quaternary ammonium salt antibacterial component in combination. More preferably, phenol and benzalkonium chloride are used in combination.
  • the content of the component (E) is preferably 0.001 to 1% by mass with respect to the total mass of the pest repellent composition, and 0.01 to 0 More preferable is 5% by mass. If content of (E) component exists in the said range, a repelling effect will be easy to be exhibited.
  • the mass ratio represented by the component (B) / (E) component (hereinafter also referred to as B / E ratio) is 0. 0.01 to 1000 is preferable, 1 to 500 is more preferable, and 5 to 200 is more preferable. If the B / E ratio is within the above range, the repellent effect is easily exhibited.
  • the (C) component is “acid-converted” and the mass ratio represented by (C) component / (E) component (
  • the C / E ratio is preferably 0.005 to 300, and more preferably 0.1 to 100.
  • the mass ratio represented by the component (D) / (E) component (hereinafter also referred to as D / E ratio) is 0. .05 to 100 is preferable, and 0.5 to 10 is preferable.
  • D / E ratio is within the above range, the repelling effect is easily exhibited.
  • anionic surfactants examples include fatty acid soap, alkylbenzene sulfonate, linear alkylbenzene sulfonate, alkyl sulfate, alpha olefin sulfonate, alkyl phosphate ester salt, polyoxyethylene alkyl ether sulfate, polyoxyethylene
  • examples thereof include alkyl ether carboxylates, polyoxyethylene alkyl phenyl ether sulfates, polyoxyethylene alkyl ether phosphates, alkyl sulfosuccinates, polyoxyethylene alkyl sulfosuccinates, and the like.
  • Nonionic surfactants include, for example, polyoxyalkylene alkyl ether, polyoxyethylene alkylphenyl ether, polyoxyethylene higher fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene hydrogenated castor oil, Examples include coconut oil fatty acid diethanolamide, fatty acid alkanolamide, and amine oxide.
  • amphoteric surfactants include alkyl carbobetaines, alkylamide carbobetaines, alkylsulfobetaines, alkylhydroxysulfobetaines, alkylamide sulfobetaines, alkylamide hydroxysulfobetaines, and the like.
  • Nonionic surfactants are preferable from the viewpoint of irritation to the skin and stability improvement at low temperatures, and polyoxyethylene hydrogenated castor oil is more preferable.
  • the average oxyethylene group of the nonionic surfactant is preferably an addition product of 10 to 100 moles from the viewpoint of stability at low temperatures.
  • a component may be used individually by 1 type and may be used in combination of 2 or more type.
  • the content of the component (F) is preferably 0.1 to 10% by mass with respect to the total mass of the pest repellent composition, and 0.1 to 5%. More preferred is mass%.
  • the content of the component (F) is within the above range, stickiness due to the component (F) is suppressed, and stability at a low temperature is improved.
  • Solvents include alcohol solvents such as ethanol, hydrocarbon solvents such as n-paraffin and isoparaffin, glycols such as propylene glycol, 1,3-butylene glycol, dipropylene glycol and diethylene glycol monobutyl ether, glycol ethers, ketones
  • a system solvent, an ester system solvent, water, etc. can be mix
  • a solvent may be used individually by 1 type and may be used in combination of 2 or more type. Ethanol is preferred from the viewpoint of irritation to the skin, odor, feeling of use (easy to dry) and repellent effect.
  • the ethanol content is preferably 0 to 90% by mass with respect to the total mass of the pest repellent composition, and 30 to 50% by mass is a feeling of use (easy to dry). ), More preferable from the viewpoint of skin irritation. If the content of ethanol is within the above range, the repellent effect is easily exhibited.
  • the pest repellent composition of the present invention can be appropriately mixed with water.
  • the thickener (excluding the component (D)) is not particularly limited as long as it is used in cosmetics, quasi-drugs and pharmaceuticals, natural water-soluble polymers, semi-synthetic water-soluble polymers, Examples include synthetic water-soluble polymers and inorganic water-soluble polymers.
  • natural water-soluble polymers include plant polymers such as gum arabic, gum tragacanth, galactan, guar gum, xanthan gum, carob gum, locust bean gum, caraya gum, carrageenan, pectin, agar, quince seed, alge colloid, starch, and dextran.
  • microbial polymers such as dextrin, succinoglucan and pullulan
  • animal polymers such as collagen, casein, albumin and gelatin.
  • semi-synthetic water-soluble polymers include starch polymers such as carboxymethyl starch and methylhydroxypropyl starch, methylcellulose, nitrocellulose, ethylcellulose, methylhydroxypropylcellulose, hydroxyethylcellulose, sodium cellulose sulfate, hydroxypropylcellulose, carboxy Examples thereof include cellulose polymers such as sodium methylcellulose (CMC), crystalline cellulose and cellulose powder, and alginic acid polymers such as sodium alginate and propylene glycol alginate.
  • CMC sodium methylcellulose
  • crystalline cellulose and cellulose powder alginic acid polymers
  • Examples of the synthetic water-soluble polymer include vinyl polymers such as polyvinyl alcohol, polyvinyl methyl ether, and carboxyvinyl polymer (carbomer), polyoxyethylene polymers such as polyethylene glycol (molecular weight 1500, 4000, 6000, etc.), Examples thereof include polyoxyethylene polyoxypropylene copolymer polymers, acrylic polymers such as sodium polyacrylate and polyethyl acrylate, polyethyleneimine, and cationic polymers.
  • Examples of the inorganic water-soluble polymer include bentonite, AlMg silicate, laponite, hectorite, and silicic anhydride.
  • a thickener may be used individually by 1 type and may be used in combination of 2 or more type.
  • Perfumes include peppermint oil, spearmint oil, anise oil, eucalyptus oil, winter green oil, cassia oil, clove oil, thyme oil, sage oil, lemon oil, orange oil, peppermint oil, cardamom oil, coriander oil, mandarin oil, Lime oil, lavender oil, rosemary oil, laurel oil, camomil oil, caraway oil, marjoram oil, bay oil, lemongrass oil, origanum oil, pine needle oil, neroli oil, rose oil, jasmine oil, iris concrete, absolute Natural fragrance ingredients such as peppermint, absoluteton rose and orange flower; processed fragrance ingredients of these natural fragrance ingredients; menthol, carvone, anethole, cineol, methyl salicylate, cinnamic aldehyde, eugenol, 2-diol, pinene, Chi le aldehyde, citral, pulegone, Cal beer acetate, separately perfume ingredients such as anisalde
  • flavor may be used individually by 1 type and may be used in combination of 2 or more type.
  • the total content of the component (A) and at least one component selected from the group consisting of the component (B), the component (C), and the component (D) is 100. Does not exceed mass%.
  • the pH at 25 ° C. of the pest repellent composition of the present invention is preferably from 3 to 9, more preferably from 5 to 8, from the viewpoint of repellent effect and low irritation to the skin.
  • the pH can be measured by a usual method using a pH meter (manufactured by Toa Denpa Kogyo Co., Ltd., HM-30G).
  • the pest repellent composition of the present invention comprises (A) component and at least one component selected from the group consisting of (B) component, (C) component, and (D) component,
  • the component is at least one selected from the group consisting of icaridin and diet, and the component (B) is at least one selected from the group consisting of trehalose, sorbitol, and maltitol, and the component (C) is It is at least one selected from the group consisting of citric acid and sodium citrate, and the component (D) is at least one selected from the group consisting of polyvinyl pyrrolidone and vinyl acetate / vinyl pyrrolidone copolymer. Is preferred.
  • the pest repellent composition of the present invention comprises (A) component and at least one component selected from the group consisting of (B) component, (C) component, and (D) component,
  • the component is at least one selected from the group consisting of icaridin and diet, and the component (B) is at least one selected from the group consisting of trehalose, sorbitol, and maltitol, and the component (C) is It is at least one selected from the group consisting of citric acid and sodium citrate, and the component (D) is at least one selected from the group consisting of polyvinyl pyrrolidone and vinyl acetate / vinyl pyrrolidone copolymer,
  • the content of the component (A) is 1 to 80% by mass with respect to the total mass of the pest repellent composition, and the content of the component (B) is 0.1 to 10% by mass,
  • Serial and (C) content is "acid conversion" components is from 0.01 to 3 wt%, the content of component (D) is
  • the pest repellent composition of the present invention comprises (A) component and at least one component selected from the group consisting of (B) component, (C) component, and (D) component,
  • the component is at least one selected from the group consisting of icaridin and diet, the component (B) is trehalose, and the component (C) is at least one selected from the group consisting of citric acid and sodium citrate.
  • the component (D) is a vinyl acetate / vinyl pyrrolidone copolymer.
  • the pest repellent composition of the present invention comprises (A) component and at least one component selected from the group consisting of (B) component, (C) component, and (D) component,
  • the component is at least one selected from the group consisting of icaridin and diet, the component (B) is trehalose, and the component (C) is at least one selected from the group consisting of citric acid and sodium citrate.
  • the component (D) is a vinyl acetate / vinyl pyrrolidone copolymer, and the content of the component (A) is 1 to 80% by mass relative to the total mass of the pest repellent composition, B) content of component is 0.1 to 10% by mass, content of said (C) component is 0.01 to 3% by mass in terms of “acid conversion”, content of said (D) component The amount is preferably 0.1 to 3% by mass.
  • the pest repellent composition of the present invention comprises (A) component, at least one component selected from the group consisting of (B) component, (C) component, and (D) component, and (E) component.
  • the component (A) is at least one selected from the group consisting of icaridin and diet, the component (B) is trehalose, and the component (C) is from the group consisting of citric acid and sodium citrate.
  • the pest repellent composition of the present invention comprises (A) component, at least one component selected from the group consisting of (B) component, (C) component, and (D) component, and (E) component.
  • the component (A) is at least one selected from the group consisting of icaridin and diet, the component (B) is trehalose, and the component (C) is from the group consisting of citric acid and sodium citrate.
  • the amount of the component (A) is 1 to 80% by mass and the content of the component (B) is 0.1 to 10% by mass with respect to the total mass of the pest repellent composition.
  • the content of the component (C) is 0.01 to 3% by mass in terms of acid
  • the content of the component (D) is 0.1 to 3% by mass
  • the component (E) The content is preferably 0.001 to 1% by mass.
  • the method for preparing the pest repellent composition of the present invention includes a method of mixing the component (A) with at least one selected from the group consisting of the component (B), the component (C), and the component (D). It is done. Further, a method of dissolving in a solvent at least one selected from the group consisting of the component (A), the component (B), the component (C), and the component (D) and, if necessary, other components Is mentioned.
  • the pest repellent composition of the present invention can be used in a dosage form such as an emulsion, cream, gel, or spray (solution).
  • a dosage form such as an emulsion, cream, gel, or spray (solution).
  • the content of the pest repellent composition of the present invention in an emulsion, cream or gel is preferably 1 to 100% by mass with respect to the total mass of the emulsion, cream or gel.
  • the content of the pest repellent composition of the present invention in the solution is preferably 1 to 100% by mass relative to the total mass of the solution.
  • the pest repellent composition of the present invention exerts a repellent effect on pests when applied to the skin, for example.
  • the method of using the pest repellent composition of the present invention includes a step of attaching an effective amount of the pest repellent composition of the present invention to the skin or clothing of a subject in need of pest repellent.
  • effective amount and is preferably 0.1 ⁇ 10mg / cm 2, more preferably 0.5 ⁇ 5mg / cm 2.
  • subjects that need to avoid pests include humans and animals.
  • the attaching method include coating and spraying.
  • the pests to be repelled by the pest repellent composition of the present invention include mosquitoes, gnats, sand flies, house dust mites, bed bugs, ticks, and tsutsugamushi. Of these, mosquitoes are preferred.
  • Repellency rate (%) ⁇ 1 ⁇ (number of entries at application ⁇ number of correction entries) / (number of entries without application ⁇ number of correction entries) ⁇ ⁇ 100
  • the number of corrected entries is the number of mosquito entries under the condition that the arm is not inserted. When the number of entries became negative after correction, it was evaluated as 0. (Evaluation criteria)
  • ⁇ : Repelling rate is 50% or more and less than 70.
  • X Repelling rate is less than 50%.
  • Table 3 shows formulation examples of the pest repellent composition of the present invention other than Examples 1 to 8.
  • a pest repellent composition having an excellent pest repellent effect and a pest repellent method using the same can be provided.

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  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Pest Control & Pesticides (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Toxicology (AREA)
  • Birds (AREA)
  • Insects & Arthropods (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

La présente invention concerne une composition répulsive contre des organismes nuisibles comprenant un constituant (A) et au moins un constituant choisi dans le groupe constitué par les constituants (B), (C) et (D), le constituant (A) étant un constituant apte à repousser efficacement, le constituant (B) étant un constituant antioxydant, le constituant (C) étant un agent de chélation, et le constituant (D) étant au moins un composé polymère choisi dans le groupe constitué par le poly(vinyl pyrrolidone) et un copolymère d'(acétate de vinyle)-(vinyl pyrrolidone).
PCT/JP2017/025574 2016-07-15 2017-07-13 Composition répulsive contre des organismes nuisibles et procédé pour repousser des organismes nuisibles Ceased WO2018012595A1 (fr)

Priority Applications (4)

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KR1020187026884A KR102387616B1 (ko) 2016-07-15 2017-07-13 해충 기피 조성물, 및 해충 기피 방법
MYPI2018003014A MY199207A (en) 2016-07-15 2017-07-13 Pest repellent composition, and method for repelling pests
CN201780031755.XA CN109310079A (zh) 2016-07-15 2017-07-13 害虫驱避组合物以及害虫驱避方法
JP2018527665A JP6971983B2 (ja) 2016-07-15 2017-07-13 害虫忌避組成物、及び害虫忌避方法

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JP2022075638A (ja) * 2020-11-06 2022-05-18 丸住製紙株式会社 防虫組成物、防虫剤および害虫忌避方法
JP2022098431A (ja) * 2020-12-21 2022-07-01 大日本除蟲菊株式会社 害虫忌避組成物
JP2022176243A (ja) * 2018-06-27 2022-11-25 大日本除蟲菊株式会社 衣料害虫産卵予防用スプレー剤、及び衣料害虫産卵予防方法
JP2023021618A (ja) * 2021-08-02 2023-02-14 大日本除蟲菊株式会社 シラミ忌避剤
TWI799669B (zh) * 2018-12-26 2023-04-21 日商大日本除蟲菊股份有限公司 消臭組成物及消臭方法，以及惡臭害蟲防除用組成物及惡臭害蟲防除方法

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US10966424B1 (en) * 2019-10-04 2021-04-06 Global Biolife Inc. Insect repelling composition
KR102291985B1 (ko) * 2021-02-17 2021-08-23 주식회사 디노보 인체에 안전한 모기 기피제 조성물

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Publication number Priority date Publication date Assignee Title
TWI705763B (zh) * 2018-04-09 2020-10-01 日商大日本除蟲菊股份有限公司 害蟲驅避劑及害蟲驅避製品
JP2022176243A (ja) * 2018-06-27 2022-11-25 大日本除蟲菊株式会社 衣料害虫産卵予防用スプレー剤、及び衣料害虫産卵予防方法
TWI799669B (zh) * 2018-12-26 2023-04-21 日商大日本除蟲菊股份有限公司 消臭組成物及消臭方法，以及惡臭害蟲防除用組成物及惡臭害蟲防除方法
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KR102387616B1 (ko) 2022-04-15
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CN109310079A (zh) 2019-02-05
MY199207A (en) 2023-10-19

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