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WO2018040788A1 - Composition germicide - Google Patents

Composition germicide Download PDF

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Publication number
WO2018040788A1
WO2018040788A1 PCT/CN2017/093883 CN2017093883W WO2018040788A1 WO 2018040788 A1 WO2018040788 A1 WO 2018040788A1 CN 2017093883 W CN2017093883 W CN 2017093883W WO 2018040788 A1 WO2018040788 A1 WO 2018040788A1
Authority
WO
WIPO (PCT)
Prior art keywords
captan
composition according
composition
bactericidal composition
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/CN2017/093883
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English (en)
Chinese (zh)
Inventor
仲汉根
季自华
季红进
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Huifeng Agrochemical Co Ltd
Original Assignee
Jiangsu Huifeng Agrochemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Huifeng Agrochemical Co Ltd filed Critical Jiangsu Huifeng Agrochemical Co Ltd
Publication of WO2018040788A1 publication Critical patent/WO2018040788A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
    • A01N47/04—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing >N—S—C≡(Hal)3 groups

Definitions

  • the invention belongs to the field of agricultural plant protection, in particular to a germicidal composition with improved properties, in particular to a germicidal composition comprising benzisothiazolinones and captan.
  • Benzoisothiazolinones are a new type of broad-spectrum fungicide mainly used for the prevention and treatment of various bacterial and fungal diseases such as cereal crops, vegetables and fruits.
  • the mechanism of bactericidal action mainly includes destroying the nuclear structure of the pathogen, causing it to lose the heart part and failing to death and interfering with the metabolism of the pathogenic cells, causing its physiological disorder and ultimately leading to death. It can effectively protect plants from pathogens in the early stage of disease occurrence. Increasing the dosage after disease occurrence can obviously control the spread of pathogens, thus achieving the dual functions of protection and eradication.
  • Captan Captan is an important variety of organic fungicides. It has good control effects on various diseases of crops such as three wheat, rice, corn, cotton, vegetables, fruit trees, melons and tobacco. The control effect on the three wheat scab is second only to carbendazim, and also has good control effects on rice sheath blight, rice blast, wheat stalk embroider, tobacco brown spot disease, cotton seedling disease, apple rot disease. The product is also used for seed dressing to control cotton seedling diseases. The oral LD50 of rats was 9000 mg/kg. It has a stimulating effect on the skin and skin.
  • the object of the present invention is to solve the resistance of the bactericide in practical application and the problem of soil residue, and to screen out the fungicides with different sterilization principles to obtain a new fungicide composition, so as to improve the control effect of the bactericide and delay the resistance.
  • Sexual production reducing the amount of application, reducing the cost of prevention.
  • Another object of the present invention is to provide a process for the preparation of a bactericidal composition comprising two active ingredients A and B and for the control of crop diseases in the agricultural sector.
  • the object of the invention can be achieved by the following measures:
  • a synergistic fungicidal composition comprising two active components A and B, wherein the active component Component A is a structural compound having formula (I) and active component B is captan.
  • R is selected from H or a C 1 - C 8 alkyl group.
  • the C 1 -C 8 alkyl group in the present invention means a linear or branched alkyl group having 1 to 8 carbon atoms, and includes a C 1 alkyl group (e.g., methyl group) and a C 2 alkyl group (e.g., ethyl group). , C 3 alkyl (such as n-propyl, isopropyl), C 4 alkyl (such as n-butyl, isobutyl, tert-butyl, sec-butyl), C 5 alkyl (such as n-pentyl, etc.) , C 6 alkyl, C 7 alkyl, C 8 alkyl. It includes, but is not limited to, C 1 -C 6 alkyl, C 1 -C 5 alkyl, C 1 -C 4 alkyl, and the like.
  • R is selected from H or a C 1 -C 4 alkyl group.
  • R is selected from the group consisting of H, -CH 3 or -C 4 H 9 .
  • A is 1,2-benzisothiazolin-3-one (abbreviated as BIT in the specification).
  • R is CH 3
  • A is 2-methyl-1,2-benzisothiazolin-3-one (abbreviated as MBIT in the specification).
  • R is C 4 H 9
  • A is 2-butyl-1,2-benzisothiazolin-3-one
  • the "butyl group” in the formula is preferably n-butyl (instruction Referred to as BBIT).
  • the inventors have found through experiments that the composition of the present invention is effective for controlling bacterial or fungal diseases of crops, and more importantly, the application amount is reduced and the use cost is lowered.
  • the compounds containing component A and component B have different structural types and different mechanisms of action. The combination of the two can expand the bactericidal spectrum, and can delay the generation and development of pathogen resistance to a certain extent, and component A and group There is no cross-resistance between points B.
  • the weight ratio between the two components in the bactericide composition of the present invention is from 1:1 to 40.
  • the weight ratio between the two components of the components A and B can be further optimized to 1:1 to 30.
  • the weight ratio between the two components of A and B can be arbitrarily adjusted within the range of the following ratios: 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:11, 1:12, 1:13, 1:14, 1:15, 1:16, 1:17, 1: 18, 1:19, 1:20, 1:21, 1:22, 1:23, 1:24, 1:25, 1:26, 1:27, 1:28, 1:29, 1:30, 1:31, 1:32, 1:33, 1:34, 1:35, 1:36, 1:37, 1:38, 1:39, 1:40 can also be composed of any two of the above ratios The selection is made within the range, which can be understood as a weight ratio, and may also include a molar ratio.
  • composition of the present invention can be made into a pesticide-acceptable dosage form from the active ingredient and agrochemical adjuvant or adjuvant. Further, the composition comprises from 2 to 80% by weight of the active component and 98 to 20% by weight of the pesticide adjuvant or auxiliary compound. The approved dosage form.
  • the present invention provides the use of a bactericidal composition comprising component A and component B for controlling crop diseases in the agricultural sector, in particular for controlling fungi or bacteria of certain crops.
  • composition may specifically comprise an agrochemical adjuvant or an auxiliary such as one or more of a carrier, a solvent, a dispersing agent, a wetting agent, an adhesive, a thickener, a binder, a surfactant or a fertilizer.
  • auxiliary such as one or more of a carrier, a solvent, a dispersing agent, a wetting agent, an adhesive, a thickener, a binder, a surfactant or a fertilizer.
  • auxiliary such as one or more of a carrier, a solvent, a dispersing agent, a wetting agent, an adhesive, a thickener, a binder, a surfactant or a fertilizer.
  • auxiliary such as one or more of a carrier, a solvent, a dispersing agent, a wetting agent, an adhesive, a thickener, a binder, a surfactant or a fertilizer.
  • Common auxiliaries can be mixed during the application.
  • auxiliaries or auxiliaries may be solid or liquid, they are usually materials commonly used in the processing of dosage forms, such as natural or regenerated minerals, solvents, dispersants, wetting agents, adhesives, thickeners, binders. .
  • the method of application of the compositions of the invention comprises the use of the compositions of the invention for aerial parts of plants, in particular leaves or foliage. You can choose to soak or apply to the surface of the control object.
  • the frequency of administration and the amount administered will depend on the biological and climatic conditions of the pathogen.
  • the plant growth site such as rice fields, may be wetted with a liquid formulation of the composition, or the composition may be applied to the soil in solid form, such as in the form of granules (soil application), the composition may be passed from the soil to the plant through the roots of the plant. In vivo (systemic action).
  • composition of the present invention can be prepared into various pesticide-acceptable dosage forms including, but not limited to, emulsifiable concentrates, suspending agents, wettable powders, water-dispersible granules, powders, granules, aqueous preparations, aqueous emulsions, microemulsions, poison baits.
  • the dosage form of the invention employs a wettable powder, a suspending agent, a water-dispersible granule, an aqueous emulsion or a microemulsion.
  • the compositions may be applied by spraying, misting, dusting, spreading or pouring, and the like.
  • composition of the present invention can be prepared into various dosage forms by a known method, and the active ingredient and the auxiliary agent, such as a solvent, a solid carrier, and, if necessary, can be uniformly mixed and ground together with the surfactant to prepare a desired preparation. Dosage form.
  • the above solvent may be selected from aromatic hydrocarbons, preferably containing from 8 to 12 carbon atoms, such as a mixture of xylenes or substituted benzenes, phthalates such as dibutyl phthalate or dicaprylic acid, aliphatic hydrocarbons such as rings.
  • aromatic hydrocarbons preferably containing from 8 to 12 carbon atoms, such as a mixture of xylenes or substituted benzenes, phthalates such as dibutyl phthalate or dicaprylic acid, aliphatic hydrocarbons such as rings.
  • Alkenes or paraffins, alcohols and glycols and their ethers and esters such as ethanol, ethylene glycol, ethylene glycol monomethyl
  • ketones such as cyclohexanone
  • highly polar solvents such as N-methyl-2 Pyrrolidone, dimethyl sulfoxide or dimethylformamide
  • vegetable or vegetable oils such as soybean oil.
  • the above solid carriers are typically natural mineral fillers such as talc, kaolin, montmorillonite or activated clay.
  • a highly dispersible silicic acid or a highly dispersible adsorbent polymer carrier such as a particulate adsorbent carrier or a non-adsorbing carrier, and a suitable particulate adsorbent carrier is porous, such as pumice, bentonite or Bentonite; a suitable non-adsorbing carrier such as calcite or sand.
  • a large amount of pre-granulated materials of inorganic or organic nature can be used as a carrier, in particular dolomite.
  • Suitable surfactants are lignosulfonic acid, naphthalenesulfonic acid, phenolsulfonic acid, alkaline earth metal or amine salts, alkylarylsulfonates, alkyl groups Sulfates, alkyl sulfonates, fatty alcohol sulphates, fatty acids and sulfated fatty alcohol glycol ethers, as well as condensates of sulfonated naphthalene and naphthalene derivatives with formaldehyde, naphthalene or naphthalene sulfonic acid with phenol and formaldehyde Condensate, polyoxyethylene octyl phenyl ether, ethoxylated isooctyl phenol, octyl phenol, nonyl phenol, alkyl aryl polyglycol ether, tributyl benzene poly
  • the active ingredient A can be first dissolved in certain specific basic substances to form a benzisothiazolin metal salt.
  • suitable basic substances include: alkali metal carbonates, alkali metal hydrogens Oxide (such as sodium hydroxide, potassium hydroxide), alkali metal alkoxy carbonate, alkali metal alkoxide or magnesium methoxide.
  • the two active ingredients in the compositions of the present invention exhibit synergistic effects, the activity of which is more pronounced than the expected sum of activity using a single compound, and the individual activity of a single compound.
  • the synergistic effect is manifested by allowing for a reduced application rate, a broader fungicidal control profile, quicker effect, longer lasting control effect, better control of plant harmful fungi by only one or a few applications, and broadening of possible application. Intervals. These properties are particularly desirable in the practice of plant fungi control.
  • the bactericidal composition of the present invention can be applied to the control of crop diseases in the agricultural field, and the crop diseases referred to herein are, in particular, cucumber powdery mildew, wheat smut, apple rot, tomato downy mildew or tobacco black shank.
  • the composition of the present invention can prevent and cure specific diseases including but not limited to wheat diseases (such as wheat scab, wheat powdery mildew, wheat rust, etc.), rice diseases (such as rice stalks).
  • corn diseases such as: corn smut, corn big spot, corn small spot disease
  • cucumber diseases such as: cucumber downy mildew, Cucumber powdery mildew, cucumber anthracnose, cucumber bacterial angular spot disease, etc.
  • tomato diseases such as: tomato anthracnose, tomato gray mold, tomato bacterial angular spot disease, etc.
  • grape diseases such as: grape downy mildew, Grape gray mold, grape powdery mildew
  • apple diseases such as apple ring disease, apple anthracnose, etc.
  • citrus diseases citrus canthosis, citrus sores, citrus anthracnose
  • tobacco diseases tobacco wildfire disease).
  • the other characteristics exhibited by the bactericidal composition of the present invention are mainly as follows: 1.
  • the compounding of the composition of the present invention has obvious synergistic effect; 2. Since the chemical composition of the two single agents of the present composition is greatly different, the effect The mechanism is completely different, there is no cross-resistance, and the problem of resistance caused by the separate use of the two single agents can be delayed; 3.
  • the composition of the present invention is safe and safe for crops. It has been proved by experiments that the bactericidal composition of the invention has stable chemical properties, remarkable synergistic effect, and exhibits obvious synergistic effect and complementary effect on the control object.
  • the active ingredient active group A and the active component B, and the auxiliary agent and the filler are uniformly mixed according to the formula, and are pulverized into a wettable powder by a jet stream, and then added with a certain amount of water to be mixed and extruded, granulated, and dried and sieved.
  • a water dispersible granule product A water dispersible granule product.
  • Example 1 24% BIT ⁇ Coffoutan water dispersible granules
  • Example 2 42% BIT ⁇ Coffoutan water dispersible granules
  • Example 3 24% MBIT ⁇ crackanium water dispersible granules
  • Example 4 42% MBIT ⁇ Coffoutan water dispersible granules
  • Example 5 24% BBIT ⁇ Coffoutan water dispersible granules
  • Example 6 42% BBIT ⁇ Coffoutan water dispersible granules
  • the active ingredient active group A and the active component B, and the components such as a dispersing agent, a wetting agent, a thickener and water are uniformly mixed according to the formula, and after being sanded and/or sheared at a high speed, a semi-finished product is obtained. After the analysis, the water is mixed and evenly filtered to obtain the finished product.
  • Example 7 41% BIT ⁇ cyandia suspension
  • Example 8 16% BIT ⁇ cyandia suspension
  • BIT 1% captan is 15%, bentonite is 6%, xylene is 5%, fatty alcohol sulfate is 10%, methyl naphthalenesulfonate sodium formaldehyde condensate is 6%, and water is made up to 100%.
  • the active ingredient A and the B active ingredient are sufficiently mixed with various auxiliary agents and fillers, and are pulverized by an ultrafine pulverizer to obtain a wettable powder.
  • Example 16 30% BIT ⁇ Coffendan wettable powder
  • captan is 15%
  • sodium sulfonate is 5%
  • fatty alcohol sulfate is 6%
  • diatomaceous earth is 8%
  • light calcium carbonate is made up to 100%.
  • Example 17 55% BIT ⁇ Keprotan WP
  • Example 18 30% MBIT ⁇ captandan wettable powder
  • Example 19 55% MBIT ⁇ c-cyandan wettable powder
  • MBIT was 5%
  • captan was 50%
  • the remaining components were prepared in accordance with the procedure of Example 17.
  • Example 20 30% BBIT ⁇ Coffendan wettable powder
  • Example 21 55% BBIT ⁇ Coffendan wettable powder
  • the control effect is converted into the probability value (y), the liquid height ( ⁇ g/ml) is converted into a logarithmic value (x), the virulence equation is calculated by the least squares method, and the neutral concentration EC50 is suppressed, and the virulence of the drug is calculated according to the method of Sun Yunpei. Exponential Co-toxicity Factor (CTC).
  • CTC Exponential Co-toxicity Factor
  • Measured virulence index (ATI) (standard drug EC50 / test drug EC50) * 100
  • Theoretical virulence index (TTI) A virulence index * Percentage of A in the mixture + B virulence index * Percentage of B in the mixture
  • CTC Co-toxicity coefficient [mixture measured virulence index (ATI) / mixed theory virulence index (TTI)] * 100
  • CTC ⁇ 80 the composition showed antagonism, 80 ⁇ CTC ⁇ 120, the composition showed an additive effect, CTC ⁇ 120, and the composition showed synergistic effect.
  • Test method In the early stage of the disease, the first spray was immediately performed, and after 7 days, the second application was carried out, each treatment of 4 cells, 20 square meters per cell. The incidence of the disease was investigated before the drug and 11 days after the second drug. Each plot was randomly sampled at 5 points, and 5 crops were investigated at each point. The percentage of the lesion area per leaf on the whole plant was counted and graded. Disease index and control effect.
  • Grade 1 less than 5 leaf lesions, less than 1 cm in length;
  • Grade 3 6-10 leaf lesions, some lesions are longer than 1 cm;
  • Grade 5 11-25 leaf lesions, some lesions are connected into pieces, and the lesion area accounts for 10-25% of the leaf area;
  • Grade 7 more than 26 leaf lesions, the lesions are connected into pieces, and the lesion area accounts for 26-50% of the leaf area;
  • Grade 9 The lesions are connected into pieces, and the area of the lesions accounts for more than 50% of the leaf area or the whole leaves are dead.

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

La présente invention concerne une composition germicide. La composition concerne deux substances actives A et B, la substance active A étant un composé ayant une structure de formule (I), la substance active B étant le captane, et le rapport pondéral entre les deux substances étant de 1 : 1 à 40. La présente invention concerne en outre un procédé de préparation et une utilisation de la composition. Des résultats expérimentaux montrent que la composition germicide ci-dessus selon la présente invention présente des effets synergiques nets et, plus important, une quantité d'application réduite et des coûts d'utilisation réduits. La composition germicide est efficace pour lutter contre certaines maladies bactériennes ou fongiques de cultures. L'association de germicides ayant différents mécanismes et modes d'action permet d'obtenir des effets favorables comprenant l'expansion du spectre bactéricide, le retardement de la résistance fongique et bactérienne et l'amélioration des effets de lutte contre les maladies.
PCT/CN2017/093883 2016-08-31 2017-07-21 Composition germicide Ceased WO2018040788A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201610794876.7 2016-08-31
CN201610794876.7A CN106234392B (zh) 2016-08-31 2016-08-31 一种杀菌剂组合物

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WO2018040788A1 true WO2018040788A1 (fr) 2018-03-08

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WO (1) WO2018040788A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106234392B (zh) * 2016-08-31 2019-04-16 江苏辉丰农化股份有限公司 一种杀菌剂组合物
CN107087628A (zh) * 2017-04-02 2017-08-25 广东中迅农科股份有限公司 一种含有克菌丹和噻霉酮的农药组合物

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101686685A (zh) * 2007-05-31 2010-03-31 先正达参股股份有限公司 保护植物繁殖材料、植物和/或植物器官的方法
JP2010155807A (ja) * 2008-12-27 2010-07-15 Kumiai Chem Ind Co Ltd 農園芸用有害生物防除剤及び有害生物の防除方法
JP2015044791A (ja) * 2013-07-29 2015-03-12 クミアイ化学工業株式会社 農園芸用有害生物防除剤及び有害生物の防除方法
CN106234392A (zh) * 2016-08-31 2016-12-21 江苏辉丰农化股份有限公司 一种杀菌剂组合物

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101669486B (zh) * 2009-10-16 2012-06-06 深圳诺普信农化股份有限公司 一种含苯醚菌酯的杀菌组合物
CN102172240B (zh) * 2011-03-01 2015-09-30 陕西西大华特科技实业有限公司 一种含有噻霉酮和甲氧基丙烯酸酯类杀菌剂的杀菌组合物
CN103704234B (zh) * 2014-01-07 2015-04-01 中国农业科学院植物保护研究所 一种防治农业细菌性病害的组合物
CN105494369A (zh) * 2015-12-02 2016-04-20 京博农化科技股份有限公司 一种含胶霉菌素的组合物
CN105685061A (zh) * 2016-02-29 2016-06-22 陕西西大华特科技实业有限公司 噻霉酮在防治马铃薯种传病害及促根发芽上的应用

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101686685A (zh) * 2007-05-31 2010-03-31 先正达参股股份有限公司 保护植物繁殖材料、植物和/或植物器官的方法
JP2010155807A (ja) * 2008-12-27 2010-07-15 Kumiai Chem Ind Co Ltd 農園芸用有害生物防除剤及び有害生物の防除方法
JP2015044791A (ja) * 2013-07-29 2015-03-12 クミアイ化学工業株式会社 農園芸用有害生物防除剤及び有害生物の防除方法
CN106234392A (zh) * 2016-08-31 2016-12-21 江苏辉丰农化股份有限公司 一种杀菌剂组合物

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CN106234392A (zh) 2016-12-21

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