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WO2017207099A1 - Moyen et procédé pour décontaminer des produits textiles et des bains de lavage - Google Patents

Moyen et procédé pour décontaminer des produits textiles et des bains de lavage Download PDF

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Publication number
WO2017207099A1
WO2017207099A1 PCT/EP2017/000634 EP2017000634W WO2017207099A1 WO 2017207099 A1 WO2017207099 A1 WO 2017207099A1 EP 2017000634 W EP2017000634 W EP 2017000634W WO 2017207099 A1 WO2017207099 A1 WO 2017207099A1
Authority
WO
WIPO (PCT)
Prior art keywords
textile products
washing
granules
washing liquor
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2017/000634
Other languages
German (de)
English (en)
Inventor
Christoph Hartmann
Marco D'Andola
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ATLANTICHEM GmbH
Original Assignee
ATLANTICHEM GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ATLANTICHEM GmbH filed Critical ATLANTICHEM GmbH
Publication of WO2017207099A1 publication Critical patent/WO2017207099A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/046—Insoluble free body dispenser
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/12—Naturally occurring clays or bleaching earth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/165—Natural alumino-silicates, e.g. zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B01J20/261—Synthetic macromolecular compounds obtained by reactions only involving carbon to carbon unsaturated bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B01J20/262—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon to carbon unsaturated bonds, e.g. obtained by polycondensation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28016—Particle form
    • B01J20/28021—Hollow particles, e.g. hollow spheres, microspheres or cenospheres
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/30—Nature of the water, waste water, sewage or sludge to be treated from the textile industry

Definitions

  • the invention relates to an agent and a method for detoxifying textile products and the wash liquor, as obtained in the washing and cleaning of textile products.
  • Called wash liquor which is generally detergents such as soap,
  • washing aids such as bleaches
  • the washing water usually also partly toxic and often allergiauslösende and
  • the object of the invention is therefore to provide a means that is used to detoxify textile products and the wash liquor, which is obtained during washing and cleaning of textile products.
  • the object of the invention is also to provide a method with which it is possible to obtain a detoxified washing wastewater or wash liquor.
  • a means for detoxifying textile products and the wash liquor which is obtained during washing and cleaning of textile products, which is characterized in that the means comprises a water-insoluble container having passages for the wash liquor and adsorbent, absorbent and Cations and anions containing exchange granules and / or powder whose diameter is greater than the diameter of the passages of the container.
  • the granules or powder consists of particles of different material, each with pollutant adsorbing, absorbing and pollutant ions
  • the container additionally contains substances which pollutants in the wash liquor in convert harmless substances. These substances can therefore also be water-soluble.
  • Another object of the invention is a method for detoxifying textile products and the wash liquor, which is obtained during washing and cleaning of textile products, which is characterized in that the textile products in the presence of an agent according to one of the claims 1, 2, 3 , 4 or 5 treated with the wash liquor.
  • textile products within the scope of the invention are also to be understood fibers and threads of natural type such as cotton or silk and synthetic type, e.g. Polyester or polyamides etc.
  • Natural fibers and products made from them may still contain residues of fertilizers used in plant growth. In addition, this also applies to synthetic products, residues of treatment and finishing agents. Because even after a washing process remains of pollutants can often remain on the textile product.
  • clothing such as suits, coats, shirts, pants, underwear, sports and functional clothing but also others
  • Articles such as blankets, curtains, diapers, towels, handkerchiefs, but also work clothing, e.g. even those by doctors and
  • adsorbing and ion-exchanging granules or powders may advantageously granules and powders of the following materials are used: activated carbon, organofunctionalized beta-cyclodextrins, ion exchangers, especially those containing cavities for receiving
  • Heavy metals bentonites, zeolites, which are structured to tend to bind to pollutants, such as Toxisorb from Clariant, natural zeolites, e.g. Clinoptiolite, modified
  • particles of highly porous polymers in particular polypropylene, polyethylene, polyamide, polylactic acids with a so-called Accurel structure. This is that the polymers
  • the pollutants to be removed during detoxification include, among others, heavy metals including ions, formaldehyde, pesticides, herbicides,
  • Insecticides dyes, impregnating agents, antistatic agents, optical brighteners, epoxy resins, disinfectants and preservatives, and generally textile auxiliaries, i.a. those that are harmful to health, cause allergies and can be harmful to the environment.
  • Detoxification within the meaning of the invention also means removal of interfering substances, even if they are not necessarily a toxic substance.
  • Containers which have passages and in which wash-active substances are present are already known and are mentioned, for example, in US Pat. Nos. 4,914,165 and 4,532,722.
  • the containers are always used to deliver substances through the passages to the wash liquors in order to achieve a better soil removal of the laundry. This is also the case with agents according to WO 2009/071296 AI.
  • WO 2009/006395 describes a container which contains so-called "color catchers” which are intended to remove dyestuffs from the wash liquor, but at the same time detergents are to be delivered to the wash liquor in WO 2008/138574 AI containers are
  • Dispense detergent to the wash liquor Dispense detergent to the wash liquor.
  • the textile products have no or at least no questionable amounts of water after the washing process with the container according to the invention due to the fact that the wash liquor is free of toxins and other interfering substances such as pollutants Remains of the harmful substances remain on the washed textile products, which could otherwise be in the wastewater and again settle on the textile products when pumping the wash liquor.
  • the wash liquor is free of toxins and other interfering substances such as pollutants Remains of the harmful substances remain on the washed textile products, which could otherwise be in the wastewater and again settle on the textile products when pumping the wash liquor.
  • a bag of 15cm x 15cm made from wet-strength and well-water-permeable paper web is filled with 60g of free-flowing mixed granules and sealed.
  • the filling and closing is done by machine according to the in the packaging industry often used next method of 3 or 4 edge sealing by means of heating jaws or ultrasonic heads.
  • the paper web was provided with a proportion of 30% of suitable melt fibers, so-called BICO fibers.
  • the granules were previously washed with water, dried and then homogenized in a laboratory blender and separated by screening of Feinstteilchen.
  • the granules have the composition 35% activated carbon, 20%
  • Clinoptilolite 5% Bentonite Toxisorb, 5% Lewatit MonoPlus S108, 15% Soda, 5% PP Accurel Powder MP1000, 15% Urea.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Dispersion Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention concerne un moyen comprenant un contenant insoluble dans l'eau qui contient des granulés ou de la poudre et qui présente des passages pour l'eau de lavage dont le diamètre est inférieur au diamètre des granulés et de la poudre. Les granulés et la poudre présentent des propriétés d'adsorption, d'absorption et d'échange d'ions et ont une tendance prononcée à fixer les substances contaminantes ou peuvent les convertir en substances inoffensives dans le bain de lavage. Ce moyen est utilisé dans le bain de lavage lors du traitement de produits textiles et permet d'obtenir un produit textile propre et décontaminé, ainsi que des eaux résiduaires de lavage décontaminées.
PCT/EP2017/000634 2016-05-31 2017-05-31 Moyen et procédé pour décontaminer des produits textiles et des bains de lavage Ceased WO2017207099A1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE102016006424 2016-05-31
DE102016006424.2 2016-05-31
DE102017001453.1A DE102017001453A1 (de) 2016-05-31 2017-02-15 Mittel und verfahren zum entgiften von waschwasser
DE102017001453.1 2017-02-15

Publications (1)

Publication Number Publication Date
WO2017207099A1 true WO2017207099A1 (fr) 2017-12-07

Family

ID=60268726

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2017/000634 Ceased WO2017207099A1 (fr) 2016-05-31 2017-05-31 Moyen et procédé pour décontaminer des produits textiles et des bains de lavage

Country Status (2)

Country Link
DE (1) DE102017001453A1 (fr)
WO (1) WO2017207099A1 (fr)

Citations (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4532722A (en) 1983-02-07 1985-08-06 Sax Stephen H Fabric conditioning device
US4914165A (en) 1988-02-03 1990-04-03 Minnesota Mining And Manufacturing Company Radiation crosslinkable compositions
US5978994A (en) * 1997-03-12 1999-11-09 Vision International Production, Inc. Device and method for use in cleaning laundry
WO2005005329A2 (fr) * 2003-07-07 2005-01-20 Reckitt Benckiser N.V. Procede d'adoucissement d'eau
EP1712612A1 (fr) * 2005-04-15 2006-10-18 Reckitt Benckiser N.V. Procédé de traitement de textiles
EP1889000A2 (fr) 2005-05-26 2008-02-20 Cymer, Inc. Systemes et procedes pour l'interaction entre un laser en forme de faisceau en ligne et un film depose sur un substrat
WO2008053177A1 (fr) * 2006-10-31 2008-05-08 Reckitt Benckiser N.V. Produit et procédé
WO2008138574A1 (fr) 2007-05-09 2008-11-20 Punch Industries Article utilisable pour le lavage de produits textiles
WO2009004295A1 (fr) 2007-07-05 2009-01-08 Reckitt Benckiser N.V. Produit pour le nettoyage du linge
WO2009006395A1 (fr) 2007-06-29 2009-01-08 Dale Sloan Système de positionnement d'enclume
WO2009007196A1 (fr) 2007-07-10 2009-01-15 Polysius Ag Presse à rouleaux avec une tôle de guidage de matière à broyer à introduire
WO2009071296A1 (fr) 2007-12-04 2009-06-11 Atlantichem Gmbh Agent pour éviter les phénomènes de décoloration lors du lavage de textiles
US20090163399A1 (en) 2006-05-18 2009-06-25 Reckitt Benckiser (Uk) Limited Detergent Product and Process for its Preparation and Use Thereof
DE202010003779U1 (de) * 2010-03-17 2010-07-15 Ostthüringische Materialprüfgesellschaft Für Textil Und Kunststoffe Mbh Eigenstabiles Filtermaterial
US20140186224A1 (en) * 2012-12-31 2014-07-03 HalolaH LLC Biodegradable odor removing article and system
AU2013200864A1 (en) * 2013-02-17 2014-09-04 Boskov, Silas Robert MR Water filter pouch for use in a drinking water pitcher

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4014165A (en) 1974-03-25 1977-03-29 Texas Instruments Incorporated DC-DC converter in watch system
ITMI20061598A1 (it) 2006-08-08 2008-02-09 Bolton Manitoba S P A Articolo peer detergenza

Patent Citations (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4532722A (en) 1983-02-07 1985-08-06 Sax Stephen H Fabric conditioning device
US4914165A (en) 1988-02-03 1990-04-03 Minnesota Mining And Manufacturing Company Radiation crosslinkable compositions
US5978994A (en) * 1997-03-12 1999-11-09 Vision International Production, Inc. Device and method for use in cleaning laundry
WO2005005329A2 (fr) * 2003-07-07 2005-01-20 Reckitt Benckiser N.V. Procede d'adoucissement d'eau
EP1712612A1 (fr) * 2005-04-15 2006-10-18 Reckitt Benckiser N.V. Procédé de traitement de textiles
EP1889000A2 (fr) 2005-05-26 2008-02-20 Cymer, Inc. Systemes et procedes pour l'interaction entre un laser en forme de faisceau en ligne et un film depose sur un substrat
US20090163399A1 (en) 2006-05-18 2009-06-25 Reckitt Benckiser (Uk) Limited Detergent Product and Process for its Preparation and Use Thereof
WO2008053177A1 (fr) * 2006-10-31 2008-05-08 Reckitt Benckiser N.V. Produit et procédé
WO2008138574A1 (fr) 2007-05-09 2008-11-20 Punch Industries Article utilisable pour le lavage de produits textiles
WO2009006395A1 (fr) 2007-06-29 2009-01-08 Dale Sloan Système de positionnement d'enclume
WO2009004295A1 (fr) 2007-07-05 2009-01-08 Reckitt Benckiser N.V. Produit pour le nettoyage du linge
WO2009007196A1 (fr) 2007-07-10 2009-01-15 Polysius Ag Presse à rouleaux avec une tôle de guidage de matière à broyer à introduire
WO2009071296A1 (fr) 2007-12-04 2009-06-11 Atlantichem Gmbh Agent pour éviter les phénomènes de décoloration lors du lavage de textiles
DE202010003779U1 (de) * 2010-03-17 2010-07-15 Ostthüringische Materialprüfgesellschaft Für Textil Und Kunststoffe Mbh Eigenstabiles Filtermaterial
US20140186224A1 (en) * 2012-12-31 2014-07-03 HalolaH LLC Biodegradable odor removing article and system
AU2013200864A1 (en) * 2013-02-17 2014-09-04 Boskov, Silas Robert MR Water filter pouch for use in a drinking water pitcher

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