[go: up one dir, main page]

WO2016121900A1 - Composition herbicide - Google Patents

Composition herbicide Download PDF

Info

Publication number
WO2016121900A1
WO2016121900A1 PCT/JP2016/052578 JP2016052578W WO2016121900A1 WO 2016121900 A1 WO2016121900 A1 WO 2016121900A1 JP 2016052578 W JP2016052578 W JP 2016052578W WO 2016121900 A1 WO2016121900 A1 WO 2016121900A1
Authority
WO
WIPO (PCT)
Prior art keywords
parts
herbicidal composition
salt
compound
methyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2016/052578
Other languages
English (en)
Japanese (ja)
Inventor
貴志 重藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yashima Chemical Industrial Co Ltd
Original Assignee
Yashima Chemical Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yashima Chemical Industrial Co Ltd filed Critical Yashima Chemical Industrial Co Ltd
Publication of WO2016121900A1 publication Critical patent/WO2016121900A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
    • A01N33/18—Nitro compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/32—Cyclic imides of polybasic carboxylic acids or thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/34—Nitriles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/48—Nitro-carboxylic acids; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
    • A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
    • A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
    • A01N39/04—Aryloxy-acetic acids; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/10—Sulfones; Sulfoxides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/12—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings condensed with a carbocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/20—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom three- or four-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • A01N43/38—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings condensed with carbocyclic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A01N43/42—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/58—1,2-Diazines; Hydrogenated 1,2-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
    • A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
    • A01N43/70—Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/707—1,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/76—1,3-Oxazoles; Hydrogenated 1,3-oxazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/16—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof the nitrogen atom being part of a heterocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds
    • A01N57/28—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds containing acyclic or cycloaliphatic radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds
    • A01N57/30—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds containing aromatic radicals

Definitions

  • the present invention relates to a herbicide composition and the like.
  • Non-Patent Document 1 Currently, many herbicides are sold and used. (For example, see Non-Patent Document 1)
  • An object of the present invention is to provide a herbicidal composition having an excellent weed control effect.
  • the present inventors have found a pyrazolyl pyrazole derivative represented by the following formula (I) and a specific herbicide other than the pyrazolyl pyrazole derivative: It has been found that a herbicidal composition containing sucrose has an excellent weed control effect, leading to the present invention. That is, the present invention is as follows.
  • herbicidal composition according to [1], wherein the herbicidal active compound is an ALS inhibitor, germination / elongation inhibitor, photosynthesis inhibitor, PPO inhibitor, whitening agent, VLCFAs inhibitor, hormone action inhibitor / disturbant A herbicidal composition selected from the group consisting of an ACCase inhibitor and a non-selective herbicide.
  • herbicidal active compound is an ALS inhibitor.
  • ALS inhibitor is amidosulfuron, azisulfuron, bensulfuron-methyl, chlorimuron-ethyl , Chlorosulfuron, cinosulfuron, cyclosulfamuron, ethamethsulfuron-uryl, flusulfuron, flusulfuron, flusulfuron, flusulfuron, flusulfuron.
  • a herbicidal composition selected from the group consisting of fluorlenol, fosamine and prodiamine.
  • [6] The herbicidal composition according to [6], wherein the germination / elongation inhibitor is esprocarb, molinate, olvencarb, prosulfocarb, thiobencarb, pendimethalin, trifluralin, pyribuchicarb, ashram, flupropanate, propizzamide, cumyluron
  • a herbicidal composition selected from the group consisting of, Dimron, Benfresate, Butamifos, Anilophos, Benthuride, Dithiopyr, Diclobenil, Bromobutide, Etobenzanide, Triadifram.
  • the photosynthesis inhibitor is chlorbromuron, chlorotoluron, chloroxuron, dimefuron, diuron, etidimuron , Phenuron, fluometuron, isoproturon, isouron, linuron, metabenzthiazuron, uron, metrobromuron, uron Nebulon (ne uron, siduron, tebuthiuron, carbutylate, ametrine, atrazine, dimethine, rothin, promethrin, methmetrin, promethrin prometryn, propazine, simazine, simetrin, terbumetone, terbutylazine, terbutridine terbutetine, triethadine , Phenmedifam, he
  • VLCFAs inhibitor is acetochlor, alachlor, butachlor, dimethachlor, dimethenamide, dimethenamide-P ( dimethenamid-P), metazachlor (metazachlor), S-metolachlor (S-metolachlor), pesoxamide, pretilachlor, propichlor, propodichlor, propodichlor.
  • composition according to [30], wherein the safener is cloquintoset mexil, ciomethrinyl, fenchlorazole ethyl, flurazole, mefenpyr diethyl, 1,8-naphthalic anhydride, diimron
  • a herbicidal composition having an excellent weed control effect can be provided.
  • the herbicidal composition of the present invention (hereinafter referred to as the present herbicidal composition) has the formula (I) Formula (I): [Wherein R 1 represents a halogen atom, R 2 represents a cyano group or a nitro group, R 3 represents a C 2 -C 4 alkyl group substituted by one or more halogen atoms, a C 1 -C 2 alkoxy (C 1 -C 3 ) alkyl group, a represents 3 to 5 and b represents 1 to 3. ] And a pyrazolyl pyrazole derivative (hereinafter referred to as the present compound), and at least one herbicidal active compound. Furthermore, you may contain an at least 1 sort (s) of safener.
  • Halogen atom includes fluorine, chlorine, bromine and iodine atoms.
  • the “alkyl group” can be linear or branched, and at least one of the hydrogen atoms contained in the substituent is substituted with a halogen atom. Examples include chloroethyl, dichloroethyl, trifluoroethyl, tetrafluoropropyl, bromoethyl, bromopropyl, chlorobutyl groups and the like, which are selected within the specified number of carbon atoms.
  • Alkoxy group means an alkyl-O— group in which the alkyl moiety has the above meaning, and includes, but is not limited to, for example, a methoxy, ethoxy group, etc. Selected by range.
  • the ALS inhibitor which is a part of the herbicidal active compound that can be contained in the herbicidal composition of the present invention, is a compound that inhibits acetolactate synthase involved in the biosynthesis of amino acids such as valine, leucine and isoleucine. .
  • the ALS inhibitors include sulfonylurea herbicides, triazolopyrimidine herbicides, pyrimidinyloxybenzoic acid herbicides, imidazolinone herbicides, sulfonylaminocarbonyltriazolinone herbicides, pyrimidinylthiobenzoic acid herbicides, respectively. And so on.
  • Suitable pyrimidinyloxybenzoic acid-based ALS inhibitors for the herbicidal composition of the present invention include, but are not limited to, for example, bispyribac and salts thereof, pyribenzoxim, pyriminobac-methyl. ), Pyrimisulfan, pyriftalid, triafamon, and the like, and preferred are bispyribac and salts thereof, pyriminobacmethyl, pyrimisulfan, pyriftalide, and triafamon.
  • imidazolinone-based ALS inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, imazametabenz-methyl, imazamox and salts thereof, imazapic And its salt, imazapyr and its salt, imazaquin and its salt, imazethapyr and its salt, preferably imazamox and its salt, imazapic and its salt, imazapyr and its salt, Imazetapyr and its salts are mentioned.
  • sulfonylaminocarbonyltriazolinone-based ALS inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, flucarbazone and its salt, propoxycarbazone and its salt, thien And carbazone methyl (thiencarbazone-methyl).
  • the pyrimidinylthiobenzoic acid ALS inhibitor suitable for the herbicidal composition of the present invention is not limited, and examples thereof include pyrithiobac and salts thereof.
  • Germination / elongation inhibitor which is a part of the herbicidal active compound that can be contained in the herbicidal composition of the present invention, is cell division, cell hypertrophy, cell elongation, protein synthesis, nucleic acid synthesis, nucleus of germination and elongation process of plants It is a compound that acts on membrane formation, spindle microtubule formation, spindle microtubule polymerization, folic acid production, etc., and inhibits cell division.
  • the germination / elongation inhibitor is thiocarbamate herbicide, dinitroaniline herbicide, carbamate herbicide, chlorocarbonate herbicide, benzamide herbicide, urea herbicide, benzofuran herbicide, organophosphorus. It is classified into herbicides, pyridine herbicides, nitrile herbicides, acid amide herbicides and the like.
  • Examples of the thiocarbamate germination / elongation inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, butyrate, hexyl-thiocarbam, dimethylpiperate, and EPTC. , Esprocarb, molinate, olvencarb, pebrate, prosulfocarb, thiobencarb, thiocarbazyl, triate valate, triate Preferably, esprocarb, molinate, olvencarb, pro Ruhokarubu, it includes the thiobencarb.
  • dinitroaniline germination / elongation inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, benfluralin, butralin, dinitramine, ethalfluralin. , Oryzalin, pendimethalin, trifluralin, and the like, preferably pendimethalin and trifluralin.
  • carbamate germination / elongation inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, carbetamide, chlorprophum, propham, pyributycarb (pyribitucarb), Asuram etc. are mentioned, Preferably, a pyributicarb and an ashram are mentioned.
  • chlorocarbonic acid germination / elongation inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, TCA, dalapon, flupropanate, and salts thereof. May include full propanate.
  • benzamide germination / elongation inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, propyzamide, tebutam, isoxaben, etc. Propizzamid is mentioned.
  • urea germination / elongation inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, cumylron, dymron, methyldymron, and the like, preferably , Cumylron, and dimron.
  • benzofuran germination / elongation inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, benfrateate, etofumesate, and preferably benfrecetate.
  • organic phosphorus germination / elongation inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, butamifos, amiprophos-methyl, anilofos, benzulide (Bensulide), piperophos (piperophos), etc. are mentioned, Preferably, butamifos, anilophos, and benzulide are mentioned.
  • Examples of the pyridine-based germination / elongation inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, dithiopyr and thiazopyr, and preferably dithiopyr.
  • germination / elongation inhibitors suitable for the herbicidal composition of the present invention include, but are not limited to, for example, chlorthal-dimethyl, fluoxam, indaziflam, methiozoline. ), Triaziflam, cinmethylin, chlorflurenol, fosamine, prodiamine and the like, and preferably, triaziflam.
  • the photosynthesis inhibitor which is a part of the herbicidal active compound that can be contained in the herbicidal composition of the present invention, is a compound that acts on the electron transfer system in photosynthesis and inhibits photosynthesis.
  • the photosynthesis inhibitors are urea herbicide, 1,3,5-triazine herbicide, phenyl carbamate herbicide, triazinone herbicide, uracil herbicide, hydroxybenzonitrile herbicide, phenyl pyridazine herbicide, respectively. And anilide herbicides.
  • urea photosynthesis inhibitors suitable for the herbicidal composition of the present invention include, but are not limited to, for example, chlorbromulon, chlorotoluron, chloroxuron, dimefuron, diuron ( diuron, ethidimuron, fenuron, fluometuron, isoproturon, isouron, linuron, mebenzenthuron, methabenzthuron ), Monolinuron (m novoluron, neburon, siduron, tebuthiuron, carbbutyrate, and the like, preferably chlorbromulone, diuron, fluometuron, isoproturon, isoururon, linuronthlon, metabenzuron And carbbutylate.
  • 1,3,5-triazine-based photosynthesis inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, amethrin, atrazine cyananadine, desmethrin. , Dimethametrin, promethon, promethrin, propazine, simazine, ziterin, terbetine, terbetetone, terbetetone
  • atrazine, cyanazine, dimetametho Down, propazine, simazine include the simetryn.
  • bromoxynil and its salt are mentioned.
  • the phenylpyridazine-based photosynthesis inhibitor suitable for the herbicidal composition of the present invention is not limited, and examples thereof include pyridate, pyridafol, and preferably pyridate.
  • anilide-based photosynthesis inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, propanil, pentanochlor, and preferably propanil.
  • Examples of other photosynthesis inhibitors suitable for the herbicidal composition of the present invention include, but are not limited to, for example, chloridazon, quinoclamamine, amicarbazone, bentazone, and salts thereof. Preferably, amicarbazone, bentazone and a salt thereof are mentioned.
  • the PPO inhibitor which is a part of the herbicidal active compound that can be contained in the herbicidal composition of the present invention, is a compound that inhibits protoporphyrinogen oxidase involved in chlorophyll biosynthesis.
  • diphenyl ether PPO inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, aciflufen and salts thereof, bifenox, clomethoxyphene, oxyfluorfen. (Oxyfluorfen), lactofen, fomesafen and its salts, fluoroglycofen-ethyl, halosafen, etc., preferably biphenox, oxyfluorfen, lactofen, fluoroglycopheneethyl Can be mentioned.
  • N-phenylphthalimide PPO inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, cinidon-ethyl, flumioxazin, full-microlac-pentyl. ) And the like, preferably flumioxazin.
  • triazolinone-based PPO inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, carfentrazone-ethyl, sulfentrazone, azaphenidin, and the like.
  • carfentrazone ethyl is used.
  • thiadiazole PPO inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, fluthiacet-methyl, thiazimine, and the like, preferably fluthiaset methyl. Is mentioned.
  • PPO inhibitors suitable for the herbicidal composition of the present invention include, but are not limited to, for example, chlorphthalim, pentoxazone, pyraclonil, flufenpyr-ethyl. , Profluazole, and the like, preferably chlorphthalim, pentoxazone, and pyraclonyl.
  • the whitening agent which is a part of the herbicidal active compound that can be contained in the herbicidal composition of the present invention, is a compound that inhibits the synthesis of pigments such as carotenoids and chlorophylls involved in plant photosynthesis.
  • the whitening agents are classified into pyrazole herbicides, triketone herbicides, isoxazole herbicides, bicyclo herbicides, pyridinecarboxamide herbicides, and the like.
  • pyrazole-based whitening agents suitable for the herbicidal composition of the present invention include, but are not limited to, for example, benzofenap, pyrasulfotole, pyrazolate, pyrazoxifene, and topramezone. (Topramzone) etc. are mentioned, Preferably a benzophenap, a pyrazolate, a pyrazoxifene, and a topramone are mentioned.
  • triketone-based whitening agent suitable for the herbicidal composition of the present invention include, but are not limited to, for example, mesotrione, sulcotrione, tembotrione, tefriltrione, and fenquino.
  • a trione (fenquintrione) etc. are mentioned, Preferably, a mesotrione, a tefryl trione, a fenquinotrione is mentioned.
  • isoxazole-based whitening agent suitable for the herbicidal composition of the present invention include, but are not limited to, isoxaflutole, isoxachlortole, etc. Flutol is mentioned.
  • bicyclo whitening agent suitable for the herbicidal composition of the present invention include, but are not limited to, for example, bicyclopyrone, benzobicyclone, and preferably benzobicyclone. It is done.
  • Examples of the pyridinecarboxamide-based whitening agent suitable for the herbicidal composition of the present invention include, but are not limited to, diflufenican, picolinafen, and preferably diflufenican.
  • whitening agents suitable for the herbicidal composition of the present invention include, but are not limited to, for example, norflurazon, amitrole, clomazone, aclonifen, cyclopyrimoleate ( Cyclopyrimorate, fluridone, flurochloridone, flurtamone, beflubutamide, and the like, preferably amitrol, chromazone, cyclopyrimoleate, and beflumide.
  • VLCFAs inhibitors which are part of the herbicidal active compounds that can be included in the herbicidal composition of the present invention, are fatty acid elongations involved in the production of very long chain fatty acids that are the main components of plant cuticular wax layers and cell membrane sphingolipids. A compound that inhibits the enzyme system.
  • VLCFAs inhibitors are classified into chloroacetamide herbicides, acetamide herbicides, oxyacetamide herbicides and the like, respectively.
  • chloroacetamide-based VLCFAs inhibitors suitable for the herbicidal composition of the present invention include, but are not limited to, for example, acetochlor, alachlor, butachlor, dimethachlor, dimethenamide. (Dimethenamide), dimethenamide-P (dimethenamide-P), metazachlor (metazachlor), S-metolachlor (S-metolachlor), pexoxamid (pretilachlor), proprochlor (pro), proprochlor (pro) ), Tenylchlor, etc. Is preferably acetochlor, alachlor, butachlor, dimethenamid -P, S- metolachlor, pretilachlor, include Thenylchlor.
  • acetamide-based VLCFAs inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, diphenamide, napropamide, and preferably diphenamide.
  • oxyacetamide-based VLCFAs inhibitors suitable for the herbicidal composition of the present invention include, but are not limited to, flufenacet, mefenacet and the like.
  • VLCFAs inhibitors suitable for the herbicidal composition of the present invention include, but are not limited to, for example, fentrazamide, fenoxasulfone, indanofan, caffentrol, piroxaz A sulfone (pyroxasulfone), an ipfencarbazone (ipfencarbazone), etc. are mentioned.
  • the hormonal action inhibiting / disturbing agent which is a part of the herbicidal active compound that can be contained in the herbicidal composition of the present invention, is a compound that inhibits or disturbs phytohormonal actions such as auxin and gibberellin related to plant growth. It is.
  • phenoxycarboxylic acid hormone action inhibitor / disturber suitable for the herbicidal composition of the present invention include, but are not limited to, for example, chromeprop, 2,4-D and salts thereof, 2,4-DB And salts thereof, dichloroprop and salts thereof, MCPA and salts thereof, MCPB and salts thereof, mecoprop and salts thereof, 2,4-PA ethyl (2,4-PA-ethyl), phenothiol (Phenothiol) and the like, and preferable examples include chromeprop, 2,4-D and salts thereof, 2,4-DB and salts thereof, MCPA and salts thereof, MCPB and salts thereof, mecoprop and salts thereof.
  • pyridinecarboxylic acid hormone inhibiting / disturbing agent suitable for the herbicidal composition of the present invention include, but are not limited to, for example, aminopyralide and its salt, clopyralid and its salt, fluroxypyr-1 -Methyl beptyl ester (methylpropyl-1-ester), picloram and its salt, triclopyr and its salt, etc., preferably triclopyr and its salt.
  • benzoic acid hormone action inhibitor / disturber suitable for the herbicidal composition of the present invention include, but are not limited to, for example, chloramben cocoon, dicamba and salts thereof, 2,3,6-TBA Preferably, dicamba and its salt are mentioned.
  • quinolinecarboxylic acid hormone action inhibitor / disturber suitable for the herbicidal composition of the present invention include, but are not limited to, quinchlorac, quinmerac, and the like, Kinclorac is mentioned.
  • the phthalamate semicarbazone hormone action inhibitor / disturber suitable for the herbicidal composition of the present invention is not limited, and examples thereof include naptalam, diflufenzopyr and salts thereof. Preferably, diflufenzopyr and its salt are mentioned.
  • hormonal action inhibiting / disturbing agents suitable for the herbicidal composition of the present invention include, but are not limited to, for example, oxadiclomephone, benazoline, aminocyclopyrachlor, and the like.
  • oxadichrome mehon is used.
  • the ACCase inhibitor which is a part of the herbicidal active compound that can be contained in the herbicidal composition of the present invention, is a compound that inhibits acetyl-CoA carboxylase involved in fatty acid biosynthesis.
  • the ACCase inhibitors are classified into aryloxyphenoxypropionic acid herbicides, cyclohexanedione oxime herbicides, phenylpyrazoline herbicides, and the like.
  • aryloxyphenoxypropionic acid-based ACCase inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, clodinafop-propargyl, cyhalofop-butyl, Diclohop-methyl, phenoxaprop-P-ethyl, fluazifop-P-butyl, haloxyhop-P-methyl, haloxyhop-P-methyl, Metamihop, propaquizahop, quizalofop-P-ethyl, etc.
  • Gerare preferably clodinafop-propargyl, cyhalofop-butyl, fenoxaprop -P- ethyl, fluazifop -P- butyl, metamifop, include quizalofop -P- ethyl.
  • cyclohexanedione oxime ACCase inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, alloxydim and salts thereof, cetoxydim, butroxydim, cletodim. , Cycloxydim, teplaloxidim, tralkoxydim, profoxydim, and the like, and preferably cetoxydim and cretodim.
  • phenylpyrazoline-based ACCase inhibitor suitable for the herbicidal composition of the present invention include, but are not limited to, for example, pinoxaden.
  • Chlorates and the like are compounds that exhibit a strong oxidizing action and cause cell protoplast separation. Cyanate and the like are compounds that cause cell cytoplasmic destruction. Paraquat and the like are compounds that cause cell destruction by the generation of active oxygen. Pelargonic acid or the like is a compound that drastically lowers the intracellular pH and causes cell destruction.
  • the non-selective herbicides are classified into inorganic herbicides, dinitrophenol herbicides, organic arsenic herbicides, phosphinic acid herbicides, bipyridinium herbicides, and the like.
  • Examples of the inorganic non-selective herbicides suitable for the herbicidal composition of the present invention include, but are not limited to, for example, sodium cyanate, sodium chlorate, endothal and the like. Examples thereof include salts, lime nitrogen (sulfamic acid), sulfamic acid (sulfamic acid), and salts thereof, preferably sodium cyanate and sodium chlorate.
  • organic arsenic non-selective herbicide suitable for the herbicidal composition of the present invention include, but are not limited to, for example, DSMA, MSMA, and preferably DSMA.
  • phosphinic acid-based non-selective herbicide suitable for the herbicidal composition of the present invention include, but are not limited to, bialaphos and salts thereof, glufosinate-ammonium, and the like.
  • the bipyridinium non-selective herbicide suitable for the herbicidal composition of the present invention is not limited, and examples thereof include diquat dibromide and paraquat dichloride.
  • non-selective herbicides suitable for the herbicidal composition of the present invention include, but are not limited to, for example, d-limonene, glyphosate and salts thereof, difenzoquat, pelargon An acid (pelargonic acid) etc. are mentioned, Preferably, a glyphosate and its salt, difenzocoat, and pelargonic acid are mentioned.
  • the herbicidal active compound is a known compound and is commercially available. Further, for example, it can be produced according to the literature described in the Pesticide Manual, The Fifteenth Edition (2009), the British Crop Production Council (ISBN: 978-1-901396-18-8), and the like.
  • a generally known compound may be used, and is not limited, and examples thereof include, but are not limited to, benoxacol, cloquintocet-mexyl. , Ciometrinil, cyprosulfamide, dichlormid, fenchlorazole-ethyl, fenchlorim, fluzole, fluzole, fluzole, fluzole, fluzole.
  • Examples include setmexyl, thiomethrinyl, fenchlorazole ethyl, flurazole, mefenpyr diethyl, 1,8-naphthalic anhydride, and diimron.
  • the above-mentioned safener is a known compound and is commercially available. Further, for example, it can be produced according to the literature described in the Pesticide Manual, The Fifteenth Edition (2009), the British Crop Production Council (ISBN: 978-1-901396-18-8), and the like.
  • the herbicidal composition of the present invention has herbicidal activity against a wide range of weeds and is effective in paddy fields, crop fields, vegetable fields, orchards, or non-agricultural lands where ordinary tillage cultivation and non-tillage cultivation are performed. A wide range of weeds can be controlled.
  • control target of the herbicidal composition of the present invention examples include, but are not limited to, the following. Crabgrass (Digitaria ciliaris), goosegrass (Eleusineindica), green foxtail (Setaria viridis), giant foxtail (Setaria faberi), Kin green foxtail (Setaria glauca), barnyardgrass (Echinochloa crus-galli), creeping bentgrass (Agrostis alba), fall panicum (Panicum dichotomiflorum), Texas Panicum (Panicum texanum), Meriken Acne (Brachiaria platyphylla), Alexander Grass (Brachiaria plantagenea), Suriname Grass (Brachiaria decumbens), Seban Sorghum (Sorghum) um halepense), shutter Kane (Andropogon sorghum) bermudagrass (Cynodon dactylon), oats (Avena fatua), darnel (Lolium mult
  • Potamogeton Pectinatus Water meal (Wolffia genus), water mills foil such (Myriophyllum spicatum, Myriophyllum heterophyllum etc.), water hyacinth (Eichhornia crassipes) or the like aquatic plants.
  • the herbicidal composition of the present invention is used as a herbicide in agricultural land such as paddy fields, fields, lawns, orchards, or non-agricultural land.
  • the composition for herbicidal use of the present invention is not limited, but can control weeds in the cultivated land, for example, in cultivated lands where the “plants” listed below are cultivated.
  • Plant Agricultural crops: corn, rice, wheat, barley, rye, sorghum, cotton, soybean, peanut, buckwheat, sugar beet, rapeseed, sunflower, sugarcane, tobacco, hop, etc.
  • Vegetables Solanum vegetables (eggplants, tomatoes, peppers, peppers, potatoes, etc.), cucurbits (cucumbers, pumpkins, zucchini, watermelons, melons, cucumbers, etc.), cruciferous vegetables (radish, turnip, horseradish, kohlrabi, Chinese cabbage) , Cabbage, mustard, broccoli, cauliflower, etc.), asteraceae vegetables (burdock, garlic, artichoke, lettuce, etc.), liliaceae vegetables (leek, onion, garlic, asparagus, etc.), celery family vegetables (carrot, parsley, celery, American Bow Fu etc.), Rubiaceae vegetables (spinach, chard, etc.), Lamiaceae vegetables (shiso, mint, basil, etc.), Legumes (peas, kidney beans, azuki bean, broad beans, chickpeas, etc.), strawberry, sweet potato, yam, taro , Konnyuk, ginger, ok Etc..
  • Fruit trees fruits (apples, pears, pears, quince, quince, etc.), nuclear fruits (peaches, plums, nectarines, umes, sweet cherry, apricots, prunes, etc.), citrus (citrus oranges, oranges, lemons, limes, grapefruits) ), Nuts (chestnut, walnut, hazel, almond, pistachio, cashew nut, macadamia nut, etc.), berries (blueberry, cranberry, blackberry, raspberry, etc.), grape, oyster, olive, loquat, banana, coffee, Date palm, coconut palm, oil palm etc.
  • Trees other than fruit trees tea, mulberry, flowering trees (Satsuki, camellia, hydrangea, sasanqua, shikimi cherry tree, yurinoki, crape myrtle, eustoma, etc.), roadside trees (ash, birch, dogwood, eucalyptus, ginkgo, lilac, maple, oak, poplar) , Japanese red clover, flatfish, plane tree, Japanese zelkova, blackfish, Japanese cypress, Japanese pine, spruce, yew, elm, Japanese cypress, coral, Japanese cypress, Japanese cedar, Japanese cypress, croton, Japanese cypress, kanamochi.
  • plants include genetically modified crops.
  • the herbicide of the present invention contains the herbicidal composition of the present invention, that is, the present compound and at least one herbicidally active compound, may contain a safener, and in some cases, two or more herbicidal activities.
  • a compound may be contained.
  • the herbicide of the present invention usually contains formulation aids and the like according to conventional methods, and is not limited to, for example, powders, emulsions, oils, solubilizers, suspoemulsions, fine granules, sprays DL powder, fine granule F, fine granule F, granule, wettable powder, wettable granule, flowable, jumbo, tablet, paste, oily suspension, aqueous solvent, granular aqueous solvent, liquid, It is preferable to formulate and use it in any dosage form such as a microcapsule.
  • Formulation aids that can be used for formulation are not limited, and examples include solid carriers, liquid carriers, binders, thickeners, surfactants, antifreeze agents, and preservatives.
  • solid carrier examples include, but are not limited to, for example, talc, bentonite, montmorillonite, clay, kaolin, calcium carbonate, sodium carbonate, sodium bicarbonate, sodium sulfate, zeolite, starch, acid clay, diatomaceous earth, white carbon, vermiculite, Examples include slaked lime, vegetable powder, alumina, activated carbon, saccharides, glass hollow bodies, silica sand, ammonium sulfate, urea, and the like.
  • liquid carrier examples include, but are not limited to, hydrocarbons (eg, kerosene, mineral oil, etc.); aromatic hydrocarbons (eg, toluene, xylene, dimethylnaphthalene, phenylxylylethane, etc.); chlorine Hydrocarbons (eg, chloroform, carbon tetrachloride, etc.); ethers (eg, dioxane, tetrahydrofuran, etc.); ketones (eg, acetone, cyclohexanone, isophorone, etc.); esters (eg, ethyl acetate, ethylene glycol acetate) Alcohols (eg, methanol, n-hexanol, ethylene glycol, etc.); polar solvents (eg, N, N-dimethylformamide, dimethyl sulfoxide, N-methylpyrrolidone, etc.); water, etc. It is done.
  • hydrocarbons eg, keros
  • binder and the thickener examples include, but are not limited to, for example, dextrin, sodium salt of carboxymethyl cellulose, polycarboxylic acid polymer compound, polyvinyl pyrrolidone, polyvinyl alcohol, sodium lignin sulfonate, calcium lignin sulfonate. , Sodium polyacrylate, gum arabic, sodium alginate, mannitol, sorbitol, bentonite minerals, polyacrylic acid and its derivatives, white carbon, natural sugar derivatives (eg, xanthan gum, guar gum, etc.), and the like.
  • surfactant examples include, but are not limited to, for example, fatty acid salts, benzoates, alkylsulfosuccinates, dialkylsulfosuccinates, polycarboxylates, alkyl sulfate esters, alkyl sulfates, alkylaryl sulfates.
  • antifreezing agent examples include, but are not limited to, ethylene glycol, diethylene glycol, propylene glycol, and glycerin.
  • solid carriers liquid carriers, binders, thickeners, surfactants, antifreezing agents and preservatives described above can be used alone or in appropriate combination depending on the purpose of use.
  • an adjuvant may be added to the sprayed solution.
  • the auxiliary agent that can be added is not limited, but includes, for example, surfactants (nonionic surfactants such as fatty acid alkyl esters and alkyl polyoxyethylene ethers, alkylbenzene sulfonates, dialkyldimethylammonium salts, and the like). Ionic surfactants), crop oil, vital oil, crop oil concentrate, methylated seed oil, organosilicon spreader, liquid fertilizer (ammonium sulfate, urea ammonia nitrate, etc.). These adjuvants may be used alone or in combination of two or more.
  • the compounding ratio of the present compound and the herbicidally active compound as an active substance of the herbicidal composition of the present invention can be varied in a wide range depending on the form of the preparation and the purpose of use. 1000, preferably 1: 0.01 to 100, more preferably 1: 0.1 to 100.
  • the method for controlling weeds with the herbicidal composition of the present invention comprises applying an effective amount of the present compound and an effective amount of the herbicidally active compound, and optionally an effective amount of at least one safener to a weed or soil where weeds grow. It is.
  • Examples of the method for applying the herbicidal composition of the present invention include a method of treating the herbicidal composition of the present invention with a foliage treatment on weeds, a method of treating the present herbicidal composition on the soil surface where weeds grow, and the present herbicidal process. And a method of admixing the composition for use in soil where weeds grow.
  • the total amount of the present compound and the herbicidal active compound per 10000 m 2 for controlling weeds, and optionally the safener is usually 1 to 10000 g, preferably 1 to 5000 g, more preferably. 1 to 1000 g.
  • the herbicidal composition of the present invention can also be prepared by formulating each active ingredient and then mixing them.
  • the herbicidal composition of the present invention can be mixed or used in combination with insecticides, acaricides, nematicides, fungicides, plant growth regulators, fertilizers, soil conditioners and the like.
  • Formulation Example 3 Compound 1 1 part Propyrisulfuron 0.9 part Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 75.1 parts After mixing and grinding uniformly, a small amount of water is added and mixed with stirring. And granulated with an extrusion granulator and dried to obtain a preparation.
  • Formulation Example 5 (wettable powder) Compound 2 10 parts Bensulfuron methyl 5 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 80 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 7 Compound 2 1 part Metazosulfuron 1 part Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 75 parts Granulate and dry to obtain the formulation.
  • Formulation Example 8 (Granule wettable powder) Compound 2 20 parts Limsulfuron 2.4 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 63.6 parts Granulate with a granulator and dry to obtain a formulation.
  • Formulation Example 11 Compound 16 1 part propyrisulfuron 0.9 part dialkylsulfosuccinate 2 parts lignin sulfonate 1 part bentonite 20 parts calcium carbonate 75.1 parts And granulated with an extrusion granulator and dried to obtain a preparation.
  • Formulation Example 12 (Granular wettable powder) Compound 16 20 parts Halosulfuron methyl 10 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrate sulfonate 5 parts Clay 56 parts Granulate and dry to obtain the formulation.
  • Formulation Example 13 (wettable powder) Compound 20 10 parts Bensulfuron methyl 5 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 80 parts
  • Formulation Example 15 Compound 20 1 part Metazosulfuron 1 part Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 75 parts Granulate and dry to obtain the formulation.
  • Formulation Example 16 (Granule wettable powder) Compound 20 20 parts rimsulfuron 2.4 parts polyoxyethylene alkyl ether sulfate 9 parts ligrin sulfonate 5 parts clay 63.6 parts Granulate with a granulator and dry to obtain a formulation.
  • Formulation Example 17 Compound 1 1 part Imazosulfuron 0.9 part Bromobutide 9 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 66.1 parts Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 18 Compound 2 1 part Imazosulfuron 0.9 part Bromobutide 9 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 66.1 parts Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 19 Compound 16 1 part imazosulfuron 0.9 part bromobutide 9 parts dialkylsulfosuccinate 2 parts lignin sulfonate 1 part bentonite 20 parts calcium carbonate 66.1 parts Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 20 Compound 23 1 part Imazosulfuron 0.9 part Bromobutide 9 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 66.1 parts After mixing and grinding uniformly, a small amount of water is added and stirred Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 22 Compound 2 1 part Propyrisulfuron 0.9 part Daimlone 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.6 parts After mixing and grinding uniformly, a small amount of water Is added to the mixture, and the mixture is stirred, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 23 Compound 16 1 part Propyrisulfuron 0.9 part Daimlone 4.5 part Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.6 parts After mixing and grinding uniformly, a small amount of water Is added to the mixture, and the mixture is stirred, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 24 Compound 20 1 part Propyrisulfuron 0.9 part Daimlone 4.5 part Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.6 parts After mixing and grinding uniformly, a small amount of water Is added to the mixture, and the mixture is stirred, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 25 Compound 23 1 part Propyrisulfuron 0.9 part Daimlone 4.5 part Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.6 parts After mixing and grinding uniformly, a small amount of water Is added to the mixture, and the mixture is stirred, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 26 (wettable powder) Compound 1 5 parts Pendimethalin 30 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 60 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 28 Compound 1 1 part Molinate 24 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 52 parts Granulate and dry to obtain the formulation.
  • Formulation Example 29 (Granule wettable powder) Compound 1 10 parts Triadifram 20 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligulin sulfonate 5 parts Clay 56 parts After mixing and grinding uniformly, a small amount of water is added and mixed with stirring, and granulated with an extrusion granulator. And dried to obtain a preparation.
  • Formulation Example 30 (wettable powder) Compound 2 10 parts isoxaben 18 parts polyoxyethylene alkyl ether sulfate 5 parts clay 67 parts uniformly mixed and pulverized to obtain a preparation.
  • Formulation Example 32 Compound 2 1 part Benthuride 30 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 46 parts After mixing and grinding uniformly, a small amount of water is added and stirred and mixed, and an extrusion granulator Granulate and dry to obtain the formulation.
  • Formulation Example 33 (granular wettable powder) Compound 2 10 parts Dithiopyr 20 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 56 parts And dried to obtain a preparation.
  • Formulation Example 34 (wettable powder) Compound 16 5 parts pendimethalin 30 parts polyoxyethylene alkyl ether sulfate 5 parts clay 60 parts uniformly mixed and pulverized to obtain a preparation.
  • Formulation Example 36 Compound 16 1 part Molinate 24 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 52 parts Granulate and dry to obtain the formulation.
  • Formulation Example 37 (Granule wettable powder) Compound 16 10 parts Triadifram 20 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 56 parts And dried to obtain a preparation.
  • Formulation Example 38 (wettable powder) Compound 20 10 parts Isoxaben 18 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 67 parts
  • Formulation Example 39 (Flowable) Compound 20 2 parts benzophenap 18 parts polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts ethylene glycol 5 parts silicone emulsion 0.5 parts sorbic acid 0.5 parts sodium montmorillonite 2 parts water 69 parts To obtain a formulation.
  • Formulation Example 40 Compound 20 1 part Benthuride 30 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 46 parts Granulate and dry to obtain the formulation.
  • Formulation Example 41 (Granule wettable powder) Compound 20 10 parts Dithiopyr 20 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 56 parts And dried to obtain a preparation.
  • Formulation Example 42 Compound 1 1 part Diclobenil 7.5 parts Diuron 10 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 58.5 parts After mixing and grinding uniformly, a small amount of water is added and stirred Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 43 Compound 2 1 part Diclobenil 7.5 parts Diuron 10 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 58.5 parts After mixing and grinding uniformly, add a small amount of water and stir Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 44 Compound 16 1 part diclobenil 7.5 parts diuron 10 parts dialkylsulfosuccinate 2 parts lignin sulfonate 1 part bentonite 20 parts calcium carbonate 58.5 parts Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 45 Compound 23 1 part Diclobenil 7.5 parts Diuron 10 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 58.5 parts After mixing and grinding uniformly, a small amount of water is added and stirred Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 46 Compound 1 1 part Bromobutide 9 parts Daimlone 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 62.5 parts After mixing and grinding uniformly, a small amount of water is added and stirred Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 47 Compound 2 1 part Bromobutide 9 parts Daimlone 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 62.5 parts After mixing and grinding uniformly, a small amount of water is added and stirred Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 48 Compound 16 1 part Bromobutide 9 parts Daimlone 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 62.5 parts After mixing and grinding uniformly, a small amount of water is added and stirred Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 49 Compound 20 1 part Bromobutide 9 parts Daimlone 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 62.5 parts After mixing and grinding uniformly, a small amount of water is added and stirred Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 51 (wettable powder) Compound 1 5 parts Diuron 24 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 66 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 53 Compound 1 1 part Propanyl 17.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 58.5 parts After mixing and grinding uniformly, a small amount of water is added and mixed with stirring. Granulate with an extrusion granulator and dry to obtain a formulation.
  • Formulation Example 54 (Granule wettable powder) Compound 1 10 parts Linuron 50 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 26 parts After mixing and crushing uniformly, a small amount of water is added and mixed with stirring, and granulated with an extrusion granulator. And dried to obtain a preparation.
  • Formulation Example 56 (Flowable) Compound 2 2 parts pyridate 1.6 parts polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts ethylene glycol 5 parts silicone emulsion 0.5 parts sorbic acid 0.5 parts sodium montmorillonite 2 parts water 85.4 parts Wet mill to obtain the formulation.
  • Formulation Example 57 Compound 2 1 part Cymetrin 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 71.5 parts After mixing and grinding uniformly, a small amount of water is added and stirred and mixed. Granulate with an extrusion granulator and dry to obtain a formulation.
  • Formulation Example 58 (Granule wettable powder) Compound 2 10 parts Aioxynil 30 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 54 parts And dried to obtain a preparation.
  • Formulation Example 59 (wettable powder) Compound 16 5 parts Diuron 24 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 66 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 61 Compound 16 1 part propanyl 17.5 parts dialkylsulfosuccinate 2 parts lignin sulfonate 1 part bentonite 20 parts calcium carbonate 58.5 parts Granulate with an extrusion granulator and dry to obtain a formulation.
  • Formulation Example 62 (granular wettable powder) Compound 16 10 parts Linuron 50 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 26 parts After mixing and grinding uniformly, a small amount of water is added and stirred and granulated with an extrusion granulator. And dried to obtain a preparation.
  • Formulation Example 63 (wettable powder) Compound 20 10 parts Bromoxinyl 50 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 35 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 64 (Flowable) Compound 20 2 parts pyridate 1.6 parts polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts ethylene glycol 5 parts silicone emulsion 0.5 parts sorbic acid 0.5 parts sodium montmorillonite 2 parts water 85.4 parts Wet mill to obtain the formulation.
  • Formulation Example 65 Compound 1 1 part Cymetrine 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 71.5 parts Granulate with an extrusion granulator and dry to obtain a formulation.
  • Formulation Example 66 (Granule wettable powder) Compound 20 10 parts Aioxynil 30 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 54 parts After mixing and grinding uniformly, a small amount of water is added and mixed with stirring, and granulated with an extrusion granulator. And dried to obtain a preparation.
  • Formulation Example 67 Compound 1 1 part Cymetrine 4.5 parts MCPB 0.24 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 71.26 parts After mixing and grinding uniformly, a small amount of water is added. The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 68 (Granule) Compound 2 1 part Cymetrine 4.5 parts MCPB 0.24 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 71.26 parts After mixing and grinding uniformly, a small amount of water is added The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 69 (Granule) Compound 16 1 part Cymetrine 4.5 parts MCPB 0.24 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 71.26 parts After mixing and grinding uniformly, a small amount of water is added The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 70 (Granule) Compound 23 1 part Cymetrine 4.5 parts MCPB 0.24 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 71.26 parts After mixing and grinding uniformly, a small amount of water is added The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 71 Compound 1 1 part Bromoxinyl 5 parts Croquintoset mexil 0.25 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.75 parts After mixing and grinding uniformly, a small amount of water Is added to the mixture, and the mixture is stirred, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 72 Compound 2 1 part Bromoxinyl 5 parts Croquintoset mexil 0.25 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.75 parts After mixing and grinding uniformly, a small amount of water Is added to the mixture, and the mixture is stirred, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 73 Compound 16 1 part Bromoxinyl 5 parts Croquintoset mexil 0.25 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.75 parts After mixing and grinding uniformly, a small amount of water Is added to the mixture, and the mixture is stirred, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 74 (Granule) Compound 20 1 part Bromoxinyl 5 parts Croquintoset mexil 0.25 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.75 parts After mixing and grinding uniformly, a small amount of water Is added to the mixture, and the mixture is stirred, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 75 Compound 23 1 part Bromoxynil 5 parts Croquintoset mexil 0.25 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.75 parts After mixing and grinding uniformly, a small amount of water Is added to the mixture, and the mixture is stirred, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 76 (wettable powder) Compound 1 10 parts flumioxazin 5 parts polyoxyethylene alkyl ether sulfate 5 parts clay 80 parts uniformly mixed and pulverized to obtain a preparation.
  • Formulation Example 77 (Flowable) Compound 1 2 parts carfentrazone ethyl 1.8 parts polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts ethylene glycol 5 parts silicone emulsion 0.5 parts sorbic acid 0.5 parts sodium montmorillonite 2 parts water 85.2 parts Are mixed and wet pulverized to obtain a preparation.
  • Formulation Example 78 (Granule) Compound 1 1 part Pyraclonil 2 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 74 parts Granulate and dry to obtain the formulation.
  • Formulation Example 79 (Granule wettable powder) Compound 1 20 parts Fruthiaset methyl 10 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 56 parts After mixing and grinding uniformly, a small amount of water is added and stirred and mixed with an extrusion granulator. Granulate and dry to obtain the formulation.
  • Formulation Example 80 (wettable powder) Compound 2 10 parts Saflufenacil 7.5 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 77.5 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 82 (Granule) Compound 2 1 part Lactofen 1 part Dialkylsulfosuccinate 1 part Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 75 parts Granulate and dry to obtain the formulation.
  • Formulation Example 83 (Granule wettable powder) Compound 2 20 parts Butaphenacil 36 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 30 parts And dried to obtain a preparation.
  • Formulation Example 84 (wettable powder) Compound 16 10 parts flumioxazin 5 parts polyoxyethylene alkyl ether sulfate 5 parts clay 80 parts uniformly mixed and pulverized to obtain a preparation.
  • Formulation Example 86 (Granule) Compound 16 1 part Pyraclonil 2 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 74 parts Granulate and dry to obtain the formulation.
  • Formulation Example 87 (Granule wettable powder) Compound 16 20 parts Fruthiaset methyl 10 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 56 parts After mixing and grinding uniformly, a small amount of water is added and stirred and mixed with an extrusion granulator. Granulate and dry to obtain the formulation.
  • Formulation Example 88 (wettable powder) Compound 20 10 parts Saflufenacyl 7.5 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 77.5 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 90 Compound 20 1 part Lactofen 1 part Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 75 parts After mixing and grinding uniformly, a small amount of water is added and stirred and mixed, and an extrusion granulator Granulate and dry to obtain the formulation.
  • Formulation Example 91 (Granule wettable powder) Compound 20 20 parts Butaphenacil 36 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 30 parts After mixing and crushing uniformly, a small amount of water is added and stirred and granulated with an extrusion granulator. And dried to obtain a preparation.
  • Formulation Example 92 Compound 1 1 part Pyraclonil 1 part Bromobutide 9 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 66 parts Granulate with a granulator and dry to obtain a formulation.
  • Formulation Example 93 (Granule) Compound 2 1 part Pyraclonil 1 part Bromobutide 9 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 66 parts After mixing and grinding uniformly, a small amount of water is added to the mixture and stirred and extruded. Granulate with a granulator and dry to obtain a formulation.
  • Formulation Example 94 (Granule) Compound 16 1 part Pyraclonil 1 part Bromobutide 9 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 66 parts Granulate with a granulator and dry to obtain a formulation.
  • Formulation Example 96 (Granule) Compound 1 1 part Pyraclonil 2 parts Daimron 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 69.5 parts After mixing and grinding uniformly, a small amount of water is added and stirred Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 97 Compound 2 1 part Pyraclonil 2 parts Daimron 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 69.5 parts After mixing and grinding uniformly, add a small amount of water and stir Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 98 (Granule) Compound 16 1 part Pyraclonil 2 parts Daimlone 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 69.5 parts After mixing and grinding uniformly, a small amount of water is added and stirred Mix, granulate with an extrusion granulator and dry to obtain a formulation.
  • Formulation Example 99 Compound 20 1 part Pyraclonil 2 parts Daimlon 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 69.5 parts After mixing and grinding uniformly, a small amount of water is added and stirred Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 100 Compound 23 1 part Pyraclonil 2 parts Daimron 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 69.5 parts After mixing and grinding uniformly, a small amount of water is added and stirred Mix, granulate with an extrusion granulator, and dry to obtain a formulation.
  • Formulation Example 101 (wettable powder) Compound 1 5 parts Mesotrione 2.5 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 87.5 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 102 (Flowable) Compound 1 2 parts isoxaflutol 1.5 parts polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts ethylene glycol 5 parts silicone emulsion 0.5 parts sorbic acid 0.5 parts sodium montmorillonite 2 parts water 85.5 parts Mix and wet mill to obtain the formulation.
  • Formulation Example 103 Compound 1 1 part Tefryltrione 3 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 73 parts Granulate with a granulator and dry to obtain a formulation.
  • Formulation Example 104 (Granule wettable powder) Compound 1 10 parts Beflubutamide 50 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 26 parts After mixing and crushing uniformly, a small amount of water is added and stirred and granulated with an extrusion granulator And dried to obtain a preparation.
  • Formulation Example 105 (wettable powder) Compound 2 10 parts Diflufenican 8 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 77 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 106 (Flowable) Compound 2 2 parts benzophenap 3.8 parts polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts ethylene glycol 5 parts silicone emulsion 0.5 parts sorbic acid 0.5 parts sodium montmorillonite 2 parts water 83.2 parts mixed And wet pulverized to obtain a preparation.
  • Formulation Example 107 (Granule) Compound 2 1 part Pyrazolate 30 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 46 parts Granulate and dry to obtain the formulation.
  • Formulation Example 108 (Granule wettable powder) Compound 2 10 parts Topramison 3.6 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligulin sulfonate 5 parts Clay 80.4 parts Granulate with a machine and dry to obtain the formulation.
  • Formulation Example 109 (wettable powder) Compound 16 5 parts Mesotrione 2.5 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 87.5 parts
  • Formulation Example 110 (Flowable) Compound 16 2 parts isoxaflutol 1.5 parts polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts ethylene glycol 5 parts silicone emulsion 0.5 parts sorbic acid 0.5 parts sodium montmorillonite 2 parts water 85.5 parts Mix and wet mill to obtain the formulation.
  • Formulation Example 112 (Granule wettable powder) Compound 16 10 parts Beflubutamide 50 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 26 parts After mixing and grinding uniformly, a small amount of water is added and mixed with stirring, and granulated with an extrusion granulator. And dried to obtain a preparation.
  • Formulation Example 113 (wettable powder) Compound 20 10 parts Diflufenican 8 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 77 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 114 (Flowable) Compound 20 2 parts benzophenap 3.8 parts polyoxyethylene allylphenyl ether phosphate amine salt 3 parts ethylene glycol 5 parts silicone emulsion 0.5 parts sorbic acid 0.5 parts sodium montmorillonite 2 parts water 83.2 parts And wet pulverized to obtain a preparation.
  • Formulation Example 115 Compound 1 1 part Pyrazolate 30 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 46 parts Granulate and dry to obtain the formulation.
  • Formulation Example 116 (Granule wettable powder) Compound 20 10 parts Topramisone 3.6 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 80.4 parts Granulate with a machine and dry to obtain the formulation.
  • Formulation Example 117 Compound 1 1 part benzophenap 1.9 parts benzobicyclone 2 parts dialkylsulfosuccinate 2 parts lignin sulfonate 1 part bentonite 20 parts calcium carbonate 72.1 parts After mixing and grinding uniformly, a small amount of water Is added to the mixture, and the mixture is stirred, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 118 (Granule) Compound 2 1 part benzophenap 1.9 parts benzobicyclone 2 parts dialkylsulfosuccinate 2 parts lignin sulfonate 1 part bentonite 20 parts calcium carbonate 72.1 parts After mixing and grinding uniformly, a small amount of water Is added to the mixture, and the mixture is stirred, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 119 Compound 16 1 part benzophenap 1.9 parts benzobicyclone 2 parts dialkylsulfosuccinate 2 parts lignin sulfonate 1 part bentonite 20 parts calcium carbonate 72.1 parts Is added to the mixture, and the mixture is stirred, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 120 Compound 23 1 part benzophenap 1.9 parts benzobicyclone 2 parts dialkylsulfosuccinate 2 parts lignin sulfonate 1 part bentonite 20 parts calcium carbonate 72.1 parts Is added to the mixture, and the mixture is stirred, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 121 (Granule) Compound 1 1 part Tefryltrione 3 parts Daimlon 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 68.5 parts After mixing and grinding uniformly, add a small amount of water The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 122 (Granule) Compound 2 1 part Tefryltrione 3 parts Daimlone 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 68.5 parts After mixing and grinding uniformly, add a small amount of water The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 123 Compound 16 1 part Tefryltrione 3 parts Daimlon 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 68.5 parts After mixing and grinding uniformly, a small amount of water is added. The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 124 (Granule) Compound 20 1 part Tefryltrione 3 parts Daimron 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 68.5 parts After mixing and grinding uniformly, a small amount of water is added. The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 125 (Granule) Compound 23 1 part Tefryltrione 3 parts Daimlone 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 68.5 parts After mixing and grinding uniformly, a small amount of water is added. The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 126 (wettable powder) Compound 1 5 parts alachlor 30 parts polyoxyethylene alkyl ether sulfate 5 parts clay 60 parts uniformly mixed and pulverized to obtain a preparation.
  • Formulation Example 127 (Flowable) Compound 1 2 parts S-metolachlor 10 parts polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts ethylene glycol 5 parts silicone emulsion 0.5 parts sorbic acid 0.5 parts sodium montmorillonite 2 parts water 77 parts Grind to obtain the formulation.
  • Formulation Example 128 Compound 1 1 part Butachlor 9 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 67 parts After uniformly mixing and pulverizing, a small amount of water is added and mixed by stirring. Granulate and dry to obtain the formulation.
  • Formulation Example 129 (granular wettable powder) Compound 1 10 parts Dimethenamide-P 40 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 36 parts After mixing and crushing uniformly, a small amount of water is added and mixed with stirring. Granulate and dry to obtain the formulation.
  • Formulation Example 130 (wettable powder) Compound 2 10 parts Flufenacet 50 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 35 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 132 (Granule) Compound 2 1 part Acetochlor 5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 71 parts After uniformly mixing and pulverizing, a small amount of water is added and mixed with stirring, followed by extrusion granulation Granulate with a machine and dry to obtain the formulation.
  • Formulation Example 133 (granular wettable powder) Compound 2 20 parts Indanophan 30 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 36 parts After mixing and crushing uniformly, a small amount of water is added and stirred and granulated using an extrusion granulator. And dried to obtain a preparation.
  • Formulation Example 134 (wettable powder) Compound 16 5 parts alachlor 30 parts polyoxyethylene alkyl ether sulfate 5 parts clay 60 parts uniformly mixed and pulverized to obtain a preparation.
  • Formulation Example 135 (Flowable) Compound 16 2 parts S-metolachlor 10 parts polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts ethylene glycol 5 parts silicone emulsion 0.5 parts sorbic acid 0.5 parts sodium montmorillonite 2 parts water 77 parts Grind to obtain the formulation.
  • Formulation Example 136 (Granule) Compound 16 1 part Butachlor 9 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 67 parts Granulate and dry to obtain the formulation.
  • Formulation Example 137 (Granule wettable powder) Compound 16 10 parts Dimethenamide-P 40 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 36 parts After mixing and grinding uniformly, a small amount of water is added and mixed with stirring. Granulate and dry to obtain the formulation.
  • Formulation Example 138 (wettable powder) Compound 20 10 parts Flufenacet 50 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 35 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 140 Compound 20 1 part acetochlor 5 parts dialkylsulfosuccinate 2 parts lignin sulfonate 1 part bentonite 20 parts calcium carbonate 71 parts Granulate with a machine and dry to obtain the formulation.
  • Formulation Example 141 (Granule wettable powder) Compound 20 20 parts Indanophan 30 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 36 parts After mixing and crushing uniformly, a small amount of water is added and stirred and granulated with an extrusion granulator. And dried to obtain a preparation.
  • Formulation Example 142 Compound 1 1 part S-metolachlor 5 parts croquintoset mexil 0.25 parts dialkylsulfosuccinate 2 parts lignin sulfonate 1 part bentonite 20 parts calcium carbonate 70.75 parts A small amount of water is added, mixed with stirring, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 143 Compound 2 1 part S-metolachlor 5 parts croquintoset mexil 0.25 parts dialkylsulfosuccinate 2 parts lignin sulfonate 1 part bentonite 20 parts calcium carbonate 70.75 parts A small amount of water is added, mixed with stirring, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 144 Compound 16 1 part S-metolachlor 5 parts croquintoset mexil 0.25 parts dialkylsulfosuccinate 2 parts lignin sulfonate 1 part bentonite 20 parts calcium carbonate 70.75 parts A small amount of water is added, mixed with stirring, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 145 (granule) Compound 23 1 part S-metolachlor 5 parts croquintoset mexil 0.25 parts dialkylsulfosuccinate 2 parts lignin sulfonate 1 part bentonite 20 parts calcium carbonate 70.75 parts A small amount of water is added, mixed with stirring, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 146 Compound 1 1 part F Caunule 5 parts Croquintoset mexil 0.25 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.75 parts The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 147 (Granule) Compound 2 1 part F Cauntoset mexil 0.25 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.75 parts The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 149 (Granule) Compound 20 1 part Flufenacet 5 parts Croquintoset mexil 0.25 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.75 parts The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 150 Compound 23 1 part fluphenacet 5 parts croquintoset mexil 0.25 parts dialkylsulfosuccinate 2 parts lignin sulfonate 1 part bentonite 20 parts calcium carbonate 70.75 parts The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 151 (wettable powder) Compound 1 5 parts Quinchlorac 20 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 70 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 152 (Flowable) Compound 1 2 parts Triclopyr 2 parts Polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts Ethylene glycol 5 parts Silicone emulsion 0.5 parts Sorbic acid 0.5 parts Sodium montmorillonite 2 parts Water 85 parts A formulation is obtained.
  • Formulation Example 153 Compound 1 1 part Chlomeprop 4.5 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 71.5 parts Granulate with an extrusion granulator and dry to obtain a formulation.
  • Formulation Example 154 (Granular wettable powder) Compound 1 10 parts Diflufenzopyr 30 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 46 parts After mixing and grinding uniformly, a small amount of water is added and mixed with stirring, and an extrusion granulator Granulate and dry to obtain the formulation.
  • Formulation Example 155 (wettable powder) Compound 2 10 parts Dichloroprop 3 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 82 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 156 (Flowable) Compound 2 2 parts oxadichromephone 1.2 parts polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts ethylene glycol 5 parts silicone emulsion 0.5 parts sorbic acid 0.5 parts sodium montmorillonite 2 parts water 85.8 parts Wet mill to obtain the formulation.
  • Formulation Example 157 (granule) Compound 2 1 part 2,4-D amine salt 5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 71 parts After mixing and grinding uniformly, a small amount of water is added and mixed with stirring And granulated with an extrusion granulator and dried to obtain a preparation.
  • Formulation Example 159 (wettable powder) Compound 16 5 parts Quinchlorac 20 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 70 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 160 (Flowable) Compound 16 2 parts triclopyr 2 parts polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts ethylene glycol 5 parts silicone emulsion 0.5 parts sorbic acid 0.5 parts sodium montmorillonite 2 parts water 85 parts A formulation is obtained.
  • Formulation Example 161 Compound 16 1 part Chlomeprop 4.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 71.5 parts After mixing and grinding uniformly, a small amount of water was added and mixed with stirring. Granulate with an extrusion granulator and dry to obtain a formulation.
  • Formulation Example 162 (Granule wettable powder) Compound 16 10 parts Diflufenzopyr 30 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 46 parts After mixing and grinding uniformly, a small amount of water is added and mixed with stirring, and an extrusion granulator Granulate and dry to obtain the formulation.
  • Formulation Example 163 (wettable powder) Compound 20 10 parts Dichloroprop 3 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 82 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 164 (Flowable) Compound 20 2 parts oxadichromephone 1.2 parts polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts ethylene glycol 5 parts silicone emulsion 0.5 parts sorbic acid 0.5 parts sodium montmorillonite 2 parts water 85.8 parts Wet mill to obtain the formulation.
  • Formulation Example 165 (granule) Compound 20 1 part 2,4-D amine salt 5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 71 parts After mixing and grinding uniformly, a small amount of water is added and mixed with stirring And granulated with an extrusion granulator and dried to obtain a preparation.
  • Formulation Example 166 (Granule wettable powder) Compound 20 20 parts MCPB 4.8 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 61.2 parts After mixing and crushing uniformly, a small amount of water is added and mixed with stirring, followed by extrusion granulation. Granulate with a machine and dry to obtain the formulation.
  • Formulation Example 167 Compound 1 1 part Cymetrine 4.5 parts MCPB 0.24 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 71.26 parts After mixing and grinding uniformly, a small amount of water is added. The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 169 (Granule) Compound 16 1 part Cymetrine 4.5 parts MCPB 0.24 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 71.26 parts After mixing and grinding uniformly, a small amount of water is added The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 170 Compound 23 1 part Cymetrine 4.5 parts MCPB 0.24 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 71.26 parts After mixing and grinding uniformly, a small amount of water is added The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 171 Compound 1 1 part Chromprop 4.5 parts Imazosulfuron 0.9 part Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.6 parts After mixing and grinding uniformly, a small amount of water is added The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 172 (Granule) Compound 2 1 part Chlomeprop 4.5 parts Imazosulfuron 0.9 part Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.6 parts After mixing and grinding uniformly, a small amount of water is added. The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 173 Compound 16 1 part Chlomeprop 4.5 parts Imazosulfuron 0.9 part Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.6 parts After mixing and grinding uniformly, a small amount of water is added. The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 174 (granule) Compound 20 1 part Chlomeprop 4.5 parts Imazosulfuron 0.9 part Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.6 parts After mixing and grinding uniformly, a small amount of water is added. The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 175 Compound 23 1 part Chlomeprop 4.5 parts Imazosulfuron 0.9 part Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 70.6 parts After mixing and grinding uniformly, a small amount of water is added. The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 176 (wettable powder) Compound 1 10 parts Metamihop 10 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 75 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 177 (Flowable) Compound 1 2 parts Cresite 0.48 parts Polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts Ethylene glycol 5 parts Silicone emulsion 0.5 parts Sorbic acid 0.5 parts Sodium montmorillonite 2 parts Water 86.52 parts Wet mill to obtain the formulation.
  • Formulation Example 178 Compound 1 1 part Cyhalohop butyl 3 parts Dialkyl sulfosuccinate ester 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 73 parts Granulate with a granulator and dry to obtain a formulation.
  • Formulation Example 179 (granular wettable powder) Compound 1 20 parts Fluazifop-P-butyl 24 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 42 parts After mixing and grinding uniformly, a small amount of water is added and mixed with stirring, followed by extrusion granulation Granulate with a machine and dry to obtain the formulation.
  • Formulation Example 180 (wettable powder) Compound 2 10 parts Crodina hop propargyl 10 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 75 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 181 (Flowable) Compound 2 2 parts Phenoxaprop-P-ethyl 2 parts Polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts Ethylene glycol 5 parts Silicone emulsion 0.5 parts Sorbic acid 0.5 parts Sodium montmorillonite 2 parts Water 85 parts And wet pulverized to obtain a preparation.
  • Formulation Example 182 Compound 2 1 part Cyhalohop butyl 3 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 73 parts Granulate with a granulator and dry to obtain a formulation.
  • Formulation Example 183 (Granule wettable powder) Compound 2 20 parts fluazifop-P-butyl 24 parts polyoxyethylene alkyl ether sulfate 9 parts lignosulfonate 5 parts clay 42 parts Granulate with a machine and dry to obtain the formulation.
  • Formulation Example 184 (wettable powder) Compound 16 10 parts Metamihop 10 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 75 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 185 (Flowable) Compound 16 2 parts Cresite 0.48 parts Polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts Ethylene glycol 5 parts Silicone emulsion 0.5 parts Sorbic acid 0.5 parts Sodium montmorillonite 2 parts Water 86.52 parts Wet mill to obtain the formulation.
  • Formulation Example 186 (granule) Compound 16 1 part Cyhalohop butyl 3 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 73 parts Granulate with a granulator and dry to obtain a formulation.
  • Formulation Example 187 (granular wettable powder) Compound 16 20 parts fluazifop-P-butyl 24 parts polyoxyethylene alkyl ether sulfate 9 parts ligrin sulfonate 5 parts clay 42 parts After mixing and grinding uniformly, a small amount of water is added and mixed with stirring, followed by extrusion granulation Granulate with a machine and dry to obtain the formulation.
  • Formulation Example 188 (wettable powder) Compound 20 10 parts Crodina hop propargyl 10 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 75 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 189 (Flowable) Compound 20 2 parts Phenoxaprop-P-ethyl 2 parts Polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts Ethylene glycol 5 parts Silicone emulsion 0.5 parts Sorbic acid 0.5 parts Sodium montmorillonite 2 parts Water 85 parts And wet pulverized to obtain a preparation.
  • Formulation Example 190 Compound 20 1 part Cyhalohop butyl 3 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 73 parts Granulate with a granulator and dry to obtain a formulation.
  • Formulation Example 191 (Granule wettable powder) Compound 20 20 parts Fluazifop-P-butyl 24 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligulin sulfonate 5 parts Clay 42 parts After mixing and grinding uniformly, a small amount of water is added and mixed with stirring, and extrusion granulation is performed. Granulate with a machine and dry to obtain the formulation.
  • Formulation Example 192 (Granule) Compound 1 1 part Cyhalohop butyl 3 parts Penox slam 0.36 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 72.64 parts After uniformly mixing and grinding, a small amount of water In addition, it is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 193 Compound 2 1 part Cyhalohop butyl 3 parts Penox slum 0.36 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 72.64 parts After uniformly mixing and grinding, a small amount of water In addition, it is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 194 Compound 16 1 part Cyhalohop butyl 3 parts Penoxsulam 0.36 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 72.64 parts After uniformly mixing and grinding, a small amount of water In addition, it is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 195 (Granule) Compound 23 1 part Cyhalohop butyl 3 parts Penox slam 0.36 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 72.64 parts After uniformly mixing and grinding, a small amount of water In addition, it is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 196 (Granule) Compound 1 1 part Cyhalohop butyl 3 parts Mesotrione 0.5 part Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 72.64 parts After uniformly mixing and grinding, a small amount of water In addition, it is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 197 (Granule) Compound 2 1 part Cyhalohop butyl 3 parts Mesotrione 0.5 part Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 72.64 parts After uniformly mixing and grinding a small amount of water In addition, it is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 198 (Granule) Compound 16 1 part Cyhalohop butyl 3 parts Mesotrione 0.5 part Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 72.64 parts After uniformly mixing and grinding a small amount of water In addition, it is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 199 Compound 20 1 part Cyhalohop butyl 3 parts Mesotrione 0.5 part Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 72.64 parts After uniformly mixing and grinding a small amount of water In addition, it is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 200 Compound 23 1 part Cyhalohop butyl 3 parts Mesotrione 0.5 part Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 72.64 parts After uniformly mixing and grinding, a small amount of water In addition, it is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 201 (wettable powder) Compound 1 5 parts Biaraphos 67.5 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 22.5 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 203 Compound 1 1 part Glyphosate ammonium 40 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 36 parts Granulate with a machine and dry to obtain the formulation.
  • Formulation Example 204 (Granule wettable powder) Compound 1 10 parts Endotal 30 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 46 parts After mixing and grinding uniformly, a small amount of water is added and mixed with stirring. Granulate and dry to obtain the formulation.
  • Formulation Example 205 (wettable powder) Compound 2 10 parts d-limonene 15 parts polyoxyethylene alkyl ether sulfate 5 parts clay 70 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 206 (Flowable) Compound 2 1 part Diquat dibromide 50 parts Polyoxyethylene allyl phenyl ether phosphate amine salt 3 parts Ethylene glycol 5 parts Silicone emulsion 0.5 parts Sorbic acid 0.5 parts Sodium montmorillonite 2 parts Water 38 parts To obtain a formulation.
  • Formulation Example 207 (granule) Compound 2 1 part Pelargonic acid 25 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 51 parts Granulate with a machine and dry to obtain the formulation.
  • Formulation Example 208 (wettable powder) Compound 16 5 parts Biaraphos 67.5 parts Polyoxyethylene alkyl ether sulfate 5 parts Clay 22.5 parts are mixed and ground uniformly to obtain a preparation.
  • Formulation Example 210 (Granule) Compound 16 1 part Glyphosate ammonium 40 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 36 parts After uniformly mixing and pulverizing, a small amount of water is added and mixed with stirring, followed by extrusion granulation Granulate with a machine and dry to obtain the formulation.
  • Formulation Example 211 (Granule wettable powder) Compound 16 10 parts Endal 30 parts Polyoxyethylene alkyl ether sulfate 9 parts Ligrin sulfonate 5 parts Clay 46 parts After mixing and crushing uniformly, a small amount of water is added and mixed with stirring. Granulate and dry to obtain the formulation.
  • Formulation Example 214 (Granule) Compound 20 1 part Pelargonic acid 25 parts Dialkylsulfosuccinic acid ester salt 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 51 parts After mixing and pulverizing uniformly, a small amount of water is added and mixed with stirring, followed by extrusion granulation Granulate with a machine and dry to obtain the formulation.
  • Formulation Example 216 (Granule) Compound 2 1 part Glyphosate ammonium 40 parts Flumioxazin 0.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 35.5 parts After mixing and grinding uniformly, a small amount of water is added. The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 217 Compound 16 1 part Glyphosate ammonium 40 parts Flumioxazin 0.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 35.5 parts After mixing and grinding uniformly, a small amount of water is added. The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Formulation Example 218 Compound 23 1 part Glyphosate ammonium 40 parts Flumioxazin 0.5 parts Dialkylsulfosuccinate 2 parts Lignin sulfonate 1 part Bentonite 20 parts Calcium carbonate 35.5 parts After mixing and grinding uniformly, a small amount of water is added. The mixture is stirred and mixed, granulated with an extrusion granulator, and dried to obtain a preparation.
  • Test Example 1 Field Cropping Soil Treatment Test A 1/6000 are pot was filled with field soil and seeded with seeds of Dingitaria ciriaris, Shiroza (Chenopodium album) and Agateanth (Amaranthus retroflexus). After the sowing and before the generation of weeds, the spraying solution of the herbicidal composition of the present invention was uniformly sprayed over the entire surface of the soil so as to have a predetermined dosage. The spray solution was prepared by diluting a predetermined amount of each compound, polyoxyethylene alkyl ether sulfate, and clay obtained by uniformly mixing and pulverizing them with water.
  • Test Example 2 Field crop foliage treatment test 1/6000 are pot filled with field soil, seeds of tiger beetle (Digitaria ciriaris), white crow (Chenopodium album), Agateanthus (Amaranthus retroflexus) are seeded and covered, glass room with an average temperature of 25 ° C Cultivated in At the time when the bark was grown at the leaf stage of 1.0 to 2.0, the entire plant was sprayed uniformly with the spray solution of the herbicidal composition of the present invention so as to have a predetermined dosage.
  • the spray solution was prepared by diluting a predetermined amount of each compound, polyoxyethylene alkyl ether sulfate, and clay obtained by uniformly mixing and pulverizing them with water. And after managing for 3 weeks in the glass room of average temperature 25 degreeC, those weeding effects were investigated. Evaluation of the herbicidal effect was performed in the same manner as in Test Example 1. The results are shown in Table 3.
  • Test Example 3 Paddy field weeding test 1 / 10,000 are pot filled with paddy soil, kneaded with appropriate amount of water and chemical fertilizer, seeded with Echinochloa oryzicola, Monochoria vaginalis, and firefly (Sirpus juncoides) seeds The submerged state was maintained at a depth of 3 cm.
  • the spray solution of the herbicidal composition of the present invention was dropped using a pipette so as to have a predetermined dosage.
  • the spray solution was prepared by diluting a predetermined amount of each compound, polyoxyethylene alkyl ether sulfate, and clay obtained by uniformly mixing and pulverizing them with water. And after managing for 30 days in the glass room of average temperature 30 degreeC, those weeding effects were investigated. Evaluation of the herbicidal effect was performed in the same manner as in Test Example 1. The results are shown in Table 4.
  • the herbicidal composition of the present invention is useful for controlling weeds.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

L'invention concerne une composition herbicide ayant une excellente action de lutte contre les mauvaises herbes. La composition herbicide est caractérisée en ce qu'elle contient un dérivé de pyrazolyl-pyrazole représenté par la formule (I) et au moins un type de composé choisi parmi des composés à action herbicide, en particulier des inhibiteurs d'ALS, des inhibiteurs de germination/croissance, des inhibiteurs de photosynthèse, des inhibiteurs de PPO, des agents induisant une chlorose, des inhibiteurs de VLCFA, des agents qui inhibent/perturbent l'action hormonale, des inhibiteurs de l'ACCase et des herbicides non-sélectifs.
PCT/JP2016/052578 2015-01-30 2016-01-29 Composition herbicide Ceased WO2016121900A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2015016906A JP2016141628A (ja) 2015-01-30 2015-01-30 除草剤組成物
JP2015-016906 2015-01-30

Publications (1)

Publication Number Publication Date
WO2016121900A1 true WO2016121900A1 (fr) 2016-08-04

Family

ID=56543504

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2016/052578 Ceased WO2016121900A1 (fr) 2015-01-30 2016-01-29 Composition herbicide

Country Status (2)

Country Link
JP (1) JP2016141628A (fr)
WO (1) WO2016121900A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112341456A (zh) * 2019-08-07 2021-02-09 海利尔药业集团股份有限公司 一种取代的吡唑基吡唑双酰胺类化合物或其作为农药可接受的盐、组合物及其用途

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08506086A (ja) * 1992-10-12 1996-07-02 ヘキスト．シェーリング アーグレヴオ ゲゼルシャフト ミット ベシュレンクテル ハフツング 新規の置換ピラゾール誘導体、その製造法および該化合物の除草剤としての使用
JP2007186460A (ja) * 2006-01-13 2007-07-26 Bayer Cropscience Kk 水田用除草剤組成物
WO2008099889A1 (fr) * 2007-02-15 2008-08-21 Ishihara Sangyo Kaisha, Ltd. Composition herbicide
WO2015022925A1 (fr) * 2013-08-13 2015-02-19 協友アグリ株式会社 Dérivés de pyrazolyl pyrazole substitué et son utilisation comme herbicide

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08506086A (ja) * 1992-10-12 1996-07-02 ヘキスト．シェーリング アーグレヴオ ゲゼルシャフト ミット ベシュレンクテル ハフツング 新規の置換ピラゾール誘導体、その製造法および該化合物の除草剤としての使用
JP2007186460A (ja) * 2006-01-13 2007-07-26 Bayer Cropscience Kk 水田用除草剤組成物
WO2008099889A1 (fr) * 2007-02-15 2008-08-21 Ishihara Sangyo Kaisha, Ltd. Composition herbicide
WO2015022925A1 (fr) * 2013-08-13 2015-02-19 協友アグリ株式会社 Dérivés de pyrazolyl pyrazole substitué et son utilisation comme herbicide

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112341456A (zh) * 2019-08-07 2021-02-09 海利尔药业集团股份有限公司 一种取代的吡唑基吡唑双酰胺类化合物或其作为农药可接受的盐、组合物及其用途
WO2021023292A1 (fr) * 2019-08-07 2021-02-11 海利尔药业集团股份有限公司 Composé de pyrazolyl pyrazole substitué ou sel ou composition pesticide acceptable de celui-ci et utilisation associée
CN112341456B (zh) * 2019-08-07 2024-01-05 海利尔药业集团股份有限公司 一种取代的吡唑基吡唑双酰胺类化合物或其作为农药可接受的盐、组合物及其用途

Also Published As

Publication number Publication date
JP2016141628A (ja) 2016-08-08

Similar Documents

Publication Publication Date Title
CA2867693C (fr) Composition herbicide comprenant un compose uracile comme ingredient actif
JP2012171928A (ja) 除草組成物および雑草の防除方法
WO2013080484A1 (fr) Composition d&#39;herbicide
EP3407719B1 (fr) Composition herbicide synergique et procédé de régulation de la pousse de plantes indésirables
JP6783575B2 (ja) 除草剤組成物
CN101778565B (zh) 除草用组合物
JP6584079B2 (ja) 除草剤組成物
WO2016121898A1 (fr) Composition herbicide
WO2010104090A1 (fr) Composition herbicide et procédé de lutte contre les mauvaises herbes
CN108366563B (zh) 用于马铃薯的除草剂混合物及制剂
WO2016121900A1 (fr) Composition herbicide
WO2016121902A1 (fr) Composition herbicide
JP2013155125A (ja) 除草用組成物
CN106489972A (zh) 一种除草组合物
CN105284849B (zh) 一种除草组合物
WO2024192154A1 (fr) Composition herbicide et procédé de lutte contre les mauvaises herbes
JP2024148446A (ja) 除草剤組成物
CN108235988A (zh) 一种除草组合物及其应用
CN106489970A (zh) 一种除草组合物
JP2024148449A (ja) 除草剤組成物
WO2024209996A1 (fr) Procédé de lutte contre les mauvaises herbes résistantes aux herbicides
CN108064861A (zh) 一种除草组合物
CN106489971A (zh) 一种除草组合物
CN108235991A (zh) 一种除草组合物及其应用
WO2025053005A1 (fr) Composition herbicide et procédé de lutte contre les mauvaises herbes

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 16743503

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 16743503

Country of ref document: EP

Kind code of ref document: A1