WO2016031528A1 - 高強度ボルト用鋼及び高強度ボルト - Google Patents
高強度ボルト用鋼及び高強度ボルト Download PDFInfo
- Publication number
- WO2016031528A1 WO2016031528A1 PCT/JP2015/072508 JP2015072508W WO2016031528A1 WO 2016031528 A1 WO2016031528 A1 WO 2016031528A1 JP 2015072508 W JP2015072508 W JP 2015072508W WO 2016031528 A1 WO2016031528 A1 WO 2016031528A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- mass
- strength
- steel
- strength bolt
- bolt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/002—Heat treatment of ferrous alloys containing Cr
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/005—Heat treatment of ferrous alloys containing Mn
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/008—Heat treatment of ferrous alloys containing Si
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/0093—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for screws; for bolts
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/34—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of silicon
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16B—DEVICES FOR FASTENING OR SECURING CONSTRUCTIONAL ELEMENTS OR MACHINE PARTS TOGETHER, e.g. NAILS, BOLTS, CIRCLIPS, CLAMPS, CLIPS OR WEDGES; JOINTS OR JOINTING
- F16B31/00—Screwed connections specially modified in view of tensile load; Break-bolts
- F16B31/06—Screwed connections specially modified in view of tensile load; Break-bolts having regard to possibility of fatigue rupture
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16B—DEVICES FOR FASTENING OR SECURING CONSTRUCTIONAL ELEMENTS OR MACHINE PARTS TOGETHER, e.g. NAILS, BOLTS, CIRCLIPS, CLAMPS, CLIPS OR WEDGES; JOINTS OR JOINTING
- F16B33/00—Features common to bolt and nut
- F16B33/06—Surface treatment of parts furnished with screw-thread, e.g. for preventing seizure or fretting
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16B—DEVICES FOR FASTENING OR SECURING CONSTRUCTIONAL ELEMENTS OR MACHINE PARTS TOGETHER, e.g. NAILS, BOLTS, CIRCLIPS, CLAMPS, CLIPS OR WEDGES; JOINTS OR JOINTING
- F16B35/00—Screw-bolts; Stay-bolts; Screw-threaded studs; Screws; Set screws
Definitions
- the present invention relates to steel for high-strength bolts and high-strength bolts. More specifically, the present invention relates to a steel for high-strength bolts excellent in delayed fracture resistance and a high-strength bolt made using the same.
- the tensile strength is 1800 MPa or more.
- the present invention has been made in view of such problems of the conventional technology. And an object of this invention is to provide the steel for high strength bolts excellent in delayed fracture resistance, and the high strength bolt which uses this.
- the inventors of the present invention made extensive studies to achieve the above object. As a result, the inventors have found that the above object can be achieved by using high strength bolt steel having a predetermined composition, and have completed the present invention.
- the steel for high-strength bolts of the present invention has a carbon content of 0.50 to 0.65% by mass, silicon of 1.5 to 2.5% by mass, chromium of 1.0% by mass or more, and manganese of 0.4%. It contains less than mass%, molybdenum more than 1.5 mass%, phosphorus and sulfur in total of 0.03 mass% or less, with the balance being iron and inevitable impurities.
- the high-strength bolt of the present invention is formed using the steel for high-strength bolts of the present invention.
- the steel for high-strength bolts is made from 0.50 to 0.65% by mass of carbon, 1.5 to 2.5% by mass of silicon, 1.0% by mass or more of chromium, and 0.4% by mass of manganese. 4 mass% or less, molybdenum more than 1.5 mass%, phosphorus and sulfur are combined in a total of 0.03 mass% or less, and the balance is composed of iron and inevitable impurities. Therefore, it is possible to provide a high-strength bolt steel excellent in delayed fracture resistance and a high-strength bolt formed using the same.
- FIG. 1 is a partial cross-sectional view showing an example of a reciprocating engine having a multi-link mechanism.
- FIG. 2 is a cross-sectional view showing an outline of an example of the lower link shown in FIG.
- the steel for high-strength bolts of this embodiment has a carbon content of 0.50 to 0.65% by mass, silicon of 1.5 to 2.5% by mass, chromium of 1.0% by mass or more, and manganese of 0.4% by mass. % Or less, molybdenum over 1.5% by mass, phosphorus and sulfur in total of 0.03% by mass or less, with the balance being iron and inevitable impurities.
- a bolt having excellent delayed fracture resistance and high strength can be realized. Further, when this is used to form a bolt, it has excellent delayed fracture resistance and high strength.
- carbon content is less than 0.50% by mass, sufficient temper softening resistance cannot be obtained, and high-temperature tempering described later cannot be performed, so that delayed fracture resistance is not excellent.
- carbon content exceeds 0.65% by mass, the amount of cementite that accumulates hydrogen is remarkably increased, so that the delayed fracture resistance is not excellent.
- content of chromium is 1.4 mass% or less.
- the manganese content is not particularly limited as long as it exceeds 0% by mass, but it is preferably 0.2% by mass or more.
- content of molybdenum is 1.5% by mass or less
- amount of molybdenum-based carbide that renders hydrogen harmless is not sufficient, so that delayed fracture resistance is not excellent.
- content of molybdenum is 1.65 mass% or less.
- the total content of phosphorus and sulfur exceeds 0.03% by mass, the grain boundary strength is remarkably reduced due to grain boundary segregation, so that delayed fracture resistance is not excellent.
- the total content of phosphorus and sulfur is 0.02% or less.
- the high-strength bolt of this embodiment is formed using the steel for high-strength bolts according to one embodiment of the present invention. By setting it as such a structure, it will be excellent in delayed fracture resistance and will have high intensity
- the above-described high-strength bolt steel is first cold forged, then rolled, quenched at 920 ° C. or higher, and 570 ° C.
- the above-mentioned high-strength bolt can be obtained by performing a heat treatment for tempering as described above. Note that the above-described high-strength bolt can be obtained even if the order of the rolling and the heat treatment (quenching and tempering) is changed. For example, when tempering at a high temperature such as 570 ° C. or higher, the grain boundary cementite is spheroidized and finely dispersed, and the grain boundary strength can be improved.
- the delayed fracture resistance can be further improved.
- FIG. 1 is a partial cross-sectional view showing an example of a reciprocating engine having a multi-link mechanism.
- FIG. 2 is a cross-sectional view schematically showing an example of the lower link shown in FIG.
- the reciprocating engine 100 includes an upper link 103 connected to the piston pin 102 of the piston 101, a lower link 106 connecting the upper link 103 and the crank pin 105 of the crankshaft 104, and one end thereof.
- a control link 107 is supported on the engine 100 side so as to be swingable and the other end is connected to the lower link 106.
- the upper link 103 and the lower link 106 are rotatably connected to each other via an upper pin 108, and the control link 107 and the lower link 106 are rotatably connected to each other via a control pin 109.
- the lower link 106 receives the combustion pressure received by the piston 101 from the upper pin 108 via the upper link 103, and transmits the force to the crank pin 105 by the operation using the control pin 109 as a fulcrum. Accordingly, a large combustion pressure or inertial load received by the piston 101 is input to the lower link 106 from the upper pin bearing portion 108a via the piston pin 102, the upper link 103, and the upper pin 108. At the same time, loads are also generated in the crank pin bearing portion 105a and the control pin bearing portion 109a so as to balance this load. Therefore, the surface pressure of each bearing portion (108a, 105a, 109a) is higher than that of a reciprocating engine having a general single link mechanism.
- the required strength for the lower link is increased. Further, from the viewpoint of improving fuel efficiency, it is desired to make the lower link compact and lightweight.
- the lower link 106 normally has a structure in which the divided lower link parts 106 ⁇ / b> A and 106 ⁇ / b> B are fastened with the high-strength bolts 1.
- a high-strength bolt excellent in delayed fracture resistance is required.
- the high-strength bolt of the present embodiment is not particularly limited, but is particularly suitable for fastening such a lower link component.
- 108a, 105a, 109a is each bearing part.
- Example 1 The steel for high-strength bolts having the composition shown in Table 1 is subjected to cold forging, then rolled, and then subjected to heat treatment that is quenched at 920 ° C. or higher and tempered at 570 ° C. or higher. An example high strength bolt was obtained.
- Examples 1 to 8 belonging to the scope of the present invention are high-strength bolts having excellent delayed fracture resistance.
- Comparative Examples 1 to 3, 5 to 8 outside the present invention are not excellent in delayed fracture resistance.
- Comparative Example 4 cannot be applied as a steel for high-strength bolts.
- each of the above-described embodiments and examples is not limited to each embodiment or each example.
- the composition of each embodiment, detailed conditions for manufacturing, the film The presence / absence can be changed, or the configuration of each embodiment or each example can be changed to a combination other than each embodiment or each example described above.
- the lower link in the engine having the multi-link mechanism is exemplified as the application site of the high-strength bolt.
- the present invention is not limited to this, and can be used for other purposes. Needless to say.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Articles (AREA)
- Joining Of Building Structures In Genera (AREA)
Abstract
Description
そのため、耐遅れ破壊性に優れた高強度ボルト用鋼及びこれを用いて成る高強度ボルトを提供することができる。
まず、本発明の第1の実施形態に係る高強度ボルト用鋼について詳細に説明する。本実施形態の高強度ボルト用鋼は、炭素を0.50~0.65質量%、ケイ素を1.5~2.5質量%、クロムを1.0質量%以上、マンガンを0.4質量%以下、モリブデンを1.5質量%超、リンと硫黄とを合計で0.03質量%以下含有し、残部が鉄及び不可避不純物からなる。
このような構成とすることにより、耐遅れ破壊性に優れ、高強度を有するボルトを実現し得るものとなる。また、これを用いてボルトを成形すると、耐遅れ破壊性に優れ、高強度を有するものとなる。
炭素の含有量が、0.50質量%未満である場合には、十分な焼き戻し軟化抵抗が得られず、後述する高温焼き戻しが実施できないため、耐遅れ破壊性が優れたものとならない。
また、炭素の含有量が、0.65質量%を超える場合には、水素を集積するセメンタイトの量が著しく増加するため、耐遅れ破壊性が優れたものとならない。
ケイ素の含有量が、1.5質量%未満である場合には、十分な焼き戻し軟化抵抗が得られず、後述する高温焼き戻しが実施できないため、耐遅れ破壊性が優れたものとならない。
また、ケイ素の含有量が、2.5質量%を超える場合には、鍛造性が著しく悪化するため、所定のボルトを成形できない。
クロムの含有量が、1.0質量%未満である場合には、十分な焼き戻し軟化抵抗が得られず、後述する高温焼き戻しが実施できないため、耐遅れ破壊性が優れたものとならない。なお、特に限定されるものではないが、クロムの含有量は、1.4質量%以下であることが好ましい。
マンガンの含有量が、0.4質量%を超える場合には、粒界偏析成分の粒界偏析が促進されることによって、粒界強度が著しく低下するため、耐遅れ破壊性が優れたものとならない。なお、マンガンの含有量は、0質量%超であれば、特に限定されるものではないが、0.2質量%以上であることが好ましい。
モリブデンの含有量が、1.5質量%以下である場合には、水素を無害化するモリブデン系炭化物の生成量が十分なものとならないため、耐遅れ破壊性が優れたものとならない。なお、特に限定されるものではないが、モリブデンの含有量は、1.65質量%以下であることが好ましい。
リンと硫黄との合計含有量が、0.03質量%を超える場合には、粒界偏析によって、粒界強度が著しく低下するため、耐遅れ破壊性が優れたものとならない。なお、特に限定されるものではないが、リンと硫黄との合計含有量が、0.02%以下であることが好ましい。
次に、本発明の第2の実施形態に係る高強度ボルトについて詳細に説明する。本実施形態の高強度ボルトは、上記本発明の一実施形態に係る高強度ボルト用鋼を用いて成るものである。
このような構成とすることにより、耐遅れ破壊性に優れ、高強度を有するものとなる。
例えば、570℃以上のような高温焼き戻しをすると、粒界セメンタイトが球状化して微細分散し、粒界強度を向上させることができる。
このような皮膜を表面に形成することにより、耐遅れ破壊性を更に向上させることができる。
表1に示す組成の高強度ボルト用鋼に対して、冷間鍛造を行い、次いで、転造を行い、しかる後、920℃以上で焼入れ、570℃以上で焼き戻しする熱処理を行って、各例の高強度ボルトを得た。
(耐遅れ破壊性評価)
各例のボルトを塩酸に規定時間浸漬し、ボルトが破損するか否かを観察した。得られた結果を表1に試験1の結果として示す。なお、試験1の項目において「OK」とはボルトが破損しなかったことを示し、「NG」とはボルトが破損したことを示す。
各例のボルトの引張強度を引張試験によって評価した。各例のボルトの引張強度が1500MPa以上であることが確認された。
実際にボルトを規定本数試作し、金型が破損・摩耗するか否かを観察した。得られた結果を表1に試験2の結果として示す。なお、試験2の項目において「OK」とは金型が破損・摩耗しなかったことを示し、「NG」とは金型が破損・摩耗したことを示す。また、試験2は試験1において結果が「OK」であったもののみ行った。
100 レシプロエンジン
101 ピストン
102 ピストンピン
103 アッパリンク
104 クランクシャフト
105 クランクピン
105a クランクピン軸受部
106 ロアリンク
106A,106B ロアリンク部品
107 コントロールリンク
108 アッパピン
108a アッパピン軸受部
109 コントロールピン
109a コントロールピン軸受部
Claims (3)
- 炭素を0.50~0.65質量%、ケイ素を1.5~2.5質量%、クロムを1.0質量%以上、マンガンを0.4質量%以下、モリブデンを1.5質量%超、リンと硫黄とを合計で0.03質量%以下含有し、残部が鉄及び不可避不純物からなることを特徴とする高強度ボルト用鋼。
- 請求項1に記載の高強度ボルト用鋼を用いて成る高強度ボルトであって、
引張強度が1500MPa以上である
ことを特徴とする高強度ボルト。 - 表面にリン酸鉄皮膜及び/又はクロムめっき皮膜を有することを特徴とする請求項2に記載の高強度ボルト。
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201580043870.XA CN106795598A (zh) | 2014-08-29 | 2015-08-07 | 高强度螺栓用钢及高强度螺栓 |
| BR112017003652-5A BR112017003652B1 (pt) | 2014-08-29 | 2015-08-07 | Parafuso de alta resistência |
| RU2017109088A RU2712458C2 (ru) | 2014-08-29 | 2015-08-07 | Сталь для высокопрочного болта и высокопрочный болт |
| MX2017002010A MX391670B (es) | 2014-08-29 | 2015-08-07 | Acero para tornillo de alta resistencia, y tornillo de alta resistencia. |
| EP15835574.3A EP3187610B1 (en) | 2014-08-29 | 2015-08-07 | Steel for high-strength bolt, and high-strength bolt |
| US15/506,506 US10913993B2 (en) | 2014-08-29 | 2015-08-07 | Steel for high-strength bolt, and high-strength bolt |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2014-175466 | 2014-08-29 | ||
| JP2014175466A JP6422176B2 (ja) | 2014-08-29 | 2014-08-29 | 高強度ボルト用鋼及び高強度ボルト |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2016031528A1 true WO2016031528A1 (ja) | 2016-03-03 |
Family
ID=55399426
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2015/072508 Ceased WO2016031528A1 (ja) | 2014-08-29 | 2015-08-07 | 高強度ボルト用鋼及び高強度ボルト |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US10913993B2 (ja) |
| EP (1) | EP3187610B1 (ja) |
| JP (1) | JP6422176B2 (ja) |
| CN (1) | CN106795598A (ja) |
| BR (1) | BR112017003652B1 (ja) |
| MX (1) | MX391670B (ja) |
| RU (1) | RU2712458C2 (ja) |
| WO (1) | WO2016031528A1 (ja) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019150434A1 (ja) | 2018-01-30 | 2019-08-08 | 日産自動車株式会社 | ボルト |
| WO2019150437A1 (ja) | 2018-01-30 | 2019-08-08 | 日産自動車株式会社 | ボルト及び締結構造 |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7069519B2 (ja) * | 2018-01-30 | 2022-05-18 | 日産自動車株式会社 | ボルト |
| CN111621714B (zh) * | 2020-06-29 | 2022-02-08 | 马鞍山钢铁股份有限公司 | 一种耐蚀耐延迟断裂性能优异的螺栓用圆钢及其生产方法 |
| JP7674861B2 (ja) * | 2021-03-09 | 2025-05-12 | 日産自動車株式会社 | 高強度ボルト |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1017985A (ja) * | 1996-06-27 | 1998-01-20 | Kobe Steel Ltd | 耐水素脆化特性に優れた高強度鋼およびその製法 |
| JP2002173739A (ja) * | 2000-12-01 | 2002-06-21 | Nippon Steel Corp | 耐水素脆化特性の優れた高強度鋼 |
| JP2006022371A (ja) * | 2004-07-07 | 2006-01-26 | Kida Seiko Kk | ボルトのメッキ方法及びメッキライン |
| JP2006045670A (ja) * | 2004-07-05 | 2006-02-16 | Nippon Steel Corp | 耐遅れ破壊特性に優れた高強度調質鋼およびその製造方法 |
| JP2006187679A (ja) * | 2004-12-28 | 2006-07-20 | Kowa Industry Co Ltd | 防錆塗装物及びその被膜形成方法 |
| JP2011084784A (ja) * | 2009-10-16 | 2011-04-28 | National Institute For Materials Science | 温間加工用鋼 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2060294C1 (ru) * | 1993-12-29 | 1996-05-20 | Тарасов Виктор Алексеевич | Сталь |
| JP2002339990A (ja) * | 2001-05-22 | 2002-11-27 | Harmonic Drive Syst Ind Co Ltd | 軽量ベアリングおよび波動歯車装置 |
| JP3861137B2 (ja) * | 2001-08-31 | 2006-12-20 | 独立行政法人物質・材料研究機構 | 高強度機械構造用鋼とその製造方法 |
| JP3836766B2 (ja) * | 2002-08-15 | 2006-10-25 | 株式会社神戸製鋼所 | 耐遅れ破壊特性に優れた高強度鋼部品及びその製造方法 |
| CN1954088B (zh) * | 2004-04-09 | 2010-12-08 | 独立行政法人物质·材料研究机构 | 冷加工性能优异的高强度钢丝、钢棒或高强度成形制品及其制造方法 |
| JP4555749B2 (ja) * | 2004-10-08 | 2010-10-06 | 新日本製鐵株式会社 | 高強度ボルトの耐遅れ破壊特性向上方法 |
| JP4441434B2 (ja) * | 2005-04-11 | 2010-03-31 | 新日本製鐵株式会社 | 耐遅れ破壊特性に優れた高強度ボルトの製造方法 |
| EP1956100B1 (en) * | 2005-11-21 | 2019-04-24 | National Institute for Materials Science | Method of warm working of a steel material and steel material obtained by the same |
| JP5334769B2 (ja) * | 2009-09-10 | 2013-11-06 | 独立行政法人物質・材料研究機構 | 高強度ボルト |
| WO2011048971A1 (ja) * | 2009-10-22 | 2011-04-28 | 日産自動車株式会社 | 高強度ボルト用鋼及び高強度ボルトの製造方法 |
| US20120247618A1 (en) * | 2010-03-11 | 2012-10-04 | Daisuke Hirakami | High strength steel material and high strength bolt excellent in delayed fracture resistance and methods of production of same |
| JP5697517B2 (ja) * | 2011-04-04 | 2015-04-08 | ニチアス株式会社 | ガスケット |
| JP6017944B2 (ja) * | 2011-12-09 | 2016-11-02 | 国立研究開発法人物質・材料研究機構 | 高力ボルト及びその製造方法 |
| JP6051031B2 (ja) * | 2011-12-09 | 2016-12-21 | 国立研究開発法人物質・材料研究機構 | 高力ボルト及びその製造方法 |
| CN102876965B (zh) * | 2012-09-11 | 2014-12-03 | 中国钢研科技集团有限公司 | 一种高强锚固螺栓及其生产方法 |
| JP6458981B2 (ja) | 2014-08-29 | 2019-01-30 | 日産自動車株式会社 | 高強度ボルト |
-
2014
- 2014-08-29 JP JP2014175466A patent/JP6422176B2/ja active Active
-
2015
- 2015-08-07 EP EP15835574.3A patent/EP3187610B1/en active Active
- 2015-08-07 WO PCT/JP2015/072508 patent/WO2016031528A1/ja not_active Ceased
- 2015-08-07 BR BR112017003652-5A patent/BR112017003652B1/pt active IP Right Grant
- 2015-08-07 RU RU2017109088A patent/RU2712458C2/ru active
- 2015-08-07 US US15/506,506 patent/US10913993B2/en active Active
- 2015-08-07 CN CN201580043870.XA patent/CN106795598A/zh active Pending
- 2015-08-07 MX MX2017002010A patent/MX391670B/es unknown
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1017985A (ja) * | 1996-06-27 | 1998-01-20 | Kobe Steel Ltd | 耐水素脆化特性に優れた高強度鋼およびその製法 |
| JP2002173739A (ja) * | 2000-12-01 | 2002-06-21 | Nippon Steel Corp | 耐水素脆化特性の優れた高強度鋼 |
| JP2006045670A (ja) * | 2004-07-05 | 2006-02-16 | Nippon Steel Corp | 耐遅れ破壊特性に優れた高強度調質鋼およびその製造方法 |
| JP2006022371A (ja) * | 2004-07-07 | 2006-01-26 | Kida Seiko Kk | ボルトのメッキ方法及びメッキライン |
| JP2006187679A (ja) * | 2004-12-28 | 2006-07-20 | Kowa Industry Co Ltd | 防錆塗装物及びその被膜形成方法 |
| JP2011084784A (ja) * | 2009-10-16 | 2011-04-28 | National Institute For Materials Science | 温間加工用鋼 |
Non-Patent Citations (2)
| Title |
|---|
| See also references of EP3187610A4 * |
| YUJI KIMURA ET AL.: "Cho-Koriki Bolt no Sosei to Kikaiteki Tokusei", STEEL CONSTRUCTION ENGINEERING, vol. 14, no. 54, June 2007 (2007-06-01), pages 121 - 127, XP008185600 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019150434A1 (ja) | 2018-01-30 | 2019-08-08 | 日産自動車株式会社 | ボルト |
| WO2019150437A1 (ja) | 2018-01-30 | 2019-08-08 | 日産自動車株式会社 | ボルト及び締結構造 |
| JPWO2019150434A1 (ja) * | 2018-01-30 | 2021-01-14 | 日産自動車株式会社 | ボルト |
| US20210017618A1 (en) * | 2018-01-30 | 2021-01-21 | Nissan Motor Co., Ltd. | Bolt and fastened structure |
| JPWO2019150437A1 (ja) * | 2018-01-30 | 2021-01-28 | 日産自動車株式会社 | ボルト及び締結構造 |
| US11333189B2 (en) | 2018-01-30 | 2022-05-17 | Nissan Motor Co., Ltd. | Bolt |
| JP7134411B2 (ja) | 2018-01-30 | 2022-09-12 | 日産自動車株式会社 | ボルト |
| US11708622B2 (en) | 2018-01-30 | 2023-07-25 | Nissan Motor Co., Ltd. | Bolt and fastened structure |
Also Published As
| Publication number | Publication date |
|---|---|
| MX2017002010A (es) | 2017-05-04 |
| RU2017109088A (ru) | 2018-10-03 |
| BR112017003652A2 (pt) | 2017-12-05 |
| CN106795598A (zh) | 2017-05-31 |
| EP3187610A4 (en) | 2018-01-17 |
| EP3187610B1 (en) | 2024-10-30 |
| RU2017109088A3 (ja) | 2019-01-31 |
| US10913993B2 (en) | 2021-02-09 |
| BR112017003652B1 (pt) | 2021-08-31 |
| JP6422176B2 (ja) | 2018-11-14 |
| JP2016050329A (ja) | 2016-04-11 |
| MX391670B (es) | 2025-03-19 |
| US20170283921A1 (en) | 2017-10-05 |
| RU2712458C2 (ru) | 2020-01-29 |
| EP3187610A1 (en) | 2017-07-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101520208B1 (ko) | 기소강 및 그의 제조 방법, 및 기소강을 이용한 기계 구조 부품 | |
| JP6422176B2 (ja) | 高強度ボルト用鋼及び高強度ボルト | |
| CN101243197A (zh) | 耐延迟断裂特性优良的高强度钢及金属螺栓 | |
| CN108291269A (zh) | 大型曲轴 | |
| JP5472573B2 (ja) | クラッキングコンロッドの製造方法 | |
| JP6458981B2 (ja) | 高強度ボルト | |
| KR101894848B1 (ko) | 오스테나이트계 내열합금 및 이를 이용한 내열볼트의 제조방법 | |
| WO2017170540A1 (ja) | 面疲労強度および曲げ疲労強度に優れた浸炭窒化部品、並びにその製造方法 | |
| JP2004238702A (ja) | 耐低サイクル衝撃疲労特性に優れた浸炭部品 | |
| JP5707938B2 (ja) | 冷間加工性に優れる肌焼鋼および高疲労強度浸炭材 | |
| JP2011084767A (ja) | クラッキングコンロッドの製造方法 | |
| JP6380910B2 (ja) | 高強度ボルト用鋼及び高強度ボルト | |
| CN108929985B (zh) | 强度和冷加工性优异的中碳线材及其制造方法 | |
| JP4302480B2 (ja) | 冷間加工性に優れた高硬度鋼 | |
| JP5713219B2 (ja) | クラッキングコンロッド及びその製造方法 | |
| JP2020139185A (ja) | 肌焼鋼の製造方法 | |
| CN104532167A (zh) | 一种耐高温合金模具钢的制备方法 | |
| WO2019035401A1 (ja) | 高硬度かつ靱性に優れる鋼 | |
| JP5463955B2 (ja) | 冷間加工性に優れた浸炭用鋼 | |
| JP2008088473A (ja) | クランクシャフトの製造方法 | |
| CN105473754B (zh) | 高强度钢、以及使用上述高强度钢的曲轴 | |
| CN119082624B (zh) | 一种超高比强度超高强钢及其制备方法 | |
| JP4821711B2 (ja) | 軟窒化用鋼材 | |
| JP2000248332A (ja) | 耐熱性に優れた金型およびその製造方法 | |
| KR20170143282A (ko) | 고강도 크랭크샤프트 제조방법 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 15835574 Country of ref document: EP Kind code of ref document: A1 |
|
| DPE2 | Request for preliminary examination filed before expiration of 19th month from priority date (pct application filed from 20040101) | ||
| WWE | Wipo information: entry into national phase |
Ref document number: MX/A/2017/002010 Country of ref document: MX |
|
| WWE | Wipo information: entry into national phase |
Ref document number: 15506506 Country of ref document: US |
|
| NENP | Non-entry into the national phase |
Ref country code: DE |
|
| REG | Reference to national code |
Ref country code: BR Ref legal event code: B01A Ref document number: 112017003652 Country of ref document: BR |
|
| REEP | Request for entry into the european phase |
Ref document number: 2015835574 Country of ref document: EP |
|
| WWE | Wipo information: entry into national phase |
Ref document number: 2015835574 Country of ref document: EP |
|
| ENP | Entry into the national phase |
Ref document number: 2017109088 Country of ref document: RU Kind code of ref document: A |
|
| ENP | Entry into the national phase |
Ref document number: 112017003652 Country of ref document: BR Kind code of ref document: A2 Effective date: 20170222 |