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WO2015020510A1 - Ecological, corrosion-resistant, water-based fireproof coating with resistance to the elements - Google Patents

Ecological, corrosion-resistant, water-based fireproof coating with resistance to the elements Download PDF

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Publication number
WO2015020510A1
WO2015020510A1 PCT/MX2014/000069 MX2014000069W WO2015020510A1 WO 2015020510 A1 WO2015020510 A1 WO 2015020510A1 MX 2014000069 W MX2014000069 W MX 2014000069W WO 2015020510 A1 WO2015020510 A1 WO 2015020510A1
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Prior art keywords
resistance
resistant
coating
corrosion
ecological
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Ceased
Application number
PCT/MX2014/000069
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Spanish (es)
French (fr)
Inventor
Moises FIGUEROA MARTINEZ
Fernando DURAZO PICOS
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AASR GLOBAL FRANCHISES SA de CV
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AASR GLOBAL FRANCHISES SA de CV
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Publication of WO2015020510A1 publication Critical patent/WO2015020510A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/01Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/016Flame-proofing or flame-retarding additives

Definitions

  • the present invention consists in the process of manufacturing a fireproof coating, with resistance to corrosion, weathering, water-based processing, without including in the formulation alkaline elements, ecological.
  • Patent MX 286750 is known, in which toxic elements are handled which harm the environment, patent application PA / a / 2005/005258, which has no weathering (exterior) and anti-corrosive properties, as well as generation of toxic gases in case of contact with the flame, in addition to requiring an anchor base.
  • the present invention is complying with the ecological standards worldwide, and without causing over time pollution or waste harmful to humans.
  • CORROSION, OUTDOOR, WATER BASED, ECOLOGICAL RESISTANT IGNIFUOUS COATING we obtain high temperature resistance in contact with the flame.
  • the flame retardant coating complies with the ecology and environmental damage standards, such as ASTM C87, chloride content, with a result obtained according to the standard method of 2 PPM (particles per million), does not generate harmful waste, gases in case of sinister (fire), fungi or molds.
  • flame retardant is implemented since it does not allow the transmission of high temperatures to the substrate where it is applied caused by contact with the flame, it is considered an environmentally friendly flame retardant coating since, in case of contact with the flame, It does not release harmful or toxic gases, in the same way in case of spillage, it is 100% biodegradable.
  • the resistance of the coating the versatility of uses and applications, generate resistance. Corrosion, weathering, salt spray, acid rain, mechanical shock that can be applied to any surface and material.
  • the composition of the invention based on water consists of the following percentages: Water (20% - 25%), Diatomite (6.0% - 7.5%), Precipitated Calcium Carbonate (6.0% - 7.5%), Titanium Dioxide (3.0% - 4.2%), Calcined Alumina (7.0% - 8.2%), Diethylene Glycol (3.0% - 4.2%), Dimethylbenzene (3.0% - 4.2%), High Solid Elastomeric Acrylic Resin (30% - 37%), Acrylic Thickener (1.0% - 1.5%), Fungicide (0.35% - 0.55%), Ammonium Hydroxide (0.80% - 1.35%), Antifoam (0.70% - 1.1%), Ceramic Fiber (8.0% - 9.2%).
  • the composition of the flame retardant coating is biodegradable, so it does not cause damage to the flora, fauna and in the same way it does not affect the personnel that is applying it.
  • the manufacturing process of the invention is as follows:
  • Diatomite (6.0% - 7.5%)
  • Precipitated Calcium Carbonate (6.0% - 7.5%)
  • Titanium Dioxide (3.0% - 4.2%)
  • Calcined Alumina (7.0% - 8.2%
  • Ceramic Fiber (8.0% - 9.2%)
  • the diversity of applications of the coating and its qualities allow us to apply it in a wide field, as a fire retardant coating, it would prevent the transmission of high temperatures in case of contact with the flame, thus generating an outstanding protection for the time it can withstand the coating on contact with the flame.
  • the quality of anticorrosive is applicable in metallic infrastructure, since tests were carried out with the method of the ASTM E-937 standard, referring to corrosion, obtaining as a result of 0.0001%, that is why it can be applied in both underground pipes as aerial, infrastructure to reduce oxidation.
  • the invention has an outstanding mechanical resistance since they were carried out through various standard methods, such as: ASTM E-790, bending effort, obtaining a result of 1,254 PSI; ASTM E-736, adhesion effort, obtaining a result of 190 PSI and the ASTM E - 781 standard, compression stress 2,150 PSI, with which we check its resistance to mechanical shock.
  • ASTM E-790 bending effort, obtaining a result of 1,254 PSI
  • ASTM E-736 adhesion effort, obtaining a result of 190 PSI
  • ASTM E - 781 standard, compression stress 2,150 PSI with which we check its resistance to mechanical shock.
  • the characteristic of resistance to the weather is outstanding since it does not require primary for anchoring and can be applied with a minimum of cleaning, it serves both indoor and outdoor.
  • the coating has a very wide field of addition having as main feature the ability to fulfill various purposes in a single product.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Paints Or Removers (AREA)

Abstract

The special coating called "ecological, corrosion-resistant, water-based fireproof coating with resistance to the elements" is resistant to burning and the transmission of high temperatures, and can be arranged on any surface without requiring the application of a primer for adhesion. The fireproof coating is ecological and does not damage the environment, does not generate harmful waste, does not produce smoke, and has corrosion-resistance properties against sea spray, acid rain and mechanical impacts. Said coating can be applied to any surface and material and is resistant to the elements, allowing it to be applied both outside and inside. The fire-resistance of the coating prevents the expansion of the substrates covered, and provides the coated element with a longer service life since it encapsulates the substrate, rendering impossible the generation of oxidation or saltpetre depending on the material to which it is applied.

Description

RECUBRIMIENTO IGNIFUGO RESISTENTE A LA CORROSIÓN, AL INTEMPERIE, BASE AGUA, ECOLÓGICO  IGNIFUGO COATING RESISTANT TO CORROSION, OUTDOOR, WATER BASED, ECOLOGICAL

OBJETO DE LA INVENCIÓN OBJECT OF THE INVENTION

La presente invención consiste en el proceso de fabricación de un recubrimiento ignifugo, con resistencia a la corrosión, al intemperie, procesado en base agua, sin incluir en la formulación elementos alcalinos, ecológico.  The present invention consists in the process of manufacturing a fireproof coating, with resistance to corrosion, weathering, water-based processing, without including in the formulation alkaline elements, ecological.

ANTECEDENTES BACKGROUND

Actualmente en el mercado (recubrimientos especializados), ciertos fabricantes han anunciado o registrado patentes o proceso de fabricación para la generación de recubrimientos ignífugos sin resistencia a la intemperie, esto quiere decir que sólo pueden ser colocados en el interior de las edificaciones, estos no cuentan con la resistencia a la corrosión, el coeficiente de transmisión de temperatura y los procesos amigables con el medio ambiente.  Currently in the market (specialized coatings), certain manufacturers have announced or registered patents or manufacturing process for the generation of fireproof coatings without weather resistance, this means that they can only be placed inside buildings, they do not count With corrosion resistance, temperature transmission coefficient and environmentally friendly processes.

Se conocen la patente MX 286750, en la cual se manejan elementos tóxicos los cuales dañan al medio ambiente, la solicitud de patente PA/a/2005/005258, la cual no tiene propiedades de resistencia al intemperie (exterior) y anticorrosivo, así como generación de gases tóxicos en caso de contacto con la flama, además de requerir de una base de anclaje. La presente invención estamos cumpliendo con las normas ecológicas a nivel mundial, y sin ocasionar a través del tiempo contaminación o desechos dañinos para el ser humano. Patent MX 286750 is known, in which toxic elements are handled which harm the environment, patent application PA / a / 2005/005258, which has no weathering (exterior) and anti-corrosive properties, as well as generation of toxic gases in case of contact with the flame, in addition to requiring an anchor base. The present invention is complying with the ecological standards worldwide, and without causing over time pollution or waste harmful to humans.

DESCRIPCIÓN DETALLADA DE LA INVENCIÓN DETAILED DESCRIPTION OF THE INVENTION

La invención de nuestro recubrimiento especial denominado "RECUBRIMIENTO IGNÍFUGO RESISTENTE A LA CORROSIÓN, AL INTEMPERIE, BASE AGUA, ECOLÓGICO" obtenemos una resistencia a altas temperaturas en contacto con la flama. Estos pueden ser instalados o colocados en cualquier superficie sin la necesidad de un primario para anclaje.  The invention of our special coating called "CORROSION, OUTDOOR, WATER BASED, ECOLOGICAL RESISTANT IGNIFUOUS COATING" we obtain high temperature resistance in contact with the flame. These can be installed or placed on any surface without the need for a primary anchor.

El recubrimiento ignífugo cumple con las normas de ecología y daños al medio ambiente, como la ASTM C87, contenido de cloruros, con un resultado obtenido según método de norma de 2 PPM (partículas por millón), no genera residuos dañinos, gases en caso de siniestro (incendio), hongos o mohos.  The flame retardant coating complies with the ecology and environmental damage standards, such as ASTM C87, chloride content, with a result obtained according to the standard method of 2 PPM (particles per million), does not generate harmful waste, gases in case of sinister (fire), fungi or molds.

El término "ignífugo" es implementado ya que no permite la transmisión de altas temperaturas al sustrato donde sea aplicado ocasionadas por el contacto con la flama, se considera un recubrimiento ignífugo amigable con el medio ambiente ya que, en caso de contacto con la flama, no desprende gases dañinos o tóxicos, del mismo modo en caso de derrame, es 100% biodegra- dable.  The term "flame retardant" is implemented since it does not allow the transmission of high temperatures to the substrate where it is applied caused by contact with the flame, it is considered an environmentally friendly flame retardant coating since, in case of contact with the flame, It does not release harmful or toxic gases, in the same way in case of spillage, it is 100% biodegradable.

La resistencia que tiene el recubrimiento, la versatilidad de usos y aplicaciones, generan que se cuente con la resisten- cia a la corrosión, al intemperie, al rocío salino, lluvia acida, choque mecánico que puede ser aplicado en cualquier superficie y material. The resistance of the coating, the versatility of uses and applications, generate resistance. Corrosion, weathering, salt spray, acid rain, mechanical shock that can be applied to any surface and material.

Cuenta con propiedades de ignífugo sobresaliente, se evaluó a través del método de la norma ASTM E-84, resistencia al quemado, obteniendo un resultado de 4 hrs. Mínimo, es por esto que se adapta a las especificaciones de la norma, cuenta con un coeficiente de dilatación alto, lo que permite absorber las dilataciones que se presenten en el sustrato.  It has outstanding flame retardant properties, it was evaluated through the method of ASTM E-84, burn resistance, obtaining a result of 4 hrs. Minimum, this is why it adapts to the specifications of the standard, has a high expansion coefficient, which allows to absorb the dilations that occur in the substrate.

Al ser un recubrimiento ignífugo, no permite la dilatación de los sustratos recubiertos, gracias a eso, no se presentan cuarteaduras o desfasamientos en la superficie, según sea el caso.  Being a flame retardant coating, it does not allow the expansion of the coated substrates, thanks to that, there are no cracks or phase shifts, as the case may be.

Genera una mayor vida útil al elemento recubierto ya que encapsula el sustrato imposibilitando la generación de oxidación o salitre dependiendo el material en donde se aplique.  It generates a longer useful life for the coated element since it encapsulates the substrate making it impossible to generate oxidation or salt depending on the material where it is applied.

La composición de la invención en base agua consisten de los siguientes porcentajes: Agua ( 20 % - 25 % ) , Diatomita (6.0%- 7.5%), Carbonato de Calcio Precipitado ( 6.0 % - 7.5 % ) , Bióxido de Titanio ( 3.0 % - 4.2 % ) , Alúmina Calcinada ( 7.0 % - 8.2 % ) , Dietilen- glicol ( 3.0 % - 4.2 % ) , Dimetilbenceno ( 3.0 % - 4.2 % ) , Resina Acrílica Elastomérica Altos Solidos ( 30 % - 37 % ) , Espesante Acrílico ( 1.0 % - 1.5 % ) , Fungicida ( 0.35 % - 0.55 % ) , Hidróxido de Amonio ( 0.80 % - 1.35%), Antiespumante ( 0.70 % - 1.1 %), Fibra Cerámica ( 8.0 % - 9.2 % ) . La composición del recubrimiento ignífugo es biodegrada- ble, por lo cual no ocasiona daño a la flora, fauna y del mismo modo tampoco afecta al personal que lo está aplicando. The composition of the invention based on water consists of the following percentages: Water (20% - 25%), Diatomite (6.0% - 7.5%), Precipitated Calcium Carbonate (6.0% - 7.5%), Titanium Dioxide (3.0% - 4.2%), Calcined Alumina (7.0% - 8.2%), Diethylene Glycol (3.0% - 4.2%), Dimethylbenzene (3.0% - 4.2%), High Solid Elastomeric Acrylic Resin (30% - 37%), Acrylic Thickener (1.0% - 1.5%), Fungicide (0.35% - 0.55%), Ammonium Hydroxide (0.80% - 1.35%), Antifoam (0.70% - 1.1%), Ceramic Fiber (8.0% - 9.2%). The composition of the flame retardant coating is biodegradable, so it does not cause damage to the flora, fauna and in the same way it does not affect the personnel that is applying it.

Todos los materiales son encontrados en el mercado nacional, con lo cual apoyamos a la industria y el comercio en México.  All materials are found in the national market, with which we support industry and commerce in Mexico.

El proceso de fabricación de la invención es la siguiente: The manufacturing process of the invention is as follows:

(1) Ingresa en el reactor los siguientes componentes en los porcentajes antes mencionados: Agua ( 2 O % - 25 % ) , Dietilenglicol ( 3.0 % - 4.2 % ) , Dimetilbenceno ( 3.0 % - 4.2 % ) , Resina Acrílica Elas- tomérica Altos Solidos ( 3 O % - 37 % ) y Fungicida ( 0.35 % - 0.55 % ) , y se deja batir por un intervalo de tiempo de 4.5 min. -5.5 min.(1) Enter the following components into the reactor in the aforementioned percentages: Water (2 O% - 25%), Diethylene Glycol (3.0% - 4.2%), Dimethylbenzene (3.0% - 4.2%), High Elasteric Acrylic Resin Solids (3 O% - 37%) and Fungicide (0.35% - 0.55%), and allowed to beat for a time interval of 4.5 min. -5.5 min.

(2) A continuación, se le agregan los siguientes componentes: Diatomíta ( 6.0 % - 7.5 % ) , Carbonato de Calcio Precipitado (6.0%- 7.5%), Bióxido de Titanio ( 3.0 % - 4.2 % ) , Alúmina Calcinada ( 7.0 % - 8.2 % ) y Fibra Cerámica ( 8.0 % - 9.2 % ) , y se deja batir por un intervalo de tiempo de 8.5 min. -10.5 min. (2) Next, the following components are added: Diatomite (6.0% - 7.5%), Precipitated Calcium Carbonate (6.0% - 7.5%), Titanium Dioxide (3.0% - 4.2%), Calcined Alumina (7.0% - 8.2%) and Ceramic Fiber (8.0% - 9.2%), and allowed to beat for a time interval of 8.5 min. -10.5 min.

(3) Después del tiempo de batido, se agrega Hidróxido de Amonio (0.80% -1.35%), y se batir por 5 min. -7.5 min.  (3) After the beating time, Ammonium Hydroxide (0.80% -1.35%) is added, and beaten for 5 min. -7.5 min.

(4) Por último, se agrega el siguiente componente: Espesante Acrílico (1.0%-1.5%), y se deja batir por 5 min. -7.5 min.  (4) Finally, the following component is added: Acrylic Thickener (1.0% -1.5%), and allowed to beat for 5 min. -7.5 min.

Los costos de venta de los productos están dentro de los márgenes de los recubrimientos similares, tomando en cuenta que ninguno de ellos tiene todas las características del nuestro. EJEMPLOS The costs of selling the products are within the margins of similar coatings, taking into account that none of them have all the characteristics of ours. EXAMPLES

La diversidad de aplicaciones del recubrimiento y las cualidades del mismo nos permiten aplicarlo en un amplio campo, como recubrimiento ignífugo, evitaría la transmisión de temperaturas altas en caso de contacto con la flama, generando de esta manera una protección sobresaliente por el tiempo que puede resistir el recubrimiento al contacto con la flama.  The diversity of applications of the coating and its qualities allow us to apply it in a wide field, as a fire retardant coating, it would prevent the transmission of high temperatures in case of contact with the flame, thus generating an outstanding protection for the time it can withstand the coating on contact with the flame.

La cualidad de anticorrosivo es aplicable en infraestructura metálica, ya que se llevaron a cabo pruebas con el método de la norma ASTM E-937, referente a corrosión, obteniendo como resultado de 0.0001 %, es por esto que se puede aplicar en tuberías tanto subterráneas como aéreas, infraestructura para disminuir la oxidación del mismo.  The quality of anticorrosive is applicable in metallic infrastructure, since tests were carried out with the method of the ASTM E-937 standard, referring to corrosion, obtaining as a result of 0.0001%, that is why it can be applied in both underground pipes as aerial, infrastructure to reduce oxidation.

La invención cuenta con una resistencia mecánica sobresaliente ya que se llevaron a cabo a través de diversos métodos de normas, como: ASTM E-790, esfuerzo de flexión, obteniendo un resultado de 1,254 PSI; ASTM E-736, esfuerzo de adherencia, obteniendo un resultado de 190 PSI y la norma ASTM E - 781 , esfuerzo a la compresión 2,150 PSI, con lo cual comprobamos su resistencia al choque mecánico. Ejemplo Composición 1 : The invention has an outstanding mechanical resistance since they were carried out through various standard methods, such as: ASTM E-790, bending effort, obtaining a result of 1,254 PSI; ASTM E-736, adhesion effort, obtaining a result of 190 PSI and the ASTM E - 781 standard, compression stress 2,150 PSI, with which we check its resistance to mechanical shock. Example Composition 1:

Figure imgf000007_0001
Figure imgf000007_0001

La característica de resistencia a la intemperie, es sobresaliente ya que no requiere primario para su anclaje y puede ser aplicado con un mínimo de limpieza, sirve tanto para interior como exterior. El recubrimiento tiene un campo de adición muy amplio teniendo como principal característica el poder cumplir con diversas finalidades en un solo producto. The characteristic of resistance to the weather, is outstanding since it does not require primary for anchoring and can be applied with a minimum of cleaning, it serves both indoor and outdoor. The coating has a very wide field of addition having as main feature the ability to fulfill various purposes in a single product.

Claims

REIVINDICACIONES 1. - Una composición química de un recubrimiento ignífugo, resistente a la corrosión, al intemperie, emulsionado en base agua, ecológico.  1. - A chemical composition of a flame retardant coating, resistant to corrosion, weathering, water-based emulsification, ecological. 2. - Un proceso de fabricación de recubrimiento ignífugo, que comprende intervalos de batido y orden de implementación de componentes.  2. - A fire-retardant coating manufacturing process, comprising beating intervals and order of component implementation.
PCT/MX2014/000069 2013-08-07 2014-05-08 Ecological, corrosion-resistant, water-based fireproof coating with resistance to the elements Ceased WO2015020510A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
MXMX/A/2013/009094 2013-08-07
MX2013009094A MX2013009094A (en) 2013-08-07 2013-08-07 Ecological, corrosion-resistant, water-based fireproof coating with resistance to the elements.

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WO2015020510A1 true WO2015020510A1 (en) 2015-02-12

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114736554A (en) * 2022-06-15 2022-07-12 浙江虹达特种橡胶制品有限公司杭州分公司 Environment-friendly fireproof coating and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0075396A1 (en) * 1981-09-14 1983-03-30 Imperial Chemical Industries Plc Aqueous coating compositions
EP0583051A1 (en) * 1992-08-11 1994-02-16 Magnumas Coatings Sdn Bhd Heat-resistant coating composition
WO2005030671A1 (en) * 2003-09-29 2005-04-07 Jun-Han Choi Incombustible composition, incombustible construction product using incombustible composition, and method of producing incombustible construction product
MXPA05005258A (en) 2005-05-17 2006-05-04 Agustin Hugo Casamayor Cazares Flame retardant outer coating applied to expandable polystyrene (eps).
US20080233295A1 (en) * 2007-01-31 2008-09-25 Institute Of Process Engineering, Chinese Academy Of Sciences Antioxidation coating for steel and antioxidation method using the same

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0075396A1 (en) * 1981-09-14 1983-03-30 Imperial Chemical Industries Plc Aqueous coating compositions
EP0583051A1 (en) * 1992-08-11 1994-02-16 Magnumas Coatings Sdn Bhd Heat-resistant coating composition
WO2005030671A1 (en) * 2003-09-29 2005-04-07 Jun-Han Choi Incombustible composition, incombustible construction product using incombustible composition, and method of producing incombustible construction product
MXPA05005258A (en) 2005-05-17 2006-05-04 Agustin Hugo Casamayor Cazares Flame retardant outer coating applied to expandable polystyrene (eps).
US20080233295A1 (en) * 2007-01-31 2008-09-25 Institute Of Process Engineering, Chinese Academy Of Sciences Antioxidation coating for steel and antioxidation method using the same

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114736554A (en) * 2022-06-15 2022-07-12 浙江虹达特种橡胶制品有限公司杭州分公司 Environment-friendly fireproof coating and preparation method thereof
CN114736554B (en) * 2022-06-15 2022-10-14 浙江虹达特种橡胶制品有限公司杭州分公司 Environment-friendly fireproof coating and preparation method thereof

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