WO2015090744A1 - Cosmetic cleaning agent containing an anionic surfactant and hardened castor oil - Google Patents

Abstract

The invention relates to a cosmetic cleaning agent, which contains, in a suitable carrier, a) at least one anionic surfactant according to the following formula (I), in which the groups R² to R⁵ stand, independently of each other, for a hydrogen atom, a C₁-C₄ alkyl group, or a C₁-C₄ hydroxyalkyl group, R¹ stands for a linear or branched, saturated or unsaturated alkyl group having 6 to 30 carbon atoms, and M⁺ stands for an ammonium cation, an alkanolammonium cation, or a metal cation, b) at least one pearlizing agent, organic and/or inorganic pigments, and/or opacifiers, and c) hardened castor oil. The invention further relates to the use of hardened castor oil to improve the care properties of cosmetic cleaning agents that contain the components a) and b) mentioned above, and a cosmetic method for improving the hair control and/or the combability of hair, wherein a cosmetic cleaning agent containing the components a) and b) mentioned above is applied to the dry or wet hair and is rinsed out with water after an exposure time of 5 seconds to 5 minutes.

Description

 The invention is in the field of cosmetics and relates to a cosmetic cleaning agent which contains at least one anionic isethionate surfactant, at least one pearlescing agent, pigment and / or opacifier and hydrogenated castor oil.

 The invention further relates to the use of hydrogenated castor oil for increasing the care properties of cosmetic cleaners containing at least one anionic isethionate surfactant and at least pearlescing, pigment and / or opacifier.

 Finally, the invention relates to a cosmetic method for improving the hair grip and / or the combing of hair, in which a cosmetic cleaning agent containing an anionic isethionate surfactant, a pearlescing agent, pigment and / or opacifier and hardened castor oil applied to the hair and is rinsed out again after a contact time.

Due to the increasing burden of the hair by environmental influences (such as intense sunlight), as well as mechanical and / or chemical stress (such as blow-drying under hair dryer or oxidative dyeing, bleaching or Haarverformungsvorgänge) are constantly increasing the requirements of the known in the art cosmetic Medium.

 For example, consumers demand particularly mild and gentle compositions that do not put extra strain on the hair and are easy to apply.

 In addition, the composition should be less complex and contain the lowest possible number of highly effective agents that optimally need not be stabilized by additional ingredients.

The use of milder ingredients with the same product performance, however, is complicated and always presents the cosmetic developers with new challenges.

 A milk-white, creamy appearance and a rich texture of cosmetic compositions are explicitly desired by many consumers, for example, because they associate optimal mildness and care.

However, such compositions usually contain pearlescing agents, pigments and / or opacifiers, which usually have to be stabilized in the compositions by special active substances, such as, for example, fatty acids or special acrylic-based polymers. It would be desirable to have cosmetic compositions which have a milky-white, opaque or pearlescent appearance without having to be stabilized by specific active ingredients.

It is an object of the present invention to provide milky white, opaque or pearlescent cosmetic cleansing compositions which need not be additionally stabilized.

 The cosmetic compositions should preferably be particularly mild hair cleansers, particularly preferably mild, sulfate-free hair cleansers. Ideally, the hair cleanser should also cause a significant care effect on the hair in addition to the attractive appearance.

It has now been found that these objects can be achieved by the combination of particularly mild anionic surfactants, pearlescing agents, pigments and / or opacifiers and hydrogenated castor oil. The corresponding agents - especially mild formulations - have an opaque, milky white or pearlescent appearance, are particularly skin and hair compatible, nourish and cleanse the hair and improve in particular the combability and the handle of the treated hair.

 Moreover, in the case of the preparation of mild, sulfate-free shampoos, the foam properties of the compositions could be improved.

For the purposes of the present invention, "opaque, milky white or pearlescent" compositions is to be understood as meaning that the cosmetic agents at 25 ° C. preferably have a turbidity> 100 NTU (Nephelometry Turbidity Unit), more preferably> 150 NTU, more preferably> 200 NTU, and in particular> 250 NTU (measured for example with a device "2100P Turbidimeter" from Hach).

A first subject of the invention is therefore a cosmetic cleansing agent, which is in a suitable carrier

a) at least one anionic surfactant according to formula (I) below,

in the the radicals R ² to R ⁵ independently of one another represent a hydrogen atom, a C 1 -C 4 -alkyl or a C 1 -C 4 -hydroxyalkyl radical,

 R is a linear or branched, saturated or unsaturated alkyl radical having 6 to 30 carbon atoms, and

M ^{+ is in} each case an ammonium, an alkanolammonium or a metal cation, b) at least one pearlescing agent, organic and / or inorganic pigments and / or opacifiers, and

 c) contains hardened castor oil.

A suitable carrier is preferably understood as meaning an aqueous or aqueous-alcoholic carrier.

 Preferably, the carrier contains at least 50% by weight, more preferably at least 60% by weight, and most preferably at least 70% by weight of water.

 Furthermore, the cosmetic carrier may contain 0.01 to 40% by weight, preferably 0.05 to 35% by weight and in particular 0.1 to 30% by weight of at least one alcohol which may be selected from ethanol, ethyl diglycol, 1-propanol, 2-propanol, isopropanol, 1, 2-propylene glycol, glycerol, diglycerol, triglycerol, 1-butanol, 2-butanol, 1, 2-butanediol, 1, 3-butanediol, 1-pentanol, 2-pentanol, 1, 2-pentanediol, 1, 5-pentanediol, 1, hexanol, 2-hexanol, 1, 2-hexanediol, 1, 6-hexanediol, polyethylene glycols, sorbitol, sorbitan, benzyl alcohol, phenoxyethanol or mixtures of these alcohols.

Preference is given to the water-soluble alcohols.

 Particularly preferred are ethanol, ethyl diglycol, 1-propanol, 2-propanol, isopropanol, 1, 2-propylene glycol, glycerol, benzyl alcohol and / or phenoxyethanol and mixtures of these alcohols.

Especially preferred is glycerin.

Preferred anionic surfactants of the abovementioned formula (I) have, as radical R, a linear or branched, saturated or unsaturated alkyl radical having 8 to 18 carbon atoms. The radical R particularly preferably represents a Cs, C10, C12, C-M, C16 radical or mixtures of these fatty acid radicals, as are obtained when the fatty acid (s) is derived from natural oils, such as coconut oil (s) ,

In further preferred anionic surfactants of the abovementioned formula (I), the radicals R ² to R ^{5 may} each stand for hydrogen or a methyl, ethyl, n-propyl, n-butyl or 2-butyl group. The radicals R ² to R ⁵ are preferably hydrogen or at least one of the radicals R ² to R ⁵ is a methyl, ethyl or n-propyl group and in particular a methyl group. In a particularly preferred embodiment, one of the radicals R ² to R ^{5 is} a C 1 -C 4 -alkyl group - in particular a methyl group - and the other radicals are each a hydrogen atom.

In principle, it is also possible that the anionic surfactant of the formula (I) contains an isomer mixture in which both components are present, for example, as the radical R ^{2 is} a C ¹ -C 4 alkyl group - especially a methyl group - and as radicals R ³ to R ⁵ each have a hydrogen atom, as well as components which, for example, as the radical R ^{5 have} a Ci-C4-alkyl group - in particular a methyl group - and as radicals R ² to R ⁴ each have a hydrogen atom. M ⁺ in the aforementioned formula (I) is preferably an alkali metal cation or an ammonium ion. Most preferably, the M ^{+ is} a potassium or a sodium ion and most preferably a sodium ion.

In a first preferred embodiment, cosmetic cleansing compositions according to the invention are characterized in that they contain at least one anionic surfactant according to formula (I) in which

all radicals R ² to R ^{5 are} a hydrogen atom or in which at least one of the radicals R ² to R ^{5 is} a C ¹ -C ⁴ -alkyl radical, and the other radicals are a hydrogen atom,

 R is a linear or branched, saturated or unsaturated alkyl radical having 8 to 18 carbon atoms, and

M ^{+ is} a sodium, potassium or ammonium ion.

Within this embodiment, the following anionic surfactants according to the aforementioned formula (I) are particularly preferred (INCI names) Sodium Cocoyl Isethionate, Sodium Lauroyl Isethionate, Sodium Myristyl Isethionate, Sodium Palmitoyl Isethionate, Sodium Stearyl Isethionate, Sodium Oleyl Isethionate, Sodium Cocoyl Methyl Isethionate, Sodium Lauroyl Methyl Isethionate, Sodium Myristyl Methyl Isethionate, Sodium Palmitoyl Methyl Isethionate, Sodium Stearyl Methyl Isethionate and / or Sodium Oleyl Methyl Isethionate. Particularly preferred are sodium cocoyl isethionates and / or sodium lauroyl methyl isethionates.

Corresponding commercial products are available, for example from the company Innospec under the trade name "Iselux ^®" and by the company Clariant or Uniqema under the trade names "Hostapon® ^®" or "Arlatone ^®".

Suitable pearlescing agents may preferably be selected from the mono- and / or diesters of ethylene glycol, 1, 2-propanediol and / or glycerol with C8-C24 fatty acids and / or

 the esters of polyethylene glycols with Cs-C24 fatty acids.

Preference is given to the mono- and / or diesters of ethylene glycol and / or PEG with C 16 -C 22 fatty acids, very particularly preferably the mono- and / or diesters of ethylene glycol and / or PEG with palmitic acid, stearic acid and / or oleic acid, particularly preferably stearic acid ,

Examples of particularly preferred pearlizing agents for the purposes of the present invention are: Glycol Distearate, such as the commercial product Cutina ^® AGS Cognis, glycol monostearates, such as the commercial product Cutina ^® EGMS from Cognis, PEG-3 Distearate, such as the commercial product Genapol ^® TS Clariant, PEG-2 distearate, such as the commercial product Kessco ^® DEGMS Akzo Nobel, propylene glycol stearates, such as the commercially available product ^® Tegin P Goldschmidt.

Among suitable organic and / or inorganic pigments, preference is given to iron oxide, titanium oxide, antimony oxide, magnesium oxide, chromium oxide, aluminum oxide, zinc oxide, zinc peroxide, calcium aluminate, silica, magnesium silicoaluminate, tallow, synthetic mica, colloidal kaolin, bentonite, zinc laurate, polyvinyl chloride, nacre, carbon black, Lanolin, silica and / or mica.

 To achieve pearlescent effects, it is advantageous if the pigments are used as finely divided, pulverulent solids.

 In a particularly preferred embodiment of the invention, the finely divided, pulverulent solid is metal oxides, in particular titanium dioxide, or a synthetic or natural mica coated with a metal oxide, wherein the metal oxide is preferably selected from iron oxide or titanium oxide or mixtures thereof.

 Examples of preferred mica pigments are: Colorona pigments from Merck KGaA, in particular Colorona Light Blue, Colorona Patina Silver, Colorona Bright Gold, Colorona Blackstar Gold, Colorona Majestic Green, Colorona Aborigine Amber, Colorona Bronze, Colorona Bordeaux, Colorona Oriental Beige, Colorona Dark Blue, Colorona Red Gold, Colorona Sienna, Colorona Copper, Colorona Blackstar Green, Colorona Russet, Colorona Patagonian Purple, Colorona Carmine Red, Colorona Passion Orange, Colorona Blackstar Blue, Colorona Red Brown, Colorona Chameleon, Colorona Imperial Red and / or Colorona Magenta and their mixtures.

 The average particle diameter of the finely divided, pulverulent solid in a preferred embodiment of the invention is more than 10 nm, particularly preferably more than 50 nm and in particular more than 100 nm.

The particle diameter in the sense of the invention means the average particle diameter. This can be determined by means of the laser diffraction method using suitable measuring devices (eg. Mastersizer 2000 from Malvern, LA-920 from Horiba) can be easily determined by a person skilled in the art. Mean particle diameter is preferably understood to mean the median particle diameter d [z]. This separates the area of the particle size distribution curve into two equal halves, ie there are as many particles with a diameter larger than d [z] than particles with a diameter smaller than d [z].

Under suitable opacifiers styrene / acrylates copolymers are preferably to be understood as the "Acudyne ^®" or "Acusol ^®" are available for example under the trade names of Dow, or "Acronal ^®" by the company BASF.

In a second particularly preferred embodiment, cleaning agents according to the invention are characterized in that component b) is selected from

 Mono- and / or diesters of ethylene glycol, 1,2-propanediol and / or glycerol with C8-C24-fatty acids, in particular of ethylene glycol with C16-C22-fatty acids,

 inorganic pigments, in particular metal oxides and / or metal oxides coated synthetic and / or natural mica, and / or

 Styrene / acrylate copolymers.

Within this embodiment, it is particularly preferred for the cosmetic cleaners to comprise as component b) one of the compounds known under the INCI names Glycol Distearate, Glycol Monostearate and / or PEG-3 Distearate, titanium dioxide, metal oxide-coated mica pigments, in particular with mica pigments coated with iron oxide and / or titanium dioxide, and / or contains the compound known by the INCI name styrene / acrylates copolymer.

Further particularly preferred cosmetic cleaning agents in the sense of the present invention are characterized in that they

 a) at least one anionic surfactant according to formula (I), wherein the proportion by weight of the at least one anionic surfactant of the formula (I) in the total weight of the compositions 0.1 to 20 wt .-%, preferably 0.5 to 15 wt .-% , particularly preferably from 0.75 to 12.5% by weight and in particular from 1 to 10% by weight,

b) at least one pearlescent agent, organic and / or inorganic pigments and / or at least one clouding agent, wherein the weight fraction of the at least one pearlescing agent, organic and / or inorganic pigment and / or the at least one opacifier on the total weight of the compositions 0.01 to 10 wt .-%, preferably 0.05 to 7.5 wt .-%, particularly preferably 0.1 to 5 wt .-% and in particular 0.25 to 4 wt .-% is, and

 c) hardened castor oil, wherein the proportion by weight of the hardened castor oil in the total weight of the compositions 0.05 to 5 wt .-%, preferably 0.075 to 4 wt .-%, particularly preferably 0.1 to 3 wt .-% and in particular 0, 2 to 2 wt .-% is.

Particularly preferred are cosmetic cleaners which

 a) 0.5 to 5 wt .-%, preferably 0.75 to 4 wt .-% of at least one anionic surfactant of formula (I), selected from those under the INCI names sodium cocoyl isethionate, sodium lauroyl isethionate, sodium myristyl Isethionate, Sodium Palmitoyl Isethionate, Sodium Stearyl Isethionate, Sodium Oleyl Isethionate, Sodium Cocoyl Methyl Isethionate, Sodium Lauroyl Methyl Isethionate, Sodium Myristyl Methyl Isethionate, Sodium Palmitoyl Methyl Isethionate, Sodium Stearyl Methyl Isethionate and / or Sodium Oleyl Methyl Isethionate Known Compounds,

 b) 0.1 to 5% by weight, preferably 0.25 to 4% by weight

 at least one mono- and / or diester of ethylene glycol, 1, 2-propanediol and / or glycerol with Cs-C24 fatty acids, in particular of ethylene glycol with C 16- C 22 fatty acids,

 at least one inorganic pigment, in particular a metal oxide and / or a metal oxide-coated synthetic and / or natural mica, and / or

 at least one styrene / acrylate copolymer, and

 c) 0.1 to 3 wt .-% and in particular 0.2 to 2 wt .-% of hardened castor oil containing a melting point in the range of 80 - 90 ° C,

wherein the quantities are based on the proportion by weight of the respective components a), b) and c) to the total weight of the cleaning agent.

Particularly preferred are cosmetic cleaners which

 a) 0.5 to 5 wt .-%, preferably 0.75 to 4 wt .-% of at least one anionic surfactant of formula (I), selected from among the INCI names sodium cocoyl isethionate and / or sodium lauroyl methyl isethionate known compounds,

b) from 0.1 to 5% by weight, preferably from 0.25 to 4% by weight, of at least one of the compounds, titanium dioxide, known under the INCI names Glycol Distearate, Glycol Monostearate and / or PEG-3 Distearate, with metal oxide ( en) coated mica pigments, in particular iron oxide and / or titanium dioxide coated mica pigments, and / or at least one known under the INCI name styrene / acrylate copolymer compound, and

 c) 0.1 to 3 wt .-% and in particular 0.2 to 2 wt .-% of at least one known under the INCI name Hydrogenated Castor Oil compound having a melting point in the range of 85 - 88 ° C,

wherein the quantities given on the weight fraction of the respective components a), b) and c) am

Refer to the total weight of the cleaning agents.

To increase the mildness of the cleaning agents according to the invention, it is advantageous if they further contain at least one nonionic surfactant and / or at least one nonionic emulsifier.

In a further preferred embodiment, cleaning agents according to the invention are accordingly characterized in that they additionally comprise at least one nonionic surfactant and / or at least one nonionic emulsifier, the weight fraction of the at least one nonionic emulsifier and / or the at least one nonionic surfactant being based on the total weight of the compositions 0, 5 to 25 wt .-%, preferably 0.75 to 20 wt .-%, particularly preferably 1 to 15 wt .-% and in particular 1, 25 to 12.5 wt .-% is.

Suitable nonionic surfactants and / or emulsifiers include, for example

 Addition products of 4 to 30 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide to linear fatty alcohols having 8 to 22 carbon atoms, to fatty acids having 12 to 22 carbon atoms and to alkylphenols having 8 to 15 carbon atoms in the alkyl group,

 Ethylene oxide and polyglycerol addition products to methyl glucoside fatty acid esters, fatty acid alkanolamides and fatty acid glucamides,

 C8-C3o fatty acid mono- and diesters of addition products of 1 to 30 moles of ethylene oxide with glycerol,

 Amine oxides,

 Sorbitan fatty acid esters and adducts of ethylene oxide with sorbitan fatty acid esters such as polysorbates,

Fatty acid alkanolamides of the general formula (VIII),

in which R is preferably a linear or branched, saturated or unsaturated alkyl or alkenyl radical having 8 to 24 carbon atoms and the radicals R 'is hydrogen or the group - (CH 2) _n OH, in which n denotes the numbers 2 or 3, with the proviso that at least one of the radicals R 'represents the abovementioned radical - (CH 2) _n OH,

 Sugar fatty acid esters and addition products of ethylene oxide with sugar fatty acid esters, addition products of ethylene oxide onto fatty acid alkanolamides and fatty amines, and / or alkyl (oligo) glucosides,

Glucosides mixtures of alkyl (oligo) and fatty alcohols, for example, the commercially available product ^® Montanov 68,

 Addition products of from 5 to 60 mol of ethylene oxide onto castor oil and hydrogenated castor oil, partial esters of polyols having 3-6 carbon atoms with saturated fatty acids having 8 to 22 carbon atoms,

 Sterols. Sterols are understood to mean a group of steroids which carry a hydroxyl group on C-atom 3 of the steroid skeleton and are isolated both from animal tissue (zoosterines) and from vegetable fats (phytosterols). Examples of zoosterols are cholesterol and lanosterol. Examples of suitable phytosterols are ergosterol, stigmasterol and sitosterol. Mushrooms and yeasts are also used to isolate sterols, the so-called mycosterols.

 Phospholipids. Of these, especially the glucose phospholipids, e.g. as lecithins or phosphatidylcholines from e.g. Egg yolk or plant seeds (e.g., soybeans).

Suitable alkyl (oligo) glycosides may be selected from compounds of the general formula RO- [G] _x , in which [G] is preferably derived from aldoses and / or ketoses having 5-6 carbon atoms, preferably glucose.

 The index number x stands for the degree of oligomerization (DP), i. for the distribution of mono- and oligoglycosides. The index number x preferably has a value in the range of 1 to 10, more preferably in the range of 1 to 3, which may not be an integer, but may be a fractional number that can be determined analytically.

 Particularly preferred alkyl (oligo) glycosides have a degree of oligomerization between 1, 2 and 1.5.

 The radical R is preferably at least one alkyl and / or alkenyl radical having 4 to 24 carbon atoms. Particularly preferred alkyl (oligo) glycosides are the compounds known under the INCI names Caprylyl / Capryl Glucoside, Decyl Glucoside, Lauryl Glucoside and Coco Glucoside.

in denen R jeweils für einen geradkettigen oder verzweigten, gesättigten oder ein- oder mehrfach ungesättigten Alkyl- oder Alkenylrest mit 6 bis 24 Kohlenstoffatomen, bevorzugt mit 8 bis 18 Kohlenstoffatomen steht. Suitable amine oxides may be selected from at least one compound of the general formulas (II) or (III)

in which R in each case represents a straight-chain or branched, saturated or mono- or polyunsaturated alkyl or alkenyl radical having 6 to 24 carbon atoms, preferably having 8 to 18 carbon atoms.

 Particularly preferred are the known under the INCI names Cocamine oxides, lauramine oxides and / or Cocamidopropylaminoxid and commercially available from various suppliers surfactants of the aforementioned formula (II) or (III).

Suitable Cs-Cso-fatty acid mono- and diesters of addition products of 1 to 30 moles of ethylene oxide with glycerol are preferably understood to mean the glyceryl cocoates, in particular PEG-7 glyceryl cocoate, under the INCI names PEG (1-10).

 It may also be advantageous to combine the ethoxylated fatty acid esters with other ethoxylated fatty acid esters. Such product mixtures are commercially available - for example, under the name "Antil 200®" (INCI name: PEG-200 Hydrogenated Glyceryl Palmate, PEG-7 Glyceryl Cocoate) from Evonik.

Particularly preferred nonionic surfactants and / or emulsifiers which may be present in the compositions according to the invention are alkyl (oligo) glucosides, in particular the compounds known under the INCI names Caprylyl / Capryl Glucoside, Decyl Glucoside, Lauryl Glucoside and Coco Glucoside, Cs. Cso-Fettsäuremono- and diesters of addition products of 1 to 30 moles of ethylene oxide to glycerol, in particular the known under the INCI name PEG-7 glyceryl cocoate compound, sorbitan fatty acid esters and / or addition products of 4 to 30 moles of ethylene oxide and / or 0 to 5 Mol of propylene oxide to linear fatty alcohols having 8 to 22 carbon atoms.

It has been found that particularly mild detergents with good foam properties can be prepared if the anionic surfactant (s) according to formula (I) with at least one further surfactant selected from further anionic surfactants and / or from amphoteric / zwitterionic Surfactants is combined.

Particularly good results could be achieved if the further anionic surfactant contains no sulfate groups. In a further preferred embodiment, cleaning agents according to the invention are therefore preferred in which the proportion by weight of sulfate-containing surfactants in the total weight of the compositions is less than 0.5% by weight, preferably less than 0.3% by weight and in particular less than 0.2 Wt .-% is.

For the purposes of the present invention, the particularly suitable other anionic surfactants other than a) include, for example:

Ether carboxylic acids of the formula R-O- (CH 2 -CH 2 O) _x -CH 2 -COOH, in which R is a linear or branched, saturated or unsaturated alkyl group having 8 to 30 C atoms and x = 0 or 1 to 16,

 Acylsarcosides having 8 to 24 carbon atoms in the acyl group,

 Acyltaurides having 8 to 24 carbon atoms in the acyl group,

 Acylglutamate having 8 to 24 carbon atoms in the acyl group and / or

 Sulfobernsteinsäuremono- and / or dialkyl ester having 8 to 24 carbon atoms in the alkyl group and sulfosuccinic monoalkylpolyoxyethylester having 8 to 24 carbon atoms in the alkyl group and 1 to 6 oxyethyl groups.

The proportion by weight of one or more of the anionic surfactant (s) differing from a) in the total weight of the cosmetic compositions is preferably from 0.1 to 25% by weight, more preferably from 0.5 to 20% by weight, particularly preferably 0, 75 to 17.5 wt .-% and in particular 1 to 15 wt .-%.

Suitable amphoteric and / or zwitterionic surfactants which can be used in the cleaning agents according to the invention preferably correspond to at least one compound of the following formulas (i) to (vii), in which the radical R is a straight-chain or branched, saturated or one or more times unsaturated alkyl or alkenyl radical having 7 to 23 carbon atoms (formulas (i) and (ii)) or a straight-chain or branched, saturated or mono- or polyunsaturated alkyl or alkenyl radical having 8 to 24 carbon atoms (formulas (iii) to ( vii)),

 Preferred amphoteric and / or zwitterionic surfactants of the abovementioned formulas (i) to (vii) contain as radical R predominantly a straight-chain or branched, saturated, mono- or polyunsaturated alkyl radical having 8 to 20, more preferably 8 to 16 and in particular with 8 to 12 carbon atoms.

 More preferred are amphoteric and / or zwitterionic surfactants in which the radical R is derived from coconut oil.

 Particularly preferred are amphoteric and / or zwitterionic surfactants of the formulas (iii), (v), (vi) and (vii).

Especially preferred are the amphoteric surfactants known under the INCI names cocamidopropyl betaine and / or cocoampho (di) acetate and commercially available from several suppliers. The proportion by weight of the amphoteric / zwitterionic surfactant (s) of one of the abovementioned formulas (i) to (vii) in the total weight of the cosmetic compositions is preferably from 0.5 to 15% by weight, preferably from 1 to 12.5% by weight. -% and in particular from 2 to 10 wt .-%.

In a further preferred embodiment, cosmetic cleansing compositions according to the invention are preferred which

 a) at least one anionic surfactant according to formula (I), wherein the proportion by weight of the at least one anionic surfactant of the formula (I) in the total weight of the compositions 0.1 to 20 wt .-%, preferably 0.5 to 15 wt .-% , particularly preferably from 0.75 to 12.5% by weight and in particular from 1 to 10% by weight,

 b) at least one pearlescent agent, organic and / or inorganic pigments and / or at least one clouding agent, wherein the weight fraction of the at least one pearlescing agent, organic and / or inorganic pigment and / or the at least one opacifier on the total weight of the compositions 0.01 to 10 Wt .-%, preferably 0.05 to 7.5 wt .-%, particularly preferably 0.1 to 5 wt .-% and in particular 0.25 to 4 wt .-% is,

c) hardened castor oil, wherein the proportion by weight of the hardened castor oil in the total weight of the compositions 0.05 to 5 wt .-%, preferably 0.075 to 4 wt .-%, particularly preferably 0.1 to 3 wt .-% and in particular 0, From 2 to 2% by weight, d) at least one contains a nonionic surfactant and / or at least one nonionic emulsifier, wherein the proportion by weight of the at least one nonionic emulsifier and / or the at least one nonionic surfactant in the total weight of the compositions from 0.5 to 25 Wt .-%, preferably 0.75 to 20 wt .-%, particularly preferably 1 to 15 wt .-% and in particular 1, 25 to 12.5 wt .-% is, and / or e) at least one further - a) various anionic surfactant, preferably a sulphate group-free anionic surfactant, and / or at least one amphoteric (zwitterionic) surfactant according to one of the formulas (i) to (vii), wherein the weight fraction of the further - of a) different - anionic Surfactants and or of the amphoteric (zwitterionic) surfactant according to one of the formulas (i) to (vii) in the total weight of the compositions in each case 0.25 to 15 wt .-%, preferably 0.5 to 12.5 wt .-%, particularly preferably 0 , 75 to 10 wt .-% and in particular 1 to 7.5 wt .-% is. In a further preferred embodiment of the use according to the invention, the care properties of the cosmetic compositions can be further increased if they contain at least one conditioning agent which can be selected from the group of

 protein,

 cationic polymers,

 vitamins,

 Fats, oils and / or waxes and / or

 Glycerol.

Suitable protein hydrolysates are product mixtures which can be obtained by acid, alkaline or enzymatically catalyzed degradation of proteins (proteins).

It can be used protein hydrolysates of plant, animal and / or marine origin. Animal protein hydrolysates are, for example, elastin, collagen, keratin, silk and milk protein hydrolysates, which may also be present in the form of salts. Such products are, for example, under the trademarks Dehylan ^® (Cognis), Promois® ^® (Interorgana) Collapuron ^® (Cognis), Nutrilan® ^® (Cognis), Gelita-Sol ^® (German Gelatinefabriken Stoess & Co), Lexein ^® (Inolex) and kerasol tm ^® (Croda) sold.

Preference is given to protein hydrolysates of plant origin, eg. Soybean, almond, rice, pea, potato and wheat protein hydrolysates. Such products are, for example, under the trademarks Gluadin ^® (Cognis), diamine ^® (Diamalt) ^® (Inolex) and Crotein ^® (Croda) available. It is also possible to use cationized protein hydrolysates, the protein hydrolyzate on which the animal is based, for example from collagen, milk or keratin, from the plant, for example from wheat, maize, rice, potatoes, soy or almonds, from marine life forms, for example from fish collages or algae, or from biotechnologically derived protein hydrolysates. The protein hydrolyzates on which the cationic derivatives are based can be obtained from the corresponding proteins by chemical, in particular alkaline or acid hydrolysis, by enzymatic hydrolysis and / or a combination of both types of hydrolysis. The hydrolysis of proteins usually results in a protein hydrolyzate having a molecular weight distribution of about 100 daltons up to several thousand daltons. Preference is given to those cationic protein hydrolyzates whose underlying protein content has a molecular weight of 100 to 25,000 daltons, preferably 250 to 5000 daltons. Furthermore, cationic protein hydrolyzates are to be understood as meaning quaternized amino acids and mixtures thereof. Quaternization of the protein hydrolyzates or amino acids is often carried out using quaternary ammonium salts such as N, N-dimethyl-N- (n-alkyl) -N- (2-hydroxy-3-chloro-n-propyl) ammonium halides. Furthermore, the cationic protein hydrolysates may also be further derivatized. As typical examples of the cationic protein hydrolysates and derivatives Cocodimium Hydroxypropyl Hydrolyzed Casein, Cocodimium Hydroxypropyl Hydrolyzed Collagen, Cocodimonium Hydroxypropyl Hydrolyzed Hair Keratin, Cocodimonium Hydroxypropyl Hydrolyzed Keratin, Cocodimonium Hydroxypropyl Hydrolyzed Rice Protein, Cocodimonium Hydroxypropyl Hydrolyzed Silk, Cocodimonium Hydroxypropyl Hydrolyzed Soy Protein, Cocodimonium Hydroxypropyl Hydrolyzed Wheat Protein, Cocodimonium Hydroxypropyl Silk Amino Acids, Hydroxypropyl Arginine Lauryl / Myristyl Ether HCl, Hydroxypropyltrimonium Gelatin, Hydroxypropyltrimonium Hydrolyzed Casein, Hydroxypropyltrimonium Hydrolyzed Collagen, Hydroxypropyltrimonium Hydrolyzed Conchiolin Protein, Hydroxypropyltrimonium Hydrolyzed keratin, Hydroxypropyltrimonium Hydrolyzed Rice Bran Protein, Hydroxyproypltrimonium Hydrolyzed Silk, Hydroxypropyltrimonium Hydrolyzed Soy Protein, Hydroxyprop Hydrolyzed Vegetable Protein, Hydroxypropyltrimonium Hydrolyzed Wheat Protein, Hydroxypropyltrimonium Hydrolyzed Wheat Protein / Siloxysilicate, Laurodimonium Hydroxypropyl Hydrolyzed Soy Protein, Lauridimonium Hydroxypropyl Hydrolyzed Wheat Protein, Laurodimonium Hydroxypropyl Hydrolyzed Wheat Protein / Siloxysilicate, Lauryldimonium Hydroxypropyl Hydrolyzed Casein, Lauryldimonium Hydroxypropyl Hydrolyzed Collagen, Lauryldimonium Hydroxypropyl Hydrolyzed Keratin, Lauryldimony Hydroxypropyl Hydrolyzed Silk, Lauryldimonium Hydroxypropyl Hydrolyzed Soy Protein, Steardimonium Hydroxypropyl Hydrolyzed Casein, Steardimonium Hydroxypropyl Hydrolyzed Collagen, Steardimonium Hydroxypropyl Hydrolyzed Keratin, Steardimonium Hydroxypropyl Hydrolyzed Rice Protein, Steardimonium Hydroxypropyl Hydrolyzed Silk, Steardimonium Hydroxypropyl Hydrolyzed Soy Protein, Steardimonium Hydroxypropyl Hydrolyzed Vegetable Protein , Steardimonium Hydroxypropyl Hydrolyzed Wheat Protein, Steartrimonium Hydroxyethyl Hy Drolyzed Collagen, Quaternium-76 Hydrolyzed Collagen, Quaternium-79 Hydrolyzed Collagen, Quaternium-79 Hydrolyzed Keratin, Quaternium-79 Hydrolyzed Milk Protein, Quaternium-79 Hydrolyzed Silk, Quaternium-79 Hydrolyzed Soy Protein, Quaternium-79 Hydrolyzed Wheat Protein. The proportion by weight of the protein hydrolyzate (s) in the total weight of the cosmetic compositions is preferably from 0.01 to 5% by weight, more preferably from 0.025 to 3% by weight and in particular from 0.05 to 2% by weight.

Suitable cationic polymers are, for example:

quaternized cellulose derivatives, such as are available under the names of Celquat ^® and Polymer JR ^® commercially

 quaternized cellulose derivatives which may be hydrophobically modified, for example

Polyquaternium-67,

 cationic alkyl polyglycosides,

cationized honey, for example the commercial product Honeyquat ^® 50, polymeric dimethyldiallylammonium salts and their copolymers with esters and amides of acrylic acid and methacrylic acid. Under the names Merquat ^® 100 (Poly (dimethyldiallylammonium chloride)) and Merquat ^® 550 (dimethyldiallylammonium chloride-acrylamide copolymer) are examples of such cationic polymers,

cationic guar derivatives, in particular under the trade name Cosmedia Guar ^® N-

^Hance® and ^Jaguar® distributed products,

Copolymers of vinylpyrrolidone with quaternized derivatives of dialkylaminoalkyl acrylate and methacrylate, such as diethyl sulfate quaternized vinylpyrrolidone-dimethylaminoethyl methacrylate copolymers. Such compounds are sold under the names Gafquat ^® 734 and Gafquat ^® 755 commercially,

Vinylpyrrolidone vinylimidazoliummethochloride copolymers, such as those offered under the names Luviquat.RTM ^® FC 370, FC 550, FC 905 and HM 552,

 quaternized polyvinyl alcohol,

as well as those under the designations

 Polyquaternium 2, Polyquaternium 17, Polyquaternium 18, Polyquaternium-24, Polyquaternium 27, Polyquaternium-32, Polyquaternium-37, Polyquaternium 74 and Polyquaternium 89 known polymers.

Preferred cationic polymers are preferably selected from the polymers known under the INCI names Guar Hydroxypropyltrimonium Chloride, Polyquaternium-67, Polyquaternium-10, Polyquaternium-6, Polyquaternium-7 and / or Polyquaternium-37. Particularly preferred are the polymers known under the INCI names guar hydroxypropyltrimonium chlorides, polyquaternium-7 and / or polyquaternium-10 known polymers.

 The proportion by weight of the cationic polymer (s) in the total weight of the cosmetic compositions is preferably from 0.01 to 5% by weight, more preferably from 0.025 to 4% by weight, particularly preferably from 0.05 to 3% by weight and in particular 0, 1 to 2 wt .-%.

Suitable vitamins are preferably the following vitamins, provitamins and vitamin precursors and their derivatives:

 • Vitamin A: the group of substances called vitamin A includes retinol (vitamin Ai) and 3,4-didehydroretinol (vitamin A2). The ß-carotene is the provitamin of retinol. As vitamin A component, for example, vitamin A acid and its esters, vitamin A aldehyde and vitamin A alcohol and its esters such as the palmitate and the acetate into consideration.

• Vitamin B: belong to the vitamin B group or to the vitamin B complex among others > Vitamin Bi (thiamine)

> Vitamin B ₂ (riboflavin)

 > Vitamin B3. Under this designation are often the compounds nicotinic acid and

 Nicotinic acid amide (niacinamide).

 > Vitamin Bs (pantothenic acid and panthenol). Within this group is preferred

 used the panthenol. Useful derivatives of panthenol are in particular the

Panthenol esters and ethers, pantolactone and cationically derivatized panthenols. Individual representatives are, for example, panthenol triacetate, panthenol monoethyl ether and its monoacetate, as well as cationic panthenol derivatives.

> Vitamin Ββ (pyridoxine and pyridoxamine and pyridoxal).

 Vitamin C (ascorbic acid): use in the form of palmitic acid ester, glucosides or phosphates may be preferred. The use in combination with tocopherols may also be preferred.

 • Vitamin E (tocopherols, especially a-tocopherol).

 • Vitamin F: the term "vitamin F" is usually understood as meaning essential fatty acids, in particular linoleic acid, linolenic acid and arachidonic acid.

 • Vitamin H: Vitamin H is the compound (3aS, 4S, 6aR) -2-oxohexahydrothienol [3,4-d] - imidazole-4-valeric acid, for which, in the meantime, the trivial name biotin has prevailed.

 Particular preference is given to vitamins, provitamins and vitamin precursors from groups A, B, E and H. Particular preference is given to nicotinamide, biotin, pantolactone and / or panthenol.

The proportion by weight of the vitamin (s), vitamin derivative (s), and / or the vitamin precursor (s) in the total weight of the cosmetic compositions is preferably from 0.001 to 2% by weight, particularly preferably from 0.005 to 1% by weight and in particular 0 , 01 to 0.5 wt .-%.

Suitable oil, wax and / or fat components may preferably be selected from mineral, natural and synthetic oil components and / or fatty substances.

As natural (vegetable) oils usually triglycerides and mixtures of triglycerides are used. Preferred natural oils are coconut oil, (sweet) almond oil, walnut oil, peach kernel oil, apricot kernel oil, avocado oil, tea tree oil, soybean oil, sesame oil, sunflower oil, tsubaki oil, evening primrose oil, rice bran oil, palm kernel oil, mango seed oil, meadowfoam seed oil, thistle oil, macadamia nut oil, grapeseed oil, Amaranth seed oil, argan oil, bamboo oil, olive oil, wheat germ oil, pumpkin seed oil, mallow oil, hazelnut oil, safflower oil, canola oil, sasanqua oil, jojoba oil, rambutan oil, cocoa butter and shea butter. As mineral oils are used in particular mineral oils, paraffin and Isoparaffinöle and synthetic hydrocarbons. An example of a usable hydrocarbon is for example that available as a commercial product 1, 3-di- (2-ethylhexyl) -cyclohexane (Cetiol ^® S). As the oil component may further serve a dialkyl ether.

 Useful dialkyl ethers are in particular di-n-alkyl ethers having a total of from 12 to 36 carbon atoms, in particular 12 to 24 carbon atoms, such as, for example, di-n-octyl ether, di-n-decyl ether, di-n-nonyl ether, di-n -undecyl ether, di-n-dodecyl ether, n-hexyl n-octyl ether, n-octyl n-decyl ether, n-decyl n-undecyl ether, n-undecyl n-dodecyl ether and n-hexyl n-undecyl ether and di tert-butyl ether, di-isopentyl ether, di-3-ethyl decyl ether, tert-butyl n-octyl ether, iso-pentyl n-octyl ether and 2-methylpentyl n-octyl ether.

Particularly preferred is the di-n-octyl ether, which is commercially available under the name Cetiol ^® OE.

 Suitable synthetic oils are preferably silicone compounds.

 Silicones have excellent conditioning properties on the hair. In particular, they cause better combability of the hair in the wet and dry state and in many cases have a positive effect on the hair and the softness of the hair.

 It is therefore desirable to use silicones in cosmetic hair treatment compositions. Suitable silicones may be selected from:

 (i) polyalkyl siloxanes, polyaryl siloxanes, polyalkylaryl siloxanes which are volatile or nonvolatile, straight chain, branched or cyclic, crosslinked or uncrosslinked;

(ii) Polysiloxanes containing in their general structure one or more organofunctional groups selected from:

 a) substituted or unsubstituted aminated groups;

 b) (per) fluorinated groups;

 c) thiol groups;

 d) carboxylate groups;

 e) hydroxylated groups;

 f) alkoxylated groups;

 g) acyloxyalkyl groups;

 h) amphoteric groups;

 ') Bisulfite groups;

 j) hydroxyacylamino groups;

 k) carboxy groups;

 I) sulfonic acid groups; and

 m) sulphate or thiosulphate groups;

(iii) linear polysiloxane (A) - polyoxyalkylene (B) - block copolymers of the type (AB) n with n>3; (iv) grafted silicone polymers having a non-silicone organic backbone consisting of an organic backbone formed from organic monomers containing no silicone grafted with at least one polysiloxane macromer in the chain and optionally at least one chain end;

 (v) grafted polysiloxane backbone silicone polymers having grafted thereto non-silicone organic monomers having a polysiloxane backbone to which at least one organic macromer not containing silicone has been grafted in the chain and optionally at least at one of its ends ;

 (vi) or mixtures thereof.

Fatty substances are to be understood fatty acids, fatty alcohols and natural and synthetic waxes, which may be present both in solid form and liquid in aqueous dispersion. The fatty acids used can be linear and / or branched, saturated and / or unsaturated fatty acids having 6 to 30 carbon atoms. Preference is given to fatty acids having 10 to 22 carbon atoms. Among these could be mentioned, for example, isostearic as the commercial products Emersol ^® 871 and Emersol ^® 875, and isopalmitic acids such as the commercial product Edenor ^® IP 95, and all other products sold under the trade names Edenor ^® (Cognis) fatty acids. Other typical examples of such fatty acids are caproic, caprylic, 2-ethylhexanoic, capric, lauric, isotridecanoic, myristic, palmitic, palmitoleic, stearic, isostearic, oleic, elaidic, petroselic, linoleic, linolenic and erucic acid and their technical mixtures.

 Particularly preferred are usually the fatty acid cuttings obtainable from coconut oil or palm oil; In particular, the use of stearic acid is usually preferred.

As fatty alcohols it is possible to use saturated, mono- or polyunsaturated, branched or unbranched fatty alcohols with C6-C30, preferably C10-C22 and very particularly preferably C12-C22, carbon atoms. For example, decanol, octanol, octenol, dodecenol, decenol, octadienol, dodecadienol, decadienol, oleyl alcohol, erucalcohol, ricinoleic alcohol, stearyl alcohol, isostearyl alcohol, cetyl alcohol, lauryl alcohol, myristyl alcohol, arachidyl alcohol, capryl alcohol, capric alcohol, linoleyl alcohol, linolenyl alcohol and behenyl alcohol, as well as their guerbet alcohols can be used , this list should have exemplary and non-limiting character. However, the fatty alcohols are derived from preferably natural fatty acids, which can usually be based on recovery from the esters of fatty acids by reduction. Also usable according to the invention are those fatty alcohol cuts which are produced by reduction of naturally occurring triglycerides such as beef tallow, palm oil, peanut oil, rapeseed oil, cottonseed oil, soybean oil, sunflower oil and linseed oil or from their transesterification products with corresponding fatty acid esters, and thus a mixture of different Represent fatty alcohols. Such substances are, for example, under the names Stenol ^® such as Stenol ^® 1618 or Lanette ^® such as Lanette ^® O or Lorol ^®, for example, Lorol ^® C8, Lorol C14 ^®, Lorol C18 ^{®, ®} Lorol C8-18, HD-Ocenol ^®, Crodacol ^® such as Crodacol ^® CS, Novol ^®, Eutanol ^® G, Guerbitol ^® 16, Guerbitol ^® 18, Guerbitol ^® 20, Isofol ^® 12, Isofol ^® 16, Isofol ^® 24, Isofol ^® 36, Isocarb ^® 12, Isocarb ^® 16 or acquire Isocarb® ^® 24 for sale. Of course, wool wax alcohols, as are commercially available, for example under the names of Corona ^®, White Swan ^®, Coronet ^® or Fluilan ^® can be used according to the invention.

 As natural or synthetic waxes may be used solid paraffins or isoparaffins, carnauba waxes, beeswaxes, candelilla waxes, ozokerites, ceresin, spermaceti, sunflower wax, fruit waxes such as apple wax or citrus wax, microwaxes of PE or PP. Such waxes are available, for example, from Kahl & Co., Trittau. Other fatty substances are, for example

 Esteröle. Ester oils are the esters of C6-C30 fatty acids with C2-C30 fatty alcohols. The monoesters of the fatty acids with alcohols having 2 to 24 carbon atoms are preferred. Examples of fatty acid components used in the esters are caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, elaeostearic acid, arachidic acid, Gadoleic acid, behenic acid and erucic acid and their technical mixtures.

Examples of the fatty alcohol components in the ester oils are isopropyl alcohol, caproic alcohol, capryl alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, linolyl alcohol, linolenyl alcohol, elaeostearyl alcohol, arachyl alcohol, Gadoleyl alcohol, behenyl alcohol, erucyl alcohol and brassidyl alcohol and their technical mixtures. Particularly preferred are isopropyl myristate (IPM Rilanit ^®), isononanoic acid C16-18 alkyl ester (Cetiol ^® SN), 2-ethylhexyl palmitate (Cegesoft ^® 24) stearic acid 2-ethylhexyl ester (Cetiol ^® 868), cetyl oleate, glycerol tricaprylate, caprate Kokosfettalkohol- / - caprylate (Cetiol ^® LC), n-butyl stearate, oleyl erucate (Cetiol ^® J 600), isopropyl palmitate (Rilanit ^® IPP), oleyl Oleate (Cetiol ^®), hexyl laurate (Cetiol ^® A), di-n-butyl adipate (Cetiol ^® B),

Myristyl myristate (Cetiol ^® MM), Cetearyl Isononanoate (Cetiol ^® SN), decyl oleate (Cetiol ^® V).

 Dicarboxylic acid esters such as di-n-butyl adipate, di- (2-ethylhexyl) adipate, di- (2-ethylhexyl) succinate and di-isotridecyl acelate, and diol esters such as ethylene glycol dioleate, ethylene glycol diisotridecanoate, propylene glycol di (2) ethylhexanoate), propylene glycol diisostearate, propylene glycol di-pelargonate, butanediol diisostearate, neopentyl glycol dicaprylate,

symmetrical, unsymmetrical or cyclic esters of carbonic acid with fatty alcohols, Glycerol carbonate or dicaprylyl carbonate (Cetiol ^® CC),

ethoxylated or non ethoxylated mono, - di- and trifatty acid esters of saturated and / or unsaturated linear and / or branched fatty acids with glycerol such as Monomuls 90-018 ^{®, ®} Monomuls 90-L12, Cetiol ^® HE or Cutina ^® MD.

The proportion by weight of the oil, wax and / or fat components in the total weight of the cosmetic compositions is preferably 0.01 to 5 wt .-%, particularly preferably 0.025 to 4 wt .-% and in particular 0.05 to 3 wt .-%.

Particularly preferred are cosmetic cleansing compositions containing as care component at least one cationic polymer, at least one water-insoluble silicone compound and / or at least one vitamin (derivative).

 Particularly preferred is a nourishing active ingredient complex which contains at least two nourishing substances from the abovementioned active ingredient groups.

Glycerin may be added to cosmetics separately in an amount of up to 10% by weight (based on the total weight of the cleanser). It may also be part of the aqueous-alcoholic carrier.

It has been found that the cosmetic compositions according to the invention are also suitable for use as antidandruff preparations.

 The total weight of anti-dandruff agents in the total weight of the cosmetic compositions may preferably 0.01 to 10 wt .-%, more preferably 0.025 to 7.5 wt .-%, particularly preferably 0.05 to 5 wt .-% and in particular 0.075 to 3 wt .-% amount.

 Suitable antidandruff active ingredients may be selected from Piroctone olamine, climbazole, zinc pyrithione, ketoconazole, salicylic acid, sulfur, selenium sulfide, tar preparations, undecenoic acid derivatives, burdock root extracts, poplar extracts, nettle extracts, walnut shell extracts, birch extracts, willow bark extracts, rosemary extracts and / or arnica extracts.

Preferred are climbazole, zinc pyrithione and piroctone olamine.

Further active ingredients, auxiliaries and additives which may preferably be present in the cleaning agents according to the invention are, for example:

 Plant extracts,

 Humectants,

 perfumes,

- UV filters, Thickening agents such as gelatin or vegetable gums, for example agar-agar, guar gum, alginates, xanthan gum, gum arabic, karaya gum, locust bean gum, linseed gums, dextrans, cellulose derivatives, e.g. As methylcellulose, hydroxyalkylcellulose and carboxymethylcellulose, starch fractions and derivatives such as amylose, amylopectin and dextrins, clays and phyllosilicates such. As bentonite or fully synthetic hydrocolloids such. B. polyvinyl alcohol, the Ca, Mg or Zn soaps,

 Structurants such as maleic acid and lactic acid,

 dimethyl isosorbide,

 cyclodextrins

 fiber-structure-improving active ingredients, in particular mono-, di- and oligosaccharides such as, for example, glucose, galactose, fructose, fructose and lactose,

 Dyes for staining the agent,

 Substances for adjusting the pH, for example α- and β-hydroxycarboxylic acids such as citric acid, lactic acid, malic acid, glycolic acid,

 Active ingredients such as bisabolol,

 Complexing agents such as EDTA, NTA, β-alaninediacetic acid and phosphonic acids,

 Ceramides. Ceramides are understood as meaning N-acylsphingosine (fatty acid amides of sphingosine) or synthetic analogs of such lipids (so-called pseudo-ceramides),

 Propellants such as propane-butane mixtures, N 2 O, dimethyl ether, CO 2 and air,

 Antioxidants,

Preservatives, such as sodium benzoate or salicylic acid,

 Additional viscosity regulators, such as salts (NaCl).

The cosmetic compositions according to the invention may preferably have a pH in the range from 3 to 8, more preferably from 3.5 to 7.5, particularly preferably from 4 to 7 and in particular from 4.5 to 6.5.

The cosmetic compositions according to the invention preferably have a viscosity in the range from 1, 000 to 15,000 mPas, preferably from 1, 500 to 12,500 mPas and in particular from 3,000 to 10,000 mPas (measured in each case with a Haake VT550 20 ° C rotary viscometer, measuring device MV Spindle MV II; 8 rpm). Compositions of such a viscosity can be well distributed on the respective application surface - particularly preferably on the hair - and, if appropriate, rinse off again with water after use.

A second object of the invention is the use of hardened castor oil to increase the care properties of cosmetic cleaners, the a) at least one anionic surfactant according to formula (I) below,

 in the

the radicals R ² to R ⁵ independently of one another represent a hydrogen atom, a C 1 -C 4 -alkyl or a C 1 -C 4 -hydroxyalkyl radical,

 R is a linear or branched, saturated or unsaturated alkyl radical having 6 to 30 carbon atoms, and

M ^{+ is in} each case an ammonium, an alkanolammonium or a metal cation, and

 b) at least one pearlescing agent, organic and / or inorganic pigments and / or at least one clouding agent.

For the purposes of the present invention, care properties are understood in particular as hair care properties and, in particular, improved combability of the hair and / or an improved hair grip.

In a preferred embodiment, the use according to the invention therefore relates to improving the combability of the hair and / or improving the hair grip.

A third aspect of the invention is a cosmetic method for improving the hair grip and / or the combability of hair, in which a cosmetic cleanser containing

a) at least one anionic surfactant according to formula (I) below,

 in the

the radicals R ² to R ⁵ independently of one another represent a hydrogen atom, a C 1 -C 4 -alkyl or a C 1 -C 4 -hydroxyalkyl radical,

 R is a linear or branched, saturated or unsaturated alkyl radical having 6 to 30 carbon atoms, and

M ^{+ is in} each case an ammonium, an alkanolammonium or a metal cation, b) at least one pearlescing agent, organic and / or inorganic pigments and / or at least one clouding agent, and

 c) hardened castor oil,

 applied to dry or wet hair, and rinsed with water after a period of 5 seconds to 5 minutes.

For preferred embodiments of the use according to the invention and of the method according to the invention, what has been said about the agents according to the invention applies mutatis mutandis.

Examples:

 The following hair cleansers according to the invention were prepared (compositions A-D in the following table; amounts in [% by weight]):

 * determined with a Haake VT550 rotational viscometer; 20 ° C; Measuring device MV; Spindle MV II; 8 rpm

In compositions A-F, the following commercial products were used:

¹ INCI name: SODIUM COCOAMPHOACETATE, GLYCERIN, LAURYL GLUCOSIDE, SODIUM COCOYL GLUTAMATE, SODIUM LAURYL GLUCOSE CARBOXYLATE; BASF,

² INCI name: SODIUM LAUROYL METHYL ISETHIONATE; 32% AS; Innospec,

³ INCI name: COCO-GLUCOSIDE, AQUA; 51 -53% AS; BASF, ⁴ INCI name: AQUA, COCAMIDOPROPYL BETAINE; 35 to 37.5% AS; Evonik,

⁵ INCI name: DICAPRYLYL ETHER, LAURYL ALCOHOL; BASF

⁶ INCI name: SUNFLOWER SEED OIL SORBITOL ESTERS; Clariant

⁷ INCI name: PROPOXYLATED TETRADECYL ALCOHOL; Evonik

⁸ INCI name: Polyquaternium-10; Shanghai Jida Meticulous Chemical Industry,

⁹ INCI name: GLYCOL DISTEARATE, LAURETH-4, COCAMIDOPROPYL BETAINE;

 Degussa

 0 INCI name: SILICONE QUATERNIUM-22, POLYGLYCERYL-3 CAPRATE, DIPROPYLENE GLYCOL, COCAMIDOPROPYL BETAINE; Evonik,

 INCI name: PEG-200 HYDROGENATED GLYCERYL PALMATE, PEG-7 GLYCERYL COCOATE; Evonik

The results in the table show that the hair cleansing compositions according to the invention have a rich, white shimmering appearance. They are storage stable (even at higher temperatures) and show no Separationserscheinungen, although no acrylate gelling agents or fatty acids have been added as stabilizers. In addition, the compositions (B, C, D) according to the invention impart improved combability (in particular improved dry combability) to the hairs treated therewith, as well as an improved hair grip.

Claims

claims:  1. Cosmetic cleanser containing in a suitable carrier a) at least one anionic surfactant according to formula (I) below,

 in the the radicals R ² to R ⁵ independently of one another represent a hydrogen atom, a C 1 -C 4 -alkyl or a C 1 -C 4 -hydroxyalkyl radical,  R is a linear or branched, saturated or unsaturated alkyl radical having 6 to 30 carbon atoms, and M ^{+ is in} each case an ammonium, an alkanolammonium or a metal cation, b) at least one pearlescing agent, organic and / or inorganic pigments and / or opacifiers, and  c) hardened castor oil. 2. Cosmetic cleaning agent according to claim 1, characterized in that it  at least one anionic surfactant according to formula (I), in which all radicals R ² to R ^{5 are} a hydrogen atom or in which at least one of the radicals R ² to R ^{5 is} a C ¹ -C ⁴ -alkyl radical, and the other radicals are a hydrogen atom,  R is a linear or branched, saturated or unsaturated alkyl radical having 8 to 18 carbon atoms, and M ^{+ is} a sodium, potassium or ammonium ion. 3. Cosmetic cleaning agent according to one of the preceding claims, characterized in that the anionic surfactant according to formula (I) at least one of the INCI names Sodium Cocoyl Isethionate, Sodium Lauroyl Isethionate, Sodium Myristyl Isethionate, Sodium Palmitoyl Isethionate, Sodium Stearyl Isethionate, Sodium Oleyl Isethionate, Sodium Cocoyl Methyl Isethionate, Sodium Lauroyl Methyl Isethionate, Sodium Myristyl Methyl Isethionate, Sodium Palmitoyl Methyl Isethionate, Sodium Stearyl Methyl Isethionate, Sodium Oleyl Methyl Isethionate, especially Sodium Cocoyl Isethionate, Sodium Lauroyl Methyl Isethionate. Cosmetic cleaning agent according to one of the preceding claims, characterized in that the component b) is selected from  Mono- and / or diesters of ethylene glycol, 1,2-propanediol and / or glycerol with C8-C24-fatty acids, in particular of ethylene glycol with C16-C22-fatty acids,  inorganic pigments, in particular metal oxides and / or metal oxides coated synthetic and / or natural mica, and / or  Styrene / acrylate copolymers. Cosmetic cleaning agent according to one of the preceding claims, characterized in that it  a) at least one anionic surfactant according to formula (I), wherein the proportion by weight of the at least one anionic surfactant of the formula (I) in the total weight of the compositions 0.1 to 20 wt .-%, preferably 0.5 to 15 wt .-% , particularly preferably from 0.75 to 12.5% by weight and in particular from 1 to 10% by weight,  b) at least one pearlescent agent, organic and / or inorganic pigments and / or at least one opacifier, wherein the weight fraction of the at least one pearlescent agent, organic and / or inorganic pigment and / or the at least one opacifier on the total weight of the compositions 0.01 to 10 Wt .-%, preferably 0.05 to 7.5 wt .-%, particularly preferably 0.1 to 5 wt .-% and in particular 0.25 to 4 wt .-% is, and  c) contains hardened castor oil, the weight fraction of the hardened castor oil in the total weight of the compositions being 0.05 to 5% by weight, preferably 0.075 to 4% by weight, particularly preferably 0.1 to 3% by weight and in particular 0, 2 to 2 wt .-% is. Cosmetic cleaning agent according to one of the preceding claims, characterized in that it additionally contains at least one nonionic surfactant and / or at least one nonionic emulsifier, wherein the weight fraction of the at least one nonionic emulsifier and / or the at least one nonionic surfactant in the total weight of the compositions 0.5 to 25 wt .-%, preferably 0.75 to 20 wt .-%, particularly preferably 1 to 15 wt .-% and in particular 1, 25 to 12.5 wt .-% is. Cosmetic cleaning agent according to one of the preceding claims, characterized in that the proportion by weight of sulfate-containing surfactants in the total weight of the compositions less than 0.5 wt .-%, preferably less than 0.3 wt .-% and in particular less than 0.2 wt .-% is. 8. Use of hardened castor oil to increase the care properties of cosmetic cleaners, the a) at least one anionic surfactant according to formula (I) below,

 in the the radicals R ² to R ⁵ independently of one another represent a hydrogen atom, a C ¹ -C ⁴ -alkyl or a C ¹ -C ⁴ -hydroxyalkyl radical,  R is a linear or branched, saturated or unsaturated alkyl radical having 6 to 30 carbon atoms, and M ^{+ is} an ammonium, an alkanolammonium or a metal cation, and b) at least one pearlescing agent, organic and / or inorganic pigments and / or at least one clouding agent. 9. Use according to claim 8, characterized in that the combability of the hair and / or the hair handle are improved. Cosmetic method for improving the hair grip and / or the combability of hair, characterized in that a cosmetic cleanser containing a) at least one anionic surfactant according to formula (I) below,

 in the the radicals R ² to R ⁵ independently of one another represent a hydrogen atom, a C ¹ -C ⁴ -alkyl or a C ¹ -C ⁴ -hydroxyalkyl radical,  R is a linear or branched, saturated or unsaturated alkyl radical having 6 to 30 carbon atoms, and M ^{+ is} an ammonium, an alkanolammonium or a metal cation, and b) at least one pearlescing agent, organic and / or inorganic pigments and / or at least one opacifier, and  c) hardened castor oil,  applied to dry or wet hair, and rinsed with water after a period of 5 seconds to 5 minutes.