WO2015072063A1 - 有機el表示パネルとその製造方法及び有機el表示装置 - Google Patents
有機el表示パネルとその製造方法及び有機el表示装置 Download PDFInfo
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- WO2015072063A1 WO2015072063A1 PCT/JP2014/005058 JP2014005058W WO2015072063A1 WO 2015072063 A1 WO2015072063 A1 WO 2015072063A1 JP 2014005058 W JP2014005058 W JP 2014005058W WO 2015072063 A1 WO2015072063 A1 WO 2015072063A1
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/10—OLED displays
- H10K59/12—Active-matrix OLED [AMOLED] displays
- H10K59/122—Pixel-defining structures or layers, e.g. banks
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/10—OLED displays
- H10K59/12—Active-matrix OLED [AMOLED] displays
- H10K59/1201—Manufacture or treatment
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/10—OLED displays
- H10K59/12—Active-matrix OLED [AMOLED] displays
- H10K59/123—Connection of the pixel electrodes to the thin film transistors [TFT]
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/30—Devices specially adapted for multicolour light emission
- H10K59/35—Devices specially adapted for multicolour light emission comprising red-green-blue [RGB] subpixels
Definitions
- the present invention relates to a display panel using an organic EL (Electroluminescence) element, a manufacturing method thereof, and an organic EL display device including such an organic EL display panel, and more particularly to a technique for controlling luminance unevenness.
- organic EL Electrode
- the organic EL element has a structure in which a functional layer including at least a light emitting layer made of an organic compound is sandwiched between a pair of electrodes.
- the film thickness of the light emitting layer correlates with the light emission luminance, and it is desirable that the film thickness is uniform among the respective light emitting portions (light emitting portions of the light emitting layer) in the display panel.
- many studies have been made on a method for uniformizing the film thickness between the light emitting portions.
- the formation method of the light emitting layer is roughly classified into a dry process such as a vacuum deposition method and a wet process such as an ink jet method.
- the wet process is a technique suitable for increasing the size of a display panel from the viewpoint of formation accuracy and cost.
- an organic EL display panel using a wet process generally includes a partition (bank) on a substrate, and a light emitting layer is formed in a region partitioned by the partition.
- partition arrangement methods There are two types of partition arrangement methods. One is a pixel bank in which partition walls are arranged in a lattice pattern and each region is divided for each light emitting portion. The other is a line bank (see, for example, Patent Document 1) in which a plurality of barrier ribs each extending in one direction are arranged in parallel and a region is divided for each row of light emitting units aligned in the one direction. is there.
- a solution containing an organic compound (hereinafter referred to as “ink”) serving as a material of the light emitting layer is referred to as a partition extending direction (hereinafter referred to as “column direction”) between the partitions. )
- a partition extending direction hereinafter referred to as “column direction”
- the ink generally has a large surface tension, and when the dried ink or foreign matter is present between the partition walls, the ink tends to aggregate at the drying progress portion or the foreign matter attached portion.
- a line bank is employed, in such a case, ink is aggregated from a wide range due to fluidity in the column direction, and large film thickness unevenness occurs in the column direction.
- Patent Documents 2, 3, and 4. Therefore, in Patent Documents 2, 3, and 4, ink flows between the light emitting portions 961 (non-light emitting portions 962) between the partition walls 95 (partition gap 960) as in the organic EL display panel 90 of FIG.
- a configuration is disclosed in which ink is prevented from aggregating by providing an obstruction (sub-wall 94) that regulates ink.
- JP 2002-75640 A JP 2009-43499 A JP 2011-23305 A JP 2011-90909 A
- the arrangement of the sub-wall 94 in the partition gap 960 is the same in each partition gap 960 in any configuration disclosed in any patent document.
- the sub-wall 94 exists in the (L ⁇ 2) th, Lth, and L + 2th non-light emitting portions 962 counted from the upper side in FIG.
- the sub-wall 94 may agglomerate ink as in the case of foreign matter (see FIG. 3 of Patent Document 2).
- the unevenness of the film thickness of the light emitting portion 961 occurs in the vicinity of the sub-wall 94.
- the occurrence portions of the film thickness unevenness are lined up in the direction intersecting the column direction along the sub-wall 94.
- the fluidity of the ink is substantially the same at the same position in the column direction in each partition gap 960. Therefore, when an ink application amount abnormality or foreign matter adhesion occurs across the plurality of partition gaps 960, the affected portions are almost the same in each partition gap 960. Therefore, the film thickness abnormality part of the light emitting part 961 also occurs along the application amount abnormality part and the foreign matter adhesion part. Therefore, also in this case, the occurrence portions of the unevenness of the light emitting portion 961 are arranged in the direction crossing the partition wall gap 960.
- the display panel 90 has uneven brightness in a band shape.
- the band-shaped luminance unevenness is more noticeable than the point-shaped luminance unevenness and causes a problem because it is more uncomfortable.
- An object of the present invention is to provide an organic EL display panel that suppresses uneven luminance unevenness as described above, a manufacturing method thereof, and an organic EL display device including such an organic EL display panel. .
- An organic EL display panel includes a substrate, a plurality of strips arranged in parallel on the substrate, each strip extending in one direction, and a partition gap between each adjacent partition.
- a plurality of pixel electrodes arranged in the one direction in each of the first partition gap and the second partition gap, and the first partition gap and the first partition gap among the respective partition gaps.
- a plurality of light emitting layers provided so as to cover each of the pixel electrodes in each of the two partition wall gaps, and a sub-wall provided in a state intersecting with the one direction at least in the first partition gap.
- a part of the plurality of light emitting layers above each of the plurality of pixel electrodes is a light emitting portion, and a portion between the light emitting portions adjacent in the one direction is defined as a non-light emitting portion. N, counting from one of the one direction
- the non-light emitting portion of the eye, in the first partition gap exists sub-wall, there is no sub-wall in the second partition wall gap.
- the location where the secondary wall exists and the location where the secondary wall does not exist on the straight line connecting the N-th non-light emission portion counted from one of the one direction of each partition gap where the light emission portion exists Therefore, it is possible to suppress the luminance unevenness from being strip-shaped.
- FIG. 1 is a schematic plan view showing a part of an organic EL display panel 10 according to Embodiment 1 of the present invention.
- FIG. 2 is an enlarged view of a part of FIG. 1, (a) is an enlarged view of the vicinity of the Lth non-light emitting portion 162, (b) is an enlarged view of the vicinity of the L + 1th non-light emitting portion 162, and (c) is L + 2. It is an enlarged view of the vicinity of the second non-light emitting portion 162.
- FIG. 2 is a schematic cross-sectional view along AA in FIG. 1.
- FIG. 2 is a schematic cross-sectional view taken along the line BB in FIG.
- FIG. 1 is a schematic perspective view showing a structure of an organic EL display panel 10 before a light emitting layer 16 is formed. It is a schematic cross-sectional view showing a manufacturing process of the organic EL display panel 10, wherein (a) is a schematic cross-sectional view showing a pixel electrode forming process, (b) is a schematic cross-sectional view showing a pixel insulating layer forming process, and (c) is a schematic cross-sectional view. It is a schematic cross section which shows a subwall formation process.
- FIG. 10 It is a schematic cross section which shows the manufacturing process of the organic electroluminescent display panel 10, Comprising: (a) is a schematic cross section which shows a partition formation process, (b) is a schematic cross section which shows a light emitting layer formation process, (c) is a counter electrode. It is a schematic cross section which shows a formation process. (A) is a figure for demonstrating the film thickness nonuniformity of the light emission part 161 which generate
- FIG. 9 is a schematic plan view showing the structure of the sub-wall according to the modification, wherein (a) is a schematic plan view showing the structure of the sub-walls 341 to 343, and (b) is a schematic plan view showing the structure of the sub-walls 441 to 443.
- FIG. It is a block diagram which shows schematic structure of the organic electroluminescence display 1 which concerns on Embodiment 2 of this invention. It is a schematic plan view which shows a part of organic electroluminescence display panel 90 which concerns on
- An organic EL display panel includes a substrate, a plurality of strips arranged in parallel on the substrate, each strip extending in one direction, and a partition gap between each adjacent partition.
- a plurality of pixel electrodes arranged in the one direction in each of the first partition gap and the second partition gap, and the first partition gap and the first partition gap among the respective partition gaps.
- a plurality of light emitting layers provided so as to cover each of the pixel electrodes in each of the two partition wall gaps, and a sub-wall provided in a state intersecting with the one direction at least in the first partition gap.
- a part of the plurality of light emitting layers above each of the plurality of pixel electrodes is a light emitting portion, and a portion between the light emitting portions adjacent in the one direction is defined as a non-light emitting portion. No. N counted from one of the one direction Of the non-light emitting portion, in the first partition gap exists sub-wall, there is no sub-wall in the second partition wall gap.
- the location and presence of the secondary wall on the straight line connecting the N-th non-light emitting portion counting from one end in the one direction of each partition gap where the light emitting portion exists There is a place not to do. Therefore, even when the ink aggregates on the sub-wall during the formation of the light emitting layer, it is possible to prevent the film thickness unevenness of the light emitting portion from being strip-shaped.
- the fluidity of the ink differs between the first partition gap and the second partition gap on the straight line, even if an application amount abnormality or foreign matter adhesion crossing the plurality of partition gaps occurs, It is suppressed that the film thickness unevenness becomes a band shape. That is, it is possible to suppress the uneven luminance from being strip-shaped.
- the sub-walls are arranged in the one direction at intervals of 300 ⁇ m or more and 3000 ⁇ m or less in each of the first partition gap and the second partition gap.
- the occurrence of film thickness unevenness between the light emitting portions is reduced, and the film thickness unevenness due to the drying progress portion or foreign matter in the partition gap is reduced.
- the interval between the sub-walls in the one direction is different between the first partition gap and the second partition gap.
- the degree of film thickness unevenness is uniform between the first partition wall gap and the second partition wall gap. Even if brightness unevenness occurs in the place, it is difficult to stand out.
- the plurality of light emitting portions existing in the first partition gap and the second partition gap all emit light of the same color.
- the occurrence of band-like luminance unevenness is reduced, and the display quality is further improved.
- the liquid repellency of the sub-wall surface is smaller than the liquid repellency of the partition wall surface.
- the light emitting layer is extended to the adjacent light emitting portion through the non-light emitting portion where the sub wall exists, and the non light emitting layer includes the sub wall.
- the height of the portion of the light emitting portion from the upper surface of the substrate is larger than the height of the portion of the adjacent light emitting portion from the upper surface of the substrate.
- a part of the sub-wall is on the pixel electrode, and the part of the surface has a curved surface that is concave toward the partition.
- ink easily spreads on the sub-wall surface on the pixel electrode, and the occurrence of electrode short-circuit due to non-wetting is reduced.
- the lower end surface of the sub wall occupies the width in the direction perpendicular to the one direction on the lower end surface of the partition wall gap in each of the non-light emitting portions where the sub wall exists. There are places where the ratio is 50% or more.
- the effect of restricting the flow of the sub-wall with respect to the ink is sufficiently ensured, and the occurrence of film thickness unevenness due to the drying progress portion and the foreign matter in the partition gap is reduced.
- the height of the sub wall from the upper surface of the substrate is 10% to 110% of the height of the partition wall from the upper surface of the substrate.
- the height of the sub wall from the upper surface of the substrate is equal to the height of the partition wall from the upper surface of the substrate.
- the sub-wall and the partition can be formed in one step, and can be manufactured efficiently.
- an organic EL display device includes the organic EL display panel according to any one of claims 1 to 10. Since the organic EL display device according to the above aspect includes an organic EL display panel that suppresses uneven luminance from being strip-shaped, high display quality is achieved.
- a method for manufacturing an organic EL display panel comprising preparing a substrate, arranging a plurality of pixel electrodes on the substrate at intervals in one direction, a first pixel electrode column, and a second pixel.
- An electrode row is formed, a part or all of the upper part of each of the plurality of pixel electrodes is set as a light emitting portion forming scheduled region, and a portion between the light emitting portion forming planned regions adjacent in the one direction is set as a non-light emitting portion forming planned region, A sub-wall is formed in a part of the non-light emitting portion formation planned region so as to intersect the one direction, and extends in the one direction at a position sandwiching each of the first pixel electrode row and the second pixel electrode row.
- the first partition electrode gap is defined as the first partition electrode gap between the first pixel electrode rows and the second partition electrode gap between the second pixel electrode columns.
- the Nth non-light-emitting portion formation schedule counted from one of the one direction In the region, in the first partition wall gap to form a sub-wall, the second partition gap, does not form a sub-wall.
- the organic EL display panel further includes arranging a plurality of discharge ports for discharging a solution containing an organic compound in the one direction and moving the discharge ports in a direction crossing the one direction. Then, a solution is discharged into the first partition gap and the second partition gap to form a light emitting layer.
- the light emitting layer forming step can be shortened.
- the solution can flow in the one direction thereafter, so that the coating amount can be leveled and the occurrence of uneven brightness between the light emitting portions can be reduced.
- upward does not indicate the upward direction (vertically upward) in absolute space recognition, but is defined by the relative positional relationship based on the stacking order in the stacking configuration. .
- the term “upward” is applied not only when there is a space between each other but also when they are in close contact with each other.
- FIG. 1 is a schematic plan view showing a part of the panel 10.
- FIG. 2 is an enlarged view of a part of FIG.
- the panel 10 is an organic EL display panel using an electroluminescence phenomenon of an organic compound.
- the panel 10 employs a line bank, and a plurality of partition walls 15 in which each strip extends in the vertical direction (hereinafter referred to as “column direction”) in FIG.
- each of the adjacent partition walls 15 is defined as a partition wall gap 160
- each of the partition wall gaps 160 includes a plurality of light emitting units 161 and a plurality of non-light emitting units 162 between the adjacent light emitting units 161. They are arranged alternately in the column direction.
- the sub-wall 14 provided in a state orthogonal to the column direction is located at a part of the plurality of non-light emitting portions 162 in the partition wall gap 160.
- the panel 10 has a configuration in which a large number of such partition walls 15 and partition wall gaps 160 are arranged.
- the direction orthogonal to the column direction (left and right direction in FIG. 1) is referred to as “row direction”. Note that the column direction corresponds to one direction in the present embodiment.
- the light emitting unit 161 includes a red light emitting unit 161R that emits red light, a green light emitting unit 161G that emits green light, and a blue light emitting unit 161B that emits blue light.
- the partition wall gap 160 there are a red partition wall gap 160R whose inner light emitting parts 161 are all red light emitting parts 161R, a green partition wall gap 160G which is a green light emitting part 161G, and a blue partition wall gap 160B which is a blue light emitting part 161B.
- the three light emitting portions 161 of the red light emitting portion 161R, the green light emitting portion 161G, and the blue light emitting portion 161B are arranged in a row in the row direction to constitute one pixel.
- the partition gaps 160 there are a first partition gap 1601 and a second partition gap 1602 having a light emitting portion 161 therein, and a certain positive integer N is counted from one in the column direction.
- the second non-light emitting portion 162 the secondary wall 14 exists in the first partition gap 1601, and the secondary wall 14 does not exist in the second partition gap 1602.
- FIG. 2A, 2B, and 2C are enlarged views of the vicinity of the L, L + 1, and L + 2 non-light emitting portions 162 from the upper side of FIG. L is a positive integer.
- the L-th non-light emitting portion 162 has the sub-wall 14 in the partition gaps 160IR, G, B and the partition gap 160I + 2G.
- the sub-wall 14 does not exist in the partition gaps 160I + 1R, G, B and the partition gaps 160I + 2R, B. Therefore, for L, any one of the partition gaps 160IR, G, B and the partition gap 160I + 2G can be used as the first partition gap 1601. Further, any one of the partition wall gaps 160I + 1R, G, B and the partition wall gaps 160I + 2R, B can be used as the second partition wall gap 1602. Similarly, as shown in FIG.
- the panel 10 there is a set of the first partition gap 1601 and the second partition gap 1602 for a plurality of positive integers N, and the first partition gap according to the positive integer N.
- the set of 1601 and the second partition gap 1602 varies.
- FIG. 3 is a schematic diagram of the AA cross section in FIG.
- FIG. 4 is a schematic view of a BB cross section in FIG.
- FIG. 5 is a schematic perspective view showing the structure of the panel 10 before the light emitting layer 16 is formed.
- the panel 10 employs a so-called top emission type in which the display surface is the upper side in FIG. 3 and FIG. In the following description, the upper side of FIG. 3 and FIG.
- the panel 10 includes a substrate 11, a pixel electrode 12, a pixel insulating layer 13, a sub-wall 14, a partition wall 15, a light emitting layer 16, a counter electrode 17, and a sealing layer 18.
- the substrate 11 includes a base material (not shown), a thin film transistor (TFT) layer (not shown) formed on the base material, and an interlayer insulating layer (not shown) formed on the base material and the TFT layer. As shown).
- TFT thin film transistor
- the base material is a support member for the panel 10 and has a flat plate shape.
- a material having electrical insulation properties for example, a glass material, a resin material, a semiconductor material, a metal material coated with an insulating layer, or the like can be used.
- the TFT layer is composed of a plurality of TFTs and wirings formed on the upper surface of the substrate.
- the TFT electrically connects the pixel electrode 12 corresponding to itself and an external power source according to a drive signal from an external circuit of the panel 10 and has a multilayer structure such as an electrode, a semiconductor layer, and an insulating layer.
- the wiring electrically connects the TFT, the pixel electrode 12, an external power source, an external circuit, and the like.
- the interlayer insulating layer flattens at least the region where the light emitting portion 161 is formed on the upper surface of the substrate 11 where the TFT layer is uneven. Further, the interlayer insulating layer fills the space between the TFT and the pixel electrode 12 in which no wiring is formed, and electrically insulates them.
- a positive photosensitive organic material having electrical insulation specifically, an acrylic resin, a polyimide resin, a siloxane resin, a phenol resin, or the like can be used.
- the pixel electrode 12 is for supplying carriers to the light emitting layer 16. For example, when the pixel electrode 12 functions as an anode, it supplies holes to the light emitting layer 16.
- the pixel electrode 12 has a flat plate shape. For example, when the connection with the TFT is made through a contact hole opened in the interlayer insulating layer, the pixel electrode 12 has an uneven portion along the contact hole.
- the pixel electrodes 12 are arranged on the substrate 11 at intervals in the column direction in each of the partition gaps 160.
- the material of the pixel electrode 12 since the panel 10 is a top emission type, it is preferable to use a conductive material having light reflectivity, for example, a metal such as silver, aluminum, molybdenum, or an alloy using these.
- the pixel insulating layer 13 is for electrically insulating the adjacent pixel electrodes 12. As shown in FIGS. 3 and 5, the shape of the pixel insulating layer 13 is a flat plate extending in the row direction of the panel 10. The pixel insulating layer 13 is formed on the substrate 11 so as to cover opposite ends of the pixel electrodes 12 adjacent in the column direction.
- a material having electrical insulating properties for example, an inorganic material such as silicon oxide or silicon nitride, an organic material exemplified as a material of the interlayer insulating layer, or the like can be used.
- the sub-wall 14 is for restricting the flow in the column direction of the ink containing the organic compound as the material when the light emitting layer 16 is formed.
- the shape of the subwall 14 is a quadrangular frustum shape, and the cross section shown in FIGS. 3 and 4 is a trapezoidal shape with a forward taper that tapers upward.
- the sub-wall 14 is provided in a state orthogonal to the column direction by projecting in the row direction from both sides of the adjacent partition 15 on a part of the pixel insulating layer 13 in each partition gap 160. Note that the protruding tips of the sub-walls 14 are not in contact with each other and are spaced apart from each other, and an ink flow path is secured.
- angular of the side surface of the subwall 14 is a curved surface as shown in FIG. This is for enhancing the wettability of ink near the sub-wall 14 when the light emitting layer 16 is formed.
- an electrically insulating material for example, an inorganic material exemplified as the material of the pixel insulating layer 13, an organic material exemplified as the material of the interlayer insulating layer, or the like can be used.
- the partition wall 15 is for restricting the flow of ink in the row direction when the light emitting layer 16 is formed.
- the shape of the partition wall 15 is a linear shape extending in the column direction, and the cross section shown in FIG. 3 is a forward tapered trapezoidal shape that tapers upward.
- At least three or more ribs 15 are formed on the substrate 11 including the pixel electrodes 12, the pixel insulating layer 13, and the sub-wall 14 so as to sandwich the pixel electrodes 12 from the row direction.
- the partition 15 also has a function of covering and electrically insulating the opposite ends of the pixel electrodes 12 adjacent in the row direction.
- the material of the partition wall 15 for example, an organic material exemplified as a material of the interlayer insulating layer can be used.
- the partition wall 15 is preferably formed of a material that has resistance to an organic solvent and does not excessively deform or alter the etching process or baking process. Further, the surface may be treated with fluorine in order to give the surface liquid repellency.
- the light emitting layer 16 is a layer made of an organic compound, and has a function of emitting light by recombination of holes and electrons inside.
- the light emitting layer 16 has a linear shape extending in the column direction, and is provided so as to cover each of the pixel electrodes 12 in each of the partition gaps 160.
- the surface of the pixel electrode 12, the pixel insulating layer 13, and the subwall 14 and It is provided along the side surface of the partition wall 15.
- the light emitting layer 16 emits light only from the portion where carriers are supplied from the pixel electrode 12. Therefore, as shown in FIG. 4, in the light emitting layer 16, a portion on the pixel electrode 12 not covered with the pixel insulating layer 13 is a light emitting portion 161, and a portion on the pixel insulating layer 13 is a non-light emitting portion 162. Become. That is, a part of the light emitting layer 16 above each pixel electrode 12 serves as the light emitting unit 161, and a portion between the light emitting units 161 adjacent in the column direction serves as the non-light emitting unit 162.
- the light emitting layer 16 is extended
- FIG. 4 the ink applied on the pixel electrode 12 can flow in the column direction through the ink applied on the pixel insulating layer 13, and the film is formed between the light emitting portions 161 in the column direction.
- the thickness can be leveled.
- the sub-wall 14 is located on a part of the pixel insulating layer 13, the flow of ink is restricted to some extent when the light emitting layer 16 is formed in the part. Therefore, it is possible to suppress the aggregation of the ink on the drying progress part and the foreign matter adhesion part, and it is difficult for the film thickness unevenness in the column direction to occur.
- a light emitting organic material that can be formed using a wet process is used.
- known fluorescent materials and phosphorescent materials such as compounds, derivatives and complexes described in Japanese Patent Publication (JP-A-5-163488) can be used.
- the counter electrode 17 is paired with the pixel electrode 12 to form an energization path by sandwiching the light emitting layer 16 and supply carriers to the light emitting layer 16. For example, when the counter electrode 17 functions as a cathode, electrons are supplied to the light emitting layer 16. Supply.
- the counter electrode 17 is formed along the upper surface of each light emitting layer 16 and the surface of each partition wall 15 exposed from the light emitting layer 16, and serves as a common electrode for each light emitting layer 16.
- the material of the counter electrode 17 since the panel 10 is a top emission type, a conductive material having optical transparency is used.
- a conductive material having optical transparency is used.
- ITO indium tin oxide
- IZO indium zinc oxide
- the sealing layer 18 is for suppressing the light emitting layer 16 from being deteriorated by contact with moisture or air.
- the sealing layer 18 is provided over the entire panel 10 so as to cover the upper surface of the counter electrode 17.
- a light transmissive material such as silicon nitride or silicon oxynitride is used.
- a color filter or an upper substrate may be installed and bonded on the sealing layer 18. Thereby, adjustment of the display color of the panel 10, improvement of rigidity, prevention of intrusion of moisture, air, and the like can be achieved.
- FIGS. 6 and 7 are schematic cross-sectional views showing the manufacturing process of the panel 10. 6 and FIG. 7 is the AA cross section of FIG. 1, like FIG.
- the substrate 11 is prepared. Specifically, for example, a necessary film is formed on a substrate by sputtering, CVD (Chemical Vapor Deposition), spin coating, or the like, and the film is patterned by photolithography to form a TFT layer and an interlayer insulating layer. Form. At this time, plasma treatment, ion implantation, baking, or the like may be performed as necessary.
- the pixel electrode 12 is formed on the substrate 11 as shown in FIG. Specifically, for example, a metal film is first formed on the substrate 11 by vacuum deposition or sputtering. Next, the metal film is patterned by a photolithography method, a plurality of pixel electrodes 12 are arranged in the column direction at intervals on the substrate 11, and a plurality of columns of such pixel electrodes 12 are arranged in parallel. In this way, the pixel electrodes 12 that are two-dimensionally arranged on the substrate 11 are formed.
- the pixel insulating layer 13 is formed on a part of the pixel electrode 12 and the substrate 11. Specifically, for example, an inorganic insulating film (silicon oxide or the like) is formed on the substrate 11 including the pixel electrode 12 by the CVD method. Then, the pixel insulating layer 13 is formed by patterning the inorganic insulating film by a photolithography method to form a flat plate extending in the row direction on the substrate 11 while covering the ends of the pixel electrodes 12 facing in the column direction. .
- an inorganic insulating film silicon oxide or the like
- the portion of the pixel electrode 12 that is not covered with the pixel insulating layer 13 corresponds to a region where the light emitting portion 161 is to be formed.
- the pixel insulating layer 13 between the light emitting portions 161 adjacent to each other in the column direction corresponds to a region where the non-light emitting portion 162 is to be formed. That is, in this embodiment, in this embodiment, a part or all of the upper part of each of the plurality of pixel electrodes is used as a light emitting portion formation scheduled region, and a region between the light emitting portion formation planned regions adjacent in the one direction (column direction) is defined. This corresponds to the step of forming a non-light emitting portion formation scheduled region.
- the subwall 14 is formed on a part of the pixel insulating layer 13.
- a positive photosensitive organic material such as an acrylic resin
- patterning is performed so as to leave the photosensitive organic material only on a part of the pixel insulating layer 13 by photolithography, thereby forming the sub-wall 14.
- the subwall 14 may be directly formed by applying an organic material to a part of the pixel insulating layer 13 by a printing method or the like.
- the sub-wall 14 is formed on a part of the pixel insulating layer 13 corresponding to the region where the non-light-emitting portion 162 is to be formed so as to be orthogonal to the column direction. For example, it forms in the position which protrudes in the row direction from the both sides of the partition 15 formed in the subsequent processes. At this time, as the flow path through which the ink flows in the subsequent processes, the protruding tips are spaced apart. Further, the corner of the side wall of the sub-wall 14 is a curved surface. These can be realized by appropriately setting the pattern of the photomask in the photolithography method.
- the sub-wall 14 is formed in at least one of the rows, and the sub-wall 14 is not formed in at least one of the rows.
- the partition is formed on the substrate 11 including a part on the pixel electrode 12, a part on the pixel insulating layer 13, and a part on the sub-wall 14.
- 15 is formed.
- a positive photosensitive organic material (acrylic resin or the like) is applied to the substrate 11 including the pixel electrode 12, the pixel insulating layer 13, and the subwall 14 by a spin coating method.
- the thickness of the applied material is made larger than the thickness of the sub-wall 14.
- the photosensitive organic material is patterned by a photolithography method, and partition walls 15 are formed so as to extend in the column direction at positions sandwiching each of the pixel electrode columns.
- the partition walls 15 are formed by linearly extending in the column direction so as to cover the end portions of the pixel electrodes 12 facing in the row direction.
- the partition 15 may be formed directly by a printing method or the like.
- the partition wall 15 may be subjected to a surface treatment with an alkaline solution, water, an organic solvent, plasma, or the like to impart liquid repellency to the ink applied in the subsequent steps on the surface of the partition wall 15. By doing in this way, it can suppress that an ink flows beyond the partition 15 in the subsequent light emitting layer formation process.
- each partition gap 160 is formed between the adjacent partition 15, and the columns formed by the light emitting portion formation planned region and the non-light emitting portion formation planned region are respectively present in the partition gap 160.
- the partition gap 160 in which the row in which the sub-wall 14 is formed is present in the N-th non-light emitting portion formation scheduled region counted from one side in the row direction with respect to a certain positive integer N.
- the partition wall gap 160 corresponding to the first partition wall gap 1601 and having the row where the sub-wall 14 is not formed corresponds to the second partition wall gap 1602.
- the light emitting layer 16 is formed in the partition gap 160.
- FIG. Specifically, for example, an organic compound as a material of the light emitting layer 16 and a solvent are mixed at a predetermined ratio to create an ink, and this ink is applied into the partition gap 160 using an inkjet method.
- the upper surface of the ink is made higher than the upper surface of the sub-wall 14, thereby allowing ink to flow over the sub-wall 14.
- the light emitting layer 16 is formed by evaporating and drying the solvent contained in the ink.
- a dispenser method a nozzle code method, a spin coating method, a printing method, or the like may be used as a method for applying the ink.
- the light emitting layer 16 since the light emitting layer 16 has the light emitting portions 161 of three colors of red, green, and blue, they are formed using different inks. Specifically, for example, using a nozzle (ejection port) that ejects only ink corresponding to any one of red, green, and blue, a method of sequentially applying three colors of ink, or each color of red, green, and blue There is a method of simultaneously applying three color inks using a triple nozzle capable of simultaneously ejecting ink corresponding to the above.
- the panel 10 employing a line bank a plurality of nozzles that eject only the same color ink are arranged in the column direction, and the light emitting layer is formed by ejecting ink to the partition gap 160 while moving in the direction intersecting the column direction.
- the forming method is preferred. According to this method, since a plurality of nozzles are first used, the ink application time is shortened and the process can be shortened. Next, since the ink discharged from a plurality of nozzles is connected in the column direction by the partition wall gap 160, even if the ink discharge amount of each nozzle varies, the ink can flow in the column direction thereafter, and the coating amount is leveled. By doing so, it is possible to reduce the occurrence of uneven film thickness between the light emitting portions 161, that is, uneven brightness.
- the light emitting layer 16 having the light emitting portion 161 that is a portion on the pixel electrode 12 that is not covered with the pixel insulating layer 13 and the non-light emitting portion 162 that is a portion on the pixel insulating layer 13 is formed. be able to.
- the counter electrode 17 is formed along the upper surface of each light emitting layer 16 and the surface of each partition wall 15 exposed from the light emitting layer 16. Specifically, it is made of a light-transmitting conductive material such as ITO or IZO along the upper surface of each light emitting layer 16 and the surface of each partition wall 15 exposed from the light emitting layer 16 by, for example, vacuum deposition or sputtering. A film is formed.
- a light-transmitting conductive material such as ITO or IZO
- an inorganic insulating film such as silicon oxide
- the first partition gap 1601 and the second partition gap 1602 having the light emitting portion 161 are present in the partition gap 160, and from one side in the column direction with respect to a certain positive integer N.
- the secondary wall 14 exists in the first partition gap 1601 and the secondary wall 14 does not exist in the second partition gap 1602.
- the panel 10 connects the Nth non-light-emitting portion 162 counted from one side in the column direction of each partition gap 160 where the light-emitting portion 161 exists.
- On the straight line there are a place where the sub-wall 14 exists and a place where the sub-wall 14 does not exist.
- the light emitting portion 161 exists in each partition gap 160.
- the sub-wall 14 does not exist.
- the former partition wall gaps 160 are first partition wall gaps 1601 with respect to L, and the latter partition wall gaps 160 are second partition wall gaps 1602 with respect to L.
- first partition wall gap 1601 and the second partition wall gap 1602 exist so that the aggregated portions are not arranged on the straight line in the row direction, and the film thickness unevenness of the light-emitting portion 161 is strip-shaped. Is suppressed.
- FIG. 8A shows the film thickness unevenness of the light emitting part 161 generated in the panel 10 according to the present embodiment
- FIG. 8B shows the film thickness unevenness of the light emitting part 961 generated in the panel 90 according to the conventional technique. ing.
- the substantially square light emitting portions 161 and 961 and the substantially rectangular non-light emitting portions 162 and 962 are arranged in the vertical direction on the paper surface to form partition wall gaps 160 and 960, respectively. There are several in the direction. Of the non-light emitting portions 162 and 962, the black coating portions 162a and 962a have the sub-walls 14 and 94 inside, and the white coating portions 162b and 962b have no sub-walls 14 and 94 inside. As shown in FIGS. 8A and 8B, in the panel 10, the arrangement of the sub-walls 14 in each partition gap 160 is different, and in the panel 90, the arrangement of the sub-walls 94 in each partition gap 960 is the same.
- Symbols L-2 to L + 4 indicate the numbers of the non-light emitting portions 162 and 962 counted from the upper side of the drawing.
- Reference numerals 701 to 706 denote nozzles (ejection ports) that eject ink.
- the nozzles 701 to 706 are arranged in the above 2.
- the ink is intermittently ejected into the partition wall gaps 160 and 960.
- the nozzles 701 to 706 discharge ink only in the red partition gaps 160R and 960R.
- the nozzles 701 to 706 eject ink at the (L ⁇ 1) th to (L + 4) th light emitting portions 161 and 961 of the partition wall gaps 160 and 960, respectively.
- the numbers in the nozzles 701 to 706 in FIG. 8 indicate the amount of ink ejected by the nozzles 701 to 706 for each of the light emitting units 161 and 961.
- the discharge amounts of the nozzles 701 to 702 and 704 to 706 are 100, but the nozzle 703 has an abnormality and the discharge amount is 40.
- the numbers in the light emitting portions 161 and 961 indicate the film thickness of the formed light emitting portions.
- the ink spreads completely and uniformly in the light emitting portions 161 and 961 and the non-light emitting portions 162b and 962b, and does not spread beyond the non-light emitting portions 162a and 962a.
- the partition walls 15 and 95 exist between the partition wall gaps 160 and 960, and the ink does not flow between the partition wall gaps 160 and 960.
- the film thickness of each of the light emitting portions 161 and 961 is indicated by the amount of ink ejected to each of the light emitting portions 161 and 961.
- the secondary wall 14 exists in the Lth non-light emitting portion 162. Therefore, the influence of the nozzle 703 does not spread in the upward direction on the paper surface than the Lth non-light emitting portion 162.
- the partition gaps 160I + 1R and 160I + 2R second partition gap 1602 with respect to L
- the secondary wall 14 does not exist in the Lth non-light emitting portion 162. Therefore, in the partition gaps 160I + 1R and 160I + 2R, the influence of the nozzle 703 spreads in the upper direction of the paper than the L-th non-light emitting portion 162.
- the influence of the application amount abnormality in the row direction spreads in different directions in the first partition gap 1601 and the second partition gap 1602 in this way. Therefore, in each partition gap 160 where the light emitting unit 161 exists, the boundary where the film thickness difference of the light emitting unit 161 occurs is not aligned in the row direction.
- the L-th non-light emitting part is the boundary
- the partition gap 160I + 1R and the partition gap 160I + 2R the L-2 non-light-emitting part is the boundary.
- the film thickness unevenness generated in the light emitting portion 161 is not lined up in the row direction, and the strip shape is suppressed.
- the ink application amount abnormality occurring only in the red partition gaps 160R and 960R has been described as an example.
- the effect of the panel 10 is not limited to such an application amount abnormality.
- the coating amount on the light emitting part 161 between the L-th non-light-emitting part 162 and the L + 1-th non-light-emitting part 162 in the partition wall gaps 160I + 2R, G, B in FIG. it is assumed that there is an abnormality in the coating amount on the light emitting part 161 between the L-th non-light-emitting part 162 and the L + 1-th non-light-emitting part 162 in the partition wall gaps 160I + 2R, G, B in FIG. .
- the application amount abnormality has been described, but the same applies to the case where foreign matter adheres in the row direction.
- the direction affected by the foreign matter adherence is the first partition gap 1601 and the second partition gap. Since the difference is 1602, unevenness in the thickness of the light-emitting portion 161 is suppressed from being strip-shaped.
- the panel 10 is configured such that the film thickness unevenness of the light-emitting portion 161 is suppressed from being band-shaped and the luminance unevenness is suppressed from being band-shaped.
- the sub-walls 14 are arranged in the column direction at intervals of 300 ⁇ m or more and 3000 ⁇ m or less in each of the first partition gap 1601 and the second partition gap 1602.
- the film thickness unevenness between the light emitting portions 161 tends to occur. This is because the range in which the ink can flow when the light emitting layer 16 is formed becomes too narrow, and the coating amount is not sufficiently leveled.
- the film thickness unevenness due to the drying progress portion and the foreign matter in the partition wall gap 160 tends to increase. This is because, when the light emitting layer 16 is formed, the range in which the ink can flow is too wide, and when a dried ink or foreign matter is present in the partition gap 160, the wide range is affected, and large film thickness unevenness occurs. It is to become.
- the first partition gap 1601 and the second partition gap 1602 have different intervals between the sub-walls 14 in the column direction. In the panel 10 having this configuration, luminance unevenness is not noticeable.
- the partition wall gap 160IR between the non-light emitting portions 162a where the sub-walls 14 exist, two light emitting portions 161 are provided in the partition wall gap 160IR, and 3 in the partition wall gap 160I + 1R. There are two light emitting portions 161. Furthermore, in the upper region of the partition gap 160I + 2R in the drawing, four light emitting portions 161 are arranged between the non-light emitting portions 162a. That is, in the panel 10, the partition wall gap 160IR, the partition wall gap 160I + 1R, and the partition wall gap 160I + 2R have different intervals between the sub-walls 14 in the column direction.
- the film thickness of the light emitting portion 161 is 70.
- the film thickness of the light emitting portion 161 is 80.
- the number of light emitting portions 161 affected by the nozzle 703 is four, and thus the film thickness of the light emitting portion 161 is 85. Therefore, in the panel 10, the unevenness of the film thickness of the light emitting part 161 is generated in each partition gap 160 due to the influence of the nozzle 703, but the thickness unevenness is not uniform in each partition gap 160 due to the above configuration.
- Such unevenness is less visible and conspicuous than the unevenness in which the degree of occurrence in the panel 90 is uniform (for example, the state where the light emitting portions having the film thickness 70 shown in FIG. 8B are arranged). It is difficult to notice brightness unevenness when the panel emits light.
- the sub-walls do not have to be arranged at equal intervals in the partition wall gap 160 as in the partition wall gap 160I + 2R in FIG.
- the interval between the sub-walls 14 between the partition wall gap 160 and the partition wall gap 160 is different. At least a part of the interval between the sub-walls 14 in one partition wall gap 160 is the other partition wall gap. What is necessary is just to differ from the space
- partition gaps 160 there are three kinds of partition gaps 160, that is, the red partition gap 160R, the green partition gap 160G, and the blue partition gap 160B. It is preferable that it becomes the structure described in. That is, for example, for a certain positive integer N in the red partition gap 160R, both the red partition gap 160R that becomes the first partition gap 1601 and the red partition gap 160R that becomes the second partition gap 1602 Preferably it is present. The same applies to the green partition wall gap 160G and the blue partition wall gap 160B.
- the partition gap 160IR is changed to the first partition gap 1601, and either the partition gap 160I + 1R or 160I + 2R is set to the second. Partition wall gap 1602.
- the liquid repellency on the surface of the sub-wall 14 is smaller than the liquid repellency on the surface of the partition wall 15.
- the liquid repellency of the surface of the partition wall 15 is often improved so that the ink does not flow beyond the partition wall 15.
- the liquid repellency on the surface of the sub-wall 14 is equal to or higher than the liquid repellency on the surface of the partition wall 15, it becomes difficult for the ink to spread to the portion where the surface of the sub-wall 14 and the surface of the partition wall 15 are joined. It becomes a cause of generation of non-wetting and uneven film thickness of the light emitting portion 161.
- the height T162 of the portion of the non-light emitting portion 162 where the subwall 14 exists from the upper surface of the substrate 11 is the portion of the substrate of the adjacent light emitting portion 161.
- 11 is preferably larger than the height T161 from the upper surface.
- the panel 10 according to one aspect of the present invention has been described.
- the present invention is not limited to the above embodiment except for essential characteristic components. Absent.
- it is realized by arbitrarily combining the components and functions in each embodiment without departing from the scope of the present invention, or the form obtained by subjecting each embodiment to various modifications conceived by those skilled in the art. Forms are also included in the present invention.
- FIG. 9 is a schematic plan view showing a sub-wall according to a modification.
- the upper surface of the shape protruding in the column direction from both adjacent partition walls 15 is triangular (subwall 341), pentagon (subwall 342), and substantially semicircular (subwall) 343).
- the sub-wall may occupy the entire width W1 of the partition gap 160.
- the sub wall may be formed on the entire surface of the pixel insulating layer 13 (between the light emitting portions 161) (sub wall 441), or may be formed on a part of the pixel insulating layer 13 (sub wall 442). It does not have to be orthogonal to the partition wall 15 (sub-wall 443).
- the auxiliary wall may be provided in a state intersecting with the column direction so that the flow restriction effect on the ink can be exhibited.
- the adjacent partition walls 15 may be in contact with only one side (subwalls 541 and 542) or may not be in contact with the partition wall 15 (subwall). 543).
- the subwall (more specifically, out of the width W1 of the partition gap 160 (more specifically, the width in the row direction at the lower end surface of the partition gap 160) W1.
- W43 is 50% or more of W1, respectively.
- the sub-walls are assumed to have the same shape of the upper surface and the shape of the lower end surface shown in the drawing. With this configuration, the effect of restricting the flow of the sub-wall with respect to the ink is sufficiently ensured, and the occurrence of film thickness unevenness due to the drying progress portion and foreign matter in the partition gap 160 is reduced. This is because, in the non-light emitting portion 162, if the proportion of the sub-wall in W1 is less than 50%, the sub-wall cannot sufficiently regulate the flow of ink.
- the ink flow is widened on the end side in the column direction of the subwall. Is easy to spread in the flow path, and is not easily wetted or uneven.
- sub-walls need not all have the same upper surface shape, and may have different upper surface shapes in each partition gap 160 as shown in FIG.
- FIG. 10 is a schematic cross-sectional view showing the structure of the sub-wall according to Embodiment 1 and a modification.
- the height T141 of the subwall 14 from the upper surface of the substrate 11 is smaller than the height T15 of the partition wall 15 from the upper surface of the substrate, but the subwall in each aspect of the present invention is It is not limited to this.
- the height T142 from the upper surface of the substrate 11 may be larger than the height T15 like the subwall 642, and the height from the upper surface of the substrate 11 is the same as the height T15 like the subwall 643. There may be.
- the height of the auxiliary wall from the upper surface of the substrate 11 is preferably 10% to 110% of the height T15. If it is less than 10% of the height T15, the effect of restricting the flow of the secondary wall with respect to ink cannot be ensured sufficiently. When the height exceeds 110% of the height T15, the ink may spread along the surface of the subwall due to its surface tension and flow over the partition wall 15 in some cases.
- the partition wall 15 and the sub wall 643 can be formed in one step. If it does in this way, the process and equipment at the time of manufacture can be reduced, and it becomes possible to manufacture efficiently.
- the sub-wall 14 is formed only on the pixel insulating layer 13. However, a part of the sub-wall 14 is formed on the pixel electrode 12 as in the sub-wall 645 shown in FIG. May be. At this time, as shown in FIG. 11, which is a schematic plan view showing the structure of the sub-wall 645, a part of the surface 645 a of the sub-wall on the pixel electrode 12 may have a curved surface that is concave toward the partition wall 15. preferable.
- the light emitting layer 16 can be formed so as not to have corners in the vicinity of the joint between the pixel electrode 12 and the sub-wall surface, and the occurrence of non-wetting of the ink and unevenness of the film thickness of the light emitting portion 161 is suppressed.
- the pixel electrode 12 and the counter electrode 17 may be short-circuited at the portion, and the above configuration is preferable. Even in this case, the light emitting layer 16 on the sub-wall 645 on the pixel electrode 12 becomes the non-light-emitting portion 162, so that the sub-wall 645 is located in the non-light-emitting portion 162.
- the present invention is not limited to this.
- a configuration including a hole injection layer, a hole transport layer, an electron transport layer, an electron injection layer, or the like, or a configuration including a plurality or all of them at the same time may be used.
- these layers do not need to consist of organic compounds, and may be composed of inorganic substances.
- the light emitting layer 16 is connected to each partition wall gap 160.
- the light emitting layer 16 may be at a position that covers at least each pixel electrode 12, and may be interrupted at a part of the partition wall gap 160, for example, at the position of the sub-wall 14.
- the light emitting unit 161 includes three types of the red light emitting unit 161R, the green light emitting unit 161G, and the blue light emitting unit 161B.
- the present invention is not limited to this.
- the light emitting unit may be one type, or the light emitting unit may be four types that emit red, green, blue, and yellow.
- all of the light emitting portions 161 in the partition wall gap 160 emit light of the same color, but the present invention is not limited to this.
- a configuration may be provided that includes partition wall gaps 160 in which red light emitting units 161R and blue light emitting units 161B are alternately arranged and green partition wall gaps 160G.
- the light emitting units 161 are arranged in a matrix, but the present invention is not limited to this.
- the present invention is effective even for a configuration in which the light emitting portions are shifted by a half pitch in the column direction between adjacent partition gaps.
- a slight shift in the column direction is difficult to distinguish visually, and even if the film thickness unevenness is arranged on a straight line (or zigzag) having a certain width, it is visually stripped. Therefore, even in such a case, the display quality of the display panel can be improved by suppressing the luminance unevenness from being arranged in a staggered manner.
- the present invention is not limited to this. I can't.
- the pixel insulating layer 13 may be formed only between the pixel electrodes 12, and not formed above the pixel electrodes 12, so that the entire light emitting unit 161 may be formed above the pixel electrodes 12.
- the partition walls 15 are electrically insulated from the pixel electrodes 12 arranged in the row direction.
- the present invention is not limited to this.
- this insulating layer may be integrated with the pixel insulating layer 13.
- the pixel electrodes 12 are arranged in all the partition gaps 160 in the drawing, but the present invention is not limited to this configuration. It suffices that the pixel electrode 12 is disposed at least in the first partition gap 1601 and the second partition gap 1602, and the configuration of the other partition gaps is not limited. For example, in order to form a bus bar or the like, there may be a partition gap 160 where the pixel electrode 12 is not formed.
- the first partition gap 1601 and the second partition gap 1602 can be selected from a plurality of candidates, respectively, and the first partition gap 1601 and the second partition gap 1602 can be selected.
- a plurality of positive integers N in which the partition gap 1602 exists can be selected, the present invention is not limited to this.
- the sub-wall 14 has a shape that can be distinguished from other components such as the pixel insulating layer 13 and the partition wall 15, but the present invention is not limited to this.
- a part of the pixel insulating layer or the partition may correspond to the sub wall.
- the flow of ink in the column direction is different from other structures and properties such as the height from the upper surface of the substrate, the length in the direction intersecting the partition, and the liquid repellency.
- the panel 10 has a top emission type configuration, but a bottom emission type may be employed. In that case, it is possible to appropriately change each configuration.
- the panel 10 has an active matrix type configuration.
- the present invention is not limited to this, and may be a passive matrix type configuration, for example.
- a plurality of linear electrodes that are parallel to the extending direction of the partition walls and a plurality of linear electrodes that are orthogonal to the extending direction of the partition walls may be provided side by side so as to sandwich the light emitting layer.
- the linear electrode perpendicular to the extending direction of the partition walls is on the lower side, a plurality of lower electrodes are arranged in the partition extending direction at intervals in each partition gap. It becomes an aspect. In that case, it is possible to appropriately change each configuration.
- the substrate 11 has the TFT layer.
- the substrate 11 is not limited to the TFT layer.
- FIG. 12 is a block diagram showing a schematic configuration of the organic EL display device 1.
- An organic EL display device 1 according to the second embodiment is an organic EL display device including the organic EL display panel 10 according to the first embodiment.
- the organic EL display device 1 includes a drive control unit 20 connected to the panel 10.
- the drive control unit 20 includes four drive circuits 21 to 24 and a control circuit 25.
- the arrangement of the drive control unit 20 with respect to the panel 10 is not limited to this.
- the organic EL display device 1 includes an organic EL display panel 10 that suppresses uneven luminance from being strip-shaped. Therefore, the organic EL display device 1 can achieve high display quality.
- the organic EL display panel, the manufacturing method thereof, and the organic EL display device according to the present invention can be widely used in various electronic devices having a display set such as a television set, a personal computer, a mobile phone, or the like.
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Abstract
Description
そこで、特許文献2、3、4では、図13の有機EL表示パネル90のように、各隔壁95間(隔壁間隙960)の発光部961同士の間(非発光部962)に、インクの流動を規制する障害物(副壁94)を設けることで、インクの凝集を抑制する構成が開示されている。
本発明の一態様に係る有機EL表示パネルは、基板と、基板上に3条以上並設され、各条が一方向に延伸する複数条の隔壁と、隣り合う隔壁間の各々を隔壁間隙と定義した場合、各隔壁間隙のうち、第1の隔壁間隙と第2の隔壁間隙とのそれぞれにおいて、前記一方向に間隔をあけて配された複数の画素電極と、第1の隔壁間隙と第2の隔壁間隙とのそれぞれにおいて、画素電極の各々を覆う状態で設けられた複数の発光層と、少なくとも第1の隔壁間隙において、前記一方向と交差する状態で設けられた副壁と、を備え、複数の画素電極の各上方にある複数の発光層の各々の一部又は全部が発光部となり、前記一方向に隣り合う発光部同士の間を非発光部と定義した場合において、ある正の整数Nに対し、前記一方向の一方から数えてN番目の非発光部に、第1の隔壁間隙では副壁が存在し、第2の隔壁間隙では副壁が存在しない。
以下では、本発明の一態様である実施の形態1に係る有機EL表示パネル10について、図面を用いて説明する。なお、図面は模式図であって、その縮尺は実際とは異なる場合がある。
本実施の形態に係る有機EL表示パネル10(以下、「パネル10」という。)の全体構成について、図1及び図2を用いて説明する。図1は、パネル10の一部を示す模式平面図である。図2は、図1の一部を拡大した図である。
パネル10の各部構成を図3、図4及び図5を用いて説明する。図3は、図1におけるA-A断面の模式図である。図4は、図1におけるB-B断面の模式図である。図5は発光層16が形成される前のパネル10の構造を示す模式斜視図である。
基板11は、基材(不図示)と、基材上に形成された薄膜トランジスタ(TFT:Thin Film Transistor) 層(不図示)と、基材上及びTFT層上に形成された層間絶縁層(不図示)とを有する。
画素電極12は、発光層16へキャリアを供給するためのものであり、例えば陽極として機能した場合は、発光層16へ正孔を供給する。画素電極12の形状は、平板状であるが、例えば、TFTとの接続を層間絶縁層に開口したコンタクトホールを通じて行う場合は、コンタクトホールに沿った凹凸部を有する。画素電極12は、隔壁間隙160のそれぞれにおいて、列方向に間隔をあけて基板11上に配されている。
画素絶縁層13は、隣接する画素電極12の間を電気的に絶縁するためのものである。図3、図5に示すように、画素絶縁層13の形状は、パネル10の行方向に延伸する平板状である。画素絶縁層13は、列方向に隣り合う画素電極12の向かい合う端部を被覆するように基板11上に形成されている。画素絶縁層13の材料としては、電気絶縁性を有する材料、例えば酸化シリコン、窒化シリコンなどの無機材料、層間絶縁層の材料として例示した有機材料などを用いることができる。
副壁14は、発光層16形成時に、その材料となる有機化合物を含んだインクの列方向への流動を規制するためのものである。副壁14の形状は、四角錐台状であり、図3及び図4に示す断面は上方を先細りとする順テーパーの台形状である。副壁14は、各隔壁間隙160内の一部の画素絶縁層13上において、隣り合う隔壁15の両側から行方向に突出することにより、列方向と直交する状態で設けられている。なお、副壁14の突出する先端同士は接触せず、間隔をあけており、インクの流路が確保されている。なお、副壁14の側面の角は、図5に示すように曲面となっている。これは、発光層16形成時に、副壁14付近でのインクの濡れ性を高めるためである。
隔壁15は、発光層16形成時に、インクが行方向へ流動することを規制するためのものである。隔壁15の形状は、列方向に延伸する線状であり、図3に示す断面は上方を先細りとする順テーパーの台形状である。隔壁15は、各画素電極12を行方向から挟むように、画素電極12上、画素絶縁層13上及び副壁14上を含む基板11上に少なくとも3条以上形成されている。また、隔壁15は、行方向に隣り合う画素電極12の向かい合う端部を被覆し、電気的に絶縁する機能も有している。
発光層16は、有機化合物からなる層であり、内部で正孔と電子が再結合することで光を発する機能を有する。発光層16は、列方向に延伸する線状であり、隔壁間隙160のそれぞれにおいて、画素電極12の各々を覆う状態で設けられ、例えば画素電極12、画素絶縁層13、副壁14の表面及び隔壁15の側面に沿って設けられている。
対向電極17は、画素電極12と対になって発光層16を挟むことで通電経路を作り、発光層16へキャリアを供給するものであり、例えば陰極として機能した場合は、発光層16へ電子を供給する。対向電極17は、各発光層16の上面及び発光層16から露出する各隔壁15の表面に沿って形成され、各発光層16に共通の電極となっている。
封止層18は、発光層16が水分や空気などに触れて劣化することを抑制するためのものである。封止層18は、対向電極17の上面を覆うようにパネル10全面に渡って設けられている。封止層18の材料としては、パネル10がトップエミッション型であるため、例えば窒化シリコン、酸窒化シリコンなどの光透過性材料が用いられる。
なお、図3及び図4では図示しないが、封止層18の上にカラーフィルタや上部基板を設置・接合してもよい。これにより、パネル10の表示色の調整や、剛性向上、水分や空気などの侵入防止などを図ることができる。
表示パネル10の製造方法について図6、図7を用いて説明する。図6、図7はパネル10の製造工程を示す模式断面図である。なお、図6、図7が示す断面は、図3と同じく、図1のA-A断面である。
まず基板11を用意する。具体的には、例えば、基材にスパッタリング法、CVD(Chemical Vapor Deposition)法、スピンコート法などによって必要な膜を形成し、フォトリソグラフィー法によって膜をパターニングすることでTFT層及び層間絶縁層を形成する。この際、必要に応じて、プラズマ処理、イオン注入、ベーキングなどの処理を行ってもよい。
次に、図6(a)に示すように、基板11上に画素電極12を形成する。具体的には、例えば、まず真空蒸着法又はスパッタリング法によって基板11上に金属膜を形成する。次に、フォトリソグラフィー法によって金属膜をパターニングし、基板11上に間隔をあけて列方向に画素電極12を複数並べ、さらにそのような画素電極12の列を複数並設する。このようにして、基板11上に二次元配置された画素電極12を形成する。
次に、図6(b)に示すように、画素電極12上の一部と基板11上に画素絶縁層13を形成する。具体的には、例えば、CVD法によって画素電極12上を含む基板11上に、無機絶縁膜(酸化シリコンなど)を形成する。そして、フォトリソグラフィー法によって無機絶縁膜をパターニングし、列方向に向かい合う画素電極12の端部を被覆しながら基板11上を行方向に延伸する平板状にすることで、画素絶縁層13を形成する。
次に、図6(c)に示すように、画素絶縁層13上の一部に副壁14を形成する。具体的には、例えば、スピンコート法によって画素絶縁層13上を含む基板11上に、ポジ型の感光性有機材料(アクリル系樹脂など)を塗布する。そして、フォトリソグラフィー法によって画素絶縁層13上の一部にのみ感光性有機材料を残すようパターニングして、副壁14を形成する。なお、印刷法などによって画素絶縁層13上の一部に有機材料を塗布して副壁14を直接形成してもよい。
次に、図7(a)に示すように、画素電極12上の一部、画素絶縁層13上の一部及び副壁14上の一部を含む基板11上に隔壁15を形成する。具体的には、例えば、スピンコート法によって画素電極12上、画素絶縁層13上及び副壁14上を含む基板11上に、ポジ型の感光性有機材料(アクリル系樹脂など)を塗布する。この際、塗布した材料の膜厚は副壁14の膜厚よりも大きくする。そして、フォトリソグラフィー法によって感光性有機材料をパターニングし、画素電極列のそれぞれを挟む位置に、列方向に延伸するように隔壁15を形成する。パネル10では、行方向に向かい合う画素電極12の端部を被覆するように列方向に延伸する線状にすることで、隔壁15を形成している。なお、印刷法などによって直接隔壁15を形成してもよい。
次に、図7(b)に示すように、隔壁間隙160に発光層16を形成する。具体的には、例えば、発光層16の材料となる有機化合物と溶媒とを所定の比率で混合してインクを作成し、インクジェット法を用いて、このインクを隔壁間隙160内に塗布する。パネル10では、インクの上面は、副壁14の上面よりも高くすることで、副壁14を超えるインクの流動を可能にしている。そして、インクに含まれる溶媒を蒸発乾燥させることにより、発光層16を形成する。なお、インクの塗布方法としては、ディスペンサー法、ノズルコード法、スピンコート法、印刷法などを用いてもよい。
次に、図7(c)に示すように、各発光層16の上面及び発光層16から露出する各隔壁15の表面に沿って、対向電極17を形成する。具体的には、例えば、真空蒸着法又はスパッタリング法などによって、各発光層16の上面及び発光層16から露出する各隔壁15の表面に沿って、ITO、IZOなどの光透過性導電材料からなる膜を形成する。
次に、対向電極17の上面を覆う封止層18を形成する。具体的には、例えば、スパッタリング法又はCVD法によって、対向電極17上に無機絶縁膜(酸化シリコンなど)を形成する。
パネル10では、隔壁間隙160のうち、内部に発光部161を有する第1の隔壁間隙1601及び第2の隔壁間隙1602が存在し、ある正の整数Nに対し、列方向の一方から数えてN番目の非発光部162に、第1の隔壁間隙1601では副壁14が存在し、第2の隔壁間隙1602では副壁14が存在しない。以下、上記構成による効果を説明する。
上記構成を有することで、パネル10では、発光部161が存在する各隔壁間隙160の列方向の一方から数えてN番目の非発光部162を繋いだ直線上に、副壁14が存在する箇所と存在しない箇所とが存在する。例えば、図1に示す範囲において、各隔壁間隙160には発光部161が存在する。また、各隔壁間隙160の図1のL番目の非発光部162を繋いだ直線上において、隔壁間隙160IR、G、B、隔壁間隙160I+2Gでは副壁が存在し、隔壁間隙160I+1R、G、B、隔壁間隙160I+2R、隔壁間隙160I+2Bでは、副壁14が存在しない。(前者の各隔壁間隙160はLに対する第1の隔壁間隙1601、後者の各隔壁間隙160はLに対する第2の隔壁間隙1602である。)したがって、発光層16の形成時に副壁14近傍へインクが凝集した場合にも、第1の隔壁間隙1601及び第2の隔壁間隙1602となる組が存在することで、凝集箇所が行方向の直線上に並ばず、発光部161の膜厚むらが帯状になることが抑制される。
上記構成を有することで、パネル10では、発光部161が存在する各隔壁間隙160のN番目の非発光部162を通る直線上では、第1の隔壁間隙1601と第2の隔壁間隙1602とで、発光層16形成時のインクの流動性が異なる。したがって、発光層16の形成時に当該場所付近で行方向の塗布量異常や異物付着などが発生しても、発光部161の膜厚むらが帯状になることが抑制される。この詳細及び効果について、図8を用いて以下に説明する。
パネル10においては、第1の隔壁間隙1601と第2の隔壁間隙1602とのそれぞれにおいて、副壁14が300μm以上3000μm以内の間隔ごとに列方向に並ぶことが好ましい。上記構成を有することで、パネル10では、発光部161の膜厚むらの発生が低減される。
上記実施の形態1では、本発明の一態様に係るパネル10を説明したが、本発明は、その本質的な特徴的構成要素を除き、以上の実施の形態に何ら限定を受けるものではない。例えば、各実施の形態に対して当業者が思いつく各種変形を施して得られる形態や、本発明の趣旨を逸脱しない範囲で各実施の形態における構成要素及び機能を任意に組み合わせることで実現される形態も本発明に含まれる。
パネル10の副壁14の上面形状は、図5に示すように、側面の角が曲面となった略四角形状が、隣り合う両隔壁15から列方向に直交する状態で配されたものであったが、本発明の各態様における副壁はこれに限られない。図9は変形例に係る副壁を示す模式平面図である。
上記実施の形態1では、画素電極12と対向電極17の間に、発光層16のみが存在する構成であったが、本発明はこれに限られない。例えば、正孔注入層、正孔輸送層、電子輸送層、電子注入層などを備える構成や、これらの複数又は全部を同時に備える構成であってもよい。また、これらの層はすべて有機化合物からなる必要はなく、無機物などで構成されていてもよい。
以下では、本発明の一態様である実施の形態2に係る有機EL表示装置1について、図12を用いて説明する。図12は有機EL表示装置1の概略構成を示すブロック図である。
実施の形態2に係る有機EL表示装置1は、実施の形態1に係る有機EL表示パネル10を備えた有機EL表示装置である。有機EL表示装置1は、その他に、パネル10に接続された駆動制御部20を有する。
パネル10に画像を表示する場合、アクティブマトリクス方式により、駆動回路21~24によって、パネル10の基板11内のTFTを介して所定の画素電極12に電圧が印加される。その結果、所定の画素電極12と対向電極17と間に電流が流れて、所定の画素電極12に対応する発光部161が発光する。この結果、パネル10は全体として、有色の画像を表示することが可能となる。
有機EL表示装置1は、輝度むらが帯状になることを抑制した有機EL表示パネル10を備える。したがって、有機EL表示装置1は、高い表示品質を実現することができる。
10、90 有機EL表示パネル
11 基板
12 画素電極
13、93 画素絶縁層
14、94、341、342、343、441、442、443、541、542、543、642、643、645 副壁
15、95 隔壁
16 発光層
17 対向電極
18 封止層
20 駆動制御部
21~24 駆動回路
25 制御回路
160、960 隔壁間隙
161、961 発光部
162、962 非発光部
701~706 ノズル(吐出口)
1601 第1の隔壁間隙
1602 第2の隔壁間隙
Claims (13)
- 基板と、
前記基板上に3条以上並設され、各条が一方向に延伸する複数条の隔壁と、
隣り合う前記隔壁間の各々を隔壁間隙と定義した場合、各前記隔壁間隙のうち、第1の隔壁間隙と第2の隔壁間隙とのそれぞれにおいて、前記一方向に間隔をあけて配された複数の画素電極と、
前記第1の隔壁間隙と前記第2の隔壁間隙とのそれぞれにおいて、前記画素電極の各々を覆う状態で設けられた複数の発光層と、
少なくとも前記第1の隔壁間隙において、前記一方向と交差する状態で設けられた副壁と、
を備え、
前記複数の画素電極の各上方にある前記複数の発光層の各々の一部又は全部が発光部となり、
前記一方向に隣り合う前記発光部同士の間を非発光部と定義した場合において、ある正の整数Nに対し、前記一方向の一方から数えてN番目の前記非発光部に、前記第1の隔壁間隙では前記副壁が存在し、前記第2の隔壁間隙では前記副壁が存在しない、
有機EL表示パネル。 - 前記第1の隔壁間隙と前記第2の隔壁間隙とのそれぞれにおいて、前記副壁が300μm以上3000μm以内の間隔ごとに前記一方向に並ぶ、
請求項1に記載の有機EL表示パネル。 - 前記第1の隔壁間隙と前記第2の隔壁間隙とでは、前記一方向における前記副壁同士の間隔が異なる、
請求項2に記載の有機EL表示パネル。 - 前記第1の隔壁間隙と前記第2の隔壁間隙とに存在する前記発光部がすべて同じ色の光を発する、
請求項1から請求項3のいずれかに記載の有機EL表示パネル。 - 前記副壁表面の撥液性が、前記隔壁表面の撥液性よりも小さい、
請求項1から請求項4のいずれかに記載の有機EL表示パネル。 - 前記発光層が、前記副壁が存在する前記非発光部を経て、隣接する前記発光部まで延伸されており、
前記発光層について、前記副壁が存在する前記非発光部における部分の前記基板上面からの高さが、隣接する前記発光部における部分の前記基板上面からの高さよりも大きい、
請求項1から請求項5のいずれかに記載の有機EL表示パネル。 - 前記副壁の一部が、前記画素電極上にあり、当該一部の表面が前記隔壁に向かって凹となる曲面を有する、
請求項1から請求項6に記載の有機EL表示パネル。 - 前記副壁が存在する前記非発光部のそれぞれにおいて、前記隔壁間隙の下端面における前記一方向と直交する方向の幅を前記副壁の下端面が占める割合が50%以上となる箇所が存在する、
請求項1から請求項7のいずれかに記載の有機EL表示パネル。 - 前記副壁の前記基板上面からの高さが、前記隔壁の前記基板上面からの高さの10%以上110%以下である、
請求項1から請求項8のいずれかに記載の有機EL表示パネル。 - 前記副壁の前記基板上面からの高さが、前記隔壁の前記基板上面からの高さに等しい、
請求項1から請求項9のいずれかに記載の有機EL表示パネル。 - 請求項1から請求項10のいずれかに記載の有機EL表示パネルを備える、
有機EL表示装置。 - 基板を用意し、
前記基板上に、間隔をあけて一方向に画素電極を複数並べて、第1画素電極列と、第2画素電極列を形成し、
前記複数の画素電極の各上方の一部又は全部を発光部形成予定領域とし、前記一方向に隣り合う前記発光部形成予定領域同士の間を非発光部形成予定領域とし、
前記複数の非発光部形成予定領域の一部に、前記一方向と交差するように副壁を形成し、
前記第1画素電極列及び前記第2画素電極列のそれぞれを挟む位置に、前記一方向に延伸する隔壁を形成し、
前記第1画素電極列が並ぶ前記隔壁の間を第1の隔壁間隙、前記第2画素電極列が並ぶ前記隔壁の間を第2の隔壁間隙と定義した場合、前記副壁を形成する際に、ある正の整数Nに対し、前記一方向の一方から数えてN番目の前記非発光部形成予定領域に、前記第1の隔壁間隙では前記副壁を形成し、前記第2の隔壁間隙では、前記副壁を形成しない、
有機EL表示パネルの製造方法。 - さらに、有機化合物を含む溶液を吐出する複数の吐出口を前記一方向に並べ、前記吐出口を前記一方向と交差する方向に移動させながら、前記第1の隔壁間隙及び前記第2の隔壁間隙へ前記溶液を吐出して発光層を形成する、
請求項12に記載の有機EL表示パネルの製造方法。
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| US12514068B2 (en) | 2021-12-24 | 2025-12-30 | Lg Display Co., Ltd. | Electroluminescent display device including bank and light emitting stack |
Also Published As
| Publication number | Publication date |
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| JPWO2015072063A1 (ja) | 2017-03-16 |
| US20160293681A1 (en) | 2016-10-06 |
| US9773848B2 (en) | 2017-09-26 |
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