WO2014203390A1 - 粉体原料と液体原料の混合装置、及びその混合装置を用いた混合物の製造方法 - Google Patents
粉体原料と液体原料の混合装置、及びその混合装置を用いた混合物の製造方法 Download PDFInfo
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- WO2014203390A1 WO2014203390A1 PCT/JP2013/067058 JP2013067058W WO2014203390A1 WO 2014203390 A1 WO2014203390 A1 WO 2014203390A1 JP 2013067058 W JP2013067058 W JP 2013067058W WO 2014203390 A1 WO2014203390 A1 WO 2014203390A1
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- WIPO (PCT)
- Prior art keywords
- disk
- raw material
- outer edge
- mixture
- gap
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Classifications
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- A—HUMAN NECESSITIES
- A21—BAKING; EDIBLE DOUGHS
- A21C—MACHINES OR EQUIPMENT FOR MAKING OR PROCESSING DOUGHS; HANDLING BAKED ARTICLES MADE FROM DOUGH
- A21C1/00—Mixing or kneading machines for the preparation of dough
- A21C1/02—Mixing or kneading machines for the preparation of dough with vertically-mounted tools; Machines for whipping or beating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/70—Spray-mixers, e.g. for mixing intersecting sheets of material
- B01F25/74—Spray-mixers, e.g. for mixing intersecting sheets of material with rotating parts, e.g. discs
- B01F25/741—Spray-mixers, e.g. for mixing intersecting sheets of material with rotating parts, e.g. discs with a disc or a set of discs mounted on a shaft rotating about a vertical axis, on top of which the material to be thrown outwardly is fed
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/50—Mixing liquids with solids
- B01F23/53—Mixing liquids with solids using driven stirrers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/27—Mixers with stator-rotor systems, e.g. with intermeshing teeth or cylinders or having orifices
- B01F27/271—Mixers with stator-rotor systems, e.g. with intermeshing teeth or cylinders or having orifices with means for moving the materials to be mixed radially between the surfaces of the rotor and the stator
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2/00—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
- B01J2/14—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic in rotating dishes or pans
Definitions
- the present invention relates to a continuous mixing technique of a powder raw material and a liquid raw material.
- the conventional technology has a big problem in the mixing process. Before explaining the problem, it is necessary to describe the importance of the gluten that is synthesized when water is added to the flour and its structure.
- Gluten is a substance that combines viscoelasticity and adhesiveness that is produced when a protein contained in wheat flour in an amount of 6 to 15% (varies depending on the variety) is hydrated. When kneading a dough containing hydrated gluten, the gluten is bound together, forming a three-dimensional giant network.
- the quality of flour foods such as bread and noodles greatly depends on the gluten structure.
- gluten determines the texture by determining how it swells due to the action of yeast.
- gluten is the main factor of so-called “waist” and “satsumi”, and is also the biggest factor of taste.
- it is important to first convert all the protein in the flour to gluten, and it is extremely important to spread the moisture evenly when mixing the flour and water. .
- An example of an improved continuous mixer is the mixer disclosed in Patent Document 2.
- the mixer device drops film-like water onto a powder layer developed on a rotating disk, and mixes by stirring.
- Patent Documents 3 and 4 are known as other conventional techniques.
- the technique of patent document 3 is related with the apparatus which coats liquids, such as fats and oils, to granular substances, such as a plant seed.
- a granular material is supplied from the upper part of the rotating disk to the central part and spread on the disk, and a liquid is flowed down or sprayed toward the center to continuously perform coating.
- this apparatus can be used as a mixing apparatus with a liquid raw material by supplying a powder raw material instead of a granular material.
- Patent Document 4 a powder raw material is quantitatively supplied to the center of a disk rotating at a medium speed, and a thin powder layer is formed at a location close to the outer periphery.
- a sprayer that rotates at high speed on the same axis as the rotating disk is installed to continuously atomize and radiate the liquid raw material to be supplied in a constant amount, and spray the powder layer developed on the rotating disk from behind the flow at high speed.
- the microscopically uniform instantaneous coupling between the two is continuously generated.
- a uniform mixture of the powder raw material and the liquid raw material is continuously obtained. This eliminates the need for stirring and mixing by uniformly mixing the powder raw material and the liquid raw material from the beginning.
- the liquid raw material to be supplied in a constant amount is continuously atomized and radiated, and sprayed at high speed from the back of the flow against the powder layer developed on the rotating disk.
- a microscopically uniform instantaneous bond could not be produced continuously.
- the powder could not be evenly distributed, and the powder was sprayed only on the surface of the powder and the moisture did not reach the inside, and furthermore, it was not possible to eliminate the scattering of the waste powder.
- the present invention provides a mixing device that uniformly mixes a powder material and a liquid material.
- the mixing apparatus includes a first disk, a second disk, a third disk, a fourth disk, and a fifth disk.
- the first disk rotates around the vertical axis and radiates the powder raw material supplied from the vertical axis direction toward the outer edge.
- the second disk is a stationary disk arranged at a predetermined distance from the upper surface of the first disk.
- the second disk is provided so as to smooth the powder raw material radiated on the first disk through a first gap formed by separating the predetermined distance.
- the third disk covers the second disk, rotates coaxially with the first disk, and has an atomizing head that atomizes the liquid raw material supplied during rotation and radiates it in the outer edge direction.
- the fourth disk has a smaller radius than the third disk, is fixed to the third disk at a predetermined distance from the lower surface of the third disk, and is coaxial with and integrated with the third disk. Rotate with.
- the fourth disk is a disk having a horizontal upper surface and a lower surface having an upward slope toward the outer edge side at the outermost peripheral portion.
- the fourth disk is provided so that the atomized liquid material passes through a second gap formed between the upper surface of the fourth disk and the lower surface of the third disk.
- the fifth disk is provided below the fourth disk, is disposed at a predetermined distance from the lower surface of the fourth disk, and rotates coaxially and integrally with the first disk.
- the powder material leveled by the second disk passes through a third gap formed between the upper surface of the fifth disk and the lower surface of the fourth disk.
- the fourth gap is opposed to the lower surface on the outer edge side of the third disk and the upper surface on the outer edge side of the fifth disk with the fourth disk sandwiched from the upper surface and the lower surface direction of the fourth disk. And combine.
- a gap formed between the outer edge of the fourth disk, the lower surface on the outer edge side of the third disk, and the upper surface on the outer edge side of the fifth disk.
- a mixture in which the liquid raw material radiated from the second gap and the powder raw material radiated from the third gap are combined to form the third disk and the fifth disk.
- the third disk and the fifth disk which are opposed to each other are pushed up, and the fifth disk is pushed down. Radiates in the circumferential direction of the fifth disk.
- the mixing device further includes an annular member and a sampling unit.
- the annular member is a circle in which the third disk and the fifth disk are arranged on the inner diameter, and the mixture radiated from the outer edge of the third disk and the fifth disk is deposited on the side surface of the inner diameter.
- the lower side of the first gap is supported by an elastic member having elasticity in the vertical direction.
- Magnets are embedded in the third disk and the fifth disk so as to face each other.
- the mixing method of the powder material and the liquid material using the mixing apparatus according to the present invention is as follows.
- the mixing apparatus according to the present invention includes a first disk, a second disk, a third disk, a fourth disk, and a fifth disk.
- the first disk rotates around the vertical axis and radiates the powder raw material supplied from the vertical axis direction toward the outer edge.
- the second disk is a stationary disk arranged at a predetermined distance from the upper surface of the first disk.
- the third disk covers the second disk and rotates coaxially with the first disk.
- the third disk has an atomizing head that atomizes the liquid material supplied during rotation and radiates it in the direction of the outer edge.
- the fourth disk has a smaller radius than the third disk, and is fixed to the third disk at a predetermined distance from the lower surface of the third disk.
- the fourth disk rotates coaxially and integrally with the third disk.
- the fourth disk has a horizontal upper surface and a lower surface having an upward slope toward the outer edge side at the outermost periphery.
- the fifth disk is provided below the fourth disk, and is arranged at a predetermined distance from the lower surface of the fourth disk.
- the fifth disk rotates coaxially and integrally with the first disk.
- the fifth disk has a larger radius than the fourth disk.
- the atomized liquid material is passed through a second gap formed between the upper surface of the fourth disk and the lower surface of the third disk.
- the powder material leveled by the second disk is passed through a third gap formed between the upper surface of the fifth disk and the lower surface of the fourth disk.
- the fourth gap the liquid raw material emitted from the second gap and the powder raw material emitted from the third gap are combined.
- the fourth gap is the lower surface on the outer edge side of the third disk and the upper surface on the outer edge side of the fifth disk across the fourth disk from the upper surface and lower surface direction of the fourth disk.
- the combined mixture is deposited on the portion where the third disk and the fifth disk face each other.
- the third disk or the fifth disk pushed together is opposed.
- the mixture is radiated in the circumferential direction of the third disk and the fifth disk.
- the powder material and the liquid material can be mixed uniformly.
- FIG. 2 is a cross-sectional view taken along the line AA in FIG. 1 is a perspective view (conceptual diagram) of a rotating disk 1.
- FIG. 2 is a perspective view (conceptual diagram) of a stationary disk 2.
- FIG. 2 is a perspective view (conceptual diagram) of a rotating disk 3.
- FIG. 2 is a perspective view (conceptual diagram) of a rotating disk 4.
- FIG. 2 is a perspective view (conceptual diagram) of a rotating disk 5.
- FIG. 1 is a perspective view (conceptual diagram) of a rotating disk 1.
- FIG. 2 is a perspective view (conceptual diagram) of a stationary disk 2.
- FIG. 2 is a perspective view (conceptual diagram) of a rotating disk 3.
- FIG. 2 is a perspective view (conceptual diagram) of a rotating disk 4.
- FIG. 2 is a perspective view (conceptual diagram) of a rotating disk 5.
- FIG. 1 is a perspective view (conceptual diagram) of
- FIG. 6 is an enlarged view near a minute gap 27.
- FIG. 4 is an enlarged view of a cross section of the rotating disk 3, the rotating disk 4, and the rotating disk 5 in FIG. 3. It is a figure which shows the transient state immediately after powder raw material particle
- 15A is a plan view of the scraper 120
- FIG. 15B is a cross-sectional view taken along the arc-shaped center line BB of FIG. 15A.
- one direction in the horizontal plane is referred to as the X direction
- a direction orthogonal to the X direction in the horizontal plane is referred to as the Y direction.
- FIG. 1 is a cross-sectional view of the mixing device viewed from the X direction in the present invention.
- FIG. 2 is a cross-sectional view of the mixing device viewed from the Y direction in the present invention.
- FIG. 3 is a cross-sectional view of the main part of the mixing device viewed from the X direction in the present invention.
- 4 is a cross-sectional view taken along the line AA in FIG.
- the mixing apparatus mainly includes a powder raw material quantitative supply device (not shown), a rotating disk 1, a rotating disk 1 ', a stationary disk 2, a rotating disk 3, a rotating disk 4, a rotating disk 5, an annular member 11, a guide 21, and a funnel 101.
- the cam followers 118 and 119, a scraper 120, a support 121, a cover 122, a middle base plate 123, and an upper base plate 124 are included.
- the mixing apparatus completes the mixing of the powder raw material and the liquid raw material at the moment of initial encounter. Thereby, it is possible to prevent the mechanical action from being applied to the mixture during the mixing process and being damaged.
- the mixing device when the mixing device is applied to the mixing of flour and water, it becomes possible to uniformly add moisture to all the proteins in the flour and prevent the destruction of the gluten network, thereby improving the quality. be able to.
- the process is simplified and shortened, which is advantageous for reducing the manufacturing cost. Therefore, according to this embodiment, it can be said that an ideal mixing method is provided.
- the mixing apparatus capable of continuously mixing the powder raw material and the liquid raw material according to the present invention supplies the powder raw material in a fixed amount to the center of the rotating disk 1 and rotates the powder raw material to adjust the diameter. Expand in a larger direction.
- the powder raw material is passed through a gap with the stationary disk 2 provided above the rotating disk 1 to level the layer thickness, and then the rotating disk 5 having a larger diameter on the lower side of the rotating disk 1 is provided. Drop on top.
- a bell-shaped rotating disk 3 that is concentric with the rotating disk 1 and rotates at the same speed is provided so as to cover the stationary disk 2.
- the liquid raw material supplied at a location close to the center is made to have a uniform film thickness.
- the liquid raw material having a uniform film thickness is guided to the spray head 7 to be atomized and radiated in the horizontal direction.
- a rotating disk 4 having an acute edge at the outer periphery is fixed.
- the rotating disk 4 has a horizontal gap space between the rotating disk 3 and the lower surface of the rotating disk 3 at a location larger in diameter than the spray head 7, and an inclined gap space (gap part 8) between the rotating disk 5.
- liquid droplets of the liquid raw material radiated uniformly in all directions fly at high speed in the horizontal direction.
- the powder raw material develops while floating in the lower gap space.
- the liquid raw material and the powder raw material are merged and mixed in a wedge-shaped space with a concavity outside the outer peripheral portion of the rotating disk 4.
- the mixture is discharged from the open end 10 at the tip of the wedge-shaped space.
- the discharged mixture is deposited on the inner peripheral concave surface 12 of the annular member 11 provided on the outer side.
- the mixture can be obtained by collecting the mixture deposited on the inner concave surface 12.
- the rotating disk 5 has a shape that is highly elastic in the vertical direction.
- the rotating disk 5 is in contact with the rotating disk 3 with a predetermined appropriate contact force in a minimum gap portion 14 near the outer periphery thereof.
- the dispersed particles and fine droplets of the powder raw material are clogged at the contact point in the minimum gap portion 14.
- Condensation starts from the contact point.
- a wedge action is applied to the upper and lower walls. As the condensation zone C increases, the wedge action also increases and eventually exceeds the contact force.
- the rotating disk 5 elastically supported is pushed down, so that the clogging is eliminated and the mixture is radiated from the open end 10.
- the decrease in the condensation zone C reduces the depression force and the radiation amount is reduced. Therefore, the condensation zone C is automatically adjusted, the condensation zone C settles to a steady state, and as a result, the mixing and the emission of the conjugate are stable in a good state.
- the annular member 11 having the inner concave surface 12 rotates concentrically with the rotating disk 1 or the like. Therefore, by providing the scraper 120 fixed to the annular member 11 at a predetermined location, the mixture deposited on the annular member 11 can be continuously taken out.
- a high-quality food using wheat flour as a main raw material can be produced at low cost.
- the mixing apparatus according to the present invention when a food containing wheat flour as a main raw material and an oil / fat raw material is made, the oil / fat raw material is pre-emulsified and contained in water. Thereby, the high-quality food can be produced at a low cost.
- the mixing device according to this embodiment will be described in more detail below.
- the rotating disks 1 and 1 ', the elastic member 13, and the rotating disk 5 are fixed so that they can rotate coaxially, that is, rotate together.
- the integrated rotating disks 1 and 1 ′, the elastic member 13, and the rotating disk 5 are referred to as a structure A.
- the rotating disk 3, the rotating disk 4, the horizontal member 22, and the hollow shaft 102 are fixed so that they can rotate coaxially, that is, rotate integrally.
- the integrated rotating disk 3, rotating disk 4, horizontal member 22, and hollow shaft 102 are referred to as a structure B.
- the structure A and the structure B are fixed by the small magnets 107 and 107 ', and thus rotate at the same rotational speed and coaxially.
- the powder raw material quantitative supply device is a device that supplies a certain amount of powder raw material.
- Bearings 109 and 109 ′ are accommodated in the housing 110.
- the rotating disk 1 is fixed to a rotating shaft 108 supported by bearings 109 and 109 ′ and can be rotated at high speed by an electric motor 111, a large pulley 112, a belt 113 and a small pulley 114.
- FIG. 5 is a perspective view (conceptual diagram) of the rotating disk 1.
- An agglomerate crusher 18 having a circular saw-like outer shape is provided on the flange of the rotary disk 1.
- the rotating disk 1 is supported by a rotating disk 1 ′ integrated with the rotating disk 1.
- FIG. 6 is a perspective view (conceptual diagram) of the stationary disk 2.
- the stationary disk 2 is a stationary disk, and an opening connected to the lower end of the funnel 101 is provided on the upper surface.
- a seal ring 32 is provided on the side surface of the stationary disk 2, and a flange is provided at the lower end.
- the stationary disk 2 has a hollow structure and is disposed so as to cover the rotating disk 1.
- the seal ring 32 is provided for the purpose of eliminating the possibility that the powder raw material in the outer space of the gap 20 enters the space inside the inclined surface 25 and enters the liquid raw material.
- FIG. 7 is a perspective view (conceptual diagram) of the rotating disk 3.
- a horizontal member 22 is provided at a position lowered from the upper end of the rotating disk 3.
- a hole 24 is formed along the outer periphery of the horizontal member.
- a groove 40 corresponding to the seal ring 31 is provided on the inner diameter side surface between the upper end portion of the rotating disk 3 and the horizontal member 22.
- Below the rotating disk 3, a flange is provided in two stages.
- the rotating disk 3 has a hollow structure and can cover the stationary disk 2.
- the shape of the lower surface of the two-stage flange is also a step shape, and the rotating disk 4 is fixed to the step portion.
- FIG. 8 is a perspective view (conceptual diagram) of the rotating disk 4.
- the rotating disk 4 has a ring structure, and the stationary disk 2 can be passed through the space surrounded by the inner diameter.
- a groove 33 corresponding to the seal ring 32 of the stationary disk 2 is provided on the side surface of the inner diameter of the rotating disk 4.
- a plurality of partition plates 34 are provided at equal intervals in the radial direction on the upper surface of the rotating disk 4.
- the partition plate 34 is provided with a hole 34a through which a screw passes.
- the rotating disk 4 is fixed to the stepped portion on the lower surface side of the rotating disk 3 through a screw through the hole 34a.
- a region divided by the partition plate 34 is referred to as a groove 26.
- a flange is provided at the lower end of the rotating disk 4.
- the flange of the rotating disk 4 has a constant thickness from the inner diameter toward the outer diameter up to a predetermined position (inner peripheral portion). From the predetermined position to the edge (outer peripheral part) is inclined and becomes thinner toward the edge.
- FIG. 9 is a perspective view (conceptual diagram) of the rotating disk 5.
- an opening through which the rotating disk 1 'passes is provided in the central portion of the upper surface of the rotating disk 5.
- the surface is horizontal to a predetermined position (inner peripheral portion), and the predetermined position to the edge (outer peripheral portion) is inclined.
- the powder raw material P falls to the center of the rotating disk 1 rotating at high speed and starts rotating, it is accelerated in the radial direction by the generated centrifugal force. Along with the rotation, the thickness of the layer of the powder material P decreases toward the radial direction, and the layer of the powder material P gradually curves outward while gradually increasing the rotational speed and the radial direction speed. It is developed while drawing.
- the powder raw material layer enters the gap 6 under the stationary disk 2 attached to the lower end of the funnel 101 while the thickness of the powder raw material layer is decreased by the speed increase due to the development.
- FIG. 10 is an enlarged view of the vicinity of the gap 6.
- a flat surface 2a is formed from the center to a predetermined position, and an inclination 2b is provided from the predetermined position.
- a plane 2c is obtained.
- the gap 6 is a gap between the upper surface of the rotating disk 1 and the flat surface 2c of the stationary disk 2, and the height of the gap 6 is larger than the maximum particle diameter of the powder raw material.
- the powder raw material layer is subjected to a leveling action by the stationary disk 2, but a rotational force is continuously applied from the rotating disk 1. Therefore, the flow to the larger diameter side is continued. Eventually, when the powder raw material P escapes from the gap 6, it flows out almost uniformly in all directions of 360 degrees.
- the powder raw material moves along the curved inner surface 16 of the stationary disk 2 and then descends while dancing in the space 17 and then falls onto the teeth of the agglomerate crusher 18 having a circular saw-like outer shape. Since some powder raw material is stored in the space 17, it has a function of leveling when there is a minute fluctuation in the supply amount of the powder raw material.
- the agglomerate crusher 18 having a tooth-shaped planar shape is fixed to the rotating disk 1 and is rotating at a high speed.
- the powder raw material P that has fallen on the agglomerate crushing disk 18 hits the vertical surface of the tooth profile and is blown off, and after colliding with the vertical wall 19 of the stationary disk 2, it falls onto the rotating disk 5.
- the agglomerates that have passed through the gap 6 due to the two impacts are decomposed, and the powder raw material P falling on the rotating disk 5 becomes free.
- the rotating disk 5 is attached to a rotating disk 1 ′ integrated with the rotating disk 1 via an elastic member 13. Since the upward force is applied to the rotating disk 5 by the spring force of the elastic member 13, the rotating disk 5 is pressed against the rotating disk 3.
- the powder raw material is subjected to a leveling action again while passing through the gap 20 formed between the flange of the stationary disk 2 and the rotating disk 5, and evenly in all directions than the state at the exit of the gap 6. It becomes a near flow and flows into the gap 8.
- the gap 8 is a gap between the inclined surface of the lower surface of the flange of the rotating disk 4 and the inclined surface of the upper surface of the rotating disk 5, and the height of the gap 8 is the powder. It is larger than the maximum particle size of the raw material.
- the height of the gap 20 is larger than the maximum particle diameter of the powder raw material.
- a conduit 105 shown in FIGS. 1 and 2 is a pipe for flowing down the liquid raw material L supplied from a liquid raw material quantitative supply device (not shown) provided above.
- the conduit 105 is inserted into the flow path hole 106 of the guide 21 fixed to the lower end surface of the housing 103.
- a plurality of conduits 105 can be provided for the purpose of supplying a plurality of liquid raw materials simultaneously. Further, for the purpose of preventing the liquid raw material L from leaking outside, it is desirable to provide a seal ring 31 on the guide 21 as shown in FIG.
- the hollow shaft 102 is supported by bearings 104 and 104 ′ inserted into the housing 103, and can be rotated concentrically with the rotating shaft 108.
- a plurality of powerful small magnets 107 are embedded in a portion near the outermost peripheral portion of the rotating disk 3 attached to the lower end portion of the hollow shaft 102.
- the small magnet 107 embedded in the rotating disk 3 attracts the small magnet 107 ′ embedded in the same position of the rotating disk 5.
- the liquid raw material L poured on the upper surface of the horizontal member 22 of the rotating disk 3 immediately starts to rotate at a high speed, and is accordingly accelerated in the radial direction to be provided on the rotating disk 3.
- the liquid is stored in the liquid reservoir 23.
- the rotational speed of the liquid raw material L becomes equal to that of the rotating disk 3.
- the liquid level of the liquid pool 23 becomes substantially vertical by the action of strong centrifugal force due to the high-speed rotation of the rotating disk 3.
- the horizontal member 22 In the vicinity of the liquid reservoir 23, the horizontal member 22 has a plurality of holes 24, and the liquid raw material tends to flow in a larger diameter direction by a strong centrifugal force. Therefore, before the liquid material L fills the liquid pool 23, the liquid material L flows through a portion far from the rotation shaft on the inner periphery of the hole 24 and reaches the lower side of the horizontal member 22. Next, the liquid raw material L goes to the inclined surface 25 and passes through the groove 26 provided on the upper surface of the rotating disk 4 as shown in FIG.
- FIG. 11 is an enlarged view of the vicinity of the minute gap 27. Since the minute gap 27 is extremely narrow, the entire amount of the liquid raw material L cannot pass through initially, and a liquid pool 29a is generated in the groove 29 as shown in FIG. Then, due to the extremely strong centrifugal force applied to the liquid raw material L, the pressure in the vicinity of the vertical wall 28 of the liquid raw material increases in proportion to the storage allowance. Then, the flow rate passing through the minute gap 27 eventually balances with the inflow amount from the slope 25. Next, the liquid raw material flows into the groove 29 and temporarily accumulates in the groove 29.
- the amount of inflow at this time is not uniform because it is immediately after passing through the groove 26, but in the groove 29, the liquid level is equidistant from the center of rotation of the rotating disk 3 by a strong centrifugal force.
- the radius of the lower vertical wall 30 is slightly larger than that of the vertical wall 28, and the distance from the center of rotation is the same over the entire circumference. As a result, the liquid material L overflows from the groove 29 with a completely uniform thickness and flow rate of 360 degrees.
- the liquid raw material L overflowing from the groove 29 flows in a thin film shape along the vertical wall 30 and reaches the spray head 7 after passing through the curved surface.
- the liquid film loses its support at the spray head 7 and is broken down into countless fine droplets immediately after the spray head 7 is detached.
- the particle diameter of these fine droplets is preferably equal to or less than the particle diameter of the powder raw material.
- the main factor that determines the diameter is the physical properties of the liquid raw material. However, the physical property conditions cannot be changed arbitrarily. Therefore, the diameter can be adjusted by adjusting the radial position of the spray head 7, the rotational speed of the rotating disk 3, or the supply amount of the liquid raw material.
- FIG. 12 is an enlarged view of a cross section of the rotating disk 3, the rotating disk 4, and the rotating disk 5 in FIG.
- the fine droplets separated from the spray head 7 fly in a flat space 36 sandwiched between the upper surface of the rotating disk 4 and the lower surface of the rotating disk 3. Since the air existing in the flat space 36 rotates at the same rotational speed as that of the rotating disk 3 and the rotating disk 4, the generated centrifugal force produces a suction action similar to that of a centrifugal fan. However, since the liquid reservoir 35 described with reference to FIG. 11 has a kind of water sealing function, the possibility of generating an air flow from the space where the powder raw material P develops to the flat space 36 is eliminated, and the wall surrounding the space is also removed. Keep clean.
- the air present in the gap 8 is rotating at high speed because it is in contact with the wall rotating at high speed in the vertical direction, and applies a force in the circumferential direction to the powder raw material particles.
- the powder raw material particles begin to move in the circumferential direction and at the same time are accelerated in the radial direction, become dispersed particle groups, expand while floating in the gaps 8, and flow into the space 9 having a wedge-shaped cross-sectional shape. To do.
- the acceleration of the powder particles in the gap 8 is weak through air, the inflow speed into the space 9 is much smaller than the peripheral speed of the upper and lower walls.
- the direction of the initial velocity of the droplets is substantially tangential to the circumferential spray head 7, and the velocity is substantially equal to the circumferential velocity of the spray head 7. Since the radiated droplet moves at a constant speed in a substantially straight line in the horizontal plane, the entrance of the space 9 separated from the spray head 7 has a very high radial velocity.
- the spatial density of the dispersed particles of the powder raw material P in the space 9 becomes considerably high. The reason is that the flying speed of the particles is slow. As a result, it frequently occurs that droplets flowing into the space 9 while flying at high speed collide with powder particles.
- the dispersed particle groups in the space 9 are strongly stirred by the collision, and the unevenness of the spatial density of the dispersed particle groups is leveled. As the spatial density of the dispersed particles is more uniform, the mixture becomes more homogeneous, and this stirring by collision is an important phenomenon.
- FIG. 13 and FIG. 14 show the phenomenon in the space 9.
- FIG. It is a figure which shows the transient state immediately after powder raw material particle
- the rotating disk 5 and the rotating disk 3 are still in contact with each other at the minimum gap portion 14. Therefore, the dispersed particle group of the powder raw material P that has flowed into the space 9 is dammed up at the minimum gap portion 14 to form a deposited layer.
- Particle groups of the powder raw material P and the liquid raw material L collide one after another with different velocity vectors on the inner surface of the deposited layer.
- the dispersed particles of the low-speed and high-density powder raw material softly land on the sedimentary layer.
- FIG. 14 is a diagram showing a state at the time when the inflow and mixing of the powder raw material particles and droplets has reached a stable state.
- FIG. 14 shows a state where the inflow and outflow of the mixture in the minimum gap 14 are balanced.
- the size of the condensation zone C at that time should not be too large or too small. If the condensation zone C is too small, there is a high possibility that a part of the space 9 where the condensation zone C is missing occurs.
- the coupling between the powder raw material and the liquid raw material is not completed, that is, the powder raw material and the liquid raw material are both fine particles, and the radiation from the open end 10 beyond the minimum gap portion 14 is performed and scattered. It becomes easy to do. Then, the rate at which the fine particles of the powder raw material and the fine particles of the liquid raw material adhere to the inner peripheral concave surface 12 is reduced, and the trapping efficiency is lowered. Conversely, if the condensation zone C develops too much, the mixing zone M becomes too small. Therefore, the coexistence in the same space between the dispersed particle group and the droplet group of the powder raw material is hindered, and homogeneous mixing is inhibited.
- the size of the condensation zone C is adjusted to an optimum state by adjusting a changeable value among these factors.
- the mixture that has flowed out from the open end 10 is initially stretched violently by centrifugal force at the moment of separation from the open end 10 and is broken down into particles while being tangential to the outer circumference of the rotating disks 3 and 5. Is released at almost peripheral speed. At that time, the particles of the mixture have a form connected by a liquid raw material, and the particle diameter is much larger than that of the powder raw material particles. Therefore, when the particles of the mixture collide with the inner peripheral concave surface 12 of the annular member 11, they often adhere and accumulate easily.
- the inner circumferential concave surface 12 may not adhere, but since the annular member 11 is rotating as will be described later, particles of the mixture accumulate on the vertical wall surface behind the inner circumferential concave surface 12 by centrifugal force. To do.
- the annular member 11 is rotatably supported by four sets of cam followers 118 and 119 arranged concentrically with the hollow shaft 102 and the rotary shaft 108.
- the annular member 11 is provided with a gear along its shape.
- the annular member 11 is rotated at a relatively low speed by the reduction gear-equipped motor 115, the gear 116, and the gear 117 shown in FIG.
- FIG. 15A is a plan view of the scraper 120.
- FIG. 15B is a cross-sectional view taken along the arc-shaped center line BB of FIG. D is a mixture deposited on the inner circumferential concave surface 12, rotates in the direction of the arrow together with the annular member 11, and is peeled off by the tip of the scraper 120.
- the peeled mixture receives a force greater than the frictional resistance on the sliding surface of the scraper from the rear. Therefore, the flow of the mixture along the scraper 120 Is generated and maintained, and the flow direction is changed downward, then, with the help of gravity, it is separated from the scraper, and falls as a string-like flow like a falling fabric D 'as shown in FIG. Since a container (not shown) or a conveyor is provided at the destination of the falling fabric D ′, the mixture D ′ is continuously collected.
- sleeves 125 are fixed to the lower surface of the upper base plate 124 at four corners.
- Support columns 127 are fixed to the upper surface of the middle base plate 123 to which the housing 110 is attached at four corners.
- the portion supported by the housing 103 that is, the stationary disk 2, the rotating disk 3, the rotating disk 4 and the like can be lifted to a necessary height from the height described in FIG. For this reason, it is possible to easily attach and remove the rotating disk 3 and the stationary disk 2.
- the upper base plate 124 is returned to its original height, and the nut 128 is tightened to firmly fix the upper base plate 124 so that it does not move during operation.
- dough for bread making is made.
- water, yeast, salt, sugar, etc. may be added to the liquid raw material in advance to make an aqueous solution in the same manner as in the normal method of making.
- the problem is that many types of bread such as white bread, butter roll, and French bread need addition of fats and oils such as butter and shortening.
- the weight of the fat When the weight of the fat is large, it reaches 15 with respect to the flour 100.
- the fats and oils are not fed into the mixer from the beginning, but are fed after the hydration has progressed to some extent so that the mixing of the hydration and the fats and oils is completed at the same time.
- a liquid raw material is charged in a subsequent process.
- a dough that has been hydrated by a mixing apparatus according to the present invention and necessary fats and oils are charged into a vertical mixer having a stirring blade, and mixing is performed while rotating the stirring blade at a low speed and suppressing the destruction of the gluten structure.
- the mixing accuracy required at this time may be much rougher than the uniformity required for hydration, so light mixing is sufficient so as not to break the gluten network.
- fats and oils are preliminarily emulsified and added to the liquid raw material.
- dispersing fine oil and fat particles uniformly it is possible to prevent the oil and fat from interfering with hydration.
- a liquid added by emulsifying fats and oils is introduced through a separate conduit provided along with the conduit 105.
- the second and third methods have the disadvantage of requiring an emulsifying device, but the post-process necessary for the first method can be omitted, and there are significant advantages when applied to mass production.
- the final fat-containing dough has an unprecedented quality.
- the reason is as follows.
- fats and oils are added in a state where hydration is not completed in some parts of the dough, and in some cases, only the fats and oils are combined with the flour in some parts of the dough, and there are gluten missing parts.
- the dough produced by the method of the present invention is uniformly hydrated, so that a much denser gluten structure than that of the prior art is evenly generated in all parts of the dough.
- the bread making method of the present invention has advantages not found in the past. This is because the mixing process and the kneading process for developing the gluten network can be completely separated. For example, in French bread, it is ideal that a network is naturally formed only after the fermentation process, so kneading is unnecessary. If the method of emulsifying and adding fats and oils is taken, a dough can be completed only with the mixing apparatus by this invention. The same is true for dough for cakes where it is better not to over-develop the gluten structure.
- this dough is kept at an appropriate temperature, fermentation by yeast will proceed.
- the gas generated during the fermentation is confined in a denser gluten three-dimensional network than before, and fine bubbles are generated uniformly. Therefore, even without adding the problematic additives, the baked bread has a fine and elastic crumb (bread contents), and the crust (skin) is thin and crisp.
- noodle making in the case of industrial noodle making of udon, noodles having a prescribed cross-sectional shape and dimensions are rolled using an incisor roll. What is likely to be a problem at this time is a trouble that the fabric adheres to the incisor roll. This trouble is likely to occur when moisture is not evenly distributed in the dough. This is because, when a portion having excessive moisture is generated in the dough, adhesion occurs from that portion.
- the water content is less than spreading dough for bread to spread moisture uniformly throughout the flour.
- Stirring must be finished in a mottled state, since the gluten network structure is destroyed when stirring to hydrate all the corners of the dough. Therefore, it is necessary to add a process that takes extra time and labor, such as laying down, reworking, and stretching.
- the production method according to the present invention moisture is uniformly distributed throughout the dough, and there is no portion that tends to stick, so that the water content can be increased to 50% or more.
- the protein which becomes a gluten element in the mixing step as in the conventional method is in a state where it has just been hydrated without being lost by unintentional destruction of gluten formation. Therefore, by adding appropriate kneading, a gluten network is efficiently developed, and a dough rich in elasticity comparable to a dough having a water content of 40% is obtained.
- dough whose viscosity and viscosity do not change can be obtained even when the water content is increased by 10% or more compared to the conventional method.
- the water content is an important index that affects the time of boiling.
- the amount of moisture necessary for gelatinization is insufficient in the noodle core (about 60% of the amount of starch). It took a long time.
- dry noodles if there is little water, it becomes hard and dense noodles, so the time to boil also becomes longer.
- the water content is increased to 50% or more by the dough manufacturing method using the mixing apparatus of the present invention
- the water content is close to the required amount, so that the deficiency penetrates into the core.
- Time is reduced and time is shortened with paddle.
- polyhydrated noodles are easy to permeate water, so that ⁇ -formation occurs in a short time, and the boiling time is shortened. If the time can be shortened with boil, the umami and aroma inherent in noodles can be reduced from leaching into the boiling water.
- the surface layer portion of the noodles is less damaged by being boiled too much. There are many advantages such as saving thermal energy to boil.
- pasta mainly made of durum semolina powder such as spaghetti and macaroni
- it is conventionally made mainly by extrusion noodle making from a die. Its purpose is to obtain accelerated hydration by eliminating air that has the property of impeding moisture penetration.
- the noodles are inevitably dense, water permeation during cooking is slow, and the cooking time is longer for the thickness.
- the absence of air prevents intermittent stimulation of miso and impairs the essential taste.
- the hydration is evenly uniform and a gluten network structure can be easily obtained, so that it can be produced by a noodle making method similar to udon. . Therefore, the irritation to the miso becomes intermittent, and as described above, the water content can be increased and the time for cooking can be reduced, so that the taste is improved. Also, many other benefits can be obtained in the same way as udon.
- the supplied powder raw material is uniformly expanded and the liquid raw material is uniformly atomized, and the uniformly expanded powder raw material and the uniformly atomized liquid raw material are the same. It is guided to the narrow space and mixed while merging. It is then condensed to form a dense mixture that is released by centrifugal force.
- the discharged mixture is deposited on the vertical wall surface of the receiver of the inner circumferential concave surface 12 of the annular member 11. By collecting the mixture deposited on the vertical wall surface of the inner peripheral concave surface 12 with the scraper 120, a homogeneous mixture of the powder raw material and the liquid raw material can be obtained continuously.
- the powder raw material P is passed through a narrow gap between the rotating disks 1 and 5 rotating at high speed and the stationary disk 2 provided on the rotating disks 1 and 5, and the powder material P is distributed twice.
- the powder material P is distributed twice.
- the liquid material L it is possible to realize the development of a group of droplets that are uniform in all directions by using a rotary atomization method that is devised for flowing the liquid material L evenly in all directions.
- the mixing area and the condensation area are stably formed in the wedge-shaped space 9.
- the fine particle droplet group is caused to collide with the dispersed particle group of the powder raw material P floating in the mixing zone M and the powder raw material P deposited on the surface of the condensation zone C at high speed.
- the dispersed particles in the mixing zone are vigorously stirred and the mixing and bonding on the inner surface of the condensation zone is maintained in the best condition.
- the mixture particles discharged from the open end 10 through the minimum gap portion 14 are deposited on the inner peripheral concave surface 12 of the annular member 11, and the mixture particles are collected by the scraper 120. Thereby, the mixture D can be obtained efficiently and continuously.
- the agglomerate crusher 18 By providing the agglomerate crusher 18 at the lower part of the space 17, the agglomerates that have passed through the gap 6 can be decomposed.
- a high-quality food using wheat flour as a main raw material can be produced with a shortened and simple facility.
- the oil / fat raw material is pre-emulsified and contained in water. Thereby, the high-quality food can be produced at a low cost.
- the powder raw material and the liquid raw material are quantitatively supplied to the mixing apparatus according to the present invention, the powder raw material and the liquid raw material can be uniformly mixed, and the mixture of the powder raw material and the liquid raw material is a certain amount each. Can be taken out continuously. In addition, only a small amount of raw material remains in the mixing apparatus when the mixing operation is completed, so that waste of the raw material can be reduced and cleaning is easy. In addition, there is an advantage of continuous processing, and the efficiency is good despite the small apparatus, so that the equipment cost can be kept low.
- the present invention is not limited to the embodiment described above, and various configurations or embodiments can be taken without departing from the gist of the present invention.
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Abstract
Description
先ず、粉体原料の流れを説明する。図3において、粉体原料Pは図示せぬ粉体原料定量供給装置から押し出され、漏斗101の中を落下して回転円盤1の中心付近に着地する。
次に液体原料が供給されてから、微粒子化されるまでの流れを述べる。図1、図2に示す導管105は、上方に設けられた図示せぬ液体原料定量供給装置から供給された液体原料Lを流下させる管である。導管105は、ハウジング103の下端面に固定されたガイド21の流路孔106に挿入されている。尚、複数の液体原料を同時に供給する目的で導管105を複数個設けることも可能である。また、液体原料Lの飛沫が外部に漏出することを防ぐ目的で、図3に示すように、ガイド21にシールリング31を設けることが望ましい。
本発明に係る混合装置を用いて、実際にパンや麺類用の生地を製造する場合について述べる。
1’ 回転円盤
2 回転円盤
3 回転円盤
4 回転円盤
5 回転円盤
6 隙間部
7 噴霧頭
8 隙間部
9 空間
10 開放端
11 円環状部材
12 内周凹面
13 弾性部材
14 最小隙間部
16 湾曲内面
17 空間
18 凝集塊粉砕盤
19 縦壁
20 隙間部
21 ガイド
22 水平部材
23 液溜まり
24 孔
25 斜面
26 溝
27 微小隙間
28 縦壁
29 溝
29a 液溜まり
30 縦壁
31 シールリング
32 シールリング
33 溝
34 仕切り板
34a 孔
35 液溜まり
36 扁平な空間
40 溝
101 漏斗
102 中空軸
103 ハウジング
104 軸受け
104’ 軸受け
105 導管
106 流路孔
107 小型マグネット
107’ 小型マグネット
108 回転軸
110 ハウジング
111 電動機
112 大プーリ
113 ベルト
114 小プーリ
115 減速機付電動機
116 ギヤ
117 ギヤ
118 カムフォロワ
119 カムフォロワ
120 スクレーパ
121 サポート
122 カバー
123 中段ベースプレート
124 上段ベースプレート
125 スリーブ
126 ブッシュ
126’ ブッシュ
127 支柱
128 ナット
Claims (4)
- 鉛直軸を中心に回転し、該鉛直軸方向より供給された粉体原料を外縁方向へ放射する第1の円盤と、
前記第1の円盤の上面から所定の距離離して配置された、静止した第2の円盤であって、該所定の距離離すことにより形成される第1の間隙に前記第1の円盤上で放射された前記紛体原料を通して均すように設けられた該第2の円盤と、
前記第2の円盤を覆い、前記第1の円盤と同軸で回転し、回転中に供給された液体原料を霧化して外縁方向に放射する霧化頭を有する第3の円盤と、
該第3の円盤より小さい半径を有し、該第3の円盤の下面から所定の距離離して該第3の円盤と固定され、該第3の円盤と同軸でかつ一体で回転し、最外周部において、水平な上面と、外縁側に向かって上り傾斜を持つ下面とを有する第4の円盤であって、該第4の円盤の上面と前記第3の円盤の下面との間に形成される第2の間隙を前記霧化した液体材料が通過するように設けられた該第4の円盤と、
前記第4の円盤の下方に設けられ、該第4の円盤の下面から所定の距離離して配置され、前記第1の円盤と同軸かつ一体で回転し、該第4の円盤より大きい半径を有する第5の円盤であって、該第5の円盤の上面と前記第4の円盤の下面との間に形成される第3の間隙を前記第2の円盤により均された前記紛体材料が通過するように設けられた該第5の円盤と、
を備え、
前記第4の円盤の上面及び下面方向より該第4の円盤を挟んで前記第3の円盤の外縁側の下面と前記第5の円盤の外縁側の上面とは対向して合わさり、前記第4の円盤の外縁と前記第3の円盤の外縁側の下面と前記第5の円盤の外縁側の上面との間に形成された第4の間隙にて、前記第2の間隙から放射された前記液体原料と前記第3の間隙から放射された前記紛体原料とが結合した混合物が前記第3の円盤と前記第5の円盤とが対向して合わさっている部分に堆積し、該堆積した混合物の量及び混合物にかかる遠心力に応じて、該対向して合わさっている前記第3の円盤の押し上げまたは前記第5の円盤の押し下げを行い、該混合物を前記第3の円盤及び前記第5の円盤の円周方向に放射する
ことを特徴とする混合装置。 - 前記混合装置は、さらに、
前記第3の円盤と前記第5の円盤を内径に配置し、前記第3の円盤と前記第5の円盤の外縁部より放射された前記混合物を内径の側面に堆積させる円環状の円環状部材と、
前記円環状部材の内径の側面に堆積した混合物をはぎ落す採取部と
を備えることを特徴とする請求項1に記載の混合装置。 - 前記第5の円盤は、前記第1の間隙の下側が鉛直方向に弾性を有する弾性部材によって支持されており、
前記第3の円盤と前記第5の円盤には、前記対向して合わさるように磁石が埋め込まれている
ことを特徴とする請求項1または2に記載の混合装置。 - 鉛直軸を中心に回転し、該鉛直軸方向より供給された粉体原料を外縁方向へ放射する第1の円盤と、
前記第1の円盤の上面から所定の距離離して配置された、静止した第2の円盤と、
前記第2の円盤を覆い、前記第1の円盤と同軸で回転し、回転中に供給された液体原料を霧化して外縁方向に放射する霧化頭を有する第3の円盤と、
該第3の円盤より小さい半径を有し、該第3の円盤の下面から所定の距離離して該第3の円盤と固定され、該第3の円盤と同軸でかつ一体で回転し、最外周部において、水平な上面と、外縁側に向かって上り傾斜を持つ下面とを有する第4の円盤と、
前記第4の円盤の下方に設けられ、該第4の円盤の下面から所定の距離離して配置され、前記第1の円盤と同軸かつ一体で回転し、該第4の円盤より大きい半径を有し、第5の円盤と、
を備える混合装置を用いた紛体材料と液体材料の混合方法であって、
前記第1の円盤と前記第2の円盤との間に形成される第1の間隙に前記第1の円盤上で放射された前記紛体原料を通して均し、
前記第4の円盤の上面と前記第3の円盤の下面との間に形成される第2の間隙に前記霧化した液体材料を通し、
前記第5の円盤の上面と前記第4の円盤の下面との間に形成される第3の間隙に前記第2の円盤により均された前記紛体材料を通し、
前記第4の円盤の上面及び下面方向より該第4の円盤を挟んで前記第3の円盤の外縁側の下面と前記第5の円盤の外縁側の上面とは対向して合わさっている状態で、前記第4の円盤の外縁と前記第3の円盤の外縁側の下面と前記第5の円盤の外縁側の上面との間に形成された第4の間隙にて、前記第2の間隙から放射された前記液体原料と前記第3の間隙から放射された前記紛体原料を結合させ、
前記結合した混合物が前記第3の円盤と前記第5の円盤とが対向して合わさっている部分に堆積し、該堆積した混合物の量及び混合物にかかる遠心力に応じて、該対向して合わさっている前記第3の円盤の押し上げまたは前記第5の円盤の押し下げを行い、該混合物を前記第3の円盤及び前記第5の円盤の円周方向に放射する
ことを特徴とする紛体材料と液体材料の混合方法。
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| PCT/JP2013/067058 WO2014203390A1 (ja) | 2013-06-21 | 2013-06-21 | 粉体原料と液体原料の混合装置、及びその混合装置を用いた混合物の製造方法 |
| US14/439,710 US9623386B2 (en) | 2013-06-21 | 2013-06-21 | Mixing apparatus for powder raw material and liquid raw material and method for manufacturing mixture using same |
| JP2014558700A JP5830616B2 (ja) | 2013-06-21 | 2013-06-21 | 粉体原料と液体原料の混合装置、及びその混合装置を用いた混合物の製造方法 |
| CN201380058550.2A CN104768636B (zh) | 2013-06-21 | 2013-06-21 | 粉体原料和液体原料的混合装置、以及使用了该混合装置的混合物的制造方法 |
| EP13887331.0A EP3012015A4 (en) | 2013-06-21 | 2013-06-21 | Mixing device for powder raw material and liquid raw material and method for manufacturing mixture using said mixing device |
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| CN114311390B (zh) * | 2022-03-17 | 2022-10-11 | 山东海科创新研究院有限公司 | 一种高粘度液相造粒设备 |
| CN114534541B (zh) * | 2022-04-01 | 2022-10-25 | 山东德宜新材料有限公司 | 一种偏氟乙烯共聚物的制备装置 |
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- 2013-06-21 CN CN201380058550.2A patent/CN104768636B/zh not_active Expired - Fee Related
- 2013-06-21 WO PCT/JP2013/067058 patent/WO2014203390A1/ja not_active Ceased
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| CN113441030A (zh) * | 2021-07-09 | 2021-09-28 | 南方科技大学 | 一种混料设备 |
| CN113753991A (zh) * | 2021-09-28 | 2021-12-07 | 青岛润扬环境科技有限公司 | 一种海水淡化处理设备 |
| CN115340794A (zh) * | 2022-08-19 | 2022-11-15 | 由星来 | 一种防水涂料及其制备工艺 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP3012015A4 (en) | 2017-03-01 |
| US20150290601A1 (en) | 2015-10-15 |
| JP5830616B2 (ja) | 2015-12-09 |
| US9623386B2 (en) | 2017-04-18 |
| CN104768636A (zh) | 2015-07-08 |
| CN104768636B (zh) | 2016-08-24 |
| EP3012015A1 (en) | 2016-04-27 |
| JPWO2014203390A1 (ja) | 2017-02-23 |
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