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WO2013039950A3 - Hydroprocessing catalysts and methods for making thereof - Google Patents

Hydroprocessing catalysts and methods for making thereof Download PDF

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Publication number
WO2013039950A3
WO2013039950A3 PCT/US2012/054723 US2012054723W WO2013039950A3 WO 2013039950 A3 WO2013039950 A3 WO 2013039950A3 US 2012054723 W US2012054723 W US 2012054723W WO 2013039950 A3 WO2013039950 A3 WO 2013039950A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
deoiled spent
feed system
methods
spent catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2012/054723
Other languages
French (fr)
Other versions
WO2013039950A2 (en
Inventor
Shuwu Yang
Julie Chabot
Bruce Edward REYNOLDS
Bo Kou
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chevron USA Inc
Original Assignee
Chevron USA Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/233,491 external-priority patent/US8927448B2/en
Priority claimed from US13/233,455 external-priority patent/US8759242B2/en
Priority claimed from US13/233,477 external-priority patent/US9068132B2/en
Priority to SG11201400662VA priority Critical patent/SG11201400662VA/en
Priority to JP2014530742A priority patent/JP2014527116A/en
Priority to CA2848508A priority patent/CA2848508A1/en
Priority to MX2014003158A priority patent/MX2014003158A/en
Priority to KR1020147009582A priority patent/KR20140064948A/en
Priority to CN201280051948.9A priority patent/CN103906828A/en
Priority to EP12831213.9A priority patent/EP2756057A4/en
Priority to RU2014114844/04A priority patent/RU2014114844A/en
Application filed by Chevron USA Inc filed Critical Chevron USA Inc
Priority to BR112014006174A priority patent/BR112014006174A2/en
Publication of WO2013039950A2 publication Critical patent/WO2013039950A2/en
Publication of WO2013039950A3 publication Critical patent/WO2013039950A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/60—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/70—Wet oxidation of material submerged in liquid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/14—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing with moving solid particles
    • C10G45/16—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing with moving solid particles suspended in the oil, e.g. slurries
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/24—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions with moving solid particles
    • C10G47/26—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions with moving solid particles suspended in the oil, e.g. slurries
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/28—Regeneration or reactivation
    • B01J27/30—Regeneration or reactivation of catalysts comprising compounds of sulfur, selenium or tellurium
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/205—Metal content
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • C10G2300/701—Use of spent catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/80—Additives
    • C10G2300/802—Diluents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

Methods for preparing and an improved slurry catalyst feed system for heavy oil upgraded are provided. The catalyst feed system comprises a fresh slurry catalyst and a deoiled spent catalyst in an amount of at least 10% the catalyst feed system. The deoiled spent catalyst is a slurry catalyst that has been used in a hydroprocessing operation with more than 10% but less than 80% of original catalytic activity, and containing less than 10 wt. % soluble hydrocarbons as unconverted heavy oil feed. In one embodiment, the deoiled spent catalyst is first treated with a solution containing at least one of plain water, a mineral acid, an oxidizing agent, and combinations thereof to reduce the concentration of at least one metal contaminant in the deoiled spent catalyst by at least 40%.
PCT/US2012/054723 2011-09-15 2012-09-12 Hydroprocessing catalysts and methods for making thereof Ceased WO2013039950A2 (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
RU2014114844/04A RU2014114844A (en) 2011-09-15 2012-09-12 HYDRAULIC CATALYSTS AND METHODS FOR THEIR MANUFACTURE
JP2014530742A JP2014527116A (en) 2011-09-15 2012-09-12 Hydrotreating catalyst and method for producing the same
BR112014006174A BR112014006174A2 (en) 2011-09-15 2012-09-12 hydroprocessing catalysts and methods for their manufacture
SG11201400662VA SG11201400662VA (en) 2011-09-15 2012-09-12 Hydroprocessing catalysts and methods for making thereof
CA2848508A CA2848508A1 (en) 2011-09-15 2012-09-12 Hydroprocessing catalysts and methods for making thereof
MX2014003158A MX2014003158A (en) 2011-09-15 2012-09-12 HYDROPROCESSING CATALYSTS AND METHODS FOR MANUFACTURING
KR1020147009582A KR20140064948A (en) 2011-09-15 2012-09-12 Hydroprocessing catalysts and methods for making thereof
CN201280051948.9A CN103906828A (en) 2011-09-15 2012-09-12 Hydroprocessing catalysts and methods for making thereof
EP12831213.9A EP2756057A4 (en) 2011-09-15 2012-09-12 HYDROTREATING CATALYSTS AND METHOD FOR THE PRODUCTION THEREOF

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US13/233,455 2011-09-15
US13/233,491 US8927448B2 (en) 2009-07-21 2011-09-15 Hydroprocessing catalysts and methods for making thereof
US13/233,477 2011-09-15
US13/233,477 US9068132B2 (en) 2009-07-21 2011-09-15 Hydroprocessing catalysts and methods for making thereof
US13/233,491 2011-09-15
US13/233,455 US8759242B2 (en) 2009-07-21 2011-09-15 Hydroprocessing catalysts and methods for making thereof

Publications (2)

Publication Number Publication Date
WO2013039950A2 WO2013039950A2 (en) 2013-03-21
WO2013039950A3 true WO2013039950A3 (en) 2013-06-27

Family

ID=47883931

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2012/054723 Ceased WO2013039950A2 (en) 2011-09-15 2012-09-12 Hydroprocessing catalysts and methods for making thereof

Country Status (10)

Country Link
EP (1) EP2756057A4 (en)
JP (1) JP2014527116A (en)
KR (1) KR20140064948A (en)
CN (1) CN103906828A (en)
BR (1) BR112014006174A2 (en)
CA (1) CA2848508A1 (en)
MX (1) MX2014003158A (en)
RU (1) RU2014114844A (en)
SG (1) SG11201400662VA (en)
WO (1) WO2013039950A2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI130335B (en) 2019-12-23 2023-06-26 Neste Oyj Catalytic hydrotreating of feedstocks

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0541994A1 (en) * 1991-11-05 1993-05-19 Idemitsu Kosan Company Limited A process for regenerating hydrocarbon oil hydrogenation catalysts
US5888919A (en) * 1996-11-25 1999-03-30 Bartholic; David B. Process for zeolitic catalyst reactivation
US7101473B2 (en) * 2002-05-31 2006-09-05 Engelhard Corporation Method of enhancing the activity of FCC catalysts
US20080135450A1 (en) * 2006-12-06 2008-06-12 Chevron U.S.A. Inc. Integrated unsupported slurry catalyst preconditioning process
US7431824B2 (en) * 2004-09-10 2008-10-07 Chevron U.S.A. Inc. Process for recycling an active slurry catalyst composition in heavy oil upgrading

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3926778A (en) * 1972-12-19 1975-12-16 Mobil Oil Corp Method and system for controlling the activity of a crystalline zeolite cracking catalyst
US4090948A (en) * 1977-01-17 1978-05-23 Schwarzenbek Eugene F Catalytic cracking process
US5589057A (en) * 1989-07-19 1996-12-31 Chevron U.S.A. Inc. Method for extending the life of hydroprocessing catalyst
US7485267B2 (en) * 2005-07-29 2009-02-03 Chevron U.S.A. Inc. Process for metals recovery from spent catalyst
US8551323B2 (en) * 2009-08-31 2013-10-08 Chevron U.S.A. Inc. Systems and methods for hydroprocessing a heavy oil feedstock

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0541994A1 (en) * 1991-11-05 1993-05-19 Idemitsu Kosan Company Limited A process for regenerating hydrocarbon oil hydrogenation catalysts
US5888919A (en) * 1996-11-25 1999-03-30 Bartholic; David B. Process for zeolitic catalyst reactivation
US7101473B2 (en) * 2002-05-31 2006-09-05 Engelhard Corporation Method of enhancing the activity of FCC catalysts
US7431824B2 (en) * 2004-09-10 2008-10-07 Chevron U.S.A. Inc. Process for recycling an active slurry catalyst composition in heavy oil upgrading
US20080135450A1 (en) * 2006-12-06 2008-06-12 Chevron U.S.A. Inc. Integrated unsupported slurry catalyst preconditioning process

Also Published As

Publication number Publication date
EP2756057A4 (en) 2015-06-24
CA2848508A1 (en) 2013-03-21
RU2014114844A (en) 2015-10-20
CN103906828A (en) 2014-07-02
JP2014527116A (en) 2014-10-09
KR20140064948A (en) 2014-05-28
MX2014003158A (en) 2014-04-30
BR112014006174A2 (en) 2017-04-04
WO2013039950A2 (en) 2013-03-21
SG11201400662VA (en) 2014-04-28
EP2756057A2 (en) 2014-07-23

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