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MX2014003158A - HYDROPROCESSING CATALYSTS AND METHODS FOR MANUFACTURING - Google Patents

HYDROPROCESSING CATALYSTS AND METHODS FOR MANUFACTURING

Info

Publication number
MX2014003158A
MX2014003158A MX2014003158A MX2014003158A MX2014003158A MX 2014003158 A MX2014003158 A MX 2014003158A MX 2014003158 A MX2014003158 A MX 2014003158A MX 2014003158 A MX2014003158 A MX 2014003158A MX 2014003158 A MX2014003158 A MX 2014003158A
Authority
MX
Mexico
Prior art keywords
catalyst
depleted
feed system
methods
manufacturing
Prior art date
Application number
MX2014003158A
Other languages
Spanish (es)
Inventor
Shuwu Yang
Julie Chabot
Bruce Edward Reynolds
Bo Kou
Original Assignee
Chevron Usa Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/233,477 external-priority patent/US9068132B2/en
Priority claimed from US13/233,455 external-priority patent/US8759242B2/en
Priority claimed from US13/233,491 external-priority patent/US8927448B2/en
Application filed by Chevron Usa Inc filed Critical Chevron Usa Inc
Publication of MX2014003158A publication Critical patent/MX2014003158A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/60—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/70—Wet oxidation of material submerged in liquid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/14—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing with moving solid particles
    • C10G45/16—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing with moving solid particles suspended in the oil, e.g. slurries
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/24—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions with moving solid particles
    • C10G47/26—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions with moving solid particles suspended in the oil, e.g. slurries
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/28—Regeneration or reactivation
    • B01J27/30—Regeneration or reactivation of catalysts comprising compounds of sulfur, selenium or tellurium
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/205—Metal content
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • C10G2300/701—Use of spent catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/80—Additives
    • C10G2300/802—Diluents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

Se proporcionan métodos para preparar un sistema de alimentación de catalizador en suspensión mejorado para aceite pesado mejorado. El sistema de alimentación de catalizador comprende un catalizador en suspensión nuevo y un catalizador agotado desaceitado en una cantidad de al menos el 10 % del sistema de alimentación de catalizador. El catalizador agotado desaceitado es un catalizador en suspensión que se ha usado en una operación de hidroprocesamiento con más del 10 % pero menos del 80 % de la actividad catalítica original, y que contiene menos del 10 % en peso de hidrocarburos solubles como una alimentación de aceite pesado no convertido. En una modalidad, el catalizador agotado desaceitado se trata en primer lugar con una solución que contiene al menos uno de agua clara, un aceite mineral, un agente de oxidación y combinaciones de estos para reducir la concentración de al menos un contaminante metálico en el catalizador agotado desaceitado en al menos un 40 %.Methods for preparing an improved suspension catalyst feed system for improved heavy oil are provided. The catalyst feed system comprises a new suspended catalyst and a depleted spent catalyst in an amount of at least 10% of the catalyst feed system. The depleted depleted catalyst is a suspended catalyst that has been used in a hydroprocessing operation with more than 10% but less than 80% of the original catalytic activity, and which contains less than 10% by weight of soluble hydrocarbons as a feed of Heavy oil not converted. In one embodiment, the depleted depleted catalyst is first treated with a solution containing at least one of clear water, a mineral oil, an oxidizing agent and combinations thereof to reduce the concentration of at least one metal contaminant in the catalyst. out of stock depleted by at least 40%.

MX2014003158A 2011-09-15 2012-09-12 HYDROPROCESSING CATALYSTS AND METHODS FOR MANUFACTURING MX2014003158A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US13/233,477 US9068132B2 (en) 2009-07-21 2011-09-15 Hydroprocessing catalysts and methods for making thereof
US13/233,455 US8759242B2 (en) 2009-07-21 2011-09-15 Hydroprocessing catalysts and methods for making thereof
US13/233,491 US8927448B2 (en) 2009-07-21 2011-09-15 Hydroprocessing catalysts and methods for making thereof
PCT/US2012/054723 WO2013039950A2 (en) 2011-09-15 2012-09-12 Hydroprocessing catalysts and methods for making thereof

Publications (1)

Publication Number Publication Date
MX2014003158A true MX2014003158A (en) 2014-04-30

Family

ID=47883931

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2014003158A MX2014003158A (en) 2011-09-15 2012-09-12 HYDROPROCESSING CATALYSTS AND METHODS FOR MANUFACTURING

Country Status (10)

Country Link
EP (1) EP2756057A4 (en)
JP (1) JP2014527116A (en)
KR (1) KR20140064948A (en)
CN (1) CN103906828A (en)
BR (1) BR112014006174A2 (en)
CA (1) CA2848508A1 (en)
MX (1) MX2014003158A (en)
RU (1) RU2014114844A (en)
SG (1) SG11201400662VA (en)
WO (1) WO2013039950A2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI130335B (en) 2019-12-23 2023-06-26 Neste Oyj Catalytic hydrotreating of feedstocks

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3926778A (en) * 1972-12-19 1975-12-16 Mobil Oil Corp Method and system for controlling the activity of a crystalline zeolite cracking catalyst
US4090948A (en) * 1977-01-17 1978-05-23 Schwarzenbek Eugene F Catalytic cracking process
US5589057A (en) * 1989-07-19 1996-12-31 Chevron U.S.A. Inc. Method for extending the life of hydroprocessing catalyst
JP3110525B2 (en) * 1991-11-05 2000-11-20 出光興産株式会社 Method for regenerating hydrocarbon oil hydrotreating catalyst
US5888919A (en) * 1996-11-25 1999-03-30 Bartholic; David B. Process for zeolitic catalyst reactivation
US7101473B2 (en) * 2002-05-31 2006-09-05 Engelhard Corporation Method of enhancing the activity of FCC catalysts
US7431824B2 (en) * 2004-09-10 2008-10-07 Chevron U.S.A. Inc. Process for recycling an active slurry catalyst composition in heavy oil upgrading
US7485267B2 (en) * 2005-07-29 2009-02-03 Chevron U.S.A. Inc. Process for metals recovery from spent catalyst
US7771584B2 (en) * 2006-12-06 2010-08-10 Chevron U.S.A. Inc. Integrated unsupported slurry catalyst preconditioning process
US8551323B2 (en) * 2009-08-31 2013-10-08 Chevron U.S.A. Inc. Systems and methods for hydroprocessing a heavy oil feedstock

Also Published As

Publication number Publication date
EP2756057A2 (en) 2014-07-23
JP2014527116A (en) 2014-10-09
CN103906828A (en) 2014-07-02
SG11201400662VA (en) 2014-04-28
CA2848508A1 (en) 2013-03-21
WO2013039950A2 (en) 2013-03-21
BR112014006174A2 (en) 2017-04-04
EP2756057A4 (en) 2015-06-24
WO2013039950A3 (en) 2013-06-27
KR20140064948A (en) 2014-05-28
RU2014114844A (en) 2015-10-20

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