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WO2013008189A3 - Phosphate de manganese lithie et materiau composite le comprenant - Google Patents

Phosphate de manganese lithie et materiau composite le comprenant Download PDF

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Publication number
WO2013008189A3
WO2013008189A3 PCT/IB2012/053541 IB2012053541W WO2013008189A3 WO 2013008189 A3 WO2013008189 A3 WO 2013008189A3 IB 2012053541 W IB2012053541 W IB 2012053541W WO 2013008189 A3 WO2013008189 A3 WO 2013008189A3
Authority
WO
WIPO (PCT)
Prior art keywords
manganese phosphate
composite material
same
lithiated manganese
lithiated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/IB2012/053541
Other languages
English (en)
Other versions
WO2013008189A2 (fr
Inventor
Thibaud GUTEL
Etienne RADVANYI
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Original Assignee
Commissariat a lEnergie Atomique CEA
Commissariat a lEnergie Atomique et aux Energies Alternatives CEA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Commissariat a lEnergie Atomique CEA, Commissariat a lEnergie Atomique et aux Energies Alternatives CEA filed Critical Commissariat a lEnergie Atomique CEA
Priority to KR1020147002727A priority Critical patent/KR20140082635A/ko
Priority to EP12758609.7A priority patent/EP2731910A2/fr
Priority to US14/232,061 priority patent/US20140295281A1/en
Publication of WO2013008189A2 publication Critical patent/WO2013008189A2/fr
Publication of WO2013008189A3 publication Critical patent/WO2013008189A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/45—Phosphates containing plural metal, or metal and ammonium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

L'invention concerne un phosphate de manganèse lithié ainsi qu'un matériau composite le comprenant. Le phosphate de manganèse lithié de l'invention à la formule I suivante : Li1-xMn1-yDyPO4 dans laquelle D représente un élément dopant, 0 ≤ x < 1, 0 ≤ y < 0,15, est composé de particules non agglomérées ayant la forme de plaquettes. L'invention trouve application dans le domaine des batteries au lithium, en particulier.
PCT/IB2012/053541 2011-07-12 2012-07-11 Phosphate de manganese lithie et materiau composite le comprenant Ceased WO2013008189A2 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
KR1020147002727A KR20140082635A (ko) 2011-07-12 2012-07-11 리튬 인산 망간 및 이를 포함하는 복합 재료
EP12758609.7A EP2731910A2 (fr) 2011-07-12 2012-07-11 Phosphate de manganese lithie et materiau composite le comprenant
US14/232,061 US20140295281A1 (en) 2011-07-12 2012-07-11 Lithiated Manganese Phosphate and Composite Material Comprising Same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1156340A FR2977887B1 (fr) 2011-07-12 2011-07-12 Phosphate de manganese lithie et materiau composite le comprenant
FR1156340 2011-07-12

Publications (2)

Publication Number Publication Date
WO2013008189A2 WO2013008189A2 (fr) 2013-01-17
WO2013008189A3 true WO2013008189A3 (fr) 2013-05-23

Family

ID=46832523

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2012/053541 Ceased WO2013008189A2 (fr) 2011-07-12 2012-07-11 Phosphate de manganese lithie et materiau composite le comprenant

Country Status (5)

Country Link
US (1) US20140295281A1 (fr)
EP (1) EP2731910A2 (fr)
KR (1) KR20140082635A (fr)
FR (1) FR2977887B1 (fr)
WO (1) WO2013008189A2 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015148300A1 (fr) * 2014-03-25 2015-10-01 Temple University-Of The Commonwealth System Of Higher Education Compositions d'électrolyte cristallin solides-souples
KR20160083630A (ko) * 2014-12-31 2016-07-12 삼성에스디아이 주식회사 리튬이차전지용 올리빈형 양극 활물질, 그것의 제조방법 및 그것을 포함하는 리튬이차전지
US10680242B2 (en) 2016-05-18 2020-06-09 Semiconductor Energy Laboratory Co., Ltd. Method for manufacturing positive electrode active material, and lithium ion battery
CN112125292A (zh) * 2020-08-14 2020-12-25 中国科学院金属研究所 一种磷酸锰铁锂的水热合成方法
CN116374985A (zh) * 2023-03-28 2023-07-04 陕西创普斯新能源科技有限公司 一种碳包覆磷酸锰铁锂的制备方法
CN119176534A (zh) * 2024-09-30 2024-12-24 中国海洋大学 一种利用表面活性剂优化橄榄石型正极材料的制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007058432A1 (fr) * 2005-11-21 2007-05-24 Jae Kook Kim Methode pour synthetiser une matiere d'electrode, faisant appel a un procede de production de polyols
WO2007113624A1 (fr) * 2006-04-06 2007-10-11 High Power Lithium S.A. Synthese de nanoparticules de materiau positif de phosphate de metal de lithium pour batterie secondaire au lithium
EP2015382A1 (fr) * 2007-07-13 2009-01-14 High Power Lithium S.A. Matériau à cathode de phosphate de manganèse de lithium recouvert de carbone
US20090117020A1 (en) * 2007-11-05 2009-05-07 Board Of Regents, The University Of Texas System Rapid microwave-solvothermal synthesis and surface modification of nanostructured phospho-olivine cathodes for lithium ion batteries

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2276698A1 (fr) * 2008-04-14 2011-01-26 Dow Global Technologies Inc. Nanocomposites de lithium métal phosphate/carbone comme matières actives de cathode pour batteries au lithium secondaires
JP4959648B2 (ja) * 2008-08-04 2012-06-27 株式会社日立製作所 非水電解質二次電池

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007058432A1 (fr) * 2005-11-21 2007-05-24 Jae Kook Kim Methode pour synthetiser une matiere d'electrode, faisant appel a un procede de production de polyols
WO2007113624A1 (fr) * 2006-04-06 2007-10-11 High Power Lithium S.A. Synthese de nanoparticules de materiau positif de phosphate de metal de lithium pour batterie secondaire au lithium
EP2015382A1 (fr) * 2007-07-13 2009-01-14 High Power Lithium S.A. Matériau à cathode de phosphate de manganèse de lithium recouvert de carbone
US20090117020A1 (en) * 2007-11-05 2009-05-07 Board Of Regents, The University Of Texas System Rapid microwave-solvothermal synthesis and surface modification of nanostructured phospho-olivine cathodes for lithium ion batteries

Non-Patent Citations (9)

* Cited by examiner, † Cited by third party
Title
"HPL PRESENTATION: NANO-TECHNOLOGY SOLUTIONS ENABLING INDUSTRIAL BATTERY APPLICATIONS:LIMNPO4 SYNTHESIZED VIA POLYOL", INTERNET CITATION, 2007, XP002454687, Retrieved from the Internet <URL:http://www.highpowerlithium.com/images/stories/HPL_presentation/HPL_C altech_2007.pdf> [retrieved on 20071011] *
A. VADIVEL MURUGAN ET AL: "Dimensionally Modulated, Single-Crystalline LiMPO 4 (M= Mn, Fe, Co, and Ni) with Nano-Thumblike Shapes for High-Power Energy Storage", INORGANIC CHEMISTRY, vol. 48, no. 3, 2 February 2009 (2009-02-02), pages 946 - 952, XP055022063, ISSN: 0020-1669, DOI: 10.1021/ic8015723 *
DELACOURT C ET AL: "One-step low-temperature route for the preparation of electrochemically active LiMnPO4 powders", CHEMISTRY OF MATERIALS, AMERICAN CHEMICAL SOCIETY, WASHINGTON, US, vol. 16, no. 1, 12 December 2003 (2003-12-12), pages 93 - 99, XP002363774, ISSN: 0897-4756, DOI: 10.1021/CM030347B *
HONGMEI JI, GANG YANG, HUAN NI, SOUMYAJIT ROY, JOAO PINTO, XUEFAN JIANG: "General synthesis and morphology control of LiMnPO4 nanocrystals via microwave-hydrothermal route", ELECTROCHIMICA ACTA, vol. 56, 28 January 2011 (2011-01-28), pages 3093 - 3100, XP002671633 *
HYUN-KON SONG ET AL: "Recent Progress in Nanostructured Cathode Materials for Lithium Secondary Batteries", ADVANCED FUNCTIONAL MATERIALS, WILEY - V C H VERLAG GMBH & CO. KGAA, DE, vol. 20, no. 22, 23 November 2010 (2010-11-23), pages 3818 - 3834, XP001558805, ISSN: 1616-301X, DOI: 10.1002/ADFM.201000231 *
KIM ET AL: "Synthesis of lithium manganese phosphate nanoparticle and its properties", JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, PERGAMON PRESS, LONDON, GB, vol. 68, no. 5-6, 1 May 2007 (2007-05-01), pages 1203 - 1206, XP022122228, ISSN: 0022-3697 *
KUPPAN SARAVANAN ET AL: "Storage performance of LiFe1â â â x Mn x PO4 nanoplates (xâ =â 0, 0.5, and 1)", JOURNAL OF SOLID STATE ELECTROCHEMISTRY ; CURRENT RESEARCH AND DEVELOPMENT IN SCIENCE AND TECHNOLOGY, SPRINGER, BERLIN, DE, vol. 14, no. 10, 19 March 2010 (2010-03-19), pages 1755 - 1760, XP019805865, ISSN: 1433-0768 *
S. K. MARTHA ET AL: "LiMnPO[sub 4] as an Advanced Cathode Material for Rechargeable Lithium Batteries", JOURNAL OF THE ELECTROCHEMICAL SOCIETY, vol. 156, no. 7, 1 January 2009 (2009-01-01), pages A541 - A552, XP055022062, ISSN: 0013-4651, DOI: 10.1149/1.3125765 *
WANG D ET AL: "High-performance, nano-structured LiMnPO4 synthesized via a polyol method", JOURNAL OF POWER SOURCES, ELSEVIER SA, CH, vol. 189, no. 1, 1 April 2009 (2009-04-01), pages 624 - 628, XP025982763, ISSN: 0378-7753, [retrieved on 20081001], DOI: 10.1016/J.JPOWSOUR.2008.09.077 *

Also Published As

Publication number Publication date
FR2977887B1 (fr) 2018-01-26
EP2731910A2 (fr) 2014-05-21
WO2013008189A2 (fr) 2013-01-17
FR2977887A1 (fr) 2013-01-18
US20140295281A1 (en) 2014-10-02
KR20140082635A (ko) 2014-07-02

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