WO2010110417A1 - アクチュエータ装置及び入力装置 - Google Patents
アクチュエータ装置及び入力装置 Download PDFInfo
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- WO2010110417A1 WO2010110417A1 PCT/JP2010/055350 JP2010055350W WO2010110417A1 WO 2010110417 A1 WO2010110417 A1 WO 2010110417A1 JP 2010055350 W JP2010055350 W JP 2010055350W WO 2010110417 A1 WO2010110417 A1 WO 2010110417A1
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- WIPO (PCT)
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- actuator
- free end
- fulcrum
- base member
- protrusion
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81B—MICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
- B81B3/00—Devices comprising flexible or deformable elements, e.g. comprising elastic tongues or membranes
- B81B3/0064—Constitution or structural means for improving or controlling the physical properties of a device
- B81B3/0067—Mechanical properties
- B81B3/0072—For controlling internal stress or strain in moving or flexible elements, e.g. stress compensating layers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B81—MICROSTRUCTURAL TECHNOLOGY
- B81B—MICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
- B81B2203/00—Basic microelectromechanical structures
- B81B2203/01—Suspended structures, i.e. structures allowing a movement
- B81B2203/0118—Cantilevers
Definitions
- the present invention relates to an actuator device and an input device including an actuator that has one end as a fixed end and the other end as a free end and can be bent when a voltage is applied.
- 14 (a) and 14 (b) are conceptual diagrams (cross-sectional views) of the input device for explaining the conventional problems.
- 14A includes an actuator 2, a base member 3, a support portion 4, a key top 5, a housing 6, and the like.
- each actuator 2 is supported by the support portion 4 in a cantilever manner.
- the actuator 2 includes an electrolyte layer and a pair of electrode layers provided on both sides in the thickness direction of the electrolyte layer. When a voltage is applied between the pair of electrode layers on the fixed end side, it is configured to bend upward as shown in FIG. 14A (see also Patent Document 1).
- a curved actuator is difficult to achieve both displacement and generated load.
- the actuator 2 has a low elasticity and low rigidity compared to a piezoelectric ceramic, a shape memory alloy, and the like, and easily obtains a large displacement. There was a problem that it was difficult to exert power. Further, if the actuator 2 has a higher elastic modulus and the element thickness is increased, the generated load can be increased, but the amount of displacement is reduced accordingly.
- an object of the present invention is to provide an actuator device and an input device that can obtain both sufficient displacement and a large generated load.
- the present invention includes an actuator having one end as a fixed end and the other end as a free end, and is bendable when a voltage is applied;
- An actuator device comprising a base member having a fixing portion for fixing a fixed end of the actuator;
- a fulcrum portion serving as a fulcrum of displacement between the fixed end and the free end of the actuator when a force is applied to the free end in a direction opposite to the bending direction with the actuator being bent. Is formed.
- the element length of the actuator when the actuator is curved, the element length of the actuator can be formed sufficiently long, and the displacement can be sufficiently obtained.
- a fulcrum portion serving as a fulcrum of displacement is formed between the fixed end and the free end of the actuator, and the element length from the fulcrum portion to the free end is formed.
- the generated load can be increased by the material mechanical principle.
- both a sufficient displacement and a large generated load can be obtained.
- a projecting portion that forms the fulcrum portion by contacting the base member can be provided between the fixed end and the free end of the actuator.
- the protrusion is formed integrally with an electrode layer constituting the polymer actuator. As a result, the manufacturing cost can be reduced, and the reliability can be increased because of being integrated.
- the base member may be provided with a support portion that forms the fulcrum portion by making point contact or line contact with the actuator at a portion between the fixed end and the free end of the actuator. You can also. If the fulcrum portion is provided on the base member side and not provided on the actuator side, an actuator device capable of obtaining a large generated load without changing the performance such as the displacement amount of the actuator can be obtained.
- the actuator is a polymer actuator that has an electrolyte layer and a pair of electrodes provided on both surfaces in the thickness direction of the electrolyte layer, and bends when a voltage is applied between the pair of electrodes. It is preferably applicable to the configuration.
- the elastic modulus or rigidity of the fulcrum portion is higher than that of the polymer actuator. A large and stable generated load can be obtained more effectively.
- the fulcrum portion is provided near the free end of the actuator. Thereby, generated load can be made larger.
- the base member is driven by being energized in contact with the electrode layer of the polymer actuator when the free end side of the curved polymer actuator is pressed and displaced in a direction opposite to the bending direction. It is preferable that an electrode portion capable of applying a voltage is provided. Moreover, it is preferable that the said electrode part serves as the said fulcrum part.
- An input device includes the actuator device according to any one of the above and an operation unit provided to face the actuator in a height direction.
- the operation unit is supported to be movable in the height direction, When the free end of the actuator is bent in the direction of the operating portion, the actuator is fixed when the operating portion is moved in the direction of the actuator and the free end side is pressed and displaced in the direction opposite to the bending direction.
- a fulcrum portion serving as a fulcrum of displacement is formed between the end and the free end.
- the fulcrum portion serving as a fulcrum of displacement is formed between the fixed end and the free end of the actuator, the generated load can be increased according to the material mechanical principle.
- the feeling of pressing when the operation unit is pressed can be made better than before.
- both a sufficient displacement and a large generated load can be obtained.
- FIG. 1A and 1B are diagrams showing a configuration of an actuator device according to a first embodiment.
- FIG. 1A is a partial cross-sectional view when the polymer actuator is not operating
- FIG. 4C is a partial cross-sectional view illustrating a state where the free end side of the actuator is pressed and the actuator and the protrusion are in contact with each other.
- the actuator 10 in the present embodiment includes, for example, a polymer actuator that includes an electrolyte layer 11 and electrode layers 12 and 13 formed on both side surfaces in the thickness direction of the electrolyte layer 11. It is.
- the actuator 10 of the present embodiment includes an electrolyte layer 11 having an ionic liquid and a base polymer, and a first electrode layer 12 and a second electrode layer 13 having a conductive filler such as a carbon nanotube, an ionic liquid and a base polymer. Configured.
- the first electrode layer 12 is an electrode layer on the side facing the base member 17.
- PVDF polyvinylidene fluoride
- PMMA polymethyl methacrylate
- the electrolyte layer 11 may include an ion exchange resin and a polar organic solvent containing a salt or a liquid organic compound that is an ionic liquid.
- the ion exchange resin is preferably a cation exchange resin.
- the anion is fixed and the cation can move freely.
- the cation exchange resin a resin obtained by introducing a functional group such as a sulfonic acid group or a carboxyl group into a resin such as polyethylene, polystyrene, or fluororesin can be preferably used.
- the electrode layers 12 and 13 may be formed by plating or sputtering with an electrode material such as gold or platinum.
- one end (fixed end) 14 of the actuator 10 is fixedly supported by the fixed portion 15.
- the actuator 10 is supported in a cantilever manner, and the free end 16 side is supported so as to be able to bend upward.
- a base member 17 is provided on the side opposite to the bending direction of the actuator 10.
- the base member 17 and the fixing part 15 may be formed separately or integrally.
- a protrusion (fulcrum) 60 is provided on the surface of the base member 17.
- the first electrode layer 12 side is a negative electrode
- the second electrode layer 13 side is a positive electrode.
- the volume tends to expand at a position biased toward the first electrode layer 12 side. That is, since an expansion stress is generated on the first electrode layer 12 side and an expansion strain is generated based on the expansion stress, a bending stress is generated in the actuator 10 so that the actuator 10 moves upward as shown in FIG. Curving towards.
- the actuator 10 When displaced by a predetermined amount, the actuator 10 comes into contact with the protrusion 60 as shown in FIG. As shown in FIG. 1C, the protrusion 60 is provided at a position facing the midway portion 21 between the fixed end 14 and the free end 16 of the actuator 10.
- the protrusion 60 forms a fulcrum part that contacts the actuator 10 and serves as a fulcrum.
- the element length of the actuator 10 from the protrusion 60 to the free end 16 is shorter than the element length from the fixed end 14 to the free end 16, and from the state of FIG. Further, a reaction force (hereinafter referred to as generated load) when a force in the direction of the base member 17 is applied to the free end 16 side of the actuator 10 can be increased.
- generated load a reaction force
- the element length of the actuator 10 can be made sufficiently long without increasing the elastic modulus and increasing the element thickness in order to increase the generated load. In the curved state in FIG. The sufficient displacement can be obtained. Therefore, according to the present embodiment, both a sufficient displacement and a large generated load can be obtained.
- the second embodiment shown in FIG. 3 is an example in which a protrusion 61 is provided on the actuator 10 side, unlike FIG.
- the protrusion 61 is provided in the middle of the lower surface of the actuator 10 (the surface facing the base member 17).
- the generated load can be increased similarly to FIG.
- the protrusion 61 may be bonded to the lower surface side of the actuator 10 with an adhesive or the like.
- the protrusion 61 is formed integrally with the first electrode layer 12 as shown in FIG. Therefore, the protrusion 61 is formed with conductivity.
- the first electrode layer 12 and the protruding portion 61 can be integrally formed with a mold.
- the protrusion 61 protruding integrally from the first electrode layer 12 can be formed by reducing the pressure applied to the formation region of the protrusion 61.
- the protrusion 61 may be formed separately from the same electrode material as that of the first electrode layer 12, and then the protrusion 61 may be integrated with the first electrode layer 12 by adhesion or press bonding, for example.
- the manufacturing cost can be reduced, and the reliability can be improved, such as being difficult to remove even when the protruding portion 61 receives a force.
- the elastic modulus or rigidity of the protrusions 60 and 61 shown in FIGS. 1 and 3 is higher than that of the actuator 10.
- the protrusion 61 is provided on the actuator 10 side
- casting is separately performed in two steps in order to increase the filling rate (density) of the electrode material and the like at the protrusion 61.
- an aggregate such as a wire is put in the structure of the protrusion 61.
- the displacement fulcrum can be strengthened, and a large and stable generated load can be obtained more effectively.
- the protrusion 60 can be easily formed on the surface of the base member 17 by adhesion or the like. Further, when the protrusion 60 is provided on the base member 17 side and not provided on the actuator 10 side, an actuator device capable of obtaining a large generated load without changing the performance of the displacement amount of the actuator 10 can be obtained. .
- FIG. 5 shows a partial cross-sectional view of the polymer actuator of the third embodiment.
- the electrode portion 18 is provided on the surface of the base member 17.
- the electrode portion 18 is connected to a drive circuit 20 connected between the electrode layers 12 and 13 on the fixed end 14 side of the actuator 10 via a power source.
- the drive circuit 20 is provided with a diode.
- the protrusion 61 provided on the actuator 10 is conductive.
- the material of the electrode layers 12 and 13 is not limited.
- a carbon film may be used, or an electrode material such as gold or platinum may be formed by plating or sputtering.
- FIG. 6 shows a potential difference in the conventional structure.
- the potential difference reduced by the voltage drop can be effectively increased from the middle part 21 of the actuator 10 to the free end 16 side as shown in FIG. Therefore, even if a carbon film is used for the electrode layers 12 and 13, if this embodiment is used, the generated load can be effectively increased.
- the carbon film includes, for example, carbon nanotubes.
- the driving voltage is higher than the driving voltage applied between the pair of electrode layers 12 and 13 from the driving circuit 20. If it controls so that it may apply to 21, after a contact energization, a bigger generated load can be obtained.
- the plurality of protrusions 62 and 63 may be arranged at intervals from the fixed end 14 side of the actuator 10 toward the free end 16. With such a configuration, the generated load can be increased stepwise multiple times as the curved actuator 10 is displaced in the direction of the base member 17.
- the actuator 10 contacts the projection 62 to form a fulcrum portion where the projection 62 serves as a fulcrum, so that an effect of increasing the generated load can be obtained.
- a fulcrum portion where the projection 63 serves as a fulcrum is formed in contact with the projection 63 on the free end 16 side than 62, and a larger generated load can be obtained.
- the protrusions 62 and 63 are all formed on the base member 17 side, or formed on the actuator 10 side, or some protrusions are on the base member 17 side and the remaining protrusions are on the actuator 10 side. It is also possible to form.
- FIG. 8 is a plan view of the actuator 10 and the protrusion 60.
- the protrusion 60 is formed to extend long in the width direction of the actuator 10.
- the projection part 60 is formed in circular shape.
- the planar shape of the protrusion 60 is not particularly limited, the displacement fulcrum can be provided over the entire width of the actuator 10 if the actuator 10 is formed so as to cross the width direction like the protrusion 60 in FIG. The generated load can be increased more effectively.
- the protrusion is formed near the free end 16 of the actuator 10. By forming the protrusion on the side close to the free end 16 in this way, the displacement fulcrum can be on the side close to the free end, so that the generated load can be further increased.
- an elastic body 65 is interposed between the protrusion 60 and the base member 17.
- the elastic body 65 becomes a cushion when the actuator 10 comes into contact with the protrusion 60, and the actuator 10 can be protected (improvement of durability). It is also possible to change the push feeling in the device.
- the formation position of the elastic body 65 is not limited. However, in the embodiment in which contact energization is performed between the electrode portion 18 and the protrusion 61 as in the embodiment of FIG. 5, it is necessary to form the elastic body 65 so as not to inhibit the contact energization. It is.
- the shape of the actuator 10 is not particularly limited as long as it has a fixed end and a free end and can be bent and deformed. It may be a strip shape or a shape provided with a slit.
- the position for supporting the actuator 10 is not limited.
- the fixing portion 53 may be provided at an intermediate position of the actuator 10, and both sides thereof may be free ends 54 and 56 (butterfly structure).
- the fulcrum portions are all described as protruding shapes, but the fulcrum portions are not limited to the protruding shapes.
- base members 70 and 70 that face each other with a gap in the width direction, a fixing portion 71 that connects the base members 70 and 70 and fixes the actuator 10, and base members 70 and 70.
- the formation position of the protrusion 60 is lower than the fixed end 14 of the actuator 10 when the actuator 10 is not operating (a position away from the bending direction of the actuator 10). May be located.
- the free end 16 bends upward, and when the free end 16 is pressed downward, the actuator 10 contacts the protrusion 60 at a position below the fixed end 14 as shown in FIG. To do.
- FIG. 12C shows a state further pressed from FIG. The amount of variation of the actuator 10 can be increased by the form of FIG.
- the electrode layer of the actuator 10 and the electrode portion 18 formed on the base member 17 may be in contact or non-contact.
- the continuity between the protruding portion 61 and the electrode portion 18 may be a structure in which crushing stress is performed.
- the actuator device of this embodiment can be applied to the input device 50 as shown in FIG.
- a plurality of actuators 10 are provided using the actuator device shown in FIG. 1, and a protrusion (fulcrum) 60 is provided on the base member 17.
- a key top (operation unit) 51 is provided on the bending direction side (upper side) of the actuator 10.
- the actuator device is housed in a housing 52, and the key top 51 is supported so as to be movable in the vertical direction through a hole 52a formed in the housing 52.
- each actuator 10 is pressed and displaced downward as shown in FIG.
- each actuator 10 is in contact with the protrusion 60.
- the projection 60 serves as a fulcrum of displacement, a large generated load can be obtained from each actuator 10 by the material mechanical principle, and the pressing feeling when the key top 51 is pressed is better than before. I can do it.
- the experiment of the generated load was performed using an example of an actuator device having a protrusion on the base member and a comparative example of an actuator device having no protrusion.
- the polymer actuator used in the experiment was applied to both the cantilever type shown in FIG. 1 and the butterfly structure.
- the total length of the actuator 10 was 5 mm, and in the example, the protrusion 60 was formed at a position of 3 mm from the fixed end 14 toward the free end 16.
- the total length of the actuator 10 is 10 mm, and in the case of the example, the protrusions 66 are formed at positions of 4 mm on both sides from the support portion 53 located in the center.
- the applied voltage between the electrode layers was set to 2 V or 2.5 V, the curve was bent away from the base member, and the maximum generated load obtained by pressing the free end side of the actuator 10 toward the base member was obtained.
- Table 1 The experimental results are shown in Table 1 below.
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Abstract
Description
前記アクチュエータの固定端を固定する固定部を有するベース部材とを備えたアクチュエータ装置において、
前記アクチュエータを湾曲させた状態で前記自由端に対して湾曲方向と逆の方向へ力が加わって変形された際に、前記アクチュエータの固定端と自由端との間で変位の支点となる支点部が形成されることを特徴とするものである。
前記操作部は前記高さ方向に移動可能に支持されており、
前記アクチュエータの自由端が前記操作部方向に湾曲した状態で、前記操作部を前記アクチュエータ方向へ移動させ前記自由端側が押圧されて前記湾曲方向とは逆方向へ変位した際に、前記アクチュエータの固定端と自由端との間で変位の支点となる支点部が形成されることを特徴とするものである。
その実験結果が以下の表1に示されている。
11 電解質層
12 第1電極層
13 第2電極層
14 固定端
16、54、56 自由端
17、70 ベース部材
18 電極部
20 駆動回路
21 途中部
50 入力装置
51 キートップ
60、61、62、63 突起部(支点部)
65 弾性体
72 支持部(支点部)
Claims (10)
- 一端を固定端、他端を自由端とされ、電圧を印加すると湾曲可能であるアクチュエータと、
前記アクチュエータの固定端を固定する固定部を有するベース部材とを備えたアクチュエータ装置において、
前記アクチュエータを湾曲させた状態で前記自由端に対して湾曲方向と逆の方向へ力が加わって変形された際に、前記アクチュエータの固定端と自由端との間で変位の支点となる支点部が形成されることを特徴とするアクチュエータ装置。 - 前記アクチュエータの前記固定端と前記自由端の間には、前記ベース部材と接触することによって前記支点部を形成する突起部が設けられる請求項1記載のアクチュエータ装置。
- 前記突起部は、前記高分子アクチュエータを構成する電極層と一体に形成されている請求項2記載のアクチュエータ装置。
- 前記ベース部材には、前記アクチュエータの前記固定端と前記自由端の間の部分で前記アクチュエータと点接触または線接触することによって前記支点部を形成する支持部が設けられる請求項1記載のアクチュエータ装置。
- 前記アクチュエータが、電解質層と、前記電解質層の厚さ方向の両面に設けられた一対の電極を有し、前記一対の電極間に電圧を付与すると湾曲する高分子アクチュエータである請求項1に記載のアクチュエータ装置。
- 前記支点部の弾性率あるいは剛性が、前記アクチュエータよりも高い請求項1に記載のアクチュエータ装置。
- 前記支点部は、前記アクチュエータの自由端寄りに形成される請求項1に記載のアクチュエータ装置。
- 前記ベース部材には、湾曲した前記高分子アクチュエータの前記自由端側が押圧されて前記湾曲方向と逆の方向に変位したときに前記高分子アクチュエータの前記電極層と接触通電して駆動電圧を印加可能な電極部が設けられている請求項5記載の高分子アクチュエータ装置。
- 前記電極部が前記支点部を兼ねる請求項8記載の高分子アクチュエータ装置。
- 請求項1ないし9のいずれか1項に記載のアクチュエータ装置と、前記アクチュエータの高さ方向に対向して設けられた操作部とを有し、
前記操作部は前記高さ方向に移動可能に支持されており、
前記アクチュエータの自由端が前記操作部方向に湾曲した状態で、前記操作部を前記アクチュエータ方向へ移動させ前記自由端側が押圧されて前記湾曲方向とは逆方向へ変位した際に、前記アクチュエータの固定端と自由端との間で変位の支点となる支点部が形成されることを特徴とする入力装置。
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201080009674.8A CN102334275B (zh) | 2009-03-27 | 2010-03-26 | 致动装置及输入装置 |
| JP2011506141A JP5097853B2 (ja) | 2009-03-27 | 2010-03-26 | アクチュエータ装置及び入力装置 |
| US13/230,450 US20120001520A1 (en) | 2009-03-27 | 2011-09-12 | Actuator device and input apparatus |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2009079623 | 2009-03-27 | ||
| JP2009-079623 | 2009-03-27 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US13/230,450 Continuation US20120001520A1 (en) | 2009-03-27 | 2011-09-12 | Actuator device and input apparatus |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2010110417A1 true WO2010110417A1 (ja) | 2010-09-30 |
Family
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| Application Number | Title | Priority Date | Filing Date |
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| PCT/JP2010/055350 Ceased WO2010110417A1 (ja) | 2009-03-27 | 2010-03-26 | アクチュエータ装置及び入力装置 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US20120001520A1 (ja) |
| JP (1) | JP5097853B2 (ja) |
| CN (1) | CN102334275B (ja) |
| WO (1) | WO2010110417A1 (ja) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018211981A1 (ja) | 2017-05-18 | 2018-11-22 | 東レ・ダウコーニング株式会社 | フルオロアルキル基含有硬化性オルガノポリシロキサン組成物、その硬化物および当該硬化物を備えたトランスデューサー等 |
| WO2020116440A1 (ja) | 2018-12-07 | 2020-06-11 | ダウ・東レ株式会社 | 硬化性オルガノポリシロキサン組成物、その硬化物および当該硬化物を備えたトランスデューサー等 |
| WO2024075661A1 (ja) | 2022-10-05 | 2024-04-11 | ダウ・東レ株式会社 | トランスデューサー用硬化性オルガノポリシロキサン組成物、その硬化物および当該硬化物を備えたトランスデューサー等 |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6152622B2 (ja) * | 2011-08-11 | 2017-06-28 | デクセリアルズ株式会社 | 駆動装置、レンズモジュールおよび撮像装置 |
| US20190225487A1 (en) * | 2017-08-15 | 2019-07-25 | Xergy Inc. | Micro-electro-mechanical device with ion exchange polymer |
| CN113589466B (zh) * | 2020-04-30 | 2023-03-10 | 维沃移动通信有限公司 | 驱动装置和电子设备 |
| CN113805302B (zh) * | 2020-05-28 | 2023-03-31 | 维沃移动通信有限公司 | 驱动装置和电子设备 |
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| JP2005259488A (ja) * | 2004-03-11 | 2005-09-22 | Toshihiro Hirai | 高分子アクチュエータを用いた電気素子 |
| JP2008238330A (ja) * | 2007-03-27 | 2008-10-09 | Toshiba Corp | Mems装置およびこのmems装置を有する携帯通信端末 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2005076452A1 (ja) * | 2004-02-05 | 2005-08-18 | Matsushita Electric Industrial Co., Ltd. | アクチュエータ及びアクチュエータ用平板状電極支持体の製造方法 |
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2010
- 2010-03-26 JP JP2011506141A patent/JP5097853B2/ja not_active Expired - Fee Related
- 2010-03-26 CN CN201080009674.8A patent/CN102334275B/zh not_active Expired - Fee Related
- 2010-03-26 WO PCT/JP2010/055350 patent/WO2010110417A1/ja not_active Ceased
-
2011
- 2011-09-12 US US13/230,450 patent/US20120001520A1/en not_active Abandoned
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| JPS50131572U (ja) * | 1974-04-03 | 1975-10-29 | ||
| JPS63102126U (ja) * | 1986-12-24 | 1988-07-02 | ||
| JP2005259488A (ja) * | 2004-03-11 | 2005-09-22 | Toshihiro Hirai | 高分子アクチュエータを用いた電気素子 |
| JP2008238330A (ja) * | 2007-03-27 | 2008-10-09 | Toshiba Corp | Mems装置およびこのmems装置を有する携帯通信端末 |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018211981A1 (ja) | 2017-05-18 | 2018-11-22 | 東レ・ダウコーニング株式会社 | フルオロアルキル基含有硬化性オルガノポリシロキサン組成物、その硬化物および当該硬化物を備えたトランスデューサー等 |
| WO2020116440A1 (ja) | 2018-12-07 | 2020-06-11 | ダウ・東レ株式会社 | 硬化性オルガノポリシロキサン組成物、その硬化物および当該硬化物を備えたトランスデューサー等 |
| WO2024075661A1 (ja) | 2022-10-05 | 2024-04-11 | ダウ・東レ株式会社 | トランスデューサー用硬化性オルガノポリシロキサン組成物、その硬化物および当該硬化物を備えたトランスデューサー等 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102334275A (zh) | 2012-01-25 |
| US20120001520A1 (en) | 2012-01-05 |
| JPWO2010110417A1 (ja) | 2012-10-04 |
| JP5097853B2 (ja) | 2012-12-12 |
| CN102334275B (zh) | 2014-10-29 |
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