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WO2009004917A1 - 極性基含有ポリオレフィン重合体及びその製造方法、並びに、水分散体及び離型剤組成物 - Google Patents

極性基含有ポリオレフィン重合体及びその製造方法、並びに、水分散体及び離型剤組成物 Download PDF

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Publication number
WO2009004917A1
WO2009004917A1 PCT/JP2008/061047 JP2008061047W WO2009004917A1 WO 2009004917 A1 WO2009004917 A1 WO 2009004917A1 JP 2008061047 W JP2008061047 W JP 2008061047W WO 2009004917 A1 WO2009004917 A1 WO 2009004917A1
Authority
WO
WIPO (PCT)
Prior art keywords
polyolefin polymer
independently represent
group
polar group
valency
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/061047
Other languages
English (en)
French (fr)
Inventor
Makoto Suzuki
Naoshi Nagai
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Chemicals Inc
Original Assignee
Mitsui Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsui Chemicals Inc filed Critical Mitsui Chemicals Inc
Priority to EP08777285.1A priority Critical patent/EP2166027B1/en
Priority to CN2008800215966A priority patent/CN101687944B/zh
Priority to US12/452,435 priority patent/US8513362B2/en
Priority to KR1020107002319A priority patent/KR101061686B1/ko
Priority to JP2009521573A priority patent/JP5215302B2/ja
Priority to TW097123548A priority patent/TWI348473B/zh
Publication of WO2009004917A1 publication Critical patent/WO2009004917A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/56Coatings, e.g. enameled or galvanised; Releasing, lubricating or separating agents
    • B29C33/60Releasing, lubricating or separating agents
    • B29C33/62Releasing, lubricating or separating agents based on polymers or oligomers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/44Preparation of metal salts or ammonium salts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/46Reaction with unsaturated dicarboxylic acids or anhydrides thereof, e.g. maleinisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/02Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/03Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
    • C08J3/05Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media from solid polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00Chemical modification of a polymer
    • C08F2810/30Chemical modification of a polymer leading to the formation or introduction of aliphatic or alicyclic unsaturated groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00Chemical modification of a polymer
    • C08F2810/40Chemical modification of a polymer taking place solely at one end or both ends of the polymer backbone, i.e. not in the side or lateral chains
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/26Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers modified by chemical after-treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Dispersion Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

 公知の方法で得られる重合体鎖の片末端、両末端または内部に二重結合を有する重合体の二重結合を、高い変性率で変性して得られる下記一般式(i)で示される極性基含有ポリオレフィン重合体及びその製造方法、並びに、前記極性基含有ポリオレフィン重合体を含む水分散体及び離型剤組成物を提供する。 【化1】 (式中、POは、エチレンまたは炭素数3乃至20のオレフィンを含む単量体を重合して得られるポリオレフィン重合体であり、かっこ内に示される基が極性基である。A及びBは、それぞれ独立に、R1、シアノ基、C(O)OR1及びC(O)NR1R2のいずれかを表し、AとBとは結合して環構造を形成してもよい。Mは、金属カチオンまたはオニウムカチオンを表す。jは、金属カチオンまたはオニウムカチオンの数を表し、0乃至4の整数である。iは、金属カチオンまたはオニウムカチオンの価数を表し、0乃至4の整数である。D及びEはそれぞれ独立に、酸素原子、窒素原子、硫黄原子、R3、OR3、SR3、NR3R4のいずれかを表し、DとEとは結合して環構造を形成してもよい。d及びeは、それぞれ置換基D及びEの価数を表し、0乃至4の整数である。なお、R1、R2、R3及びR4は、それぞれ独立に、水素、任意選択で置換した炭素数20以下のアルキル基、アルケニル基、アルキニル基、アラルキル基、アリール基及び複素環を有する基のいずれかを表す。nは平均官能基数を表し、0.80乃至10.0である。)
PCT/JP2008/061047 2007-07-02 2008-06-17 極性基含有ポリオレフィン重合体及びその製造方法、並びに、水分散体及び離型剤組成物 Ceased WO2009004917A1 (ja)

Priority Applications (6)

Application Number Priority Date Filing Date Title
EP08777285.1A EP2166027B1 (en) 2007-07-02 2008-06-17 Polyolefin polymer having polar group, method for production thereof, and water dispersion material and mold release agent composition
CN2008800215966A CN101687944B (zh) 2007-07-02 2008-06-17 含极性基团的聚烯烃聚合物及其制造方法、及水分散体及脱模剂组合物
US12/452,435 US8513362B2 (en) 2007-07-02 2008-06-17 Polyolefin polymer having polar group, method for production thereof, and water dispersion material and mold release agent composition
KR1020107002319A KR101061686B1 (ko) 2007-07-02 2008-06-17 극성기 함유 폴리올레핀 중합체 및 그의 제조방법과, 수분산체 및 이형제 조성물
JP2009521573A JP5215302B2 (ja) 2007-07-02 2008-06-17 極性基含有ポリオレフィン重合体及びその製造方法、並びに、水分散体及び離型剤組成物
TW097123548A TWI348473B (en) 2007-07-02 2008-06-23 Polyolefin polymer containing polar group, method of producing the same, aqueous dispersion and releasing agent composition

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2007-174422 2007-07-02
JP2007174422 2007-07-02
JP2007-336085 2007-12-27
JP2007336085 2007-12-27

Publications (1)

Publication Number Publication Date
WO2009004917A1 true WO2009004917A1 (ja) 2009-01-08

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Application Number Title Priority Date Filing Date
PCT/JP2008/061047 Ceased WO2009004917A1 (ja) 2007-07-02 2008-06-17 極性基含有ポリオレフィン重合体及びその製造方法、並びに、水分散体及び離型剤組成物

Country Status (7)

Country Link
US (1) US8513362B2 (ja)
EP (1) EP2166027B1 (ja)
JP (1) JP5215302B2 (ja)
KR (1) KR101061686B1 (ja)
CN (1) CN101687944B (ja)
TW (1) TWI348473B (ja)
WO (1) WO2009004917A1 (ja)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011057728A (ja) * 2009-09-04 2011-03-24 Mitsui Chemicals Inc 離型剤、樹脂組成物、及び樹脂成形体

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9914687B2 (en) * 2013-03-29 2018-03-13 Tokyo Ohka Kogyo Co., Ltd. Composition containing vinyl-group-containing compound
CN109207244B (zh) * 2017-06-30 2021-10-26 北京市建筑工程研究院有限责任公司 一种混凝土预制构件用水性脱模剂
WO2020158546A1 (ja) * 2019-01-31 2020-08-06 ダイキン工業株式会社 離型剤
KR102259306B1 (ko) * 2019-10-21 2021-05-31 한화토탈 주식회사 프로필렌 중합용 고체 촉매의 제조 방법

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0391547A (ja) * 1989-09-01 1991-04-17 Sanyo Chem Ind Ltd 樹脂用添加剤およびその製造法
JPH0778098B2 (ja) * 1986-07-17 1995-08-23 三井石油化学工業株式会社 液状変性エチレン系ランダム共重合体
JP2000351813A (ja) * 1999-04-09 2000-12-19 Mitsui Chemicals Inc エチレン・α−オレフィン共重合体およびその製造方法ならびにその用途
JP2003073412A (ja) * 2001-06-20 2003-03-12 Mitsui Chemicals Inc オレフィン重合用触媒、オレフィンの重合方法、該方法によって得られるエチレン系重合体およびその用途
JP2003252927A (ja) * 2002-03-06 2003-09-10 Mitsui Chemicals Inc 変性ポリオレフィンとその製造方法およびポリオレフィン置換ジカルボン酸誘導体の製造方法
JP2006077163A (ja) * 2004-09-10 2006-03-23 Mitsui Chemicals Inc 末端に極性基を有するポリオレフィンの製造方法

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EP0329891A2 (en) 1988-02-23 1989-08-30 Petrolite Corporation End-functionalized low molecular weight polymers of ethylene
JPH0778098A (ja) 1993-09-08 1995-03-20 Fujitsu Ltd ファイル管理システム
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DE60137463D1 (de) * 2000-11-24 2009-03-05 Takashi Sawaguchi funktionale substanzen aus oligoolefinen mit funktionalen endgruppen
EP1270603B1 (en) * 2001-06-20 2014-04-09 Mitsui Chemicals, Inc. Olefin polymerization catalyst, process for polymerizing olefins
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JPH0778098B2 (ja) * 1986-07-17 1995-08-23 三井石油化学工業株式会社 液状変性エチレン系ランダム共重合体
JPH0391547A (ja) * 1989-09-01 1991-04-17 Sanyo Chem Ind Ltd 樹脂用添加剤およびその製造法
JP2000351813A (ja) * 1999-04-09 2000-12-19 Mitsui Chemicals Inc エチレン・α−オレフィン共重合体およびその製造方法ならびにその用途
JP2003073412A (ja) * 2001-06-20 2003-03-12 Mitsui Chemicals Inc オレフィン重合用触媒、オレフィンの重合方法、該方法によって得られるエチレン系重合体およびその用途
JP2003252927A (ja) * 2002-03-06 2003-09-10 Mitsui Chemicals Inc 変性ポリオレフィンとその製造方法およびポリオレフィン置換ジカルボン酸誘導体の製造方法
JP2006077163A (ja) * 2004-09-10 2006-03-23 Mitsui Chemicals Inc 末端に極性基を有するポリオレフィンの製造方法

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011057728A (ja) * 2009-09-04 2011-03-24 Mitsui Chemicals Inc 離型剤、樹脂組成物、及び樹脂成形体

Also Published As

Publication number Publication date
EP2166027A4 (en) 2010-09-01
JP5215302B2 (ja) 2013-06-19
KR20100028128A (ko) 2010-03-11
EP2166027B1 (en) 2015-06-10
TWI348473B (en) 2011-09-11
CN101687944B (zh) 2012-07-25
EP2166027A1 (en) 2010-03-24
KR101061686B1 (ko) 2011-09-01
US20100113728A1 (en) 2010-05-06
CN101687944A (zh) 2010-03-31
TW200914478A (en) 2009-04-01
US8513362B2 (en) 2013-08-20
JPWO2009004917A1 (ja) 2010-08-26

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