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WO2009072488A2 - 陰イオン交換性層状複水酸化物の製造方法 - Google Patents

陰イオン交換性層状複水酸化物の製造方法 Download PDF

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Publication number
WO2009072488A2
WO2009072488A2 PCT/JP2008/071869 JP2008071869W WO2009072488A2 WO 2009072488 A2 WO2009072488 A2 WO 2009072488A2 JP 2008071869 W JP2008071869 W JP 2008071869W WO 2009072488 A2 WO2009072488 A2 WO 2009072488A2
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anion
layered double
double hydroxide
value
anion exchange
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WO2009072488A3 (ja
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Nobuo Iyi
Takayoshi Sasaki
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National Institute for Materials Science
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National Institute for Materials Science
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Priority to US12/734,955 priority Critical patent/US8435910B2/en
Priority to EP08858187.1A priority patent/EP2228345B1/en
Priority to JP2009544675A priority patent/JP5317293B2/ja
Publication of WO2009072488A2 publication Critical patent/WO2009072488A2/ja
Publication of WO2009072488A3 publication Critical patent/WO2009072488A3/ja
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
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    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/62Carbon oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01J20/0203Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0274Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
    • B01J20/0277Carbonates of compounds other than those provided for in B01J20/043
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    • B01J20/04Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/041Oxides or hydroxides
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01J20/08Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01J41/00Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B01J41/08Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B01J41/10Inorganic material
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01FCOMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00Compounds of aluminium
    • C01F7/78Compounds containing aluminium, with or without oxygen or hydrogen, and containing two or more other elements
    • C01F7/784Layered double hydroxide, e.g. comprising nitrate, sulfate or carbonate ions as intercalating anions
    • C01F7/785Hydrotalcite
    • CCHEMISTRY; METALLURGY
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  • Chemical & Material Sciences (AREA)
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  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)

Abstract

一般式;QxR(OH)z(CO3 2-)0.5-y/2(X-)y・nH2O(式中、xは、1.8≦x≦4.2の数値範囲を示す。zは、2(x+1)を示す。yは、最小値0であり、陰イオン(X−)が残存若しくは一部導入されている場合は、1未満まで増加する。Qは、2価の金属イオン。Rは、3価の金属イオン。nは、2±2。)で表される組成を有する炭酸イオン型の層状複水酸化物を出発原料とし、その炭酸イオンサイトに−1価の陰イオンを置換して前記式中のyを最大1 にまで増加する陰イオン交換性層状複水酸化物の製造方法において、前記出発原料を、その炭酸イオンサイトを置換するに足る−1価の陰イオンを含む塩を混合した水溶液中に分散させて、置換するにあたり、その水溶液のpHを4超かつ7未満に維持することで、安全確実に、連続的に、結晶外形・結晶構造・結晶性を保ったまま脱炭酸イオンを行うことを提供する。
PCT/JP2008/071869 2007-12-05 2008-12-02 陰イオン交換性層状複水酸化物の製造方法 Ceased WO2009072488A2 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US12/734,955 US8435910B2 (en) 2007-12-05 2008-12-02 Preparation method for anion-exchangeable, layered double hydroxides
EP08858187.1A EP2228345B1 (en) 2007-12-05 2008-12-02 Process for producing anion exchange layered double hydroxide
JP2009544675A JP5317293B2 (ja) 2007-12-05 2008-12-02 陰イオン交換性層状複水酸化物の製造方法

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JP2007-314339 2007-12-05
JP2007314339 2007-12-05
JP2008-119873 2008-05-01
JP2008119873 2008-05-01

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JP2009173482A (ja) * 2008-01-23 2009-08-06 National Institute For Materials Science 膨潤性層状複水酸化物およびその製造方法とそれを用いたゲル状物質、ゾル状物質ならびにナノシート
JP2010235437A (ja) * 2009-03-09 2010-10-21 Nagoya City 酸化チタン/層状複水酸化物複合体及びその製造方法
WO2012102150A1 (ja) 2011-01-27 2012-08-02 独立行政法人物質・材料研究機構 水膨潤性層状複水酸化物とその製造方法、ゲル状又はゾル状物質及び、複水酸化物ナノシートとその製造方法
WO2012102151A1 (ja) 2011-01-27 2012-08-02 独立行政法人物質・材料研究機構 陰イオン交換性層状複水酸化物の製造方法及び炭酸イオンを含む層状複水酸化物の炭酸イオンを置換する方法
KR20130089587A (ko) * 2012-02-02 2013-08-12 삼성전자주식회사 이산화탄소 흡착제, 그 제조 방법 및 이를 포함하는 이산화탄소 포집 모듈
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