WO2009072488A2 - 陰イオン交換性層状複水酸化物の製造方法 - Google Patents
陰イオン交換性層状複水酸化物の製造方法 Download PDFInfo
- Publication number
- WO2009072488A2 WO2009072488A2 PCT/JP2008/071869 JP2008071869W WO2009072488A2 WO 2009072488 A2 WO2009072488 A2 WO 2009072488A2 JP 2008071869 W JP2008071869 W JP 2008071869W WO 2009072488 A2 WO2009072488 A2 WO 2009072488A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- anion
- layered double
- double hydroxide
- value
- anion exchange
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/62—Carbon oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0274—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
- B01J20/0277—Carbonates of compounds other than those provided for in B01J20/043
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/041—Oxides or hydroxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/043—Carbonates or bicarbonates, e.g. limestone, dolomite, aragonite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
- B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/08—Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/10—Inorganic material
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/78—Compounds containing aluminium, with or without oxygen or hydrogen, and containing two or more other elements
- C01F7/784—Layered double hydroxide, e.g. comprising nitrate, sulfate or carbonate ions as intercalating anions
- C01F7/785—Hydrotalcite
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/80—Compounds containing nickel, with or without oxygen or hydrogen, and containing one or more other elements
- C01G53/82—Compounds containing nickel, with or without oxygen or hydrogen, and containing two or more other elements
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G9/00—Compounds of zinc
- C01G9/006—Compounds containing zinc, with or without oxygen or hydrogen, and containing two or more other elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/40—Alkaline earth metal or magnesium compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/60—Inorganic bases or salts
- B01D2251/604—Hydroxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/60—Inorganic bases or salts
- B01D2251/606—Carbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/104—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/112—Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/20—Two-dimensional structures
- C01P2002/22—Two-dimensional structures layered hydroxide-type, e.g. of the hydrotalcite-type
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
- C01P2002/82—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by IR- or Raman-data
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
- C02F2001/422—Treatment of water, waste water, or sewage by ion-exchange using anionic exchangers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Geology (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Abstract
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/734,955 US8435910B2 (en) | 2007-12-05 | 2008-12-02 | Preparation method for anion-exchangeable, layered double hydroxides |
| EP08858187.1A EP2228345B1 (en) | 2007-12-05 | 2008-12-02 | Process for producing anion exchange layered double hydroxide |
| JP2009544675A JP5317293B2 (ja) | 2007-12-05 | 2008-12-02 | 陰イオン交換性層状複水酸化物の製造方法 |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007-314339 | 2007-12-05 | ||
| JP2007314339 | 2007-12-05 | ||
| JP2008-119873 | 2008-05-01 | ||
| JP2008119873 | 2008-05-01 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| WO2009072488A2 true WO2009072488A2 (ja) | 2009-06-11 |
| WO2009072488A3 WO2009072488A3 (ja) | 2009-08-06 |
Family
ID=40718308
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2008/071869 Ceased WO2009072488A2 (ja) | 2007-12-05 | 2008-12-02 | 陰イオン交換性層状複水酸化物の製造方法 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US8435910B2 (ja) |
| EP (1) | EP2228345B1 (ja) |
| JP (1) | JP5317293B2 (ja) |
| WO (1) | WO2009072488A2 (ja) |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009173482A (ja) * | 2008-01-23 | 2009-08-06 | National Institute For Materials Science | 膨潤性層状複水酸化物およびその製造方法とそれを用いたゲル状物質、ゾル状物質ならびにナノシート |
| JP2010235437A (ja) * | 2009-03-09 | 2010-10-21 | Nagoya City | 酸化チタン/層状複水酸化物複合体及びその製造方法 |
| WO2012102150A1 (ja) | 2011-01-27 | 2012-08-02 | 独立行政法人物質・材料研究機構 | 水膨潤性層状複水酸化物とその製造方法、ゲル状又はゾル状物質及び、複水酸化物ナノシートとその製造方法 |
| WO2012102151A1 (ja) | 2011-01-27 | 2012-08-02 | 独立行政法人物質・材料研究機構 | 陰イオン交換性層状複水酸化物の製造方法及び炭酸イオンを含む層状複水酸化物の炭酸イオンを置換する方法 |
| KR20130089587A (ko) * | 2012-02-02 | 2013-08-12 | 삼성전자주식회사 | 이산화탄소 흡착제, 그 제조 방법 및 이를 포함하는 이산화탄소 포집 모듈 |
| JP2013158770A (ja) * | 2012-02-02 | 2013-08-19 | Samsung Electronics Co Ltd | 二酸化炭素吸着剤、その製造方法およびこれを含む二酸化炭素捕集モジュール |
| KR20140113169A (ko) * | 2013-03-15 | 2014-09-24 | 삼성전자주식회사 | 이산화탄소 흡착제와 그 제조방법, 이를 포함한 이산화탄소 포집 모듈, 및 이를 이용한 이산화탄소 분리 방법 |
| CN105967323A (zh) * | 2016-05-24 | 2016-09-28 | 武汉理工大学 | 一种提高快速渗滤系统除铬效果的填料及其制备方法 |
| JPWO2015012078A1 (ja) * | 2013-07-25 | 2017-03-02 | 株式会社ノリタケカンパニーリミテド | 陰イオン伝導材料およびその製造方法 |
| CN107555465A (zh) * | 2017-09-13 | 2018-01-09 | 太原理工大学 | 一种硝酸根插层铜铝类水滑石的快速制备方法 |
| CN107570106A (zh) * | 2017-10-17 | 2018-01-12 | 西南大学 | 一种铁锰类层状双氢氧化物、制备方法及应用 |
| JP2020040872A (ja) * | 2018-09-10 | 2020-03-19 | 共栄社化学株式会社 | イオン伝導性材料、電池用機能層及びその製造方法 |
| JPWO2020213398A1 (ja) * | 2019-04-19 | 2020-10-22 | ||
| JP2023026979A (ja) * | 2021-08-16 | 2023-03-01 | 公立大学法人大阪 | ハイドロタルサイト化合物及び光活性触媒 |
| WO2025154462A1 (ja) * | 2024-01-18 | 2025-07-24 | パナソニックIpマネジメント株式会社 | 水電解用電極のリサイクル方法及び水電解用電極のリサイクル装置 |
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| CN102633285B (zh) * | 2012-04-17 | 2014-04-02 | 北京化工大学 | 一种一维形貌类水滑石材料及其制备方法 |
| AU2016250295B2 (en) * | 2015-04-15 | 2021-08-05 | Commonwealth Scientific And Industrial Research Organisation | Selective separation of elements or commodities of interest in aqueous streams |
| US10087355B2 (en) | 2016-03-17 | 2018-10-02 | Saudi Arabian Oil Company | Oil-based drilling fluids containing an alkaline-earth diamondoid compound as rheology modifier |
| US10252245B2 (en) | 2016-03-17 | 2019-04-09 | Saudi Arabian Oil Company | High temperature layered mixed-metal oxide materials with enhanced stability |
| US10138199B2 (en) | 2016-03-17 | 2018-11-27 | Saudi Arabian Oil Company | High aspect ratio layered double hydroxide materials and methods for preparation thereof |
| US10106482B2 (en) | 2016-03-17 | 2018-10-23 | Saudi Arabian Oil Company | Synthesis of magnesium adamantane salts and magnesium oxide nanocomposites, and systems and methods including the salts or the nanocomposites |
| KR102146239B1 (ko) | 2016-03-17 | 2020-08-21 | 사우디 아라비안 오일 컴퍼니 | 전이금속 아다만탄 카복실레이트염 및 산화물 나노복합체의 합성 |
| US10875092B2 (en) | 2017-05-19 | 2020-12-29 | Saudi Arabian Oil Company | Methods for preparing mixed-metal oxide diamondoid nanocomposites and catalytic systems including the nanocomposites |
| KR20200010372A (ko) | 2017-05-19 | 2020-01-30 | 사우디 아라비안 오일 컴퍼니 | 전이 금속 아다만탄 염 및 산화물 나노복합체의 합성 |
| US10793762B2 (en) | 2017-08-15 | 2020-10-06 | Saudi Arabian Oil Company | Layered double hydroxides for oil-based drilling fluids |
| US10988659B2 (en) * | 2017-08-15 | 2021-04-27 | Saudi Arabian Oil Company | Layered double hydroxides for oil-based drilling fluids |
| US10647903B2 (en) * | 2017-08-15 | 2020-05-12 | Saudi Arabian Oil Company | Oil-based drilling fluid compositions which include layered double hydroxides as rheology modifiers and amino amides as emulsifiers |
| US10745606B2 (en) * | 2017-08-15 | 2020-08-18 | Saudi Arabian Oil Company | Oil-based drilling fluid compositions which include layered double hydroxides as rheology modifiers |
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| JP2001187336A (ja) | 1997-06-12 | 2001-07-10 | Tomita Pharmaceutical Co Ltd | 脱リン剤造粒物及び排水処理方法 |
| JP2005255441A (ja) | 2004-03-10 | 2005-09-22 | National Institute For Materials Science | ハイドロタルサイトの脱炭酸イオンによる、イオン交換性のある陰イオンを有する層状複水酸化物の製造方法およびその用途 |
| JP2007031189A (ja) | 2005-07-25 | 2007-02-08 | National Institute For Materials Science | 層状複水酸化物を剥離する方法、複水酸化物ナノシート、該複合薄膜材料、該製造方法、および、層状複水酸化物薄膜材料の製造方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6333290B1 (en) * | 1998-02-11 | 2001-12-25 | Akzo Nobel Nv | Process for producing anionic clays using magnesium acetate |
| JP2000024658A (ja) * | 1998-07-08 | 2000-01-25 | Kaisui Kagaku Kenkyusho:Kk | 水の脱リン剤およびリンの除去、再生方法 |
| JP2004099391A (ja) * | 2002-09-11 | 2004-04-02 | Mizusawa Ind Chem Ltd | 層状複水酸化物の製造方法 |
-
2008
- 2008-12-02 WO PCT/JP2008/071869 patent/WO2009072488A2/ja not_active Ceased
- 2008-12-02 JP JP2009544675A patent/JP5317293B2/ja not_active Expired - Fee Related
- 2008-12-02 EP EP08858187.1A patent/EP2228345B1/en not_active Not-in-force
- 2008-12-02 US US12/734,955 patent/US8435910B2/en not_active Expired - Fee Related
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Also Published As
| Publication number | Publication date |
|---|---|
| JP5317293B2 (ja) | 2013-10-16 |
| US8435910B2 (en) | 2013-05-07 |
| JPWO2009072488A1 (ja) | 2011-04-21 |
| US20100279848A1 (en) | 2010-11-04 |
| EP2228345B1 (en) | 2017-04-12 |
| EP2228345A2 (en) | 2010-09-15 |
| WO2009072488A3 (ja) | 2009-08-06 |
| EP2228345A4 (en) | 2016-05-25 |
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