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WO2008101603A3 - Nouveau catalyseur et hydrogénations associées - Google Patents

Nouveau catalyseur et hydrogénations associées Download PDF

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Publication number
WO2008101603A3
WO2008101603A3 PCT/EP2008/000995 EP2008000995W WO2008101603A3 WO 2008101603 A3 WO2008101603 A3 WO 2008101603A3 EP 2008000995 W EP2008000995 W EP 2008000995W WO 2008101603 A3 WO2008101603 A3 WO 2008101603A3
Authority
WO
WIPO (PCT)
Prior art keywords
sintered metal
metal fibers
alkynols
hydrogenation
oxide layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2008/000995
Other languages
English (en)
Other versions
WO2008101603A2 (fr
Inventor
Werner Bonrath
Martin Grasemann
Albert Renken
Natalia Semagina
Lioubov Kiwi-Minsker
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DSM IP Assets BV
Original Assignee
DSM IP Assets BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DSM IP Assets BV filed Critical DSM IP Assets BV
Priority to CN2008800055172A priority Critical patent/CN101616733B/zh
Priority to EP08707639A priority patent/EP2125199A2/fr
Publication of WO2008101603A2 publication Critical patent/WO2008101603A2/fr
Publication of WO2008101603A3 publication Critical patent/WO2008101603A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/60—Platinum group metals with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6525—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/393—Metal or metal oxide crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/58—Fabrics or filaments
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0225—Coating of metal substrates
    • B01J37/0226—Oxidation of the substrate, e.g. anodisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0242—Coating followed by impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0244—Coatings comprising several layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/50—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids
    • B01J38/52—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids oxygen-containing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

L'invention concerne un catalyseur structuré à base de fibres métalliques frittées (SMF) revêtues par une couche de ZnO imprégnée de nanoparticules de Pd; des réactions d'un produit de départ organique avec de l'hydrogène en présence dudit catalyseur ainsi que des vitamines, caroténoïdes, des ingrédients de parfum, et/ou des aliments ou ingrédients alimentaires préparés au moyen de cette réaction.
PCT/EP2008/000995 2007-02-19 2008-02-09 Nouveau catalyseur et hydrogénations associées Ceased WO2008101603A2 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN2008800055172A CN101616733B (zh) 2007-02-19 2008-02-09 基于包覆有经钯纳米颗粒浸渍的氧化锌层的经烧结金属纤维的用于炔醇氢化的催化剂
EP08707639A EP2125199A2 (fr) 2007-02-19 2008-02-09 Nouveau catalyseur et hydrogénations associées

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP07003423 2007-02-19
EP07003423.6 2007-02-19

Publications (2)

Publication Number Publication Date
WO2008101603A2 WO2008101603A2 (fr) 2008-08-28
WO2008101603A3 true WO2008101603A3 (fr) 2008-12-18

Family

ID=39643801

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2008/000995 Ceased WO2008101603A2 (fr) 2007-02-19 2008-02-09 Nouveau catalyseur et hydrogénations associées

Country Status (3)

Country Link
EP (1) EP2125199A2 (fr)
CN (1) CN101616733B (fr)
WO (1) WO2008101603A2 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104136120A (zh) * 2012-02-24 2014-11-05 帝斯曼知识产权资产管理有限公司 包含钴铬钼-合金的金属粉末状催化剂

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101780406B (zh) * 2009-01-19 2012-06-27 中国科学院化学研究所 一种纳米金属催化剂及其制备方法与应用
ES2616741T3 (es) 2010-01-28 2017-06-14 Dsm Ip Assets B.V. Procedimiento de hidrogenación
ES2725203T3 (es) 2010-07-01 2019-09-20 Dsm Ip Assets Bv Nuevo catalizador estructurado
CN102503772A (zh) * 2011-10-11 2012-06-20 上海博鹤企业发展有限公司 一种生产2-甲基-3-丁烯-2-醇的方法
EP2771110B1 (fr) * 2011-10-27 2017-11-22 DSM IP Assets B.V. Procedé d'hydrogenation avec un catalyseur Pd/Ag supporté sur des fibres metalliques
US9238218B2 (en) 2012-02-24 2016-01-19 Dsm Ip Assets B.V. Metal powderdous catalyst for hydrogenation process
JP6232672B2 (ja) * 2012-02-24 2017-11-22 ディーエスエム アイピー アセッツ ビー．ブイ． Ｆｅ合金を含む金属粉末状触媒
KR102082530B1 (ko) * 2012-04-18 2020-02-27 디에스엠 아이피 어셋츠 비.브이. 수소화 반응에 유용한 장치(i)
KR102082531B1 (ko) * 2012-04-18 2020-02-27 디에스엠 아이피 어셋츠 비.브이. 수소화 반응에 유용한 장치(iii)
CN104245117A (zh) * 2012-04-18 2014-12-24 帝斯曼知识产权资产管理有限公司 适用于氢化反应(ii)的装置
ES3006459T3 (en) * 2013-09-30 2025-03-18 Dsm Ip Assets Bv Pd on boehmite catalytic system for selective hydrogenation of triple bonds
CN109382100A (zh) * 2018-11-12 2019-02-26 大连理工大学 一种选择加氢获取1,4-丁烯二醇的含锌金属间化合物催化剂及其制备方法
CN114364461A (zh) * 2019-06-21 2022-04-15 联邦科学技术研究组织 用于催化涂覆支架的工艺
CN114073959B (zh) * 2020-08-19 2023-08-29 中国石油化工股份有限公司 一种丁烯氧化脱氢催化剂及其制备方法和应用
CN115368209B (zh) * 2022-08-30 2023-09-19 万华化学集团股份有限公司 一种甲基丁烯醇的制备方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3192168A (en) * 1959-02-02 1965-06-29 Rhone Poulenc Sa Palladium-tin catalysts
JP2002170429A (ja) * 2000-11-29 2002-06-14 C Uyemura & Co Ltd 高密度触媒核分散層を有する基体並びに改質酸化亜鉛皮膜を有する導電性物品及びその作製方法
US20030187294A1 (en) * 1997-08-13 2003-10-02 Celanese Chemical Europe Gmbh Process for producing catalysts comprising nanosize metal particles on a porous support, in particular for the gas-phase oxidation of ethylene and acetic acid to give vinyl acetate
WO2005030390A1 (fr) * 2003-05-07 2005-04-07 Battelle Memorial Institute Catalyseurs de reformage d'alcools a la vapeur et procedes de reformage d'alcools a la vapeur
CN1721063A (zh) * 2004-07-13 2006-01-18 中国科学院大连化学物理研究所 一种甲醇氧化重整制氢催化剂及制法和应用
JP2007244963A (ja) * 2006-03-14 2007-09-27 Ihi Corp メタノール改質触媒及びその製造方法及びメタノール改質方法及びメタノール改質器

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3192168A (en) * 1959-02-02 1965-06-29 Rhone Poulenc Sa Palladium-tin catalysts
US20030187294A1 (en) * 1997-08-13 2003-10-02 Celanese Chemical Europe Gmbh Process for producing catalysts comprising nanosize metal particles on a porous support, in particular for the gas-phase oxidation of ethylene and acetic acid to give vinyl acetate
JP2002170429A (ja) * 2000-11-29 2002-06-14 C Uyemura & Co Ltd 高密度触媒核分散層を有する基体並びに改質酸化亜鉛皮膜を有する導電性物品及びその作製方法
WO2005030390A1 (fr) * 2003-05-07 2005-04-07 Battelle Memorial Institute Catalyseurs de reformage d'alcools a la vapeur et procedes de reformage d'alcools a la vapeur
CN1721063A (zh) * 2004-07-13 2006-01-18 中国科学院大连化学物理研究所 一种甲醇氧化重整制氢催化剂及制法和应用
JP2007244963A (ja) * 2006-03-14 2007-09-27 Ihi Corp メタノール改質触媒及びその製造方法及びメタノール改質方法及びメタノール改質器

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
TRIBOLET P ET AL: "Palladium on carbon nanofibers grown on metallic filters as novel structured catalyst", 15 August 2005, CATALYSIS TODAY, ELSEVIER, PAGE(S) 337 - 343, ISSN: 0920-5861, XP004998972 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104136120A (zh) * 2012-02-24 2014-11-05 帝斯曼知识产权资产管理有限公司 包含钴铬钼-合金的金属粉末状催化剂
CN104136120B (zh) * 2012-02-24 2017-02-22 帝斯曼知识产权资产管理有限公司 包含钴铬钼‑合金的金属粉末状催化剂

Also Published As

Publication number Publication date
CN101616733A (zh) 2009-12-30
WO2008101603A2 (fr) 2008-08-28
CN101616733B (zh) 2013-05-15
EP2125199A2 (fr) 2009-12-02

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