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MX2010004517A - Proceso para la reduccion en la cantidad de compuestos de azufre, cianuro de hidrogeno y acido formico en un gas de sintesis. - Google Patents

Proceso para la reduccion en la cantidad de compuestos de azufre, cianuro de hidrogeno y acido formico en un gas de sintesis.

Info

Publication number
MX2010004517A
MX2010004517A MX2010004517A MX2010004517A MX2010004517A MX 2010004517 A MX2010004517 A MX 2010004517A MX 2010004517 A MX2010004517 A MX 2010004517A MX 2010004517 A MX2010004517 A MX 2010004517A MX 2010004517 A MX2010004517 A MX 2010004517A
Authority
MX
Mexico
Prior art keywords
formic acid
synthesis gas
reduction
amount
hydrogen cyanide
Prior art date
Application number
MX2010004517A
Other languages
English (en)
Inventor
Poul Erik Hojlund Nielsen
Ib Dybkjaer
Kim Aasberg-Petersen
Original Assignee
Haldor Topsoe As
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Haldor Topsoe As filed Critical Haldor Topsoe As
Publication of MX2010004517A publication Critical patent/MX2010004517A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8603—Removing sulfur compounds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • C01B3/58—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/104—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/112—Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/102—Platinum group metals
    • B01D2255/1021—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/102—Platinum group metals
    • B01D2255/1023—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/104—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/106—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042—Purification by adsorption on solids
    • C01B2203/0425—In-situ adsorption process during hydrogen production
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0435—Catalytic purification
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/048—Composition of the impurity the impurity being an organic compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0485—Composition of the impurity the impurity being a sulfur compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Un proceso para una reducción en la cantidad de compuestos de azufre, cianuro de hidrógeno, ácido fórmico y derivados de ácido fórmico en un gas de síntesis que comprende estos compuestos, el proceso comprende el paso que consiste en poner en contacto el gas de síntesis con un material que comprende absorbente de azufre y después con un catalizador que comprende uno o más metales seleccionados del grupo que consiste de plata, oro, cobre, paladio, platino y sus mezclas y soportado en un portador que comprende por lo menos uno de los óxidos de escandio, itrio, lantano, cerio, titanio, zirconio, aluminio, zinc, cromo y molibdeno.
MX2010004517A 2007-10-26 2008-10-23 Proceso para la reduccion en la cantidad de compuestos de azufre, cianuro de hidrogeno y acido formico en un gas de sintesis. MX2010004517A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DKPA200701532 2007-10-26
PCT/EP2008/008961 WO2009053065A1 (en) 2007-10-26 2008-10-23 Process for a reduction in the amount of sulphur compounds, hydrogen cyanide and formic acid in synthesis gas

Publications (1)

Publication Number Publication Date
MX2010004517A true MX2010004517A (es) 2010-06-02

Family

ID=40380136

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2010004517A MX2010004517A (es) 2007-10-26 2008-10-23 Proceso para la reduccion en la cantidad de compuestos de azufre, cianuro de hidrogeno y acido formico en un gas de sintesis.

Country Status (11)

Country Link
US (1) US8889089B2 (es)
CN (1) CN101918111B (es)
AU (1) AU2008315615B2 (es)
BR (1) BRPI0818853B1 (es)
CA (1) CA2704211C (es)
EA (1) EA017772B1 (es)
MX (1) MX2010004517A (es)
MY (1) MY148441A (es)
UA (1) UA100395C2 (es)
WO (1) WO2009053065A1 (es)
ZA (1) ZA201002727B (es)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103086499B (zh) * 2013-01-31 2014-06-25 中国水产科学研究院淡水渔业研究中心 用于养殖池塘改善水体环境、降低饵料成本的生物膜装置
US9517447B1 (en) 2015-06-01 2016-12-13 Uop Llc Processes for removing contaminants from a dehydrogenation effluent
CN109569272B (zh) * 2017-09-28 2021-11-30 中国石油化工股份有限公司 含氰废气处理方法
US10710056B2 (en) 2018-10-31 2020-07-14 King Abdulaziz University Ceria supported palladium/calcium catalyst for hydrogenating CO2 to dimethyl ether
TWI739254B (zh) 2019-12-26 2021-09-11 財團法人工業技術研究院 將碳氧化合物轉化為甲醇的觸媒及製程
CN111359629B (zh) * 2020-03-19 2021-04-23 昆明理工大学 一种金属单原子位点催化剂及其制备方法和应用
CN113617195A (zh) * 2021-06-30 2021-11-09 中海油天津化工研究设计院有限公司 一种高性能电石渣基固硫剂

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US175327A (en) * 1876-03-28 Improvement in scrap-books
GB939254A (en) 1959-06-15 1963-10-09 Engelhard Ind Inc Improvements in or relating to removing hydrocyanic acid from gases
DE2733105B1 (de) 1977-07-22 1979-01-18 Basf Ag Verfahren zur Herstellung von Synthesegasen durch partielle Oxidation
DE3041324A1 (de) 1980-11-03 1982-06-16 Basf Ag, 6700 Ludwigshafen Verfahren zum gleichzeitigen abbau von spurenbestandteilen in den reaktionsabgasen der melaminsynthese
DE3243206A1 (de) * 1982-11-23 1984-05-24 Basf Ag, 6700 Ludwigshafen Verfahren zur reinigung von co und/oder co(pfeil abwaerts)2(pfeil abwaerts) enthaltenden gasen
US4704137A (en) * 1987-02-09 1987-11-03 Texaco Inc. Process for upgrading water used in cooling and cleaning of raw synthesis gas
US5685890A (en) * 1987-12-17 1997-11-11 Osaka Gas Company Limited Process for steam reforming of hydrocarbons
DE69215345T2 (de) * 1991-12-30 1997-03-13 Texaco Development Corp Behandlung von Synthesegas
EP0757969B1 (en) * 1995-08-08 2000-03-29 Exxon Research And Engineering Company Process for removing hydrogen cyanide from synthesis gas
US6107353A (en) 1995-08-08 2000-08-22 Exxon Research And Engineering Company Cyanide and ammonia removal from synthesis gas
KR100319922B1 (ko) 1999-03-05 2002-01-09 이형도 디젤엔진 배기가스 정화용 촉매
US20020061277A1 (en) * 2000-09-25 2002-05-23 Engelhard Corporation Non-pyrophoric water-gas shift reaction catalysts
CA2511018A1 (en) * 2002-12-20 2004-07-15 Honda Giken Kogyo Kabushiki Kaisha Catalyst formulations for hydrogen generation
JP3855994B2 (ja) 2003-12-25 2006-12-13 日産自動車株式会社 触媒及びその製造方法
MY140997A (en) * 2004-07-22 2010-02-12 Shell Int Research Process for the removal of cos from a synthesis gas stream comprising h2s and cos
WO2007082896A1 (en) 2006-01-18 2007-07-26 Shell Internationale Research Maatschappij B.V. Process for removing carbonyl sulphide and hydrogen sulphide from a synthesis gas stream
CN101484230B (zh) 2006-04-28 2012-12-26 赫多特普索化工设备公司 从合成气中除去氰化氢和甲酸的方法

Also Published As

Publication number Publication date
WO2009053065A1 (en) 2009-04-30
AU2008315615A1 (en) 2009-04-30
US8889089B2 (en) 2014-11-18
CN101918111B (zh) 2014-10-08
US20100311848A1 (en) 2010-12-09
ZA201002727B (en) 2011-06-29
BRPI0818853B1 (pt) 2018-11-21
CA2704211A1 (en) 2009-04-30
UA100395C2 (en) 2012-12-25
CA2704211C (en) 2015-05-26
AU2008315615B2 (en) 2012-05-24
MY148441A (en) 2013-04-30
CN101918111A (zh) 2010-12-15
BRPI0818853A2 (pt) 2015-04-14
EA017772B1 (ru) 2013-03-29
EA201000700A1 (ru) 2010-10-29

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