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WO2008153075A1 - 撥水撥油剤組成物、その製造方法および物品 - Google Patents

撥水撥油剤組成物、その製造方法および物品 Download PDF

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Publication number
WO2008153075A1
WO2008153075A1 PCT/JP2008/060703 JP2008060703W WO2008153075A1 WO 2008153075 A1 WO2008153075 A1 WO 2008153075A1 JP 2008060703 W JP2008060703 W JP 2008060703W WO 2008153075 A1 WO2008153075 A1 WO 2008153075A1
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WIPO (PCT)
Prior art keywords
repellent
monomer
oil
group
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/060703
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English (en)
French (fr)
Inventor
Kazunori Sugiyama
Kyouichi Kaneko
Yuichi Ohmori
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
AGC Inc
Original Assignee
Asahi Glass Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Glass Co Ltd filed Critical Asahi Glass Co Ltd
Priority to KR20097023209A priority Critical patent/KR101493540B1/ko
Priority to JP2009519287A priority patent/JP5353697B2/ja
Priority to EP08765482.8A priority patent/EP2166059B1/en
Priority to CN200880019223A priority patent/CN101679840A/zh
Publication of WO2008153075A1 publication Critical patent/WO2008153075A1/ja
Priority to US12/607,134 priority patent/US8791218B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/22—Esters containing halogen
    • C08F220/24—Esters containing halogen containing perhaloalkyl radicals
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
    • C09D133/16—Homopolymers or copolymers of esters containing halogen atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
    • D06M15/256—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/285—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing a polyether chain in the alcohol moiety
    • C08F220/286—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing a polyether chain in the alcohol moiety and containing polyethylene oxide in the alcohol moiety, e.g. methoxy polyethylene glycol (meth)acrylate
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    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
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    • C08F220/10—Esters
    • C08F220/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
    • C08F220/36—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate containing oxygen in addition to the carboxy oxygen, e.g. 2-N-morpholinoethyl (meth)acrylate or 2-isocyanatoethyl (meth)acrylate
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F238/00—Copolymers of compounds having one or more carbon-to-carbon triple bonds
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    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/11—Oleophobic properties
    • D—TEXTILES; PAPER
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    • D06M2200/10—Repellency against liquids
    • D06M2200/12—Hydrophobic properties

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

　物品の風合いを低下させることなく、物品の表面に撥水撥油性を付与でき、かつ洗濯耐久性、安定性に優れる撥水撥油剤組成物、その製造方法、および該撥水撥油剤組成物で処理した物品を提供する。 　単量体（ａ）に基づく重合単位と単量体（ｂ）に基づく重合単位と単量体（ｃ）に基づく重合単位とを有する共重合体を含むことを特徴とする撥水撥油剤組成物。単量体（ａ）：（Ｚ－Ｙ）ｎＸで表される化合物。ただし、Ｚは炭素数が１～６のパーフルオロアルキル基等、Ｙは２価有機基または単結合、ｎは１または２、Ｘは重合性不飽和基である。単量体（ｂ）：Ｒｆ基を有さず、炭素数が１２～１８のアルキル基を有する（メタ）アクリレート。単量体（ｃ）：Ｒｆ基を有さず、ブロックドイソシアネート基を有する単量体（ｃ１）またはＲｆ基を有さず、重合性不飽和基を２つ以上有する単量体（ｃ２）。
PCT/JP2008/060703 2007-06-12 2008-06-11 撥水撥油剤組成物、その製造方法および物品 Ceased WO2008153075A1 (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
KR20097023209A KR101493540B1 (ko) 2007-06-12 2008-06-11 발수발유제 조성물, 그 제조 방법 및 물품
JP2009519287A JP5353697B2 (ja) 2007-06-12 2008-06-11 撥水撥油剤組成物、その製造方法および物品
EP08765482.8A EP2166059B1 (en) 2007-06-12 2008-06-11 Water-repellent/oil-repellent composition, method for producing the same, and article
CN200880019223A CN101679840A (zh) 2007-06-12 2008-06-11 斥水斥油剂组合物及其制造方法及物品
US12/607,134 US8791218B2 (en) 2007-06-12 2009-10-28 Water/oil repellent composition, method for production thereof, and article

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007155450 2007-06-12
JP2007-155450 2007-06-12

Related Child Applications (1)

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US12/607,134 Continuation US8791218B2 (en) 2007-06-12 2009-10-28 Water/oil repellent composition, method for production thereof, and article

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Publication Number Publication Date
WO2008153075A1 true WO2008153075A1 (ja) 2008-12-18

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US (1) US8791218B2 (ja)
EP (1) EP2166059B1 (ja)
JP (1) JP5353697B2 (ja)
KR (1) KR101493540B1 (ja)
CN (1) CN101679840A (ja)
TW (1) TWI453274B (ja)
WO (1) WO2008153075A1 (ja)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009113589A1 (ja) * 2008-03-12 2009-09-17 旭硝子株式会社 共重合体およびその製造方法
WO2009148029A1 (ja) * 2008-06-02 2009-12-10 旭硝子株式会社 共重合体、その製造方法および撥油剤組成物ならびにその処理物品
EP2351807A4 (en) * 2008-10-24 2012-03-28 Asahi Glass Co Ltd HYDRO- AND OLEOPHOBIERMITTEL AND MANUFACTURING METHOD THEREFOR
US8975348B2 (en) 2010-02-12 2015-03-10 E I Du Pont De Nemours And Company Non-aqueous composition comprising partially fluorinated methacrylic polymers
WO2015064360A1 (ja) * 2013-11-01 2015-05-07 ユニマテック株式会社 含フッ素重合体およびこれを有効成分とする表面改質剤
WO2017154816A1 (ja) * 2016-03-11 2017-09-14 ダイキン工業株式会社 樹脂組成物および成形体

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KR101544627B1 (ko) * 2007-09-28 2015-08-17 아사히 가라스 가부시키가이샤 발수 발유제 조성물 및 물품
JP5678660B2 (ja) * 2008-06-04 2015-03-04 旭硝子株式会社 共重合体、その製造方法および撥水撥油剤組成物
WO2011125892A1 (ja) * 2010-04-01 2011-10-13 旭硝子株式会社 含フッ素化合物および含フッ素重合体
CN104583254B (zh) 2012-08-21 2017-03-08 旭硝子株式会社 含氟共聚物及其制造方法、拒水剂组合物、物品
KR101962816B1 (ko) * 2017-06-14 2019-03-27 (주)대동켐텍 폴리아크릴계 표면 발수제 및 그를 이용한 발수성 섬유제품
JP7204656B2 (ja) * 2017-10-20 2023-01-16 リケンテクノス株式会社 艶消しハードコート形成用塗料、及びこれを用いた化粧シート
CN107700214B (zh) * 2017-10-24 2019-12-24 广东德美精细化工集团股份有限公司 包含遥爪聚合物的高效无氟防水剂及制备方法
CN110485160B (zh) * 2017-10-24 2022-02-15 广东德美精细化工集团股份有限公司 包含遥爪聚合物的高效防水防油剂的制备方法
CN108181207A (zh) * 2017-11-23 2018-06-19 南昌航空大学 一种土体等散体材料斥水度检测评价方法
CN110761074B (zh) * 2018-07-26 2023-08-08 乳源东阳光氟有限公司 一种环保低温型拒水拒油组合物
CN110670359B (zh) * 2019-10-10 2022-02-11 广东中联邦精细化工有限公司 一种低温型防水防油剂及其制备方法
CN116410405B (zh) * 2022-03-10 2025-01-28 北京马普新材料有限公司 共聚物、纸张用处理剂和纸制品
CN114573768B (zh) * 2022-03-10 2023-05-12 北京马普新材料有限公司 一种水分散型聚合物、包含该聚合物的组合物及其应用
CN117265875A (zh) * 2023-08-07 2023-12-22 北京马普新材料有限公司 处理剂及纤维织物或涂料

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DE602007012219D1 (de) * 2006-03-30 2011-03-10 Asahi Glass Co Ltd Flüssigkeitabweisende zusammensetzung, verfahren zur flüssigkeitabweisenden ausrüstung und erzeugnisse mit flüssigkeitabweisenden filmen
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JPS62138579A (ja) * 1985-12-13 1987-06-22 Nippon Mektron Ltd 撥水撥油剤
JPH05214198A (ja) * 1992-01-31 1993-08-24 Dainippon Ink & Chem Inc パーフルオロアルキル基含有共重合体非水分散液及び撥水撥油剤
JPH1192752A (ja) * 1997-07-23 1999-04-06 Asahi Glass Co Ltd 撥水撥油剤組成物
WO2002083809A1 (en) 2001-04-13 2002-10-24 Asahi Glass Company, Limited Water-and-oil repellant composition
WO2004035708A1 (ja) 2002-10-15 2004-04-29 Asahi Glass Company, Limited 撥水撥油剤組成物
WO2005090423A1 (ja) * 2004-03-23 2005-09-29 Asahi Glass Company, Limited 耐水耐油剤組成物
WO2006022122A1 (ja) * 2004-08-25 2006-03-02 Daikin Industries, Ltd. 撥水撥油剤組成物
JP2007333564A (ja) 2006-06-15 2007-12-27 Nec Network & Sensor Systems Ltd 海洋波計測システムおよび海洋波計測方法

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009113589A1 (ja) * 2008-03-12 2009-09-17 旭硝子株式会社 共重合体およびその製造方法
US8901264B2 (en) 2008-03-12 2014-12-02 Asahi Glass Company, Limited Copolymer and method for producing the same
WO2009148029A1 (ja) * 2008-06-02 2009-12-10 旭硝子株式会社 共重合体、その製造方法および撥油剤組成物ならびにその処理物品
US8431664B2 (en) 2008-06-02 2013-04-30 Asahi Glass Company, Limited Copolymer, method for its production, oil repellent composition and article treated therewith
JP5589841B2 (ja) * 2008-06-02 2014-09-17 旭硝子株式会社 共重合体、その製造方法および撥油剤組成物ならびにその処理物品
EP2351807A4 (en) * 2008-10-24 2012-03-28 Asahi Glass Co Ltd HYDRO- AND OLEOPHOBIERMITTEL AND MANUFACTURING METHOD THEREFOR
US8975348B2 (en) 2010-02-12 2015-03-10 E I Du Pont De Nemours And Company Non-aqueous composition comprising partially fluorinated methacrylic polymers
WO2015064360A1 (ja) * 2013-11-01 2015-05-07 ユニマテック株式会社 含フッ素重合体およびこれを有効成分とする表面改質剤
JPWO2015064360A1 (ja) * 2013-11-01 2017-03-09 ユニマテック株式会社 含フッ素重合体およびこれを有効成分とする表面改質剤
WO2017154816A1 (ja) * 2016-03-11 2017-09-14 ダイキン工業株式会社 樹脂組成物および成形体

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US8791218B2 (en) 2014-07-29
US20100048846A1 (en) 2010-02-25
CN101679840A (zh) 2010-03-24
JP5353697B2 (ja) 2013-11-27
JPWO2008153075A1 (ja) 2010-08-26
EP2166059B1 (en) 2015-09-02
TW200914597A (en) 2009-04-01
KR101493540B1 (ko) 2015-02-13

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