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WO2008147013A3 - Procédés de préparation d'hydrocarbures liquides à partir de gaz synthétique à l'aide de catalyseurs fischer-tropsch à base d'oxyde de zirconium et d'aluminium - Google Patents

Procédés de préparation d'hydrocarbures liquides à partir de gaz synthétique à l'aide de catalyseurs fischer-tropsch à base d'oxyde de zirconium et d'aluminium Download PDF

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Publication number
WO2008147013A3
WO2008147013A3 PCT/KR2008/000547 KR2008000547W WO2008147013A3 WO 2008147013 A3 WO2008147013 A3 WO 2008147013A3 KR 2008000547 W KR2008000547 W KR 2008000547W WO 2008147013 A3 WO2008147013 A3 WO 2008147013A3
Authority
WO
WIPO (PCT)
Prior art keywords
zirconia
syngas
liquid hydrocarbons
aluminum oxide
preparation methods
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2008/000547
Other languages
English (en)
Other versions
WO2008147013A2 (fr
Inventor
Ki-Won Jun
Jong-Wook Bae
Seung-Moon Kim
Jong-Hyeok Oh
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Korea Research Institute of Chemical Technology KRICT
Hyundai Engineering Co Ltd
KOREA INTERNATIONAL CORP
Doosan Mecatec Co Ltd
SK Energy Co Ltd
DL Holdings Co Ltd
Original Assignee
Korea Research Institute of Chemical Technology KRICT
Hyundai Engineering Co Ltd
Daelim Industrial Co Ltd
KOREA INTERNATIONAL CORP
Doosan Mecatec Co Ltd
SK Energy Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Korea Research Institute of Chemical Technology KRICT, Hyundai Engineering Co Ltd, Daelim Industrial Co Ltd, KOREA INTERNATIONAL CORP, Doosan Mecatec Co Ltd, SK Energy Co Ltd filed Critical Korea Research Institute of Chemical Technology KRICT
Priority to EP08705003A priority Critical patent/EP2152413A2/fr
Publication of WO2008147013A2 publication Critical patent/WO2008147013A2/fr
Publication of WO2008147013A3 publication Critical patent/WO2008147013A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/69—Pore distribution bimodal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8896—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/30—Constitutive chemical elements of heterogeneous catalysts of Group III (IIIA or IIIB) of the Periodic Table
    • B01J2523/31—Aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/40—Constitutive chemical elements of heterogeneous catalysts of Group IV (IVA or IVB) of the Periodic Table
    • B01J2523/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

La présente invention concerne un catalyseur à base de cobalt/zircone-aluminium dans lequel le cobalt est supporté sous forme d'un ingrédient actif sur le zircone-aluminium obtenu par co-précipitation, ce catalyseur ayant une structure de pores bimodale avec différentes grosseurs de pores et conservant un rapport volumique de pore spécifique. L'invention concerne également un procédé de préparation d'hydrocarbures liquides à rendement élevé à partir de la synthèse de Fischer-Tropsch d'un gaz synthétique (CO/H2/CO2 ) en présence du catalyseur de cobalt/zircone-aluminium.
PCT/KR2008/000547 2007-05-29 2008-01-30 Procédés de préparation d'hydrocarbures liquides à partir de gaz synthétique à l'aide de catalyseurs fischer-tropsch à base d'oxyde de zirconium et d'aluminium Ceased WO2008147013A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP08705003A EP2152413A2 (fr) 2007-05-29 2008-01-30 Procédés de préparation d'hydrocarbures liquides à partir de gaz synthétique à l'aide de catalyseurs fischer-tropsch à base d'oxyde de zirconium et d'aluminium

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020070052243A KR100837377B1 (ko) 2007-05-29 2007-05-29 지르코니아와 알루미나의 혼합담체를 이용한 피셔-트롭쉬 반응용 촉매 및 이를 이용한 합성가스로부터 액체탄화수소의 제조방법
KR10-2007-0052243 2007-05-29

Publications (2)

Publication Number Publication Date
WO2008147013A2 WO2008147013A2 (fr) 2008-12-04
WO2008147013A3 true WO2008147013A3 (fr) 2009-03-26

Family

ID=39771004

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2008/000547 Ceased WO2008147013A2 (fr) 2007-05-29 2008-01-30 Procédés de préparation d'hydrocarbures liquides à partir de gaz synthétique à l'aide de catalyseurs fischer-tropsch à base d'oxyde de zirconium et d'aluminium

Country Status (3)

Country Link
EP (1) EP2152413A2 (fr)
KR (1) KR100837377B1 (fr)
WO (1) WO2008147013A2 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11104575B2 (en) 2016-05-12 2021-08-31 Fujian Institute Of Research On The Structure Of Matter, Chinese Academy Of Science Nanocatalysts, preparation methods and applications for reforming carbon dioxide and methane to syngas

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102489312B (zh) * 2011-11-24 2013-06-19 武汉凯迪工程技术研究总院有限公司 基于多孔材料限域的费托合成钴基纳米催化剂及其制备方法
KR101469183B1 (ko) * 2013-08-23 2014-12-10 한국화학연구원 촉매활성 성분이 지지체에 담지된 촉매의 제조방법
KR20150108437A (ko) * 2014-03-17 2015-09-30 씨큐브 주식회사 판상 산화 알루미늄 및 이의 제조방법
CN104226315B (zh) * 2014-09-30 2017-01-11 厦门大学 一氧化碳加氢制混合烃的Co基催化剂及其制备方法
CN113117683A (zh) * 2021-04-16 2021-07-16 郑州大学 负载型催化剂及其制备方法
CN116943662B (zh) * 2023-06-13 2024-02-20 北京海望氢能科技有限公司 一种非均相催化剂及其制备方法与应用

Citations (1)

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US4619910A (en) * 1985-06-05 1986-10-28 Air Products And Chemicals, Inc. Catalyst for selective conversion of synthesis gas and method of making the catalyst

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JP2859270B2 (ja) * 1987-06-11 1999-02-17 旭光学工業株式会社 カメラの視線方向検出装置
US4799077A (en) * 1987-11-23 1989-01-17 Polaroid Corporation Common drive for shutter blades and objective lens assembly
US7541310B2 (en) 2003-10-16 2009-06-02 Conocophillips Company Silica-alumina catalyst support, catalysts made therefrom and methods of making and using same

Patent Citations (1)

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Publication number Priority date Publication date Assignee Title
US4619910A (en) * 1985-06-05 1986-10-28 Air Products And Chemicals, Inc. Catalyst for selective conversion of synthesis gas and method of making the catalyst

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11104575B2 (en) 2016-05-12 2021-08-31 Fujian Institute Of Research On The Structure Of Matter, Chinese Academy Of Science Nanocatalysts, preparation methods and applications for reforming carbon dioxide and methane to syngas

Also Published As

Publication number Publication date
WO2008147013A2 (fr) 2008-12-04
KR100837377B1 (ko) 2008-06-12
EP2152413A2 (fr) 2010-02-17

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