[go: up one dir, main page]

WO2008147013A3 - Preparation methods for liquid hydrocarbons from syngas by using the zirconia-aluminum oxide-based fischer-tropsch catalysts - Google Patents

Preparation methods for liquid hydrocarbons from syngas by using the zirconia-aluminum oxide-based fischer-tropsch catalysts Download PDF

Info

Publication number
WO2008147013A3
WO2008147013A3 PCT/KR2008/000547 KR2008000547W WO2008147013A3 WO 2008147013 A3 WO2008147013 A3 WO 2008147013A3 KR 2008000547 W KR2008000547 W KR 2008000547W WO 2008147013 A3 WO2008147013 A3 WO 2008147013A3
Authority
WO
WIPO (PCT)
Prior art keywords
zirconia
syngas
liquid hydrocarbons
aluminum oxide
preparation methods
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2008/000547
Other languages
French (fr)
Other versions
WO2008147013A2 (en
Inventor
Ki-Won Jun
Jong-Wook Bae
Seung-Moon Kim
Jong-Hyeok Oh
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Korea Research Institute of Chemical Technology KRICT
Hyundai Engineering Co Ltd
KOREA INTERNATIONAL CORP
Doosan Mecatec Co Ltd
SK Energy Co Ltd
DL Holdings Co Ltd
Original Assignee
Korea Research Institute of Chemical Technology KRICT
Hyundai Engineering Co Ltd
Daelim Industrial Co Ltd
KOREA INTERNATIONAL CORP
Doosan Mecatec Co Ltd
SK Energy Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Korea Research Institute of Chemical Technology KRICT, Hyundai Engineering Co Ltd, Daelim Industrial Co Ltd, KOREA INTERNATIONAL CORP, Doosan Mecatec Co Ltd, SK Energy Co Ltd filed Critical Korea Research Institute of Chemical Technology KRICT
Priority to EP08705003A priority Critical patent/EP2152413A2/en
Publication of WO2008147013A2 publication Critical patent/WO2008147013A2/en
Publication of WO2008147013A3 publication Critical patent/WO2008147013A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/69—Pore distribution bimodal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8896—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/30—Constitutive chemical elements of heterogeneous catalysts of Group III (IIIA or IIIB) of the Periodic Table
    • B01J2523/31—Aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/40—Constitutive chemical elements of heterogeneous catalysts of Group IV (IVA or IVB) of the Periodic Table
    • B01J2523/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

The present invention relates to a cobalt/zirconia-alumina catalyst, in which cobalt is supported as an active ingredient on zirconia-alumina prepared by co-precipitation, having a bimodal pore structure with different pore sizes and maintaining a specific pore volume ratio and a method for preparing liquid hydrocarbons with high yield from the Fischer- Tropsch of a syngas (CO/H2/CO2 ) in the presence of the cobalt/zirconia-alumina catalyst.
PCT/KR2008/000547 2007-05-29 2008-01-30 Preparation methods for liquid hydrocarbons from syngas by using the zirconia-aluminum oxide-based fischer-tropsch catalysts Ceased WO2008147013A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP08705003A EP2152413A2 (en) 2007-05-29 2008-01-30 Preparation methods for liquid hydrocarbons from syngas by using the zirconia-aluminum oxide-based fischer-tropsch catalysts

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020070052243A KR100837377B1 (en) 2007-05-29 2007-05-29 Fischer-Tropsch reaction catalyst using a mixed carrier of zirconia and alumina and method for producing liquid hydrocarbon from syngas using the same
KR10-2007-0052243 2007-05-29

Publications (2)

Publication Number Publication Date
WO2008147013A2 WO2008147013A2 (en) 2008-12-04
WO2008147013A3 true WO2008147013A3 (en) 2009-03-26

Family

ID=39771004

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2008/000547 Ceased WO2008147013A2 (en) 2007-05-29 2008-01-30 Preparation methods for liquid hydrocarbons from syngas by using the zirconia-aluminum oxide-based fischer-tropsch catalysts

Country Status (3)

Country Link
EP (1) EP2152413A2 (en)
KR (1) KR100837377B1 (en)
WO (1) WO2008147013A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11104575B2 (en) 2016-05-12 2021-08-31 Fujian Institute Of Research On The Structure Of Matter, Chinese Academy Of Science Nanocatalysts, preparation methods and applications for reforming carbon dioxide and methane to syngas

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102489312B (en) * 2011-11-24 2013-06-19 武汉凯迪工程技术研究总院有限公司 Fischer-Tropsch synthesis cobalt-based nanocatalyst based on porous material confinement and its preparation method
KR101469183B1 (en) * 2013-08-23 2014-12-10 한국화학연구원 method of prepering supported catalyst
KR20150108437A (en) * 2014-03-17 2015-09-30 씨큐브 주식회사 Flaky aluminum oxide and method of producing thereof
CN104226315B (en) * 2014-09-30 2017-01-11 厦门大学 Co-based catalyst used for preparing hydrocarbon mixture through CO hydrogenation and preparation method thereof
CN113117683A (en) * 2021-04-16 2021-07-16 郑州大学 Supported catalyst and preparation method thereof
CN116943662B (en) * 2023-06-13 2024-02-20 北京海望氢能科技有限公司 Heterogeneous catalyst and preparation method and application thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4619910A (en) * 1985-06-05 1986-10-28 Air Products And Chemicals, Inc. Catalyst for selective conversion of synthesis gas and method of making the catalyst

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2859270B2 (en) * 1987-06-11 1999-02-17 旭光学工業株式会社 Camera gaze direction detection device
US4799077A (en) * 1987-11-23 1989-01-17 Polaroid Corporation Common drive for shutter blades and objective lens assembly
US7541310B2 (en) 2003-10-16 2009-06-02 Conocophillips Company Silica-alumina catalyst support, catalysts made therefrom and methods of making and using same

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4619910A (en) * 1985-06-05 1986-10-28 Air Products And Chemicals, Inc. Catalyst for selective conversion of synthesis gas and method of making the catalyst

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11104575B2 (en) 2016-05-12 2021-08-31 Fujian Institute Of Research On The Structure Of Matter, Chinese Academy Of Science Nanocatalysts, preparation methods and applications for reforming carbon dioxide and methane to syngas

Also Published As

Publication number Publication date
WO2008147013A2 (en) 2008-12-04
KR100837377B1 (en) 2008-06-12
EP2152413A2 (en) 2010-02-17

Similar Documents

Publication Publication Date Title
WO2008147013A3 (en) Preparation methods for liquid hydrocarbons from syngas by using the zirconia-aluminum oxide-based fischer-tropsch catalysts
WO2009014292A3 (en) Catalysts for fischer-tropsch synthesis on cobalt/phosphorus-aluminum oxide and preparation methods thereof
WO2010097754A3 (en) Process for the preparation of fischer - tropsch catalysts and their use
WO2008047103A8 (en) Process for the conversion of hydrocarbons to alcohols
WO2009119977A3 (en) Cobalt/zirconium-phosphorus/silica catalyst for fischer-tropsch synthesis and method of preparing the same
WO2010089265A3 (en) Hydrogenation catalysts, the production and the use thereof
EP2990103A4 (en) Fischer-tropsch synthesis catalyst for syngas to low carbon olefins, modified molecular sieve carrier and preparation method thereof
CA2862554A1 (en) Improved carbon capture in fermentation
WO2009003026A3 (en) Method of making alcohols
WO2008036563A3 (en) Methods for conversion of methane to useful hydrocarbons and catalysts for use therein
WO2007075428A3 (en) Alcohol synthesis from co or co2
WO2009022262A3 (en) Method of activating a fischer-tropsch catalyst
IN2012DN00739A (en)
MY159723A (en) A process for preparing methanol, dimethyl ether, and low carbon olefins from syngas
EP2311560A4 (en) Complex oxide for hydrocarbon reforming catalyst, method for producing the same, and method for producing synthetic gas using the same
IN2012DN00461A (en)
WO2011062773A3 (en) Zeolite supported cobalt hybrid fischer-tropsch catalyst
EP2474355A4 (en) Hydrocarbon gas reforming catalyst, method for producing same, and method for producing synthetic gas
WO2012122057A3 (en) Catalysts for the reduction of carbon dioxide to methanol
EP2829319A8 (en) A porous organic polymer capable of adsorbing gas and the method of preparing thereof
WO2011031017A3 (en) Molded zeolite-based catalyst for an olefin cracking reaction, and method for producing light olefins from synthetic gas
EP2732865A3 (en) Integrated hybrid membrane/absorption process for CO2 capture and utilization
WO2017085594A3 (en) Process and catalyst for conversion of co2 to syngas for a simultaneous production of olefins and methanol
WO2008093073A3 (en) Preparation of fischer-tropsch catalysts
WO2011053953A3 (en) Supported rhodium synthesis gas conversion catalyst compositions

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 08705003

Country of ref document: EP

Kind code of ref document: A2

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 2008705003

Country of ref document: EP