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WO2008081726A1 - アミド又はラクタムの製造法 - Google Patents

アミド又はラクタムの製造法 Download PDF

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Publication number
WO2008081726A1
WO2008081726A1 PCT/JP2007/074499 JP2007074499W WO2008081726A1 WO 2008081726 A1 WO2008081726 A1 WO 2008081726A1 JP 2007074499 W JP2007074499 W JP 2007074499W WO 2008081726 A1 WO2008081726 A1 WO 2008081726A1
Authority
WO
WIPO (PCT)
Prior art keywords
lactam
amide
production
producing
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2007/074499
Other languages
English (en)
French (fr)
Inventor
Yasutaka Ishii
Takahiro Iwahama
Tatsuya Nakano
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Daicel Corp
Original Assignee
Daicel Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Daicel Chemical Industries Ltd filed Critical Daicel Chemical Industries Ltd
Priority to US12/519,675 priority Critical patent/US20100029932A1/en
Priority to EP07859896A priority patent/EP2116529A4/en
Publication of WO2008081726A1 publication Critical patent/WO2008081726A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00—Preparation of carboxylic acid amides
    • C07C231/10—Preparation of carboxylic acid amides from compounds not provided for in groups C07C231/02 - C07C231/08
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D201/00—Preparation, separation, purification or stabilisation of unsubstituted lactams
    • C07D201/02—Preparation of lactams
    • C07D201/04—Preparation of lactams from or via oximes by Beckmann rearrangement
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/68—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
    • C07D211/72—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D211/74—Oxygen atoms
    • C07D211/76—Oxygen atoms attached in position 2 or 6
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D223/00—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom
    • C07D223/02—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C07D223/06—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D223/08—Oxygen atoms
    • C07D223/10—Oxygen atoms attached in position 2
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D225/00—Heterocyclic compounds containing rings of more than seven members having one nitrogen atom as the only ring hetero atom
    • C07D225/02—Heterocyclic compounds containing rings of more than seven members having one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D227/00—Heterocyclic compounds containing rings having one nitrogen atom as the only ring hetero atom, according to more than one of groups C07D203/00 - C07D225/00
    • C07D227/02—Heterocyclic compounds containing rings having one nitrogen atom as the only ring hetero atom, according to more than one of groups C07D203/00 - C07D225/00 with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D227/06—Heterocyclic compounds containing rings having one nitrogen atom as the only ring hetero atom, according to more than one of groups C07D203/00 - C07D225/00 with only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D227/08—Oxygen atoms
    • C07D227/087—One doubly-bound oxygen atom in position 2, e.g. lactams

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Other In-Based Heterocyclic Compounds (AREA)

Abstract

　硫酸アンモニウム等の多量の副生成物を生じさせることなくオキシム化合物の転位反応を進行させ、アミド又はラクタムを簡易かつ高い収率で製造する方法を提供する。 　本発明のアミド又はラクタムの製造方法では、下記式（１） －Ｚ－Ｘ （１） （式中、ＺはＰ、Ｎ、Ｓ、Ｂ又はＳｉ原子を示し、Ｘは脱離基を示す。ＺはＸ以外に、１又は２以上の原子又は基と結合している） で示される構造を含む化合物の存在下、オキシム化合物を転位させ、対応するアミド又はラクタムを生成させる。この製造方法において、Ｘはハロゲン原子であってもよい。
PCT/JP2007/074499 2006-12-28 2007-12-20 アミド又はラクタムの製造法 Ceased WO2008081726A1 (ja)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US12/519,675 US20100029932A1 (en) 2006-12-28 2007-12-20 Process for production of amide or lactam
EP07859896A EP2116529A4 (en) 2006-12-28 2007-12-20 METHOD FOR PRODUCING AN AMID OR LACTAM

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2006-353956 2006-12-28
JP2006353956A JP2008162935A (ja) 2006-12-28 2006-12-28 アミド又はラクタムの製造法

Publications (1)

Publication Number Publication Date
WO2008081726A1 true WO2008081726A1 (ja) 2008-07-10

Family

ID=39588411

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2007/074499 Ceased WO2008081726A1 (ja) 2006-12-28 2007-12-20 アミド又はラクタムの製造法

Country Status (6)

Country Link
US (1) US20100029932A1 (ja)
EP (1) EP2116529A4 (ja)
JP (1) JP2008162935A (ja)
KR (1) KR20090094170A (ja)
CN (1) CN101547897A (ja)
WO (1) WO2008081726A1 (ja)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009298706A (ja) * 2008-06-11 2009-12-24 Daicel Chem Ind Ltd アミド又はラクタムの製造法
US8530645B2 (en) 2009-03-04 2013-09-10 Ube Industries, Ltd. Method for producing amide compound
EP2481728B1 (en) * 2009-09-24 2014-07-16 Ube Industries, Ltd. Novel compound and method for producing amide compound using same
JP5708637B2 (ja) 2010-03-15 2015-04-30 宇部興産株式会社 アミド化合物の製造方法
CN103965097A (zh) * 2014-05-22 2014-08-06 南开大学 一种2-哌啶酮的制备方法
JP6918647B2 (ja) 2017-08-30 2021-08-11 キヤノン株式会社 力センサ、トルクセンサ、力覚センサ、指先力センサ、およびその製造方法
CN113943239A (zh) * 2020-07-15 2022-01-18 中国石油化工股份有限公司 制备戊内酰胺的方法和系统

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5141376A (en) * 1974-08-01 1976-04-07 Aquitaine Total Organico Rakutamuo taiono okishimukaraeruhoho
JP2003529578A (ja) * 2000-03-31 2003-10-07 メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフトング 有機オキシムのベックマン転位のための方法
JP2006219470A (ja) 2005-01-14 2006-08-24 Univ Nagoya オキシム化合物のベックマン転位反応用触媒、及びそれを用いたアミド化合物の製造方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW223622B (ja) * 1991-05-21 1994-05-11 Sumitomo Chemical Co
FR2784103B1 (fr) * 1998-09-21 2000-12-08 Atochem Elf Sa Procede de preparation de lauryllactame par photonitrosation de cyclododecane et transposition de beckmann en presence d'acide methanesulfonique
EP1214294A1 (en) * 1999-06-28 2002-06-19 Biocryst Pharmaceuticals, Inc. Process for preparing substituted cyclopentane derivatives and novel crystalline structures thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5141376A (en) * 1974-08-01 1976-04-07 Aquitaine Total Organico Rakutamuo taiono okishimukaraeruhoho
JP2003529578A (ja) * 2000-03-31 2003-10-07 メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフトング 有機オキシムのベックマン転位のための方法
JP2006219470A (ja) 2005-01-14 2006-08-24 Univ Nagoya オキシム化合物のベックマン転位反応用触媒、及びそれを用いたアミド化合物の製造方法

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
FERNANDEZ F. ET AL.: "The role of acids in the Beckmann rearrangement of (-)-(1R,trans)-p-menthan-3-one (E)-oxime", JOURNAL OF CHEMICAL RESEARCH, SYNOPSES, no. 10, 1987, pages 340 - 341, XP008110357 *
J. AM. CHEM. SOC., vol. 127, 2005, pages 11240 - 11241
See also references of EP2116529A4 *

Also Published As

Publication number Publication date
JP2008162935A (ja) 2008-07-17
EP2116529A4 (en) 2010-09-08
CN101547897A (zh) 2009-09-30
EP2116529A1 (en) 2009-11-11
KR20090094170A (ko) 2009-09-03
US20100029932A1 (en) 2010-02-04

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