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WO2008052920A1 - Procédé de fabrication de produits plats en acier à partir d'un acier multiphase allié à de l'aluminium - Google Patents

Procédé de fabrication de produits plats en acier à partir d'un acier multiphase allié à de l'aluminium Download PDF

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Publication number
WO2008052920A1
WO2008052920A1 PCT/EP2007/061391 EP2007061391W WO2008052920A1 WO 2008052920 A1 WO2008052920 A1 WO 2008052920A1 EP 2007061391 W EP2007061391 W EP 2007061391W WO 2008052920 A1 WO2008052920 A1 WO 2008052920A1
Authority
WO
WIPO (PCT)
Prior art keywords
strip
hot
rolled
cold
thickness
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2007/061391
Other languages
German (de)
English (en)
Inventor
Brigitte Hammer
Thomas Heller
Johann Wilhelm Schmitz
Jochen Wans
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ThyssenKrupp Steel Europe AG
Original Assignee
ThyssenKrupp Steel AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ThyssenKrupp Steel AG filed Critical ThyssenKrupp Steel AG
Priority to JP2009533823A priority Critical patent/JP5350254B2/ja
Priority to KR1020097007486A priority patent/KR101461584B1/ko
Priority to CN2007800393899A priority patent/CN101528966B/zh
Priority to US12/447,627 priority patent/US20100065162A1/en
Publication of WO2008052920A1 publication Critical patent/WO2008052920A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/04—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
    • C21D8/041—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing involving a particular fabrication or treatment of ingot or slab
    • C21D8/0415—Rapid solidification; Thin strip casting
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/04—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/001—Continuous casting of metals, i.e. casting in indefinite lengths of specific alloys
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/06—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/04—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
    • C21D8/0421—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing characterised by the working steps
    • C21D8/0426—Hot rolling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/04—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
    • C21D8/0447—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing characterised by the heat treatment
    • C21D8/0473—Final recrystallisation annealing
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/002—Bainite
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/008—Martensite

Definitions

  • the invention relates to a method for producing steel flat products, such as strips or sheet metal blanks, from high-strength, aluminum-alloyed steels.
  • steels belong to the group of multiphase steels. These are usually steels whose properties are determined by the type, amount and arrangement of the phases of the structure.
  • the structure therefore has at least two phases (eg ferrite, martensite, bainite). This gives them a strength / formability combination that is superior to conventional steels.
  • This preparation route presents problems in particular when casting peritectically solidifying compositions.
  • These steel grades there is the danger of the formation of longitudinal cracks during continuous casting.
  • the formation of such longitudinal cracks can reduce the quality of the hot strips produced from the cast slabs or thin slabs so much that they become unusable.
  • extensive measures such as increased insulation costs, are required, which can go so far that the processing of such steel grades becomes uneconomical.
  • multiphase steels are of particular interest for the automotive industry because of their high strength, they allow the use of lower material thicknesses and concomitantly a reduction in vehicle weight and, secondly, the safety of the vehicle body in the event of a collision (crash behavior) ,
  • multiphase steels with at least constant strength of the overall body allow a reduction in the sheet thickness of a component produced from such multiphase steels compared to a body produced from conventional steels.
  • multiphase steels are melted in the converter steelworks and cast on a continuous casting plant into slabs or thin slabs, which are then hot rolled into hot strip and coiled.
  • the mechanical properties of the hot strip can be varied.
  • the hot strips can be cold-rolled to cold-rolled strip in order to provide thinner sheet-metal thicknesses (EP 0 910 675 B1, EP 0 966 547 B1, EP 1 169 486 B1, EP 1 319 725 B1, EP 1 398 390 A1).
  • the cast strip is then hot rolled in-line in one or more passes of between 25% and 70% strain to a hot strip.
  • the final temperature of hot rolling is above the Ar 3 temperature.
  • the hot strip obtained is then cooled in two stages. In the first stage of this cooling, a cooling rate of 5 -
  • the object of the invention was therefore to provide a method by means of which high-strength steel flat products can be produced over a wide range of geometric dimensions with reduced manufacturing outlay.
  • this object has been achieved by a method for producing steel flat products, in which a multiphase structure forming steel, the (in wt .-%) 0.10 - 0.14% C, 1 , 30 - 1.70% Mn, up to 0.030% P, up to 0.004% S, 0.10 - 0.30% Si, 0.90 - 1.2% Al, up to 0.0070% N, 0.070 0.130% Ti, 0.040-0.060% Nb, 0.140-0.260% Mo and the remainder contains iron and unavoidable impurities, is cast into a cast strip with a thickness of 1-4 mm, in which the cast strip in a continuous operation a degree of deformation of more than 20% in-line at a lying in the range of 850 - 1000 0 C hot rolling end temperature is hot rolled to a hot strip with a thickness of 0.5 - 3.2 mm and the
  • the hot strip at a 350 - 480 0 C forming amount coiling temperature is coiled, so that a hot strip is obtained, the tensile strength R m of at least 800 MPa at an elongation at break A 8 o of at least 5%.
  • the invention uses the possibility of strip casting to process a particularly high-strength, peritectically solidifying multiphase steel into a hot strip. Since the cast strip itself already has a small thickness, in the course of hot rolling of this strip only relatively low degrees of deformation must be maintained in order to produce flat products with small thicknesses, as are required in particular in the automotive industry. Thus, by specifying a corresponding output thickness of the cast strip, it is easily possible to produce hot strips with the method according to the invention, which have a maximum property distribution of at most 1.5 mm and from which, for example, elements for the support structure of an automobile can be produced.
  • the invention makes it possible to manufacture high-strength hot strips consisting of a martensitic steel of the specified composition processed according to the invention, whose width is more than 1,200 mm, in particular more than 1,600 mm.
  • a further particular advantage of the procedure according to the invention is that hot strip produced according to the invention has high strengths of at least 800 MPa, without having to observe a special cooling cycle of the hot strip between the end of the hot rolling and the hasp, as described in EP 1 072 689 Bl is required by the need for a cooling break.
  • it merely has to be ensured that the hot rolling ends in a relatively narrow temperature window and that the reeling is also carried out in a precisely defined temperature range. In between there is a one-stage cooling down.
  • Hot strips produced according to the invention are particularly suitable for further processing into cold rolled strip. Accordingly, a practice-oriented embodiment of the invention provides that the hot strip is cold rolled to a cold strip having a thickness of 0.5-1.4 mm, in particular 0.7 mm to 1.3 mm, as is required for the construction of automobile bodies. In order to eliminate arising during cold hardening, the cold strip is at an annealing temperature from 750 to 850 0 C to be annealed. For cold rolled strip produced in this way from the hot strip produced according to the invention, tensile strengths of at least 800 MPa can be reliably ensured. The breaking elongation A 50 of the cold strip is just as safe at least 10%.
  • the flat product produced according to the invention is characterized by a particularly good coatability.
  • the cold strip is provided in a conventional manner with a metallic coating, which may be, for example, a galvanizing.
  • the strength and elongation values according to the invention produced hot strips can be adjusted over a wide range by an appropriate vote of the hot rolling and reel temperatures.
  • R m tensile strength
  • the tapes cast from steels A and B were hot rolled into a hot strip whose thickness was 1.25 mm in four different trials immediately after in-line strip casting at a hot rolling end temperature WET. Subsequently, each hot strip obtained has been cooled directly in a cooling step to a coiler temperature HT and coiled. After coiling, the hot strips produced from steels A and B each had a tensile strength R m and an elongation at break A 80 , which, like the hot rolling end temperature WET and reel temperature HT, respectively, maintained in their preparation, are given in Table 2.
  • the tensile strength R m of the cold strip thus obtained was 985 MPa.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Heat Treatment Of Sheet Steel (AREA)
  • Metal Rolling (AREA)
  • Coating With Molten Metal (AREA)
  • Heat Treatment Of Steel (AREA)
  • Treatment Of Steel In Its Molten State (AREA)

Abstract

L'invention concerne un procédé permettant de fabriquer des produits plats en acier très résistants sur une grande gamme de dimensions géométriques, avec des moyens de fabrication réduits. A cet effet, un acier formant une structure multiphase contenant (en % en poids) 0,10 - 0,14 % C, 1,30 - 1,70 % Mn, jusqu'à 0,030 % P, jusqu'à 0,004 % S, 0,10 - 0,30 % Si, 0,90 - 1,2 % Al, jusqu'à 0,0070 % N, 0,070 - 0,130 % Ti, 0,040 - 0,060 % Nb, 0,140 - 0,260 % Mo, et le reste de fer et d'impuretés inévitables, est coulé sous forme de bande coulée ayant une épaisseur de 1 - 4 mm; la bande coulée est laminée à chaud en continu avec un degré de déformation de plus de 20 % en ligne, à une température terminale de laminage à chaud de 850 - 1000 °C, sous forme de bande à chaud présentant une épaisseur de 0,5 - 3,2 mm; puis la bande à chaud est bobinée à une température de bobinage de 350 - 480 °C de manière à obtenir une bande à chaud dont la résistance à la traction R<SUB>m</SUB> est d'au moins 800 MPa pour un allongement à la rupture A<SUB>80</SUB> d'au moins 5 %.
PCT/EP2007/061391 2006-10-30 2007-10-24 Procédé de fabrication de produits plats en acier à partir d'un acier multiphase allié à de l'aluminium Ceased WO2008052920A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2009533823A JP5350254B2 (ja) 2006-10-30 2007-10-24 アルミニウム合金化多相鋼からフラット鋼生成物を製造する方法
KR1020097007486A KR101461584B1 (ko) 2006-10-30 2007-10-24 알루미늄으로 합금화된 다상 강으로부터 평판형 강 제품을 제조하는 방법
CN2007800393899A CN101528966B (zh) 2006-10-30 2007-10-24 由铝合金化多相钢制备扁钢产品的方法
US12/447,627 US20100065162A1 (en) 2006-10-30 2007-10-24 Method for Manufacturing Flat Steel Products From Aluminum Alloyed Multi-Phase Steel

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP06123140.3 2006-10-30
EP06123140A EP1918404B1 (fr) 2006-10-30 2006-10-30 Procédé pour la fabrication de produits plats à partir d'un acier à plusieurs phases allié en aluminium

Publications (1)

Publication Number Publication Date
WO2008052920A1 true WO2008052920A1 (fr) 2008-05-08

Family

ID=37733702

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2007/061391 Ceased WO2008052920A1 (fr) 2006-10-30 2007-10-24 Procédé de fabrication de produits plats en acier à partir d'un acier multiphase allié à de l'aluminium

Country Status (10)

Country Link
US (1) US20100065162A1 (fr)
EP (1) EP1918404B1 (fr)
JP (1) JP5350254B2 (fr)
KR (1) KR101461584B1 (fr)
CN (1) CN101528966B (fr)
AT (1) ATE432374T1 (fr)
DE (1) DE502006003832D1 (fr)
ES (1) ES2325963T3 (fr)
PL (1) PL1918404T3 (fr)
WO (1) WO2008052920A1 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10071416B2 (en) * 2005-10-20 2018-09-11 Nucor Corporation High strength thin cast strip product and method for making the same
US8435363B2 (en) * 2007-10-10 2013-05-07 Nucor Corporation Complex metallographic structured high strength steel and manufacturing same
WO2011100798A1 (fr) 2010-02-20 2011-08-25 Bluescope Steel Limited Nitratation d'acier au niobium et produit fabriqué par ce moyen
MX2017008027A (es) 2014-12-19 2017-10-20 Nucor Corp Hoja de acero martensitico de calibre liviano laminada en caliente y metodo para fabricarla.

Citations (6)

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Publication number Priority date Publication date Assignee Title
US5470529A (en) * 1994-03-08 1995-11-28 Sumitomo Metal Industries, Ltd. High tensile strength steel sheet having improved formability
JPH10130776A (ja) * 1996-10-23 1998-05-19 Sumitomo Metal Ind Ltd 高延性型高張力冷延鋼板
EP1072689A1 (fr) * 1999-07-30 2001-01-31 Usinor Procédé de fabrication de bandes minces en acier de type "TRIP" , et bandes minces ainsi obtenues
FR2798871A1 (fr) * 1999-09-24 2001-03-30 Usinor Procede de fabrication de bandes d'acier au carbone, notamment d'acier pour emballages, et bandes ainsi produites
WO2002026424A1 (fr) * 2000-09-29 2002-04-04 Ishikawajima-Harima Heavy Industries Company Limited Production de bandes d'acier fines
EP1396550A1 (fr) * 2002-08-28 2004-03-10 ThyssenKrupp Stahl AG Procédé pour la fabrication d' une bande à chaud

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ES2230613T3 (es) * 1996-07-12 2005-05-01 Thyssenkrupp Stahl Ag Banda de acero de laminacion en caliente y metodo para su fabricacion.
AUPQ779900A0 (en) * 2000-05-26 2000-06-22 Bhp Steel (Jla) Pty Limited Hot rolling thin strip
WO2002033141A1 (fr) * 2000-10-19 2002-04-25 Nkk Corporation Tole d"acier plaque de zinc et procede de preparation de cette tole, et procede de fabrication d"un article forme par usinage a la presse
DE10128544C2 (de) * 2001-06-13 2003-06-05 Thyssenkrupp Stahl Ag Höherfestes, kaltumformbares Stahlblech, Verfahren zu seiner Herstellung und Verwendung eines solchen Blechs
US6878920B2 (en) * 2002-06-28 2005-04-12 Intel Corporation Optical receiver circuit, method, and system
JP4510488B2 (ja) * 2004-03-11 2010-07-21 新日本製鐵株式会社 成形性および穴拡げ性に優れた溶融亜鉛めっき複合高強度鋼板およびその製造方法
TW200604352A (en) 2004-03-31 2006-02-01 Jfe Steel Corp High-rigidity high-strength thin steel sheet and method for producing same

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5470529A (en) * 1994-03-08 1995-11-28 Sumitomo Metal Industries, Ltd. High tensile strength steel sheet having improved formability
JPH10130776A (ja) * 1996-10-23 1998-05-19 Sumitomo Metal Ind Ltd 高延性型高張力冷延鋼板
EP1072689A1 (fr) * 1999-07-30 2001-01-31 Usinor Procédé de fabrication de bandes minces en acier de type "TRIP" , et bandes minces ainsi obtenues
FR2798871A1 (fr) * 1999-09-24 2001-03-30 Usinor Procede de fabrication de bandes d'acier au carbone, notamment d'acier pour emballages, et bandes ainsi produites
WO2002026424A1 (fr) * 2000-09-29 2002-04-04 Ishikawajima-Harima Heavy Industries Company Limited Production de bandes d'acier fines
EP1396550A1 (fr) * 2002-08-28 2004-03-10 ThyssenKrupp Stahl AG Procédé pour la fabrication d' une bande à chaud

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
LINDENBERG H-U ET AL: "EUROSTRIP - STATE OF THE ART OF STRIP CASTING EUROSTRIP - STAND DER TECHNIK BEIM BANDGIESSEN", STAHL UND EISEN, VERLAG STAHLEISEN, DUSSELDORF, DE, vol. 121, no. 12, 14 December 2001 (2001-12-14), pages 97 - 104, XP001103986, ISSN: 0340-4803 *
SENK D ET AL: "UMFORMEN UND KUEHLEN VON DIREKTGEGOSSENEM STAHLBAND IN-LINE ROLLING AND COOLING OF DIRECT CAST STEEL STRIP", STAHL UND EISEN, VERLAG STAHLEISEN, DUSSELDORF, DE, vol. 120, no. 6, 16 June 2000 (2000-06-16), pages 65 - 69, XP001118293, ISSN: 0340-4803 *

Also Published As

Publication number Publication date
DE502006003832D1 (de) 2009-07-09
ES2325963T3 (es) 2009-09-25
KR20090090302A (ko) 2009-08-25
CN101528966B (zh) 2011-06-15
ATE432374T1 (de) 2009-06-15
KR101461584B1 (ko) 2014-11-13
JP5350254B2 (ja) 2013-11-27
PL1918404T3 (pl) 2009-10-30
JP2010508436A (ja) 2010-03-18
EP1918404B1 (fr) 2009-05-27
US20100065162A1 (en) 2010-03-18
EP1918404A1 (fr) 2008-05-07
CN101528966A (zh) 2009-09-09

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