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WO2007018160A1 - Composé herbicide du type en suspension aqueuse - Google Patents

Composé herbicide du type en suspension aqueuse Download PDF

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Publication number
WO2007018160A1
WO2007018160A1 PCT/JP2006/315531 JP2006315531W WO2007018160A1 WO 2007018160 A1 WO2007018160 A1 WO 2007018160A1 JP 2006315531 W JP2006315531 W JP 2006315531W WO 2007018160 A1 WO2007018160 A1 WO 2007018160A1
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WO
WIPO (PCT)
Prior art keywords
aqueous suspension
herbicidal composition
weight
parts
sulfonate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2006/315531
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English (en)
Japanese (ja)
Inventor
Yoshiaki Ishihara
Tatsuhiko Tsuruta
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ishihara Sangyo Kaisha Ltd
Original Assignee
Ishihara Sangyo Kaisha Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ishihara Sangyo Kaisha Ltd filed Critical Ishihara Sangyo Kaisha Ltd
Priority to CN2006800286676A priority Critical patent/CN101237770B/zh
Priority to KR1020087003231A priority patent/KR101246484B1/ko
Publication of WO2007018160A1 publication Critical patent/WO2007018160A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof

Definitions

  • the present invention relates to an aqueous suspension herbicidal composition in which the herbicidal sulfo-urea compound or a salt thereof is inhibited from being decomposed in water and stable suspension is maintained.
  • herbicides have been developed and put to practical use for the purpose of crop protection in cultivated land and weed control in non-agricultural land.
  • these herbicides are applied in the form of solid powders, granules, and other solid preparations that are sprayed by diluting in water at the time of use, such as power wettable powders and granular wettable powders.
  • it may be a liquid suspension formulation in which an active ingredient is suspended in water, vegetable oil, etc., together with a surfactant, etc. and diluted with water at the time of use.
  • a liquid suspension formulation is desirable to avoid.
  • the scale on the drug product bottle can be easily adjusted.
  • the liquid preparation that can be used is more advantageous than the solid preparation that requires a weighing machine such as a balance to measure the weight.
  • those suspended in vegetable oil are often used for cultivated cereals.
  • the organic solvent used in the emulsion is preferably not used as much as possible from the viewpoint of the effect on the surrounding environment to be applied or the flammability of the preparation, or even if used, the amount is preferably as small as possible. It is desired to prepare an aqueous suspension herbicidal composition that is stably suspended in water!
  • a sulfonylurea compound as a compound blended as an active ingredient of a herbicide is a compound that exhibits an excellent herbicidal effect at a relatively small application amount, and is therefore used as an active ingredient in many herbicides.
  • sulfo-urea compounds or their salts formulated as herbicidal active ingredients generally have a property that they are easily decomposed during storage. If the active ingredient concentration in the formulation decreases due to their decomposition, the herbicidal effect expected at the time of application cannot be exhibited, or the internal pressure of the suspension storage container is stored due to gas generation due to decomposition. May be high inside. As a result, the suspension liquid blows out at the time of opening, and the contents may cause various inconveniences such as contamination of workers and surroundings.
  • Japanese Patent Application Laid-Open No. 2000-159603 discloses an aqueous suspension herbicidal composition containing a herbicidal sulfo-lurea compound and phenol sulfonate or a formalin condensate thereof.
  • JP-A-59-205305 discloses an aqueous suspension herbicidal composition
  • a herbicidal sulfo-urea compound salt and an ammonium or alkali metal salt of a carboxylic acid or inorganic acid. It is disclosed. Specifically, at the time of producing the aqueous suspension herbicidal composition, the herbicidal sulfonylurea compound and the surfactant are mixed in water, and then added to the carboxylic acid or inorganic acid ammonium salt or alkali.
  • Patent No. 3,175,850 discloses preparing an aqueous suspension preparation of pyrazosulfuron using an inorganic acid, an organic acid or a buffer.
  • Patent Document 1 JP 2000-159603 A
  • Patent Document 2 JP 59-205305 A
  • Patent Document 3 Japanese Patent No. 3,175,850
  • the herbicidal sulfonylurea compound which is an active ingredient used in the present invention, is easily decomposed in water or produced as a suspension thereof. Since the process is complicated, practical examples have been seldom seen. Therefore, it is desired to prepare an aqueous suspension herbicidal composition that does not decompose a herbicidal sulfonylurea compound in water and maintains a stable suspended state without going through complicated steps.
  • the present inventors have conducted various studies to solve the above problems. As a result, by using an inorganic salt and a sulfonate salt as a specific surfactant, the herbicidal sulfo-urea compound does not decompose in water and maintains an aqueous suspension herb. The present inventors have found that the composition can be prepared without going through complicated steps and completed the present invention.
  • the present invention relates to (1) 1- [3-— [(4,6 dimethoxypyrimidine-2-ylcarbamoyl) sulfamoyl] -2-pyridyl] -2-fluoropropyl methoxyacetate, N-[(4, 6 dimethoxypyrimidine 2-yl) aminocarbol] — 2— (2 fluoro 1-hydroxypropyl) — 3-pyridinesulfonamides and their salt strength group power at least one herbicidal sulfonyl selected Urea compounds, (2) inorganic salts, (3) at least one sulfonate selected from the group consisting of aryl sulfonates, alkyl aryl sulfonates and their formalin condensates, and (4)
  • the present invention relates to an aqueous suspension herbicidal composition containing water, and a method for controlling undesired plants or suppressing the growth thereof using the composition.
  • the present invention provides an aqueous solution using an inorganic salt and an arylene sulfonate, an alkylaryl sulfonate, and at least one sulfonic acid salt selected from the group strength of their formalin condensate.
  • the present invention provides at least (1) 1- [3-[(4,6 dimethoxypyrimidine-2-ylcarbamoyl) sulfamoyl] -2-pyridyl] -2-fluoropropyl methoxyacetate , N- [(4, 6 dimethoxypyrimidine 1-2-yl) aminocarbol] — 2— (2 fluoro — 1 hydroxypropyl) 1 3 pyridinesulfonamide and at least one selected from the group consisting of their salt strength At least one sulfonic acid selected from the group consisting of (2) inorganic salts, (3) aryl sulfonates, alkyl aryl sulfonates and their formalin condensates
  • the present invention relates to a method for producing an aqueous suspension herbicidal composition by mixing a salt and (4) water and, if desired, wet milling.
  • an aqueous suspension herbicide in which the decomposition of the herbicidal sulfonylurea compound or a salt thereof is suppressed in the aqueous suspension herbicidal composition and the suspension of the preparation is sufficiently maintained.
  • a composition and a herbicidal method using the composition can be provided.
  • an aqueous suspension herbicidal composition can be prepared by mixing each component of the preparation and optionally wet-grinding, so that the active ingredient is once dissolved and reprecipitated. No manufacturing process is required.
  • the herbicidal sulfo-lurea compound used in the present invention is 1 [3— [(4,6-Dimethyoxypyrimidine-2-ylcarbamoyl) sulfamoyl] -2-cyclopyridyl] -2-fluoropropyl.
  • It is an amide (hereinafter referred to as Compound A2) or a salt thereof.
  • the salt include various salts. For example, salts with alkali metals such as sodium and potassium; salts with alkaline earth metals such as magnesium and calcium; salts with amines such as monomethylamine, dimethylamine and triethylamine.
  • Various inorganic salts are used in the present invention.
  • alkali metal phosphates and alkaline earth metal phosphates are used in the present invention.
  • alkali metal phosphates are desirable, and among these, sodium dihydrogen phosphate and potassium dihydrogen phosphate are more desirable.
  • the alkyl moiety in the sulfonates used in the present invention may be a linear one. However, it may be branched. Examples thereof include those having C to c such as methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl and the like.
  • Examples of the aryl moiety in the sulfonates include monocyclic or polycyclic compounds such as a benzene ring or a naphthalene ring.
  • Examples of the sulfonate salts include various salts. Examples include salts with alkali metals such as sodium and potassium; salts with alkaline earth metals such as magnesium and calcium.
  • the sulfonates are preferably alkylaryl sulfonates or formalin condensates thereof, more preferably alkylbenzene sulfonates, alkyl naphthalene sulfonates, alkylbenzene sulfonate formalin condensates, It is an alkyl naphthalene sulfonate formalin condensate.
  • alkylbenzene sulfonate formalin condensate and alkyl naphthalene sulfonate formalin condensate are more desirable.
  • the aqueous suspension herbicidal composition of the present invention may contain various adjuvants as desired.
  • Various adjuvants may be used as long as they are used in the technical field.
  • Specific examples of these various adjuvants include the following.
  • the preparation of the preparation can be performed according to a usual method in the technical field.
  • surfactants include, for example, fatty acid salts, benzoates, alkylsulfosuccinates, dialkylsulfosuccinates, polycarboxylates, alkyl sulfate esters, alkyl sulfates, alkyl diglycol ether sulfates.
  • anti-settling agent examples include silica, organic bentonite (Bentonite-alkylamino complex), bentonite, white carbon, and aluminum magnesium caustic acid. If desired, two or more of these may be mixed as appropriate.
  • thickener examples include heteropolysaccharides such as xanthan gum and guar gum; water-soluble polymers such as polybulal alcohol, sodium carboxymethylcellulose and sodium alginate; bentonite and white carbon. If desired, two or more of these may be mixed as appropriate.
  • antifoaming agent examples include polydimethylsiloxane and acetylene alcohol. If desired, two or more of these may be mixed as appropriate.
  • antifreezing agent examples include ethylene glycol, propylene glycol, glycerin, urea and the like. If desired, two or more of these may be mixed as appropriate.
  • preservatives examples include formalin, parachlorometaxylenol, 1,2-benzisothia Zolin-3-one and the like. If desired, two or more of these may be mixed as appropriate.
  • the solvent examples include monohydric alcohols such as propanol and isobutanol; polyhydric alcohols such as ethylene glycol, propylene glycol, diethylene glycol, hexylene glycol, polyethylene glycol, polypropylene glycol, and glycerin; propyl Such as cellosolve, butylcerosolve, ferrulecetosolve, propylene glycol monomethino ethenore, propylene glycol monomethino enoate, propylene glycol monopropyl ether, propylene glycol monobutyl ether, propylene glycol monophenol ether Glycol ethers; Ethers such as dioxane; Ketones such as cyclohexanone and methyl isobutyl ketone; Fatty acids such as acetic acid and butyric acid Esters such as isopropyl acetate and butyl acetate; nitrogen-containing sulfur-containing solvents such as N-
  • herbicidal compounds other than the herbicidal sulfonylurea compound or a salt thereof can be mixed or used together, and in this case, a further excellent effect, May exhibit activity.
  • the range of applicable grass species, the timing of chemical treatment, herbicidal activity, etc. may be improved in the preferred direction.
  • the herbicidal sulfo-lurea compound or its salt and other herbicidal compounds may be used separately in the form of a mixture prepared at the time of spraying. Use it as a turbid mixed herbicidal composition.
  • the present invention includes the above-described aqueous suspension mixed herbicidal composition and a method for controlling undesired plants or suppressing the growth thereof using the composition.
  • the present invention also includes a method for controlling undesired plants or suppressing the growth thereof by using separately prepared herbicidal sulfonylurea compounds or salts thereof and other herbicidal compounds. included.
  • herbicidal compounds can be selected as appropriate from, for example, the following compound groups (1) to (11) (generic names; some including those in the application for ISO). Even if there is no specific description, this When these compounds contain various structural isomers such as salts, alkyl esters and optical isomers, they are naturally included.
  • a quaternary ammonia such as paraquat or diquat, which is said to be a free radical in the plant itself, generating active oxygen and exhibiting rapid herbicidal efficacy. Salt system.
  • Uron imazosulfuron (imazosulfuron), cyclosulfamuron (cyclosulfamuron), prosulforon (prosulforon), flupirsulfuron (flupyrsulluron), triflusulfuron-methyl (triflusulforon-methyl), Halosulforon-methyl, thifensulforon- methyl), ethoxysulforon, oxasulforon, ethametsulfuron, iodosnorephron uodosulfuron, snolefosnoreflon sulfosulfuron, triasulforon, tribenuron methyl (tribenuron methyl) , Tritosulforon, foramsulforon, tri floxysulluron, isosulforon-methyl, mesosulfuron-methyl, talent noresosno Sulfo-Rule
  • Di-troaline systems such as trifluralin, oryzalin, oritalin, nitraline, pendimethalin, ethalfluralin, benfluralin, prodiamine Amides such as bensulide, napronamide, pronamide; amiprofos-methyl, butamifos, alofos, hyperophos, Organophosphorus such as piperophos; phelocarbamates such as propham, chlorpropham, and barban; daimuron, cumyluron, bromobutide Cumylamines such as asuram, dithiopyr, thiazopyr, cafenst role), indanofan, etc., which are said to show herbicidal efficacy by inhibiting cell mitosis in plants.
  • Di-troaline systems such as trifluralin, oryzalin, oritalin, nitraline, pendimethalin, ethalfluralin, benfluralin, pro
  • herbicidal efficacy by inhibiting plant protein biosynthesis or lipid biosynthesis.
  • EPTC butylate, vernolate, pebulate, cycloate, prosulfocarb, esprocarb, thiobencarb, dialate Thiocarbamates such as diallate and triallate; MSMA, DSMA, endothal, etho! Umesate, sodium chlorate, befrugonic acid ), Fosamine, pinoxaden, HOK-201 and the like.
  • the blending ratio of each component in the aqueous suspension herbicidal composition of the present invention cannot be specified unconditionally because it may be changed as appropriate according to the type of the blending component, the formulation form, the application scene, and the like.
  • Compound Al, Compound A 2 or a salt thereof as a herbicidal sulfonylurea compound is 0.1 to 60 parts by weight, preferably 0.5 to 50 parts by weight, and an inorganic salt is 0.1 to 25 parts by weight, preferably 1 to 20 parts by weight, more preferably 2 to 10 parts by weight, sulfonates are 0.01 to 30 parts by weight, preferably 0.1 to 20 parts by weight, and the remaining main component is water.
  • 0.01 to 10 parts by weight, preferably 0.05 to 5 parts by weight when blending thickeners 0.001 to 10 parts by weight, desirably 0.01 to 5 parts by weight when blending antifoaming agents 0.01 to 10 parts by weight, preferably 0.05 to 5 parts by weight when preservatives are added, 1 to 70 parts by weight, preferably 1 to 50 parts by weight, etc.
  • the herbicidal compound When the herbicidal compound is added, it is 0.1 to 60 parts by weight, preferably 0.1 to 50 parts by weight.
  • the aqueous suspension herbicidal composition of the present invention is applied to an undesired plant or a place where it grows, and is treated with, for example, a foliage treatment, a soil treatment, or a flooding treatment to produce annual weeds or perennials.
  • a foliage treatment for example, a foliage treatment, a soil treatment, or a flooding treatment to produce annual weeds or perennials.
  • a wide range of harmful plants such as weeds can be controlled or their growth can be suppressed.
  • Examples of harmful plants include Inubie, Tainubie, Barefoot, Enokorogusa, Akinoenokorogosa, Ohashiba, Oats, Oats, Sowbill, Cypress, Velvet Millet, Paragrass, Azegaya, Itasegaya, Sparrows Mosquitoes, fireflies, staghorns, moths, crabs and weeds; Of Camiaceae; Ichibi, Maruba morning glory, white-tailed, American goldfish, Suberuhi, Aobu, Aguayte, Yebisuda, Inho Examples include zuki bean, sanaetade, chickweed, onamomi, tanekikebana, photokenosa, ragweed, yaemdara, hinoki hinagao, datura, ezonokine thisami, and enoki tasa.
  • Herbicidal Compound Al, Compound A2 or a salt thereof as a sulfo-lurea compound can be applied at a rate of 1 to 500 g, preferably 2 to 250 g per lha.
  • Example 1 The ability to describe examples of the present invention below The present invention is not limited to these.
  • Example 1 The ability to describe examples of the present invention below The present invention is not limited to these.
  • Example 2 An aqueous suspension herbicidal composition was obtained by mixing the above ingredients and pulverizing with a wet pulverizer for 5 minutes.
  • Example 3 Aqueous suspension herbicidal composition was prepared by mixing 10.0 parts by weight or more of water containing 1,2-benzisothiazolin-3-one (1.0 part by weight) and then wet-grinding it with a wet grinder for 5 minutes.
  • Rhodorsil 432 (same as above) 0.1 parts by weight
  • Rhodorsil 432 (same as above) 0.1 parts by weight
  • Example 5 The above ingredients were mixed and pulverized with a wet pulverizer for 5 minutes to obtain an aqueous suspension herbicidal composition. [0046] Example 5
  • the above ingredients were mixed and pulverized with a wet pulverizer for 5 minutes to obtain an aqueous suspension herbicidal composition.
  • Rhodorsil 432 (same as above) 0.1 parts by weight
  • Rhodorsil 432 (same as above) 0.1 parts by weight
  • the above ingredients were mixed and pulverized with a wet pulverizer for 5 minutes to obtain an aqueous suspension herbicidal composition.
  • Example 1 The aqueous suspension herbicidal compositions of Example 1 and Comparative Example 1 were stored in a thermostat at 54 ° C. for 14 days.
  • Decomposition rate (%) [(Content immediately after production Content after storage) Z Content immediately after production] X 1 00
  • aqueous suspension of the present invention A predetermined amount (100 g ai / ha) of a herbicidal composition is diluted with water equivalent to 300 L / ha, and a spreading agent (trade name: Surfatatanto WK, manufactured by Kao Corporation) is added here. , Handle the foliage. On the 21st day after treatment, investigate the growth of the plant. As a result, the aqueous suspension herbicidal composition of the present invention exhibits excellent herbicidal activity.
  • the aqueous suspension herbicidal composition of the present invention is effectively used for crop protection in cultivated land and weed control in non-agricultural land.
  • the Japanese Patent Application 2005- 231841 filed on August 10, 2005 the Japanese Patent Application 2005-326624 filed on November 10, 2005, and the February 21, 2006 application
  • the entire contents of the specification, claims, and summary of Japanese Patent Application No. 2006-044472 are incorporated herein by reference as the disclosure of the specification of the present invention.

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

L'invention concerne l'élaboration d'un composé herbicide du type en suspension aqueuse qui permet d'éviter la décomposition d'une sulfonylurée herbicide dans l'eau tout en conservant un état de suspension constant, sans faire appel à aucune étape complexe. Le composé herbicide du type en suspension aqueuse comporte : (1) au moins un composé de sulfonylurée herbicide choisi dans le groupe composé de 1-[3-[(4,6-dimethoxypyrimidin- 2-ylcarbamoyl)sulfamoyl]-2-pyridyl]-2-fluoropropyl methoxyacetate, N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-2-(2-fluoro-1-hydroxypropyl)-3- pyridinesulfonamide et de leurs sels ; (2) un sel inorganique ; (3) au moins un sel de sulfonate choisi dans le groupe composé d'un arylsulfonate, d'un alkylarylsulfonate et de leurs condensés de formaline ; et (4) de l'eau.
PCT/JP2006/315531 2005-08-10 2006-08-04 Composé herbicide du type en suspension aqueuse Ceased WO2007018160A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN2006800286676A CN101237770B (zh) 2005-08-10 2006-08-04 水性悬浮状除草组合物
KR1020087003231A KR101246484B1 (ko) 2005-08-10 2006-08-04 수성 현탁상 제초 조성물

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP2005-231841 2005-08-10
JP2005231841 2005-08-10
JP2005-326624 2005-11-10
JP2005326624 2005-11-10
JP2006044472 2006-02-21
JP2006-044472 2006-02-21

Publications (1)

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WO2007018160A1 true WO2007018160A1 (fr) 2007-02-15

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PCT/JP2006/315531 Ceased WO2007018160A1 (fr) 2005-08-10 2006-08-04 Composé herbicide du type en suspension aqueuse

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JP (1) JP5137349B2 (fr)
KR (1) KR101246484B1 (fr)
CN (1) CN101237770B (fr)
WO (1) WO2007018160A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008099889A1 (fr) * 2007-02-15 2008-08-21 Ishihara Sangyo Kaisha, Ltd. Composition herbicide
JP2010530381A (ja) * 2007-06-21 2010-09-09 バイエル・クロツプサイエンス・アクチエンゲゼルシヤフト グリセロール中の活性化合物懸濁剤

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JP5233698B2 (ja) * 2009-01-28 2013-07-10 住友化学株式会社 農薬粒剤
TWI702000B (zh) * 2017-11-16 2020-08-21 南韓商Ｌｇ化學股份有限公司 液體除草組成物
TWI722335B (zh) * 2017-11-16 2021-03-21 南韓商Ｌｇ化學股份有限公司 除草組成物
TWI713933B (zh) * 2017-11-16 2020-12-21 南韓商Ｌｇ化學股份有限公司 液體除草組成物
CN116458509A (zh) * 2022-01-12 2023-07-21 江苏龙灯化学有限公司 一种稳定的杀虫组合物

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