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WO2007066032A3 - Composition réticulée comprenant un copolymère coeur-écorce, son procédé d'obtention, ses utilisations. - Google Patents

Composition réticulée comprenant un copolymère coeur-écorce, son procédé d'obtention, ses utilisations. Download PDF

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Publication number
WO2007066032A3
WO2007066032A3 PCT/FR2006/051272 FR2006051272W WO2007066032A3 WO 2007066032 A3 WO2007066032 A3 WO 2007066032A3 FR 2006051272 W FR2006051272 W FR 2006051272W WO 2007066032 A3 WO2007066032 A3 WO 2007066032A3
Authority
WO
WIPO (PCT)
Prior art keywords
parts
core
crosslinked composition
shell copolymer
crosslinked
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/FR2006/051272
Other languages
English (en)
Other versions
WO2007066032A2 (fr
Inventor
Laurent Gervat
Gilles Meunier
Christophe Navarro
Elisabeth Bay
Laure Mauboules
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Arkema France SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to EP06842083A priority Critical patent/EP1957576A2/fr
Priority to US12/096,237 priority patent/US20090306246A1/en
Publication of WO2007066032A2 publication Critical patent/WO2007066032A2/fr
Publication of WO2007066032A3 publication Critical patent/WO2007066032A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Ethene-propene or ethene-propene-diene copolymers
    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00—Soles; Sole-and-heel integral units
    • A43B13/02—Soles; Sole-and-heel integral units characterised by the material
    • A43B13/04—Plastics, rubber or vulcanised fibre
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0008—Compositions of the inner liner
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0016—Compositions of the tread
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0025—Compositions of the sidewalls
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00—Compositions of unspecified rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • C08L23/22—Copolymers of isobutene; Butyl rubber; Homopolymers or copolymers of other iso-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C9/00—Reinforcements or ply arrangement of pneumatic tyres
    • B60C9/0007—Reinforcements made of metallic elements, e.g. cords, yarns, filaments or fibres made from metal
    • B60C2009/0021—Coating rubbers for steel cords
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/06—Sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0025—Crosslinking or vulcanising agents; including accelerators
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/06—Metallocene or single site catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
    • C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

Le premier objet de l'invention est une composition réticulée comprenant en parties en poids: 20 à 100 parties d'au moins un élastomère (I), 2 à 50 parties d'au moins un copolymère cœur écorce (II), et 0 à 100 parties d'au moins un polymère thermoplastique (III). La présente invention a également pour objet un procédé de fabrication d'une composition réticulée telle que définie ci-dessus, caractérisé en ce qu'il comprend le mélange d'un élastomère et d'un copolymère cœur écorce en présence éventuellement : d'une polyoléfine greffée, d'un plastifiant, de charges et/ou d'adjuvants et d'un système de réticulation convenablement choisi, puis la réticulation de ce mélange à une température appropriée. Selon un mode de mise en oeuvre préféré du procédé conforme à l'invention, la température à laquelle est effectuée la réticulation est comprise entre 150 et 32O0C. Ce procédé peut être mis en oeuvre dans un mélangeur interne ou, en variante, dans une extrudeuse bi-vis ou un co-malaxeur du type BUSS®. La masse résultante est, selon le cas, calandrée ou extrudée, puis refroidie et soumise à une granulation. Les granulés ainsi obtenus sont prêts à être transformés - par chauffage de ces granulés- en feuilles, plaques, profilés, tubes ou autres produits désirés. La présente invention a, en outre, pour objet l'utilisation d'une telle composition dans la fabrication de conduits, de tubes, de tuyaux, de tubulures, de raccords ou analogues pour le transfert de fluides. A titre d'exemples, on peut citer les conduites, tuyaux et autres éléments prévus pour l'acheminement des fluides qui sont utilisés par l'industrie automobile dans les circuits de freinage, de refroidissement, d'assistance de direction ou encore de climatisation. On peut aussi citer l'utilisation de la composition réticulée de l'invention dans la fabrication de courroies, de pneus, de gaines de câbles électriques et de semelles de chaussures.
PCT/FR2006/051272 2005-12-07 2006-12-01 Composition réticulée comprenant un copolymère coeur-écorce, son procédé d'obtention, ses utilisations. Ceased WO2007066032A2 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP06842083A EP1957576A2 (fr) 2005-12-07 2006-12-01 Composition réticulée comprenant un copolymère coeur-écorce, son procédé d'obtention, ses utilisations
US12/096,237 US20090306246A1 (en) 2005-12-07 2006-12-01 Crosslinked composition comprising a core/shell copolymer, method of obtaining same and uses thereof

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR0512400A FR2894252B1 (fr) 2005-12-07 2005-12-07 Composition reticulee comprenant un copolymere coeur ecorce, son procede d'obtention et ses utilisations
FR0512400 2005-12-07
US76546006P 2006-02-03 2006-02-03
US60/765,460 2006-02-03

Publications (2)

Publication Number Publication Date
WO2007066032A2 WO2007066032A2 (fr) 2007-06-14
WO2007066032A3 true WO2007066032A3 (fr) 2007-07-26

Family

ID=36928208

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2006/051272 Ceased WO2007066032A2 (fr) 2005-12-07 2006-12-01 Composition réticulée comprenant un copolymère coeur-écorce, son procédé d'obtention, ses utilisations.

Country Status (4)

Country Link
US (1) US20090306246A1 (fr)
EP (1) EP1957576A2 (fr)
FR (1) FR2894252B1 (fr)
WO (1) WO2007066032A2 (fr)

Families Citing this family (19)

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Publication number Priority date Publication date Assignee Title
EP1844086B1 (fr) * 2004-11-22 2010-07-21 Arkema Inc. Composition de resine thermoplastique rendue antichoc
US9061900B2 (en) 2005-12-16 2015-06-23 Bridgestone Corporation Combined use of liquid polymer and polymeric nanoparticles for rubber applications
US8288473B2 (en) 2005-12-19 2012-10-16 Bridgestone Corporation Disk-like nanoparticles
US8697775B2 (en) 2005-12-20 2014-04-15 Bridgestone Corporation Vulcanizable nanoparticles having a core with a high glass transition temperature
US8877250B2 (en) 2005-12-20 2014-11-04 Bridgestone Corporation Hollow nano-particles and method thereof
EP3495322A1 (fr) * 2006-07-28 2019-06-12 Bridgestone Corporation Nanoparticules de polymères de type noyau-enveloppe comportant une région d'interphase
US7597959B2 (en) 2006-12-19 2009-10-06 Bridgestone Corporation Core-shell fluorescent nanoparticles
ES2527600T3 (es) 2008-12-31 2015-01-27 Bridgestone Corporation Procedimiento de formación de nanopartículas formando primero el núcleo, nanopartícula y composición
US9062144B2 (en) 2009-04-03 2015-06-23 Bridgestone Corporation Hairy polymeric nanoparticles with first and second shell block polymer arms
US9115222B2 (en) 2009-12-29 2015-08-25 Bridgestone Corporation Well defined, highly crosslinked nanoparticles and method for making same
FR2955116B1 (fr) * 2010-01-14 2013-05-24 Soc Tech Michelin Composition de caoutchouc comprenant un elastomere thermoplastique polaire comprenant un bloc alkylacrylate
EP2559727B1 (fr) * 2011-08-16 2014-05-14 Nexans Mélange de gaine au chloroprène résistant au froid
NL2007737C2 (en) 2011-11-07 2013-05-08 Bluemarine Offshore Yard Service B V Method for filling a gap in the coating of a pipeline coated with a coating, preferably a thermo-insulating coating.
US9428604B1 (en) 2011-12-30 2016-08-30 Bridgestone Corporation Nanoparticle fillers and methods of mixing into elastomers
CN104311898B (zh) * 2014-10-30 2016-08-17 际华三五三七制鞋有限责任公司 解放鞋用压延型黑色橡胶围条胶的塑炼工艺
CN104558734A (zh) * 2015-02-01 2015-04-29 晋江市科创源专利服务有限公司 一种鞋底材料及其制备方法
JP6805863B2 (ja) * 2017-02-13 2020-12-23 住友ゴム工業株式会社 タイヤ用ゴム組成物及び空気入りタイヤ
US20210403626A1 (en) * 2018-08-23 2021-12-30 3M Innovative Properties Company Curable compositions for forming light scattering layers
CN112500536A (zh) * 2020-12-31 2021-03-16 常州市五洲化工有限公司 一种长效抗变色防老剂的制备方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4351875A (en) * 1978-09-25 1982-09-28 Rohm And Haas Company Heteropolymer acrylic latices and textiles treated therewith
US4952636A (en) * 1987-12-31 1990-08-28 E. I. Du Pont De Nemours And Company Modified polytetrafluoroethylene resins and blends thereof
EP0643104A2 (fr) * 1993-09-09 1995-03-15 BASF Aktiengesellschaft Masses à mouler thermoplastiques
US5760134A (en) * 1995-10-02 1998-06-02 Basf Aktiengesellschaft Thermoplastic molding materials
WO2005082996A1 (fr) * 2004-02-24 2005-09-09 Arkema France Composition reticulee comprenant un copolymere sequence triblocs, son procede d'obtention et ses utilisations

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Publication number Priority date Publication date Assignee Title
CA1332992C (fr) * 1986-08-27 1994-11-08 Susan Marie Liwak Modificateurs de resilience pour polymeres thermoplastiques
JPH08259899A (ja) * 1995-03-23 1996-10-08 Three Bond Co Ltd シアノアクリレート系接着剤組成物
FR2749018B1 (fr) * 1996-05-21 1998-07-31 Hutchinson Elastomere reticule a transformation thermoplastique, son procede de fabrication et ses utilisations
ATE277121T1 (de) * 1998-06-22 2004-10-15 Gen Electric Silanvulkanisierte thermoplastische elastomeren
US6608142B1 (en) * 2000-05-08 2003-08-19 Teknor Apex Company Polyvinyl chloride compositions
EP1239015A1 (fr) * 2001-03-08 2002-09-11 Sika AG, vorm. Kaspar Winkler & Co. Compositions d'adhésifs methacryliques aisées à préparer
US7244783B2 (en) * 2004-06-24 2007-07-17 The Goodyear Tire & Rubber Company Thermoplastic elastomer composition
ATE534703T1 (de) * 2005-08-24 2011-12-15 Henkel Kgaa Epoxidzusammensetzungen mit verbesserter schlagzähigkeit

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4351875A (en) * 1978-09-25 1982-09-28 Rohm And Haas Company Heteropolymer acrylic latices and textiles treated therewith
US4952636A (en) * 1987-12-31 1990-08-28 E. I. Du Pont De Nemours And Company Modified polytetrafluoroethylene resins and blends thereof
EP0643104A2 (fr) * 1993-09-09 1995-03-15 BASF Aktiengesellschaft Masses à mouler thermoplastiques
US5760134A (en) * 1995-10-02 1998-06-02 Basf Aktiengesellschaft Thermoplastic molding materials
WO2005082996A1 (fr) * 2004-02-24 2005-09-09 Arkema France Composition reticulee comprenant un copolymere sequence triblocs, son procede d'obtention et ses utilisations

Also Published As

Publication number Publication date
FR2894252A1 (fr) 2007-06-08
US20090306246A1 (en) 2009-12-10
EP1957576A2 (fr) 2008-08-20
FR2894252B1 (fr) 2013-01-04
WO2007066032A2 (fr) 2007-06-14

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