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WO2003008342A1 - Dispositif permettant d'ameliorer la qualite de l'eau potable et/ou industrielle - Google Patents

Dispositif permettant d'ameliorer la qualite de l'eau potable et/ou industrielle Download PDF

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Publication number
WO2003008342A1
WO2003008342A1 PCT/EP2002/007712 EP0207712W WO03008342A1 WO 2003008342 A1 WO2003008342 A1 WO 2003008342A1 EP 0207712 W EP0207712 W EP 0207712W WO 03008342 A1 WO03008342 A1 WO 03008342A1
Authority
WO
WIPO (PCT)
Prior art keywords
silver
silver wire
spring
wire
line
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2002/007712
Other languages
German (de)
English (en)
Inventor
Peter Mitschke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE20112556U external-priority patent/DE20112556U1/de
Application filed by Individual filed Critical Individual
Priority to DE20220851U priority Critical patent/DE20220851U1/de
Publication of WO2003008342A1 publication Critical patent/WO2003008342A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46176Galvanic cells
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/4606Treatment of water, waste water, or sewage by electrochemical methods for producing oligodynamic substances to disinfect the water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/50Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • C02F1/505Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment by oligodynamic treatment

Definitions

  • the invention relates to a device for improving the quality of drinking and / or industrial water according to the preamble of claim 1.
  • oligodynamically acting metal such as silver
  • the oligodynamically acting metal can be assigned an element with a different electrodynamic potential, as described in DE 35 43 223 AI.
  • Drinking water treated with UV radiation is used in particular in piping systems in the Federal Republic of Germany. This water is actually dead immediately after the irradiation and is therefore an excellent breeding ground for bacteria etc. It is also known that drinking water is often in pipes or pipe sections over a longer period of time. A Plastic pipes or other sections consisting of plastics, in which drinking water is stored for a longer period, represent a particular risk of a resulting bacteriological load up to contamination. Outbreaks of so-called legionnaires' disease have repeatedly become known from bathing establishments in recent years, the germs of which could multiply explosively and unpredictably in temperate sections of the drinking or fresh water pipes. At or in these breeding grounds, arrangements of filters, particularly against legionella, have proven to be largely ineffective.
  • oligodynamics describes a disinfection effect by releasing, for example, silver ions, which is disclosed, among other things, in German published patent application DE 35 43 223 AI for a water storage container made of stainless steel and in German patent specification DE 44 36 927 CI for an oral irrigator Plastic is used to kill germs.
  • the invention has for its object to provide a device for improving the quality of drinking and / or industrial water, which is suitable for use in shower hoses and for subsequent introduction in water-carrying pipes.
  • the device according to the invention consists of a flexible silver wire, over the entire length of which another metallic material extends, which is also designed to be flexible.
  • the other metallic material is preferably designed as an elongated coil spring in which the silver wire lies. It is particularly advantageous to manufacture the coil spring from stainless steel and to design it as a compression spring. Training as a compression spring has the advantage that There is a small free space between the individual turns of the coil spring, through which water can come into contact with the inserted silver wire. This has a positive influence on the oligodynamic effect.
  • a preferred embodiment provides that an end piece with a retaining pin engaging in the helical spring is placed on each end of the helical spring.
  • the coil spring can enclose the retaining pin so tightly that the end piece is held in the coil spring in a self-locking manner. Additional gluing or soldering is not necessary.
  • a braid of silver wires can represent an embodiment according to the invention.
  • a device comprises a silver wire or a braid made of silver, a silver wire being arranged together with a wire-shaped body or braid of a material with a different normal potential in the same line or in essentially the same line section. Due to the joint arrangement of the relatively inexpensive precious metal silver together with another material, a line or line section is also standing water according to the electrochemical voltage series of the metals and non-metals build up a potential gradient that counteracts the formation and / or multiplication of bacteria and germs in a very strong way. On the one hand, a static electric field is built up in a line or in a line section due to the difference in the normal potentials, which significantly impedes bacterial growth and is not dependent on an external supply of electrical energy.
  • silver ions are secreted, which are harmless to humans in the normally soluble concentrations in water and yet have a very strong oligodynamic property.
  • silver alloys with copper and / or palladium etc. should also be included synonymously by the designation of the precious metal, since silver alloys are also suitable for the separation of silver ions in a known manner.
  • the material with a normal potential other than silver essentially consists of a stainless steel.
  • a stainless steel in particular changes the taste of drinking water only insignificantly even in a device according to the invention, since it is largely corrosion-resistant in water at pH values of 6.5 to 6.9 and usual operating temperatures between about 6 ° and about 70 ° C. Even in interaction with silver, there is no taste impairment, discoloration or the like in drinking water.
  • other materials can also be added to the stainless steel as a carrier or added in particular by adding, fixing inlays, stranding etc.
  • the silver wire is advantageously coated on the surface with silver, in particular in a galvanic process.
  • the silver wire is washed before and / or after processing or in some other way superficially cleaned. Both measures ensure in themselves that a device according to the invention releases silver as particles and silver ions only to an extent immediately after installation, which is permitted under food law in drinking water.
  • a silver-plated wire for example a silver-plated copper wire, can also be used as the silver wire in the context of the present invention. Due to the decidedly longer service life, a wire made of solid silver is preferred. The same applies to a braid which, despite a concentration of the presentation of embodiments and further developments of the invention, should always be included on wire-shaped bodies without their own mention.
  • the silver wire and / or the other material are preferably arranged in a spiral in the one line or the line section.
  • a sufficiently large active surface is also created on a very short path.
  • the active surface can be further increased by training in the form of a braid or similar shapes.
  • the antibacterial effect is increased very effectively or is sufficiently strong when viewed over small lengths.
  • part of a device according to the invention is always in contact with the water or residual water from the silver wire and / or the other material, even when a line or line section is partially emptied, so that there is always a sufficient disinfection effect.
  • the at least two components of a device according to the invention are at least partially in close contact.
  • a silver wire is twisted with the other material or arranged around the other material.
  • a device according to the invention in a further development as twisted arrangement itself in a spiral shape, so that they also through small openings in a Cable, a hose or a piece of pipe can be virtually screwed in, pushed or inserted.
  • an average diameter of a spiral device is chosen such that it is smaller than a free diameter of the line or the line section.
  • a major advantage of a device constructed in accordance with the invention in accordance with this embodiment then lies primarily in the fact that it is flexible in a wide range, at least in this preferred embodiment.
  • a device according to the invention can thus be supplemented in a simple and quick manner in a line or a line section without substantial intervention in its mechanical stability or even weakening damage.
  • a spacer is advantageously provided on the device.
  • the spacer serves to prevent contact of the combination of silver and the other material with the material of the line section. This is particularly important in the case when the line or the line section does not consist of an insulator and thus additional ionization processes and consequently also corrosion phenomena can occur in contact with a device according to the invention.
  • the spacer itself is therefore preferably made of a plastic.
  • two or more spacers can also be connected to one another. This connection is preferably made flexible, as will be described below with reference to an exemplary embodiment with reference to the drawing.
  • a device according to the invention thus has a small overall length and is particularly suitable as a retrofit part.
  • An inventive The device is also designed as a line piece, which can advantageously be flexible in the form of a hose.
  • This opens up a wide variety of possible uses for a device according to the invention, from a shower hose, use on or with a aerator to use in an air conditioning system.
  • the defined and slow processes in a device according to the invention require, if at all, only very long maintenance intervals.
  • the service life of a hose, a seal, a sieve etc. can easily be achieved, so that no separate maintenance intervals need to be monitored.
  • a device according to the invention can also be attached quickly and easily due to its flexibility.
  • External connections by current sources are advantageously no more necessary than, for example, the provision of buffers against electrolytic decomposition of water with the risk of oxyhydrogen formation.
  • FIG. 1 shows a first embodiment of a device according to the invention in a sectional view in a plastic line for drinking and industrial water
  • FIG. 1 is an enlarged sectional view of the embodiment of FIG. 1,
  • FIG. 3 shows a further embodiment of a device according to the invention in an installed position in a shower
  • FIG. 4 shows a further embodiment of the invention
  • 5 is a simplified view of a hand shower with a shower hose incorporating a flexible embodiment of the invention
  • FIG. 6 shows the embodiment of the invention used in FIG. 5 in the form of an elongated coil spring with an inserted silver wire
  • Fig. 7 shows the end portion of the coil spring of Fig. 6 with a notched end piece and a sliding spring
  • Fig. 8 shows the coil spring of Fig. 7 with the retaining spring pushed on, which engages in a blank.
  • the device 1 shows a sketch of a first embodiment of an apparatus 1 according to the invention in a line 2 or another tubular body in a sectional view.
  • the device 1 comprises a silver wire 4, which is arranged in the line 2 together with a body 5 made of a material 6 with a different or different normal potential from silver.
  • Material 6 with a normal potential other than silver is a commercially available V2A stainless steel in wire form.
  • the silver wire 4 and the stainless steel wire 5 are arranged in the embodiment of FIG. 1 without a direct connection between them in the form of a spiral 7 in the line 2, so that an electrostatic field is formed in contact with water between these two partners in accordance with the electrochemical voltage series of the elements builds.
  • This E-field is generated without the addition of an external source simply by dissolving ions and cations in the water and has experimentally proven to inhibit the growth of germs. moreover silver ions have a strong oligodynamic effect, that is, they kill bacteria and germs.
  • no effects which are negative for human health or disadvantageous in long-term use are produced, since silver ions cannot be dissolved in water of the qualities mentioned with a high concentration.
  • Spacers 8 consist of a plastic and are injection-molded in short sections around the two components 4, 5. In the present embodiment, they have an approximately elliptical cross-sectional area, as shown in the sketch of FIG. 2. In addition to the function as a spacer for the wires 4, 5, the spacers 8 also serve as a spacer with respect to the inner walls of the line 2 in order to prevent contact corrosion with less noble materials.
  • the device 1 can also be introduced into a line 2 through very narrow openings.
  • a type of screwing in has turned out to be advantageous as an alternative to pushing in, with the spacers 8 as sliding elements or sliding aids in a subsequent one Insert the spiral device 1 in the line 2 serve.
  • an average diameter d of the spiral 7 has been chosen to be smaller than a free diameter D of the line 2.
  • a connection 10 between two spacers 8, which is flexible and resilient against bending is indicated by way of example in the illustration in FIG. 1.
  • the connection 10 has been produced in one piece with the spacers 8 in one and the same injection molding process, with flexibility and elasticity being determined in a known manner by material selection and material thickness and length.
  • a plastic line has been selected as line 2, which can be regarded as a veritable breeding ground for germs at water temperatures of well below 60 C and longer standing times or immobile dwell times of residual water in line 2, especially for the pathogens, which are always very dangerous for humans legionnaires' disease.
  • line 2 can be regarded as a veritable breeding ground for germs at water temperatures of well below 60 C and longer standing times or immobile dwell times of residual water in line 2, especially for the pathogens, which are always very dangerous for humans legionnaires' disease.
  • FIG. 3 shows a further embodiment of the invention, an enlarged representation of a combination of a wire 5 made of stainless steel and selected here Silver wires 4 in the illustration of Fig. 4 is sketched.
  • the embodiment according to FIG. 3 represents the use of a device 1 in combination with a coarse sieve 12, as used for example in a hand shower 13.
  • the spiral 7 is inserted into a handle 14 of the hand shower 13, which also serves as a line 2.
  • the spiral 7 extends through the handle 14 to an actual shower head 15, so that all water-carrying parts, in which water remains even after the shower 13 has been switched off and only slowly cools to room temperature, with the oligodynamic effect of the device 1 are adequately supplied.
  • the spiral 7 is fixed with the sieve 12 at an attachment point 16 which is located at an end region 17 of the device 1, so that a relatively easy-to-use unit is formed.
  • FIG. A silver wire 4 is located within a helical stainless steel wire 5.
  • the stainless steel wire 5 preferably forms an elongated coil spring.
  • the embodiment according to FIG. 4 is inserted into the shower hose 19 of a hand shower 20.
  • the end region of the preferred embodiment is shown in simplified form in the illustration in FIG. 6, the stainless steel wire 5 designed as a helical spring being shown as interrupted double lines.
  • the inserted silver wire 4 lies with little play in the helical spring 21 made of stainless steel wire 5 and is secured at both ends of the helical spring 21 by attached end pieces 22.
  • only one of the two end pieces 22 is shown, which with an in Diameter reduced retaining pin 23 engages self-locking in the coil spring 21.
  • the stainless steel wire 5 is preferably wound in accordance with a compression spring, so that there is a free space between each of its turns, through which the water to be sterilized can come into contact with the inserted silver wire 4.
  • the attached end piece 22 is preferably made of stainless steel and has at its projecting end section 24 the same outer diameter as the adjoining coil spring 21, the entire design having the following dimensions:
  • the coil spring 21 has an outer diameter of 2.5 mm and a wire thickness of 0.5 mm, the silver wire 4 lying as the core in the coil spring 21 having a length of 750 mm and a diameter of 1 mm.
  • the total length of the flexible arrangement consisting of coil spring 21 and silver wire 4 with end pieces 22 attached at both ends is approximately 800 mm.
  • the end piece 22 can be provided with an annular groove 24, in which a retaining spring 25 with a molded spring ring 26 can engage in a springy manner.
  • the retaining spring 25 is pushed in the arrow direction 27 onto the end piece 22 up to the annular groove 24.
  • FIG. 8 shows how the helical spring 21 can be fastened with an attached retaining spring 25 in the area of an adjacent sealing ring 28.
  • the retaining spring 25 is pushed with its bent end, which forms a kind of spring hook 29, through the opening of the sealing ring 28 into the adjacent tube piece 30.
  • the spring hook 29 is dimensioned such that it is a slightly larger one Outside diameter has as the opening of the sealing ring 28.
  • the pipe section 30 can be part of a wall shower or part of the handle of a hand shower or another pipe end piece to which the sealing ring 28 is stuck in a known manner after installation by means of a screw connection, not shown here.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Bathtubs, Showers, And Their Attachments (AREA)

Abstract

L'invention concerne un dispositif permettant d'améliorer la qualité de l'eau potable et/ou industrielle. Ce dispositif comprend au moins un élément en argent ou autre métal oligodynamique, agencé dans une conduite d'eau. Selon cette invention, cet élément oligodynamique est un fil d'argent souple (4), au moins un autre matériau métallique et également souple s'étendant sur toute la longueur dudit fil, lequel matériau présente un potentiel normal différent de l'argent.
PCT/EP2002/007712 2001-07-16 2002-07-11 Dispositif permettant d'ameliorer la qualite de l'eau potable et/ou industrielle Ceased WO2003008342A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE20220851U DE20220851U1 (de) 2001-07-16 2002-07-11 Vorrichtung zur Verbesserung der Qualität von Trink- und/oder Brauchwasser

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE20112556.0 2001-07-16
DE20112556U DE20112556U1 (de) 2001-07-16 2001-07-16 Vorrichtung zur Verbesserung der Qualität von Trink- und/oder Brauchwasser

Publications (1)

Publication Number Publication Date
WO2003008342A1 true WO2003008342A1 (fr) 2003-01-30

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PCT/EP2002/007712 Ceased WO2003008342A1 (fr) 2001-07-16 2002-07-11 Dispositif permettant d'ameliorer la qualite de l'eau potable et/ou industrielle

Country Status (2)

Country Link
DE (1) DE20220851U1 (fr)
WO (1) WO2003008342A1 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10337363A1 (de) * 2003-08-12 2005-03-17 Štrlek, Krešimir Einrichtung zur Verbesserung der Wasserqualität
WO2005047192A1 (fr) * 2003-11-11 2005-05-26 Keith Froggatt Systeme de distribution d'eau
WO2006024477A1 (fr) * 2004-08-30 2006-03-09 Global Pet Ag Dispositif et procede pour eliminer des micro-organismes
WO2006108399A3 (fr) * 2005-04-15 2007-08-02 Aquacarat Gmbh Dispositif de desinfection d'eau et procede d'installation dudit dispositif
WO2021239860A1 (fr) 2020-05-28 2021-12-02 Swiss Aqua Technologies Ag Dispositif de traitement physique de l'eau
EP4089057A1 (fr) * 2021-05-12 2022-11-16 Challis Maritime Securities Limited Dispositif antimicrobien

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE202008007610U1 (de) 2008-06-07 2008-08-14 Mitschke, Jonathan Vorrichtung zur Verbesserung der Qualität von Trink- und/oder Brauchwasser
DE202011051098U1 (de) 2011-08-11 2011-11-08 Jonathan Mitschke Vorrichtung zur Verbesserung der Qualität von Trink- und/oder Brauchwasser
DE102011052604B4 (de) 2011-08-11 2014-04-24 Jonathan Mitschke Vorrichtung und Verfahren zur Verbesserung der Qualität von Trink- und/oder Brauchwasser
DE202013100329U1 (de) 2013-01-24 2013-02-06 Ueli Maurer Vorrichtung zur Verbesserung der Qualität von Trink- und/oder Brauchwasser
CN108018434A (zh) * 2017-12-05 2018-05-11 安徽旺达铜业发展有限公司 一种螺旋型铜粉回收管

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3970530A (en) * 1973-08-06 1976-07-20 Battelle Memorial Institute Method of and system for the destruction and/or limitation of the reproduction of micro-organisms in nutritive media
FR2721309A1 (fr) * 1994-06-21 1995-12-22 Centre Nat Rech Scient Procédé et dispositif de diffusion d'ions cuivriques pour le traitement d'un milieu liquide salé.

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3970530A (en) * 1973-08-06 1976-07-20 Battelle Memorial Institute Method of and system for the destruction and/or limitation of the reproduction of micro-organisms in nutritive media
FR2721309A1 (fr) * 1994-06-21 1995-12-22 Centre Nat Rech Scient Procédé et dispositif de diffusion d'ions cuivriques pour le traitement d'un milieu liquide salé.

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10337363A1 (de) * 2003-08-12 2005-03-17 Štrlek, Krešimir Einrichtung zur Verbesserung der Wasserqualität
WO2005047192A1 (fr) * 2003-11-11 2005-05-26 Keith Froggatt Systeme de distribution d'eau
WO2006024477A1 (fr) * 2004-08-30 2006-03-09 Global Pet Ag Dispositif et procede pour eliminer des micro-organismes
WO2006108399A3 (fr) * 2005-04-15 2007-08-02 Aquacarat Gmbh Dispositif de desinfection d'eau et procede d'installation dudit dispositif
WO2021239860A1 (fr) 2020-05-28 2021-12-02 Swiss Aqua Technologies Ag Dispositif de traitement physique de l'eau
DE112021003001T5 (de) 2020-05-28 2023-03-23 Swiss Aqua Technologies Ag Anlage für die physikalische Wasseraufbereitung
EP4089057A1 (fr) * 2021-05-12 2022-11-16 Challis Maritime Securities Limited Dispositif antimicrobien

Also Published As

Publication number Publication date
DE20220851U1 (de) 2004-04-08

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