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WO2003000398A3 - Procede d'obtention de gaz de synthese par oxydation catalytique partielle - Google Patents

Procede d'obtention de gaz de synthese par oxydation catalytique partielle Download PDF

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Publication number
WO2003000398A3
WO2003000398A3 PCT/FR2002/002093 FR0202093W WO03000398A3 WO 2003000398 A3 WO2003000398 A3 WO 2003000398A3 FR 0202093 W FR0202093 W FR 0202093W WO 03000398 A3 WO03000398 A3 WO 03000398A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalytic oxidation
synthesis gas
silicon carbide
partial catalytic
obtaining synthesis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/FR2002/002093
Other languages
English (en)
Other versions
WO2003000398A9 (fr
WO2003000398A2 (fr
Inventor
Cuong Pham-Huu
Marc-Jacques Ledoux
Pascaline Leroi
Sabine Savin-Poncet
Jacques Bousquet
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Elf Antar France
Original Assignee
Elf Antar France
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to US10/481,106 priority Critical patent/US7101494B2/en
Priority to EP02751263A priority patent/EP1399249A2/fr
Priority to NZ530197A priority patent/NZ530197A/en
Priority to BR0210564-0A priority patent/BR0210564A/pt
Priority to CA002450447A priority patent/CA2450447A1/fr
Priority to MXPA03011763A priority patent/MXPA03011763A/es
Application filed by Elf Antar France filed Critical Elf Antar France
Priority to EA200400060A priority patent/EA006849B1/ru
Publication of WO2003000398A2 publication Critical patent/WO2003000398A2/fr
Publication of WO2003000398A3 publication Critical patent/WO2003000398A3/fr
Priority to NO20035720A priority patent/NO20035720L/no
Anticipated expiration legal-status Critical
Publication of WO2003000398A9 publication Critical patent/WO2003000398A9/fr
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20—Carbon compounds
    • B01J27/22—Carbides
    • B01J27/224—Silicon carbide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386—Catalytic partial combustion
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1011—Packed bed of catalytic structures, e.g. particles, packing elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Silicon Compounds (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

L'invention concerne un procédé d'obtention de gaz de synthèse par oxydation catalytique partielle, consistant à mettre en contact un hydrocarbure à l'état gazeux et un gaz oxydant, ainsi qu'éventuellement une faible quantité de vapeur d'eau, en présence d'un catalyseur comprenant au moins un carbure de silicium, à une température supérieure à 800 °C. Selon l'invention, le carbure de silicium a une surface spécifique déterminée par la méthode BET inférieure ou égale à 100 m2/g, le temps de contact entre le mélange de l'hydrocarbure gazeux, du gaz oxydant et éventuellement de la vapeur d'eau et le carbure de silicium est supérieur à 0,05 seconde et la pression à l'intérieur du réacteur est supérieure à la pression atmosphérique.
PCT/FR2002/002093 2001-06-21 2002-06-18 Procede d'obtention de gaz de synthese par oxydation catalytique partielle Ceased WO2003000398A2 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
EA200400060A EA006849B1 (ru) 2001-06-21 2002-06-18 Способ получения синтез-газа частичным каталитическим окислением
EP02751263A EP1399249A2 (fr) 2001-06-21 2002-06-18 Procede d'obtention de gaz de synthese par oxydation catalytique partielle
NZ530197A NZ530197A (en) 2001-06-21 2002-06-18 Process for obtaining synthesis gas by partial catalytic oxidation
BR0210564-0A BR0210564A (pt) 2001-06-21 2002-06-18 Processo de obtenção de gás de sìntese por oxidação catalìtica parcial
CA002450447A CA2450447A1 (fr) 2001-06-21 2002-06-18 Procede d'obtention de gaz de synthese par oxydation catalytique partielle
US10/481,106 US7101494B2 (en) 2001-06-21 2002-06-18 Method for obtaining synthesis gas by partial catalytic oxidation
MXPA03011763A MXPA03011763A (es) 2001-06-21 2002-06-18 Procedimiento de obtencion de gas de sintesis por oxidacion catalitica parcial.
NO20035720A NO20035720L (no) 2001-06-21 2003-12-19 Fremgangsmate for a oppna syntesegass ved partiell katalytisk oksydasjon

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0108170A FR2826293B1 (fr) 2001-06-21 2001-06-21 Procede d'obtention de gaz de synthese par oxydation catalytique partielle
FR0108170 2001-06-21

Publications (3)

Publication Number Publication Date
WO2003000398A2 WO2003000398A2 (fr) 2003-01-03
WO2003000398A3 true WO2003000398A3 (fr) 2003-03-13
WO2003000398A9 WO2003000398A9 (fr) 2004-01-29

Family

ID=8864594

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2002/002093 Ceased WO2003000398A2 (fr) 2001-06-21 2002-06-18 Procede d'obtention de gaz de synthese par oxydation catalytique partielle

Country Status (13)

Country Link
US (1) US7101494B2 (fr)
EP (1) EP1399249A2 (fr)
AR (1) AR034537A1 (fr)
BR (1) BR0210564A (fr)
CA (1) CA2450447A1 (fr)
CO (1) CO5560593A2 (fr)
EA (1) EA006849B1 (fr)
FR (1) FR2826293B1 (fr)
MX (1) MXPA03011763A (fr)
NO (1) NO20035720L (fr)
NZ (1) NZ530197A (fr)
PE (1) PE20030028A1 (fr)
WO (1) WO2003000398A2 (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7220390B2 (en) 2003-05-16 2007-05-22 Velocys, Inc. Microchannel with internal fin support for catalyst or sorption medium
RU2005139412A (ru) * 2003-05-16 2006-06-27 Вилосис Инк. (Us) Способ конверсии углеводородов (варианты), катализатор (варианты) и способ получения катализатора на подложке
EP1484108A1 (fr) * 2003-06-06 2004-12-08 L'air Liquide, S.A. à Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procédés Georges Claude Catalyseur supporté pour la production de H2 et/ou CO à partir de hydrocarbures de faible poids moléculaire
FR2864528B1 (fr) * 2003-12-31 2006-12-15 Total France Procede de traitement des melanges methane/dioxyde de carbone
FR2864532B1 (fr) 2003-12-31 2007-04-13 Total France Procede de transformation d'un gaz de synthese en hydrocarbures en presence de sic beta et effluent de ce procede
CA2575165C (fr) 2004-08-12 2014-03-18 Velocys Inc. Procede de conversion de l'ethylene en oxyde d'ethylene en utilisant une technologie de procede par microcanaux
FR2900937B1 (fr) * 2006-05-15 2008-08-22 Peugeot Citroen Automobiles Sa Procede d'inhibition du depot sur une surface metallique de produits tels que des gommes, et piece metallique ainsi obtenue
US8877206B2 (en) 2007-03-22 2014-11-04 Pds Biotechnology Corporation Stimulation of an immune response by cationic lipids
AU2013274235B2 (en) 2012-06-15 2018-01-18 Samir N. Khleif Cationic lipid vaccine compositions and methods of use

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2062615A5 (en) * 1969-11-19 1971-06-25 Ustav Pro Vyzkum Vyuziti Nickel/gamma-alumina as catalyst for steam cracking - natural gas
US4914070A (en) * 1987-10-19 1990-04-03 Pechiney Electrometallurgie Process for the production of silicon carbide with a large specific surface area and use for high-temperature catalytic reactions
WO1996004200A1 (fr) * 1994-08-02 1996-02-15 Shell Internationale Research Maatschappij B.V. Procede pour l'oxydation partielle catalytique d'hydrocarbures
WO1997037929A1 (fr) * 1996-04-11 1997-10-16 Snamprogetti S.P.A. Materiel destine a des reactions d'oxydation partielle
WO1999035082A1 (fr) * 1998-01-12 1999-07-15 Regents Of The University Of Minnesota Regulation du h2 et du co produits lors d'un processus d'oxydation partielle
WO2000076651A1 (fr) * 1999-06-14 2000-12-21 International Fuel Cells, Llc Ensemble de reformage autothermique au carburant-methane compact et leger

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4394137A (en) * 1980-12-03 1983-07-19 Texaco, Inc. Partial oxidation process
US5023276A (en) * 1982-09-30 1991-06-11 Engelhard Corporation Preparation of normally liquid hydrocarbons and a synthesis gas to make the same, from a normally gaseous hydrocarbon feed
US6488838B1 (en) * 1999-08-17 2002-12-03 Battelle Memorial Institute Chemical reactor and method for gas phase reactant catalytic reactions
US6409940B1 (en) * 1999-10-18 2002-06-25 Conoco Inc. Nickel-rhodium based catalysts and process for preparing synthesis gas
US6409939B1 (en) * 2000-05-31 2002-06-25 Uop Llc Method for producing a hydrogen-rich fuel stream
US6911161B2 (en) * 2002-07-02 2005-06-28 Conocophillips Company Stabilized nickel-containing catalysts and process for production of syngas

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2062615A5 (en) * 1969-11-19 1971-06-25 Ustav Pro Vyzkum Vyuziti Nickel/gamma-alumina as catalyst for steam cracking - natural gas
US4914070A (en) * 1987-10-19 1990-04-03 Pechiney Electrometallurgie Process for the production of silicon carbide with a large specific surface area and use for high-temperature catalytic reactions
WO1996004200A1 (fr) * 1994-08-02 1996-02-15 Shell Internationale Research Maatschappij B.V. Procede pour l'oxydation partielle catalytique d'hydrocarbures
WO1997037929A1 (fr) * 1996-04-11 1997-10-16 Snamprogetti S.P.A. Materiel destine a des reactions d'oxydation partielle
WO1999035082A1 (fr) * 1998-01-12 1999-07-15 Regents Of The University Of Minnesota Regulation du h2 et du co produits lors d'un processus d'oxydation partielle
WO2000076651A1 (fr) * 1999-06-14 2000-12-21 International Fuel Cells, Llc Ensemble de reformage autothermique au carburant-methane compact et leger

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
K. HEITNES HOFSTAD ET AL.: "Partial oxidation of methane to synthesis gas over rhodium catalysts", CATALYSIS TODAY, vol. 40, 1998, pages 157 - 170, XP002192602 *

Also Published As

Publication number Publication date
BR0210564A (pt) 2004-05-25
NO20035720D0 (no) 2003-12-19
US20050119355A1 (en) 2005-06-02
PE20030028A1 (es) 2003-01-31
CO5560593A2 (es) 2005-09-30
US7101494B2 (en) 2006-09-05
EP1399249A2 (fr) 2004-03-24
NO20035720L (no) 2004-02-19
CA2450447A1 (fr) 2003-01-03
FR2826293A1 (fr) 2002-12-27
WO2003000398A9 (fr) 2004-01-29
MXPA03011763A (es) 2005-04-19
AR034537A1 (es) 2004-02-25
EA200400060A1 (ru) 2004-06-24
FR2826293B1 (fr) 2004-01-30
NZ530197A (en) 2004-09-24
WO2003000398A2 (fr) 2003-01-03
EA006849B1 (ru) 2006-04-28

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