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WO2002013964A3 - Catalyseur apte a la production de nitriles et procedes de production de nitriles - Google Patents

Catalyseur apte a la production de nitriles et procedes de production de nitriles Download PDF

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Publication number
WO2002013964A3
WO2002013964A3 PCT/EP2001/008522 EP0108522W WO0213964A3 WO 2002013964 A3 WO2002013964 A3 WO 2002013964A3 EP 0108522 W EP0108522 W EP 0108522W WO 0213964 A3 WO0213964 A3 WO 0213964A3
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WO
WIPO (PCT)
Prior art keywords
independently represent
different
same
suitable catalyst
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2001/008522
Other languages
German (de)
English (en)
Other versions
WO2002013964A2 (fr
Inventor
Michael Bartsch
Dagmar Pascale Kunsmann-Keitel
Robert Baumann
Gerd Haderlein
Wolfgang Siegel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to AU2001282012A priority Critical patent/AU2001282012A1/en
Publication of WO2002013964A2 publication Critical patent/WO2002013964A2/fr
Publication of WO2002013964A3 publication Critical patent/WO2002013964A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/04—Nickel compounds
    • C07F15/045—Nickel compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1865—Phosphonites (RP(OR)2), their isomeric phosphinates (R2(RO)P=O) and RO-substitution derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/08—Esters of oxyacids of phosphorus
    • C07F9/141—Esters of phosphorous acids
    • C07F9/145—Esters of phosphorous acids with hydroxyaryl compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/46—Phosphinous acids [R2POH], [R2P(= O)H]: Thiophosphinous acids including[R2PSH]; [R2P(=S)H]; Aminophosphines [R2PNH2]; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/48—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof
    • C07F9/4866—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof the ester moiety containing a substituent or structure which is considered as characteristic
    • C07F9/4875—Esters with hydroxy aryl compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574—Esters of oxyacids of phosphorus
    • C07F9/65746—Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Molecular Biology (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

L'invention concerne un catalyseur, contenant un complexe nickel (0) avec un ligand de formule (I) Y1 - E1 - X - E2 - Y2, dans laquelle X signifie aryles ou hétéroaryles, E1, E2 représentent, indépendamment l'un de l'autre, O ou NZ?5, Y1, Y2¿ peuvent être identiques ou différents et représentent, indépendamment l'un de l'autre, un reste de formule (II.1) ou (II.2), -P(-E?3-R1)(-E4-R2), où E33, E4, E5, E6¿ peuvent être identiques ou différents et, indépendamment l'un de l'autre, peuvent être une liaison chimique ou représenter O ou NZ?11, R1, R2¿ peuvent être identiques ou différents et représentent, indépendamment l'un de l'autre, un groupe cycloalkyle, aryle, hétérocycloalkyle ou hétéroaryle, R3, avec la partie du système -E5-P-E6- à laquelle il est lié, représente un hétérocycle à 5, 6, 7 ou 8 chaînons.
PCT/EP2001/008522 2000-08-02 2001-07-24 Catalyseur apte a la production de nitriles et procedes de production de nitriles Ceased WO2002013964A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2001282012A AU2001282012A1 (en) 2000-08-02 2001-07-24 Suitable catalyst for producing nitriles

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE2000138037 DE10038037A1 (de) 2000-08-02 2000-08-02 Zur Herstellung von Nitrilen geeigneter Katalysator und Verfahren zur Herstellung von Nitrilen
DE10038037.9 2000-08-02

Publications (2)

Publication Number Publication Date
WO2002013964A2 WO2002013964A2 (fr) 2002-02-21
WO2002013964A3 true WO2002013964A3 (fr) 2002-07-18

Family

ID=7651302

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2001/008522 Ceased WO2002013964A2 (fr) 2000-08-02 2001-07-24 Catalyseur apte a la production de nitriles et procedes de production de nitriles

Country Status (4)

Country Link
AR (1) AR030084A1 (fr)
AU (1) AU2001282012A1 (fr)
DE (1) DE10038037A1 (fr)
WO (1) WO2002013964A2 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8906334B2 (en) 2007-05-14 2014-12-09 Invista North America S.A R.L. High efficiency reactor and process

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10136488A1 (de) 2001-07-27 2003-02-06 Basf Ag Ni(O) enthaltendes Katalysatorsystem
FR2842196B1 (fr) * 2002-07-15 2006-01-13 Rhodia Polyamide Intermediates Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
FR2850966B1 (fr) 2003-02-10 2005-03-18 Rhodia Polyamide Intermediates Procede de fabrication de composes dinitriles
AP2005003409A0 (en) 2003-04-09 2005-12-31 Bayer Bioscience Nv Methods and means for increasing the tolerance of plants to stress conditions.
FR2854891B1 (fr) 2003-05-12 2006-07-07 Rhodia Polyamide Intermediates Procede de preparation de dinitriles
DE102004004718A1 (de) 2004-01-29 2005-08-18 Basf Ag Verfahren zur Hydrocyanierung
EP2322503B1 (fr) 2005-10-18 2014-12-31 Invista Technologies S.à.r.l. Procédé de fabrication de 3-aminopentanenitrile
WO2007109005A2 (fr) 2006-03-17 2007-09-27 Invista Technologies S.A R.L. Procédé pour purifier des triorganophosphites grâce au traitement à l'aide d'un adjuvant basique
WO2007131699A2 (fr) 2006-05-12 2007-11-22 Bayer Bioscience N.V. Nouvelles molécules de micro-arn liées au stress et leurs utilisations
US7880028B2 (en) 2006-07-14 2011-02-01 Invista North America S.A R.L. Process for making 3-pentenenitrile by hydrocyanation of butadiene
US7919646B2 (en) 2006-07-14 2011-04-05 Invista North America S.A R.L. Hydrocyanation of 2-pentenenitrile
WO2008157218A1 (fr) 2007-06-13 2008-12-24 Invista Technologies S.A.R.L. Procédé pour améliorer la qualité de l'adiponitrile
CN101918356B (zh) 2008-01-15 2013-09-25 因温斯特技术公司 戊烯腈的氢氰化
CN101910119B (zh) 2008-01-15 2013-05-29 因温斯特技术公司 用于制备和精制3-戊烯腈，和用于精制2-甲基-3-丁烯腈的方法
FR2926816B1 (fr) 2008-01-25 2010-05-14 Rhodia Operations Procede de fabrication de composes comprenant des fonctions nitriles
FR2932477B1 (fr) 2008-06-17 2013-01-18 Rhodia Operations Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
KR101610423B1 (ko) 2008-10-14 2016-04-08 인비스타 테크놀러지스 에스.에이 알.엘. 2-ｓｅｃ-알킬-4,5-디-(ｎ-알킬)페놀의 제조 방법
FR2937321B1 (fr) 2008-10-21 2010-10-22 Rhodia Operations Procede de fabrication de composes comprenant des fonctions nitriles
FR2941455B1 (fr) 2009-01-29 2011-02-11 Rhodia Operations Procede de fabrication de composes comprenant des fonctions nitriles
EP2462103A4 (fr) 2009-08-07 2014-01-08 Invista Tech Sarl Hydrogénation et estérification pour former des diesters
US9371346B2 (en) 2010-09-07 2016-06-21 Invista North America S.A.R.L. Preparing a nickel phosphorus ligand complex

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0214622A2 (fr) * 1985-09-05 1987-03-18 Union Carbide Corporation Procédés catalysés par des complexes de métaux de transition
EP0518241A2 (fr) * 1991-06-11 1992-12-16 Mitsubishi Chemical Corporation Procédé d'hydroformylation et composé bisphosphite utilisé
WO1996022968A1 (fr) * 1995-01-27 1996-08-01 E.I. Du Pont De Nemours And Company Hydrocyanation de diolefines et isomerisation de 2-alkyl-3-monoalcenenitriles non conjugues
WO1999006357A1 (fr) * 1997-07-29 1999-02-11 E.I. Du Pont De Nemours And Company Cyanhydratation de diolefines et isomerisation de 2-alkyl-3-monoalcenenitriles non conjugues

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0214622A2 (fr) * 1985-09-05 1987-03-18 Union Carbide Corporation Procédés catalysés par des complexes de métaux de transition
EP0518241A2 (fr) * 1991-06-11 1992-12-16 Mitsubishi Chemical Corporation Procédé d'hydroformylation et composé bisphosphite utilisé
WO1996022968A1 (fr) * 1995-01-27 1996-08-01 E.I. Du Pont De Nemours And Company Hydrocyanation de diolefines et isomerisation de 2-alkyl-3-monoalcenenitriles non conjugues
WO1999006357A1 (fr) * 1997-07-29 1999-02-11 E.I. Du Pont De Nemours And Company Cyanhydratation de diolefines et isomerisation de 2-alkyl-3-monoalcenenitriles non conjugues

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
BAKER M J ET AL: "Chiral aryl diphosphites: a new class of ligands for hydrocyanation catalysis", CHEMICAL COMMUNICATIONS, ROYAL SOCIETY OF CHEMISTRY, GB, no. 18, 1991, pages 1292 - 1293, XP002180130, ISSN: 1359-7345 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8906334B2 (en) 2007-05-14 2014-12-09 Invista North America S.A R.L. High efficiency reactor and process

Also Published As

Publication number Publication date
DE10038037A1 (de) 2002-04-18
AU2001282012A1 (en) 2002-02-25
WO2002013964A2 (fr) 2002-02-21
AR030084A1 (es) 2003-08-13

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