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WO2000064648A1 - Elements de fermeture traites 2 - Google Patents

Elements de fermeture traites 2 Download PDF

Info

Publication number
WO2000064648A1
WO2000064648A1 PCT/AU2000/000366 AU0000366W WO0064648A1 WO 2000064648 A1 WO2000064648 A1 WO 2000064648A1 AU 0000366 W AU0000366 W AU 0000366W WO 0064648 A1 WO0064648 A1 WO 0064648A1
Authority
WO
WIPO (PCT)
Prior art keywords
substrate
copolymer
active
cork
reactive polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/AU2000/000366
Other languages
English (en)
Inventor
Phillip Mackie
Darren Lange
Russell Johnson
Leanne Britcher
Janis Matisons
Terry Wilks
Rosalind Ma
Mark Franson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Vinpac International Pty Ltd
Original Assignee
Vinpac International Pty Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vinpac International Pty Ltd filed Critical Vinpac International Pty Ltd
Priority to NZ515545A priority Critical patent/NZ515545A/en
Priority to AU39493/00A priority patent/AU776471B2/en
Priority to EP00918603A priority patent/EP1173312A4/fr
Publication of WO2000064648A1 publication Critical patent/WO2000064648A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K7/00Chemical or physical treatment of cork
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B67OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
    • B67BAPPLYING CLOSURE MEMBERS TO BOTTLES JARS, OR SIMILAR CONTAINERS; OPENING CLOSED CONTAINERS
    • B67B1/00Closing bottles, jars or similar containers by applying stoppers
    • B67B1/03Pretreatment of stoppers, e.g. cleaning, steaming, heating, impregnating or coating; Applying resilient rings to stoppers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02Processes; Apparatus
    • B27K3/15Impregnating involving polymerisation including use of polymer-containing impregnating agents
    • B27K3/156Combined with grafting onto wood fibres

Definitions

  • This invention provides improved closures for use in connection with food or
  • One application is in relation to closures for wine bottles.
  • this material can be subject to initial flaws, or deteriorate in use,
  • flavour-active or odour-active compounds in the cork imparts a musty or mouldy smell
  • cork is a
  • flavours to wines Furthermore, there is considerable consumer resistance to use of
  • the first cork coatings were simply lubricants such as paraffin and Vaseline.
  • materials used in surface treatment of corks include oils and silicone resins,
  • Hybrid corks have been moulded from natural cork and synthetic cork cells made from
  • the synthetic cells fill the gaps between the cork cells, and a
  • binding agent such as polyurethane
  • the present invention provides an improved closure having a surface coating or
  • This coating or diffusion layer comprising an appropriate polymer. This coating or diffusion layer has
  • flavour-active or odour-active compounds from the cork to the alcoholic
  • an appropriate polymer having functional groups
  • taint compounds e.g. TCA
  • TCA taint compounds
  • the substrate may, for example, be a bottle closure (such as a cork), packaging and wrapping materials (such as packaging for cheese), or a bottle or
  • the present invention provides a method for producing a coating or
  • diffusion layer on a substrate eg a cork for use in contact with a food product or
  • said coating or diffusion layer preventing or inhibiting passage therethrough
  • flavour-active or odour-active compounds e.g from a cork to an alcoholic beverage
  • flavour-active comprising first functional groups which react with at least one flavour-active or
  • odour-active compound and second functional groups (which may be the same as or
  • the present invention provides a coated substrate, and in particular a
  • coated natural or synthetic cork produced according to that method.
  • the polymer is selected so as to be reactive with both the substrate
  • flavour-active or odour-active compound eg TCA
  • the polymer may comprise first functional groups which can react with the TCA or
  • flavour-active or odour-active compound thus anchoring it to the polymer
  • the polymer may interact using one or a combination of the above.
  • the polymer has functional groups which are reactive with a
  • flavour-active or odour-active compounds substrate and with one or more flavour-active or odour-active compounds.
  • the polymer coating or diffusion layer in addition to acting as a partial
  • the polymer of the coating or diffusion layer will be reactive with any one of the following properties:
  • flavour-active or odour-active compounds in a cork, to prevent them from migrating
  • the polymer is also selected to be sufficiently
  • the corking process if the substrate is a cork). Furthermore, if the substrate is a cork, the
  • the polymer coating or diffusion layer will also be resistant to
  • Suitable polymers and copolymers which may be used include those described in the
  • SAN styrene-acrylonitrile
  • ABS acrylonirrile-butadiene-styrene
  • siloxane copolymers eg comprising polyethyleneglycol (PEG), isoprene,
  • Modifications of the polymers may be necessary to improve resistance to reactions with
  • the polymer coatings and diffusion layers of the present invention may be used in any order.
  • the method of applying the polymer to the substrate will be dependent on the nature of
  • the polymer and of the substrate will include such conventional processes as film
  • thermoforming thermoforming, vacuum forming and plasma polymerisation
  • the polymers may also be components of
  • the substrate eg cork
  • a solution eg ethanol, water or a
  • FIG 1 illustrates the reactivity of polyethyleneglycol (PEG) with TCA, and is a graph of
  • FIG's 2A-C are the results of Scanning Electrode Microscopy (SEM) of the coating of
  • FIG's 3A-D are the results of SEM of the coating of Example 6.
  • the instrument used for these experiments was a Waters 2690 Separations Module with
  • Wavelength 230nm Three injections with an injection volume of 10 ⁇ L per vial were made. Each run was for
  • TCA was dissolved in n-Heptane (lmg/L). ImL of this solution was eluted through the
  • FIG 1 is a graph of residual TCA (in mg) versus PEG (in mg).
  • Corks were spiked with TCA by soaking 100 corks in 1.5 litres of a lOOmg/L solution of
  • the wine was evaluated for unacceptable odours by a team of experts, being a
  • rating 1 indicated a slight odour
  • rating 2 a indicated a slight odour
  • TCA spiked cork and a non-TCA cork were coated with the coatings described below
  • Corks were dipped into an epoxysilicone solution and then into a 0.1% solution of
  • the coating consisted of a mixture of 75mL of Polyvinylacetate emulsion (PVA) and PVA.
  • caprolactone (4.1g, 0.036mol) was heated to 75 C under nitrogen before the catalyst,
  • Example 8 Polyvinylidene Chloride / Polymethylhydrogen Siloxane Emulsion
  • the cork was dipped into a solution consisting of 75% Polyvinylidene chloride and 25%
  • a cork was dipped in a solution of mercapto silicone emulsion and was submitted for
  • a cork was dipped into a solution of 46% acrylic methacrylic acid ester in water and
  • Corks can be rinsed or soaked with hot or cold water, alcohol, or a mixture of both
  • corks are then dried, eg in an oven at 40 C for 24 hours, prior to being coated.
  • the simplest application method is dip coating, involving a container filled with the
  • a typical dip coating unit consists of a bath, filled with the coating formulation, and a
  • the fluid is atomised into fine droplets for application to
  • the size of the droplets formed during atomisation can be controlled by
  • air spray nozzles airless spray nozzles, and hot spray systems.
  • the methods involve a stationary die, which delivers a layer of coating onto
  • the coating is transferred from the die to the moving substrate.
  • the coating is spread by
  • curtain coating Multiple slots in the die face or converging feed to a single slot can produce multilayer
  • Roll coating is another method used in continuous manufacturing operations primarily
  • a substrate is fed between two rotating cylinders, while
  • heating, and ovens can be incorporated into batch and continuous-mode systems.
  • ultraviolet light It can be a more rapid process than thermal curing, sometimes taking less than a second to act. Very little heat is generated during the exposure, which can
  • Electron beam (E-beam) radiation shares the same benefits as UV radiation, without the
  • ⁇ -radiation cure Yet another type of irradiation that is rapid at ambient temperatures is ⁇ -radiation cure.
  • Cycle times for Y-ray systems can be longer than for E-beam, at least for conventional
  • Thin polymer films can be deposited onto various substrates through the use of plasma
  • a plasma is generated by means of electron excitation, with a gas
  • Cross-linking density is usually greater than in
  • the substrate surface through secondary molecular interactions such as hydrogen
  • UV ultraviolet
  • electron beam, and Y-rays may be used to cause the formation of peroxide groups on

Landscapes

  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Details Of Rigid Or Semi-Rigid Containers (AREA)
  • Paints Or Removers (AREA)

Abstract

Dans un premier aspect, la présente invention concerne un procédé permettant de former un revêtement ou une couche de diffusion sur un substrat (p. ex. bouchon) destiné à entrer en contact avec un produit alimentaire ou une boisson. Ce revêtement ou cette couche de diffusion empêchent ou inhibent le passage (p. ex. du bouchon dans une boisson alcoolisée) de composés vecteurs de goûts ou d'odeurs (habituellement désignés par « goût de bouchon »). Ce procédé consiste à appliquer à la surface de ce substrat une quantité efficace de polymère réactif, composé d'un matériau polymère comprenant une première série de groupes fonctionnels qui réagissent avec au moins un composé vecteur de goût ou d'odeur, et une seconde série de groupes fonctionnels (qui peuvent être identiques aux premiers ou différents de ceux-ci) qui réagissent avec ce substrat. Un second aspect de l'invention concerne un substrat recouvert d'un revêtement, en particulier un bouchon naturel ou synthétique recouvert d'un revêtement, produit selon le procédé ci-dessus.
PCT/AU2000/000366 1999-04-22 2000-04-20 Elements de fermeture traites 2 Ceased WO2000064648A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
NZ515545A NZ515545A (en) 1999-04-22 2000-04-20 Method of treating closure for food or beverage, typically treated cork
AU39493/00A AU776471B2 (en) 1999-04-22 2000-04-20 Treated closures 2
EP00918603A EP1173312A4 (fr) 1999-04-22 2000-04-20 Elements de fermeture traites 2

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AUPP9893A AUPP989399A0 (en) 1999-04-22 1999-04-22 Treated closures 2
AUPP9893 1999-04-22

Publications (1)

Publication Number Publication Date
WO2000064648A1 true WO2000064648A1 (fr) 2000-11-02

Family

ID=3814093

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/AU2000/000366 Ceased WO2000064648A1 (fr) 1999-04-22 2000-04-20 Elements de fermeture traites 2

Country Status (5)

Country Link
EP (1) EP1173312A4 (fr)
AU (1) AUPP989399A0 (fr)
NZ (1) NZ515545A (fr)
WO (1) WO2000064648A1 (fr)
ZA (1) ZA200109605B (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001066660A3 (fr) * 2000-03-03 2002-03-07 Dow Corning Revetements d'isolement dans lesquels des polyacides sont utilises
US6793972B2 (en) * 2000-09-12 2004-09-21 The Dow Chemical Company Gas permeation resistant synthetic cork closure
WO2004076607A3 (fr) * 2003-02-26 2004-12-02 Charles A Wicht Procedes et articles permettant d'empecher le gout de bouchon dans les boissons
WO2006024767A1 (fr) * 2004-07-30 2006-03-09 Vect'oeur (Sarl) Procede d'elimination de composes polyhalogenes toxiques ou indesirables dans les boissons et notamment dans le vin
DE102006013102A1 (de) * 2006-03-20 2007-09-27 Henkel Kgaa Diffusionsreduzierende Korkbeschichtung
DE102006016054A1 (de) * 2006-04-04 2007-10-11 Henkel Kgaa PU Korkbeschichtung

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4254170A (en) * 1978-02-13 1981-03-03 Rhone-Poulenc Industries Process for rendering polyester hollow bodies gastight
EP0093626A1 (fr) * 1982-04-29 1983-11-09 Antoine Cassese Agrafe universelle
AU4799585A (en) * 1984-09-26 1986-04-10 Laporte Chemicals (Australia) Pty. Limited Treated corks
EP0341937A2 (fr) * 1988-05-09 1989-11-15 International Paper Company Récipient sans fuites et imperméable à l'oxygène
EP0423511A1 (fr) * 1989-10-16 1991-04-24 Tetra Laval Holdings & Finance SA Matériau d'emballage stratifié
EP0538774A2 (fr) * 1991-10-22 1993-04-28 Toyo Boseki Kabushiki Kaisha Composition de polyester pour le revêtement d'un feuille métallique utilisée pour la fabrication de boîtes en deux parties, et feuille revêtue de cette composition
WO1996028378A1 (fr) * 1995-03-16 1996-09-19 Dewco Investments Pty. Ltd. Dispositif de fermeture en liege presentant une couche impermeable aux liquides et resistante pour eviter toute alteration
US5576068A (en) * 1995-05-04 1996-11-19 Societe De Transformation Des Elastomers A Usages Medicaux Et Industriels Method of treating a packaging element, especially for medical or pharmaceutical use; packaging element thus treated
WO1997001427A1 (fr) * 1995-06-26 1997-01-16 Valyi Emery I Recipient pour aliments et boissons en plastique moule et procede correspondant
WO1997011894A1 (fr) * 1995-09-28 1997-04-03 Jess Paul Fuller Bouchon de liege pourvu d'un revetement
WO1997030122A1 (fr) * 1996-02-20 1997-08-21 Cellresin Technologies, L.L.C. Bouteilles pour boissons en polymere rigide dotees d'une resistance amelioree a l'elution de permeants
DE29912842U1 (de) * 1999-07-22 1999-09-16 Bleckmann GmbH & Co., 74080 Heilbronn Flaschenkorken

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5114794A (en) * 1987-06-23 1992-05-19 Daikyo Gomu Seiko Ltd. Modified polysiloxane-coated sanitary rubber article and a process for the production of the same

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4254170A (en) * 1978-02-13 1981-03-03 Rhone-Poulenc Industries Process for rendering polyester hollow bodies gastight
EP0093626A1 (fr) * 1982-04-29 1983-11-09 Antoine Cassese Agrafe universelle
AU4799585A (en) * 1984-09-26 1986-04-10 Laporte Chemicals (Australia) Pty. Limited Treated corks
EP0341937A2 (fr) * 1988-05-09 1989-11-15 International Paper Company Récipient sans fuites et imperméable à l'oxygène
EP0423511A1 (fr) * 1989-10-16 1991-04-24 Tetra Laval Holdings & Finance SA Matériau d'emballage stratifié
EP0538774A2 (fr) * 1991-10-22 1993-04-28 Toyo Boseki Kabushiki Kaisha Composition de polyester pour le revêtement d'un feuille métallique utilisée pour la fabrication de boîtes en deux parties, et feuille revêtue de cette composition
WO1996028378A1 (fr) * 1995-03-16 1996-09-19 Dewco Investments Pty. Ltd. Dispositif de fermeture en liege presentant une couche impermeable aux liquides et resistante pour eviter toute alteration
US5576068A (en) * 1995-05-04 1996-11-19 Societe De Transformation Des Elastomers A Usages Medicaux Et Industriels Method of treating a packaging element, especially for medical or pharmaceutical use; packaging element thus treated
WO1997001427A1 (fr) * 1995-06-26 1997-01-16 Valyi Emery I Recipient pour aliments et boissons en plastique moule et procede correspondant
WO1997011894A1 (fr) * 1995-09-28 1997-04-03 Jess Paul Fuller Bouchon de liege pourvu d'un revetement
WO1997030122A1 (fr) * 1996-02-20 1997-08-21 Cellresin Technologies, L.L.C. Bouteilles pour boissons en polymere rigide dotees d'une resistance amelioree a l'elution de permeants
DE29912842U1 (de) * 1999-07-22 1999-09-16 Bleckmann GmbH & Co., 74080 Heilbronn Flaschenkorken

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Derwent World Patents Index; Class A92, AN 1999-529425/45 *
See also references of EP1173312A4 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001066660A3 (fr) * 2000-03-03 2002-03-07 Dow Corning Revetements d'isolement dans lesquels des polyacides sont utilises
US6447845B1 (en) 2000-03-03 2002-09-10 Dow Corning Corporation Barrier coatings using polyacids
US6793972B2 (en) * 2000-09-12 2004-09-21 The Dow Chemical Company Gas permeation resistant synthetic cork closure
WO2004076607A3 (fr) * 2003-02-26 2004-12-02 Charles A Wicht Procedes et articles permettant d'empecher le gout de bouchon dans les boissons
WO2006024767A1 (fr) * 2004-07-30 2006-03-09 Vect'oeur (Sarl) Procede d'elimination de composes polyhalogenes toxiques ou indesirables dans les boissons et notamment dans le vin
DE102006013102A1 (de) * 2006-03-20 2007-09-27 Henkel Kgaa Diffusionsreduzierende Korkbeschichtung
DE102006016054A1 (de) * 2006-04-04 2007-10-11 Henkel Kgaa PU Korkbeschichtung

Also Published As

Publication number Publication date
NZ515545A (en) 2003-09-26
EP1173312A4 (fr) 2002-07-24
ZA200109605B (en) 2003-04-30
EP1173312A1 (fr) 2002-01-23
AUPP989399A0 (en) 1999-05-13

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